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group 16
group 17
group 18
Nitrogen
Chalogens or
Halogen Group
Noble Gas
Identification
group
Oxygen group
Electronic configuration
ns2np3
ns2np4
ns2np5
ns2np6
Ne
3, to +5
2, 1, +1, +2
P, As
S, Se, Te
Cl, Br, I
Xe
3, +3, +5
2, +2, +4, +6
Sb, Bi
+3, +5
Po
+2, +4
Common name/
Group
of valence shell
Oxidation state
18
15
16
17
He
2p
Ne
3p
Cl
Ar
4p
As
Se
Br
Kr
5p
Sb
Te
Xe
6p
Bi
Po
At
Rn
Polonium element of group 16 is radioactive. Oxygen forms metal oxides with metals. Ozone is a strong
oxidising agent. Sulphur element possessess different allotropes. Out of these and allotropes are very
important. Sulphur element combines with oxygen and forms oxide compounds like SO2 and SO3. Out
of the different oxoacids of sulphur, sulphuric acid is very important. It is called 'King of Chemicals.'
Astatine element of group 17 is radioactaive. As these elements require one electron to have stable
electronic configuration, they are very reactive. As a result of this, the elements of this group are not
available in free state, but are availalbe in the combined state as negative ions. The elements of this
group form oxides, hydrogen halides, interhalogen compounds and oxoacid compounds.
Radon element of group 18 is radioactive. As the octet structure is complete in all the elements of this
group they are chemically inert. Xenon element of this group, under specific reaction conditions combine
with fluorine and oxygen elements and form fluoride and oxide compounds.
(2)
(a) 60 , 120
(b) 95 ,120
(c) 95 ,150
(d) 120 ,180
(3) The stability of +1 oxidation state increases in the sequence
(a) Al<Ga<In<Tl
(b) Tl<In<Ga<Al
(c) In<Tl<Ga<Al
(d)Ga<In<Al<Tl
(4) Which of the following is most acidic
(a) Na2O
(b) Mgo
(c) Al2O3
(d) Cao
(5) Cohen Orthoboric acid (H3BO3) is strongly heated, the residue is
(a) Meta boric acid
(b) Boron
(c) Al2O3, 2H2O
(d) None of above
(6)
Bauxite has the composition
(a) Al2O3
(b) Al2O3, H2O
(c) Al2O3 2H2O
(d) None of above
(7) Which one of the following is correct statement
(a) The hydroxide of aluminium is more acidic than that of boron
(b) The hydroxide of boron is basic, while that of aluminium is amphoteric
(c) The hydroxide of boron is acidic, while that of aluminium is amphoteric
(d) The hydroxide of boron & aluminium are amphoteric
(8) AlCl3 is
(a) Anhydrous & covalent
(b) Anhydrous & ionic
(c) covalent & basic
(d) coordinate & acidic
(9) Aluminium (III) chloride forms a dimer because
(a) Higher coordination number can be achieved by aluminium
(b) Aluminium has high ionization energy
(c) Aluminium belongs to III group
(d) It cannot form a trimer
(10) Aluminium has a great affinity for oxygen & its oxidation is an exothermic process. This fact
is used in
(a) Preparing thin foils of aluminium
(b) Making utensils
(c) Preparing duralumin alloy
(d) Thermite welding
(11) Which of the following is an amphoteric oxide.
