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2.
3.
4.
6.
(C) 20 40
(D) 1 10
(B) Covalent
(D) H-bonding
8.
(B) 40 100
7.
Which one of the following characteristics is not correct for physical adsorption?
(A)
(B)
(C)
(D)
5.
(B) 2
(C) 3
(D) 4
9.
10.
The volumes of gases H2, CH4, CO2 and NH3 adsorbed by 1 g of charcoal at 288K are in the order
(A) H2 > CH4 > CO2 > NH3
(C) CO2 > NH3 > H2 > CH4
11.
The slope of the straight line graph between log x/m and log P for the adsorption of a gas on solid is
(A) k
(B) log k
(C) n
(D) 1/n
2
12.
According to Langmuir adsorption isotherm, the amount of gas adsorbed at very high pressure
(A)
(B)
(C)
(D)
13.
Graph between log(x/m) and log P is a straight line at an angle 45 with intercept on y-axis, 0.3010. Calculate
amount of the gas absorbed in gram per gram of the adsorbent when pressure is 0.2 atm.
(A) 0.4
14.
(B)
The decomposition of hydrogen peroxide can be slowed down by addition of a small amount of acetamide.
The latter act as
(B) Promoter
22.
TEL minimizes the knocking effect when mixed with petrol. It acts as
(A) Positive catalyst
(C) Autocatalyst
21.
(D) Poison
20.
(C) Moderator
19.
(D)
(A) Inhibitor
18.
(C)
17.
(D) 0.2
16.
(C) 0.8
(A)
15.
(B) 0.6
(B) Cr2O3
(D) Cu
3
23.
In the Ostwalds process for the manufacture of HNO 3, the catalyst used is
(A) Fe
24.
(B) Pt
Which of the following types of metals make the most efficient catalysts?
(A) Transition metals
(C) Alkaline earth metals
26.
30.
29.
A catalyst
(A)
(B)
(C)
(D)
28.
31.
27.
(D) Mo
25.
(C) V2O5
(B) Irreversible
32.
When freshly precipitated Fe(OH) 3 is boiled with water in the presence of few drops of dil. HCl, a hydrated
ferric oxide sol is obtained. The method is termed as
(A) Electro dispersion
(B) Peptization
(C) Ultra filtration
(D) Dialysis
33.
Greater the valency, the higher is the coagulating power of ion. This rule was introduced by
(A) Hardy-Schulze
34.
(B) Graham
(D) Faraday
35.
An examples of micelle is
36.
37.
38.
(C) Paramagnetism
(D) Flocculation
(C) Oil
(D) NaCl
Micelles are
(A) adsorbent solutes
39.
Substances whose solutions can readily diffuse through animal membranes are called
(A) Colloids
(B) Crystalloids
(C) Electrolytes
(D) Non-electrolytes
40.
41.
(C) Dialysis
(D) Filtration
(C) Dissolved
44.
Peptization is a process of
(A)
(B)
(C)
(D)
42.
45.
46.
On addition of one ml solution of 10% NaCl to 10 ml. gold sol in presence of 0.0025 g of starch, the
coagulation is just prevented. The gold number of starch is
(A) 25
47.
(D) 0.025
(B) Pb4+
(C) Sr2+
(D) Na+
49.
(C) 0.25
48.
(B) 2.5
(B) Electrical
(C) Kinetic
(D) Chemical
A freshly prepared Fe(OH) 3 precipitate is peptized by adding FeCl 3 solution. The charge on the colloidal
particle is due to preferential absorption of
5
(A) Cl ions
50.
(C) OH ions
(D) None
51.
52.
Which of the following is most effective in causing the coagulation of ferric hydroxide sol?
(A) KCl
53.
(B) KNO3
56.
Regarding criteria of catalyst, which one of the following statements is not true?
(A)
(B)
(C)
(D)
59.
58.
In oxidation of oxalic acid by KMnO4, the colour of KMnO4 disappears slowly in the start of reaction but
disappears very fast afterwards. This is an example of
(A) Auto catalysis
(C) Induced catalysis
57.
(D)K3Fe(CN)6
(C) K2SO4
54.
reaction
6
(D) There is no change in the energy of activation
60.
