Académique Documents
Professionnel Documents
Culture Documents
com
Maximum marks: 70
Instructions:
1. The question paper has four parts: A, B, C and D. All parts are compulsory.
g.
co
2. Write balanced chemical equations and draw labeled diagrams wherever required.
PART-A
10x1=10
ib
lo
ik
.p
ed
ia
ln[R]0
k = - slope
ln[R]
NO2SO
(g) (g). Is this reaction an example for Homogenous or
3
5. 2SO2(g)+O2(g)
Heterogeneous catalysis.
6. Name the depressant used in separation of ZnS from PbS by froth floatation process.
Model paper 3
II PUC CHEMISTRY (34)
Dry Acetone
R-I + NaX. This reaction is known as
5x2=10
g.
co
5x3=15
ib
lo
ik
3
2
1
1
2
.p
ed
ia
3
2
1
2
1
3
1
1
1
PART-D
3x5=15
IV. Answer any FIVE of the following. (Each question carries 3 marks)
30.a) Rate constant of a reaction at 300K & 400K are 0.034S-1& 0.136S-1 respectively.
Calculate the activation energy for the reaction [ Given: R = 8.314JK-1mol-1]
4
1
3
2
3
2
g.
co
dilNaOH
H2O
1
2
2
2
ik
2CH3CHO
ib
lo
.p
ed
ia
1
3
2
2
2
1
2
2
1
m
1
1
1
1
1
1
1
1
ik
PART-B
n-type
1. Doped with pentavalent atoms(P,As,Sb)
2. Holes contributes to conduction
p-type
1. Doped with trivalent atoms(B,Al)
2. Negative charges (electrons) contributes
to conduction
.p
ed
ia
12
1
1
g.
co
Decreases
External pressure to be applied on the solution side just to stop the flow solvent from its
side to solution side across SPM
1M or 1 Molar
First order
Homogenous
Sodium cyanide or NaCN
Radon or Rn
Finkelstein reaction
Due to the formation of hydrogen bond (H-bond) b/w acetic acid molecules & water
Vitamin-D
II
11
Marks
lo
3
4
5
6
7
8
9
10
Value points
PART-A
ib
Q.No
I
1
2
13
t1/2 =
t1/2 =
1
.
(i)The steady decrease in atomic size of the actinides with increase in the atomic number
(ii)+3
1
1
H2SO4
CH3CH2OCH2CH3
413K
CH3CH2OH
15
OR
OR
g.
co
16
When benzamide is heated with dil acid hydrolysis takes place to form benzoic acid
COOH
H3O+
lo
CONH2
ib
OR
18
.p
ed
ia
17
ik
O
ll
CH2 O C C17H35
O
ll
CH O C C17H+353NaOH
3C17H35COONa + CH OH
w
w
OR
PART-C
Impure copper is made as anode & thin sheet of pure copper is made as cathode. Acidified
copper sulphate solution is taken as electrolyte
On passing electric current, pure copper deposits on the cathode
At anode : Cu Cu2+ + 2e
At cathode : Cu2+ + 2e Cu
(i)
1
1
1
CH2 OH
20
CH2 OH
O
ll
CH2 O C C17H35
III
19
OR
OR
2
1
1
1
O
ll
P
OH
Cooling Tower
Absorption
Catalytic
Converter
Pre
Tower
Tower
Arsenic
purifier
Heater
ik
The compounds formed by the trapping of small atoms like H, C, N etc into the crystal lattice
of metals
Characteristics
1. High m.p. than the pure metal
2. Very hard
3. Chemically inert
4. Retain metallic conductivity
(any two)
2CrO42- + 2H+ Cr2O72- + H2O
Cr2O72- + 2OH- 2CrO42- + H2O
1
1
25
g.
co
Precipitator
24
Burner
Drying
23
Washing &
.p
ed
ia
22
Dust
ib
Oleum
Sulphur
lo
Air
E C of Co3+ = 3d6 or
3d
4s
4p
3d
6 pairs of electrons
from 6 NH3
1
1
1
1
g.
co
(ii)Potassium tetrahydroxidozincate(II)
IV
27
26
PART-D
a)
Let a is the edge length of the cube,
lo
a =2 2ar
ib
Each unit cell in hcp has effectively 4 spheres. Total volume of four sphere is equal to 4 X
ik
.p
ed
ia
Packing efficiency =
Packing efficiency =
= 74%
b)1 or One
28
a)
= 0.2atm
b)
1.Obeys Raoults law
2. H of mixing is zero
3. V of mixing is zero
4. Does not forms azeotropic mixtures
5. (A-B) interactions are same as that of (A-A) or (B-B) interactions
1
1
29
a)
=
log
1
.
= 1.05 -
log
( .
ww
w.
pe
dia
wi
kib
log
.co
m
= 0.914V
b) Secondary cell
Example : Lead-storage battery or Nicad storage cell or any other example
(Any one)
30
a) log
.
or Ea =
log
1
1
.
.
Ea =
= 13834Jmol-1 or 13.8KJmol-1
1
1
k=
or t =
t1/2 =
31
a)
HO
C
H
H
l
HO C H + Cl
l
H
Cl
H
ib
OH +
lo
H
l
H C Cl
l
H
PART-D
ik
V
32
g.
co
c) Due to the collision of the dispersed phase particles with molecules of the dispersion
medium.
.p
ed
ia
1
1
a) When acetic acid is heated with ethyl alcohol in the presence of Con H2SO4 as dehydrating
agent, ethyl acetate is formed.
Con HCH
2SO
4
3COOC2H5 + H2O
CH3COOH + C2H5OH
OR
1
OR
34
1
1
b) H-bonding
c) Increases
Since NO2 is electron withdrawing group OR Due to I effect
1
1
a) When toluene treated with CrO2Cl2& CS2, followed by hydrolysis benzaldehyde is formed.
CH3
H
l
C=O
1.CrO2Cl2/CS2
2. H2O
OR
OR
b) A = Aldol or 3-hydroxybutanal
B = Chrotanaldehyde or But-2-enal
1
1
35
g.
co
c) Sodalime
a) When benzene diazonium chloride reacts with Cuprous chloride in HCl, chlorobenzene is
formed
Cl
Cu2Cl2/HCl
+ N2
ik
OR
ib
lo
+
N2Cl
OR
2
1
.p
ed
ia
OR
a) When benzene diazonium chloride reacts with Copper in the presence of HCl,
chlorobenzene is formed
Cl
Cu/HCl
+
N2Cl
+ N2 + HCl
OR
OR
H
OH
OH
OH
OH
OH
H
CH2OH
co
CH2OH
g.
36
OH
lo
ib
37
ik
1
1
1
1
Adipic acid
ia
ed
Cl
l
CH2 C = CH CH2
.p
Cl
l
n CH2 = C CH = CH2
(any one)