(a) MgO
(b) Al2O3
(c) Cl2O7
(d) Ti2O2
(12) When Al is added to KOH solution
(a) No action takes place
(b) Oxygen is evolved
(c) Water is produced
(14) Aluminium vessels should not be washed with materials containing washing soda since
(a) Washing soda is expensive
(b) Washing soda is easily decomposed
(c) Washing soda reacts with aluminium to form soluble aluminate
(d) Washing soda reats with aluminium to form insoluble aluminium oxide
(15) Which of the statements about anhydrous aluminium chloride is corret
(a) It exists as AlCl3 molecule
(b) 6
(c) 5
(d) 8
(c) Zn
(d) Ca
(b) Al
(18) Aluminium chloride exists as dimer, Al2Cl6 in solid state as well as in solution of non-polar solvents
such as benzene when dissolved in water gives
(d) Al2O3+6HCl
(b) Graphite
(c) Titanium
(d) SiC
(b) B3N3H6
(c) B3O3H6
(d) (BH3)3
(21) Anhydrous AlCl3 cannot be obtained from which of the following reactions
(a) Heating AlCl3 6H2O
(b) By Passing dry HCl over hot aluminium powder
(c) By Passing dry Cl2 over hot aluminium powder
(d) By passing dry Cl2 over a hot mixture of alumina and coke
(22) Diborane combines with ammonia at 120 C to give
(a) B2H6 NH3
(b) B2H6. 2NH3 (c) B2H6.3NH3
(23) Which metal burn in air at high temperature with the evolution of much heat.
(a) Cu
(b) Hg
(c) Pb
(d) Al
(24) Aluminium hydroxide is soluble in excess of sodium hydroxide forming the ion
(a) AlO 23
(c) AlO 2
(b) AlO23
5
(d) AlO3
(b) Mg(OH)2
(c) B(OH)3
(d) Al(OH)3
(b) BCl3
(c) BBr3
(d) BH3
(b) Basic
(c) Amphoteric
(32) Which is true for an element & present in III group of the periodic table
(33)
(b) acidic
(c) basic
(d) none
(b) Ag
(c) Au
(d) Fe
(36) B(OH)3 + NaOH NaBO2+Na[B(OH)4] +H2O How can this reaction is made to proceed
in forward direction.
(a) Addition of cis Benzene - 1,2-diol
(b) B3H6
(c)B4H10
(c) Na3AlF6
(b) BCl2
(c) B2Cl2
(d) CCl2
(c) B2O3
(d) As2O3
(b) Sb2O3
(b) Al2Cl6
(c) Al2O3
(d) Al(OH)Cl2
(b) C2H6
(c) PH3
(d) SiH4
(b) C2 H6
(c) Na3AlF6
(d) SiH4
(b) In
(c) Th
(59) Which one of the following statements about diborane is not true
(a) The B atoms in it are SP3 hybridised
(b) It contains two 3-centre-2-electron bonds
(c) All B-H bond lengths in it are equal due to resonance
(d) The molecule contains 12 valence electrons
8
(d) B
(d) None
(a) AlF3-6
(c) BF62
(d) SiF62
(c) Diborane
(d) Methanol
(64) The tendency of BF3 , BCl3 & BBr3 to behave as lewis acid decreases in the sequence
(a) BF3 > BCl3 >BBr3
(65) Which one of the following molecular hydrides acts a a lewis acid
(a) CH4
(b) NH3
(c) H2O
(d) B2H6
ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
d
b
a
c
a
c
c
a
a
d
b
d
b
c
c
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
b
a
b
c
b
a
b
d
c
c
c
d
c
d
c
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
c
c
c
d
a
a
d
b
c
c
d
c
b
a
a
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
d
a
c
d
a
a
c
c
a
a
c
a
d
c
a
61
62
63
64
65
c
b
c
c
d
122
97
H
(3)
H
0
B
H
(20) AlCl3-6H2O
Al(OH)3 + 3HCl + 3H2O
(26)
(27)
(28)
(31)
(32)
(36)
(39)
(40)
(49)
(55)
B
H
3C - 2e : BHB
2C 2e : HBH
(57) 2Al(s) + 2NaOH(aq) + 6H2O(l) 2Na+ [Al(OH)4]-(aq) + 3H2(g)
sodium tetra hydroxo aluminate (III)
10
(B) CrO5
(C) H2SO5
(D) PbO2
(2) Soldiers of Napolean army while at Alps during freezing winter suffered a serious problem as
regards To the tin buttons of their uniforms. white metallic tin buttons got converted to grey
powder. This Transformation is related to
(A) A change in the partial pressure of oxygen in the air
(B) A change in the crystalline structure of tin
(C) An interaction with nitrogen of air at very low to temperatures
(D) An interaction with water vapour contained in the humid air.
