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ConceptsinBiochemistryConceptReviews
Sections14.2,17.1
RedoxReactions
Whatisaredoxreaction?
Theformalnameforaredoxreactionis"oxidationreductionreaction,"andyoucanseethat"redox"isjustshorthand
forthewordsreductionandoxidation.Thus,inaredoxreaction,twothingshappen.Youguesseditoxidationand
reduction.Thesetwohavetohappentogether.Youcannothaveanoxidationreactionwithoutacorresponding
reductionreaction.Itsabitliketheideabehindabloodtransfusionoranorgantransplant.Youcannothavea
recipientunlessyouhaveadonor,anditdoesnotmakeanysensetobeadonorunlessthereisarecipient.
Youmayhavenoticedthat"oxidation"startswiththesameprefixasoxygen,suggestingthatoxygenmaybesomehow
involvedinthisprocess.Indeed,onedefinitionofoxidationstatesthat:
Oxidationisthegainingofbondstooxygen
Organicfuelsubstances(suchaswood,coalorgas)areexamplesofcompoundsthatcanbeoxidized.Intheprocess
ofburning,thecarboninthesesubstancesbecomesbondedwithoxygen,whilesomeoftheoxygenusedto"burn"the
fuelbondstothehydrogenatomsfromthefuel.Thus,oneofthedefinitionsofreductionstatesthat:
Reductionisthegainingofhydrogen
Therefore,combustionreactionsaregoodexamplesofredoxreactionswhereonemoleculegainsoxygen(is
oxidized)andonemoleculegainshydrogen(isreduced).
Forexample,letslookatwhathappenswhengasolineinyourcarisburnedasyoudrivearoundtown(heptaneisa
commonhydrocarboncomponentofgasoline):
C7 H12
heptane
11O2
7CO2
oxygen
carbondioxide
8H2 O
water
Notehowthecarbonatomsinheptaneareoxidized(becausethecarbonatomsinheptanebecomebondedwith
oxygenatoms),whiletheoxygenisreduced(becomesbondedwithhydrogenatoms).
Thesedefinitionsofoxidationandreductionareuseful.However,moregeneraldefinitionsofoxidationandreduction
involvethemovementofelectronsbetweenthecompoundsinvolvedintheredoxreaction.Inthemostbroaddefinition
ofredoxreactions:
Oxidationisthelossofelectrons
Reductionisthegainofelectrons
Becauseelectronsarenegativelycharged,anincreaseinelectronsmeansa
decreaseinoverallcharge(thecompoundbecomesmorenegatively
charged).Ontheotherhand,anatomthatisoxidizedhasgivenupsomeof
thosenegativelychargedelectrons,whichwillincreaseitsoverallcharge(the
compoundbecomesmorepositivelycharged).Noticethatthesedefinitions
donotinvolveoxygenandhydrogen.Thus,redoxreactionscanoccurwith
compoundsthatdonotcontainoxygenorhydrogenatoms.
Aneverydayexampleofaredoxreactionthatweareallfamiliarwithisthe
processofrusting.Rustistheflakybrownsubstancethatformsonironobjectsleftexposedtotheelementsfortoo
long,especiallyiftheobjectsgetwet.Rustdoesntjustformontheironobject,theironactuallyturnsintorust(rustis
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actuallyaformofoxidizediron).
Weallintuitivelyknowthechemicalreactionofrusting:
iron
water
air
Fe
H2 O
O2
rust
Fe2 O3
Letsexaminetheoxidationandreductionreactionsthatareinvolvedintheredoxreactionofrusting.First,iron,inthe
presenceofmoisture(H2 O)willloseelectrons,becomingapositivelychargedioninwater:
Oxidationreaction:Ironisoxidized(losese)
Fe2 +(aq)+2e
Fe(s)
Thoseelectronsarethenusedtoreducetheoxygendissolvedinthewater(rememberthatwaterwillhavesome
dissolvedoxygenandalsoH+andOHions):
Reductionreaction:Oxygenisreduced(gainse)
O2 +4e+4H+
2H2 O
ThoseFe2 +ionsreactwiththeOHionsinwatertoproduceironhydroxide,whichwilldryinseveralstepstoproduce
rust:
Fe2 ++2OH
Fe(OH)2
Fe2 O3 (rust)
Noticethattheredoxreactionneedswater,whichexplainswhyamoistenvironmentspeedsuptherustingprocess.
Rustingcanoccurindryclimates,butittendstohappenmuchmoreslowlyduetotherelativelylowhumidityintheair.
Becauseitisdifficulttorememberthedefinitionsofoxidationandreductionthatinvolvethemovementofelectrons,a
commonmnemonicthatcanhelpyoukeeptheserulesinmindis:
"OILRIG"
O
Oxidation
Is
Lossofelectrons
Reduction
Is
Gainofelectrons
Thisisanespeciallyappropriatemnemonicforrememberingredoxreactionsbecausetheburningofoil(a
hydrocarbonfuel)isaredoxreaction!
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Copyright2002,JohnWiley&SonsPublishers,Inc.
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