61.
Fe3+ ions coagulate blood. This shows blood contains colloidal particles bearing
(A) Negative charge
(C) No charge
62.
The gold numbers of A, B, C and D are 0.04, 0.002, 10 and 25, respectively. The protective powers of A, B, C
and D are in the order
(A) A > B > C > D
63.
(B) Electrophoresis
(D) Brownian movement
The potential difference between the fixed charged layer and the diffused layer having opposite charge is
called
(A) Colloidal potential
(C) Electrostatic potential
65.
(C) Au
(D) Pt
70.
(B) Cu
Micelles have
(A)
(B)
(C)
(D)
69.
On adding AgNO3 solution into KI solution, a negatively charged colloidal sol is obtained when they are in
(A)
(B)
(C)
(D)
68.
(B) Cataphoresis
67.
66.
The movement of dispersion medium in an electric field when the dispersed particles are prevented from
moving is called
(A) Cataphoresis
(C) Electroosmosis
64.
(B) SO42
(C) PO43
(D) [Fe(CN)6]4
A liquid is found to scatter a beam of light but leaves no residue when passed through the filter paper. The
liquid can be described as
(A) A suspension
(B) Oil
7
71.
72.
73.
74.
Which one of the following method is commonly used for destruction of colloid?
(A) Dialysis
(C) Filtration by animal membrane
75.
76.
77.
Milk is a colloidal
(A) Liquid is dispersed in a liquid
(C) Gas is dispersed in a liquid
(B) Gum
(C) Gelatin
(D) Starch
81.
Which one of the following substances is not used for preparing lyophilic sols?
(A) Metal sulphide
80.
79.
78.
(B) Condensation
(D) By adding electrolyte
MULTIPLE CHOICE QUESTIONS MAY HAVE ONE OR MORE THAN ONE CORRECT OPTION.
82.
8
(B) Physical adsorption involves vander waals forces
(C) Rate of physical adsorption increases with increase of pressure on the adsorbate
(D) High activation energy is involved in physical adsorption
83.
Adsorption is accompanied by
(A) Decrease in entropy of the system
(C) Decrease in free energy of system
84.
85.
86.
87.
88.
89.
(B) B
(C) C
(D) D
Assertion: Addition of AgNO3(aq.) to KI (aq.) gives negative sol whereas addition of KI (aq) to AgNO 3 gives
positive sol of AgI.
Reason: The sol particles adsorb the common ions present in solution and acquire their charge.
(A) A
90.
(B) B
(C) C
(D) D
(B) B
(C) C
(D) D
9
91.
Assertion : The presence of catalyst a increases the speed of the forward and backward reactions to the same
extent.
Reason : Activation energy for both the forward and backward reactions is lowered to the same extent.
(A) a
(B) b
(C) c
(D) d
92.
93.
94.
(D) d
95.
96.
97.
(D) d
Column I
Coagulation
Peptization
Tyndall effect
Dialysis
(P)
(Q)
(R)
(S)
Column II
Scattering of light
Purification of colloidal solution
Addition of electrolyte
Precipitation of colloidal solution
Column II
(Disperesed phase)
(P) Water
(Q) Cellulose
(R) Fat
(S) Water
Column III
(Dispersion medium)
(U) Ethanol
(V) Oil
(W) Air
(X) Water
98.
1 gm of charcoal adsorbs 100 ml 0.5 M CH3COOH to form a monolayer, and thereby the molarity of
CH3COOH reduces to 0.49. Calculate the surface area of the charcoal adsorbed by each molecule of acetic
acid. Surface area of charcoal = 3.01 102 m2/gm.
(IIT 2003, 2 Marks)
99.
100.
101.
decrease in temperature
decrease in pressure
enthalpy is positive
entropy increases
Irreversible sols
10
(c)
102.
(d) Self-stabilizing
20% of surface sites are occupied by N 2 molecules. The density of surface site is 6.023 10 14 cm2 and total
surface area is 1000 cm2. The catalyst is heated to 300 K while N 2 is completely desorbed into a pressure of
0.001 atm and volume of 2.46 cm3. Find the number of active sites occupied by each N2 molecule.