(3)
(4)
(5)
(C)H2SiO3
(D) Na3AlF6
(8)
(7)
(D) None
The Stability of dihalides of Si, Ge, Sn and Pb increases steadily in the sequence
(A) Gex2 SiX2 SnX2 PbX2
(C) SiX2 GeX2 SnX2 PbX2
(6)
(C) Pyrex
(B) H2SiF6
(9)
(D) None
(B) PbO2
(C) Pb3O4
(D) BaO2
(D) Coconut
(B) Charcoal
(16) Carborundum is
(A) SiC
(B) AlCl3
(C)Al2(SO4)3
(C) PbO2
(D) PbHSO4
(B) PbSO4
(B) Si(OH)2F2
(C) H2SiF6
(D)Si(OH)4
(C) Chlorophyll
(D) Haemoglobin
(C) 3
(D) 4
(B) Amalgams
(B) 2
(23) Which of the following glass is used in making wind screen of automobiles.
(A) Crook's Glass
(C) ZnCO3
(D) Al2(CO3)3
(B) CaCO3
(25) In which of the following the inert pair effect is most prominent
(A) C
(B) Si
(C) Ge
12
(D) pb
(B) Acids
(D) CuSO4
(27) Which of the following glass is used to make lenses and prisms
(A) Flint
(B) Jena
(C) Pyrex
(D) Quartz
(B) PbO
(C) PbO2
(D) Pb4O3
(31) Name of the structure of silicates in which three oxygen atoms of [SiO4]4 are shared is
(A) pyrosilicate
(B) Lead
(C) Tin
(D) Nickel
(B) Pb+Zn
(C) Pb+Sn
(D) Sn+Zn
(34) Which of the following statement is correct with respect ot the property of elements in the
carbon Family with an increase in atomic number their.
(A) Atomic size decreases
(B) Graphite
(C) FeS
(D) Pb
(B) Mg2C3
(C)B4C
(D) La4C3
(B) TiC
(C)SiC
(D) CaC2
(B) NH+4
(C) SCl4
(D) SO42
(B) PbO2
(C) Pb3O4
13
(D)PbSO4
(D) None
(B) Pb(NO2)2, O2
(C) Pb2O3
(D) Pb3O4
(C) 80
(D) 70
(C)N2O5
(d) NO2
(B) PbO2
(B) 20
(B) NH4NO3
(B) PbO2
(C) Pb3O4
(D) Pb(CH3COO)2
(C) B
(D) Pb
(C) Mixed
(D) Amphoteric
(B) Ca
(B) Super
(B) Lead
(C) Tin
(D) Copper
(C) Ge
(D) C
(C) C2H6
(D) CO2
(C) HI
(D) HBr
(B) Sn
(B) C2H2
(B) HF
14
(D) None
(56) SiCl4 on hydrolysis forms 'X' & HCl Compound 'X' loses water at 1000oC & gives 'Y'. Compound
'X' & 'Y' are respectively.
(A) H2SiCl6, SiO2
(B) H2SiO4, Si
(C) SiO2, Si
(B) PbNO3 + NO
(B) Si
(C) Ge
(D) Sn
(B) Acidic
(C) Neutral
(D) Amphoteric
(60) PbO2 is
(A) Basic
(D) R3Si4O4
(B) TiCl4
(C) SiCl4
(D) CCl4
(B) Insulator
(B) CO + O2
(C) CO2+ O2
(D) C + H2 + N2
(65) The element evolving two different gases on reaction with conc. H2SO4 is ______.
(A) P
(B) C
(C) Hg
(D) S
(B) CO
(C) CO2
(D) CaCo3
(D) Water
(C)+3, +4
(D) +4
(B) Conc.H2SO4
(B) +1, +2
15
Answer Key
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
D
B
B
B
C
C
B
A
A
C
B
A
C
B
C
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
A
B
C
D
A
B
B
c
D
D
C
A
C
C
A
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
D
B
C
D
C
B
B
D
C
C
D
C
C
D
A
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
A
A
A
D
C
C
C
A
B
A
D
A
D
C
D
16
61
62
63
64
65
66
67
68
69
A
D
C
C
B
A
C
A
D
Grey tin is very brittle & easily crumbles down to a powder in very cold climates
Grey Tin
White Tin
(Cubic)
(Tetragonal)
The change of white tin to grey is accompanied by increase in volume. This is called disease
or tin Plague.
(3)
Zeolite have SiO4 & AlO4 tetrahadrones linked together in a three dimensional open structure
in which four or six member ring predominate. Due to open chain structure they have cavities
& can take up water & other small molecules.
(4)
Crook's glass is a special type of glass containain cerium oxide. It does not allow the passage
of ultraviolate rays & is used for making lense.
(5)
Due to inert pair effect, stability of +2 oxidation state increases as we move down this
groupSiX2 GeX2 SnX2 pbX2
(6)
Sodium oxalate react with conc. H2SO4 to form CO & CO2 gas
(10) tin is oxidized to meta stannic acid when it is treated with nitricacid
Sn + 4 HNO3 H2SnO3 + 4NO2 + H2O
(11) Inert pair effect become significant for 6th & 7th period of p- block element.
(12) Carbon Suboxide has linear structure with C - C bond lenth equal to 130 Ao & C - O
bond length equal to 120Ao O = C = C = C = O O C C C O+
(13) Pb3O4 is mixed oxide. It can be represented as 2PbO PbO2
(14) Noble gas are found in very minute amount in atmosphers. These are separated from each other
by using coconut char coal. Which absorb different gas at different tempera tures.
(15) SolidCO2 is known as dry ice because it evaporate at -18oC without changing in Liquid state.
(17) When hydrogen peroxide reacts with PbS then they forms PbSO4
(18) Silicon occurs in combined state in nature as silica, SiO2
1s2
2s2
(21)
No of unpaired e- in p = 2.
(22) Metal oxides or some salts are fused with glass to imparted colour of glass.
(24) Al2(CO3)3 is less soluble in water than Na2CO3, ZnCO3
(25) inert pair effect is most prominent in Pb because from top to bottom due to increase in number
of shells.
17
(47)
O
O
O Si O Si O
O
O
18
Pb + 4HNO3
Pb (NO3)2 + 2NO2 +2H2O
SiO2 + 3C
SiC + 2CO2
1
O Pb (CH3 COO)2 + H2O.
2 2
19
Which of the following elements does not form stable diatomic molecules
(A) Iodine
(2)
(B) Phosphorous
(B) N2O
(B) NO
(C) N2O5
(B) NCl3
(C) Cu
(D) Ag
(C)NBr3
(D) NI3
(C)HPO3
(D) H3PO4
(C) As
(D) Bi
(9)
(d) NO2
(A) H3PO3
(8)
(C) HNO3
(B) Zn
(A) NF3
(7)
Which of the following metal produces nitrous oxide with dil HNO3
(A) Fe
(6)
(5)
(4)
(D) Oxygen
(3)
(C)Nitrogen
(B) P
(B) KNO3
(C) NaNO2
(D) NaNO3
(D) H2 is evolved
(B) HNO3
(C) NH3
(D) PH3
(D) It is paramagnetic
(A) PCl5
(C) PCl6-
(B) H6P4O13
(C) H5P5O15
(D) H7P5O16
(19) Which catalyst is used in the haber process for the manufacture of NH3
(A) Pt
(B) Fe+Mo
(C) CuO
(D) Al2O3
(B) PH3
(C) SbH3
(D) ASH3
(C) Pb(OH)Cl
(D) Na2HPO4
(B) BiOCl
(22) Which of the following is manufactured from the molecular nitrogen by bacteria
(A) NO3
(B) NO2
(D) Ammonia
(23) Which of the following Tendencies remains unchanged on going down in the nitrogen family
(A) Highest Oxi. State
(24) (NH4)2 Cr2O7 on heating liberates a gas. The same gas will be obtained by
(A) heating NH4NO2
(25) When plants and animals decay, the organic N is converted in to inorganic N. The inorganic
N is in the form is
(A) NH3
(B) Elements of N
(C) Nitrates
21
(D) Nitrides
(B) Mg3(PO4)2
(C) H3PO4
(D) P2O5
(C) CO and H2
(C) N, H, O3
(B) PH3
(C) ASH3
(D) SbH3
(30) The element which catches fire in air at 30oC and is stored under water is
(A) Calcium
(B) Sodium
(C) Phosphorous
(D) Zinc
(C) H3PO4
(D) None
(C) H3PO2
(D) NF3
(B) PF3
(C) SbCl3
(D) NF3
(B) PH3
(C) AsH3
(D) SbH3
(B) H4P2O7
(B) H3PO4
(35) The cyaide ion, CN, N2 are iso electronic. But in contrast to CN, N2 is chemically inert because
of
(A) Low bond energy
(37) A mixture of ammonia and air at about 800oC in the presence of Pt gauze forms
(A) N2O
(B) NO
(C) NH2OH
(D) N2O3
(C) Al2O3
(D) Sb2O3
(B) SeO2
(B) Brine
(C) Water
22
(D) Mercury
(B) NH4OH
(C) NH4Cl
(B) Chlorobenzene
(D) Dichlorobenzene
(B) White
(C) Black
(C) AsH3
(D) BiH3
(B) CO2
(C) Cl2
(D) CCl3NO2
(B) NH3
(C) P4O6
(D) P4O10
(B) NaH2PO2
(C) Na3HP2O6
(D) Na4P2O7
(B) PH3
(B) 4
(C) 5
(D) 7
(B) Arsine
(C) Phosphine
(D) Ammonia
(C) AsH3
(D) SbH3
(B) PH3
(B) PH3
(C) AsH3
(D) SbH3
(C) NO 2 and OH
(D) -3,+3,+4
(C) Sb
(D) Bi
(B) Tin
23
(B) 2
(C) 3
(D) 4
(B) Ammonia
(D) Urea
(B) H2
(C)NO2
(D) NH3
(B) PH3
(C) SbH3
(D) AsH3
(59) Aquaregia is
(A) 1:3 conc. HNO3 and conc. HCl
(B) SbH3
(C) NH3
(D) PH3
(C) AsH3
(D) SbH3
(C) AsH3
(D) SbH3
(B) PCl3
(C) AsCl3
(D) All
(B) P2O3
(C) Sb2O3
(D) Bi2O3
(B) As2O3
(C) SbCl2
(D) As2H3
(C) N2O + Ca
(D) (NH4)2Cr2O7
(C) NH4NO2
(D) Ba(NO3)2
(C) NaNO2
(D) NaNO3
(B) PH3
(B) PH3
(B) Ca3N2
(B) KNO3
24
(B) N2O3
(C) N2O4
(D) N2O
(C)N2H2
(D) N3H
(B) N2H4
(B) (NH4)2SO4
(B) H4P2O7
(C) HPO3
(D) H3PO4
(C) PH3
(D) SbH3
(C) SbCl3
(D)
(B) NH3
(B) PF3
NF3
(B) Bi(OH)3
(C) BiOCl
(D) BiOCl2
(D) Hg(OH)2
(B) IV A Group
(B) Phosphorus
(C) Arsenic
(D) Antimony
(78) Which of the following elements of group VA does not show allotropy
(A) N
(B) Bi
(C) P
(D) As
ANSWER KEY
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
B
C
A
D
B
A
A
A
D
A
D
A
B
C
A
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
D
C
C
B
A
D
A
A
A
A
A
A
B
A
C
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
A
D
D
A
D
D
B
A
D
D
C
A
D
D
A
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
D
B
D
D
A
B
A
A
B
C
D
D
D
A
B
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
A
B
A
B
C
B
C
A
D
D
D
A
B
D
C
25
76
77
78
A
A
B
(6)
NF3
It is least basic bacause of high electronegativity of 3F atoms. The lone pair present on
nitrogen atom is not easily available for donation.
(7)
(8)
(9)
COOH
|
(11) C12 H22O11
HNO 3
COOH
+ H2O
(24) (NH4)2Cr2O7
N2 + Cr2O3+4H2O
NH4NO2
N2+2H2O
(28) NH4NO3
2H2O + N2O
(30) because of its very low ignition temp (303K) it is always kept under water.
(32) 3H2O + PCl3 H3PO3 + 3HCl
(33) Due to absence of d - orbital in N - atom, it can't accept e from H2O for hydrolysis of NF3
Pt
4NO + 6H O
(37) 4NH3 + 5O2
2
800 C
NH3
BP 238.5
PH3
185.5
AsH3
SbH3
210.6
254.6
(2)
(B) O2
(B) S2
(B) HCl
(9)
(D) Plymorphic
(C) Trizone
(D) Ozone
(C) H2SO4
(D) HNO2
(C) CaCl2
(D) P4O10
(8)
(C) Radioactive
(B) Matalloids
(B) Polyzone
(A) HNO3
(6)
(D) S8
(5)
(C)S4
(4)
(D) CO2
(3)
(C) SO2
(B) Cr2O3
(C) V2O3
(D) MnO2
Which of the following is the best scientific method to test presence of water in a liquid
(A)Taste
(B) Smell
(B) CdSO4
(C) PbSO4
(D) Bi2(SO4)3
(10) When sulphur is boiled with Na2SO3 solution, the compound formed is
(A) Sodium Sulphide
(B) 6
(C) 8
(D) 1
(D) H2SO4 + S
(C) KO2
(D) BaO2
(15) Which of the element of the oxygen family is most poisonous to human race
(A) O
(B) S
(C) Se
27
(D) None
(D) None
+
(B) H2S
(C)H2Te
(D) H2Se
(19) Among H2O, H2S, H2Se and H2Te the one with highest boiling point
(A) H2O
(B) H2Te
(C) H2S
(D)H2Se
(B) O2 + CO
(C) O2 + H2
(21) Carbogen is
(A) Pureform of C
(B) COCl2
(22) The products of the chemical reaction between Na2S2O3, Cl2 and H2O are
(A) S+ HCl + Na2S
(25) Aqueous solutions of H2S and SO2 when mixed together yield
(A) Sulphur and water
(B) CO2
(C)CaO
(D) ZnO
(C)Water
(B) K2Cr2O7
(C)KMnO4
(D) All
(C) Sulphite
(D) Sulphid
(B) Sulphurate
(31) The final acid obtained during the manufacture of H2SO4 by contact process
(A) H2SO4(conc.)
(B) H2SO4(dil)
(C) H2SO4
(D) H2S2O7
(B) MnO2
(C) Al2O3
(D) CrO3
(C) Hydrolysis
(B) Oxidisation(oxide)
(37) When conc.H2SO4 comes in contact with sugar it becomes black due to
(A) Hydrolysis
(B) Hydration
(C) Decolourisation
(D) Dehydration
(C) H2S2O7
(D) H2S2O8
(B) H2SO4
(B) H2S
(C) S2O
(D) SO3
(D) None
(C) S2 O32
(D) S2 O 72
(C) Ur
(D) Ag
(42) Oleum is
(A) Castor oil
(B) S2 O52
(B) S
29
(B) Ba(OH)2
(C) KOH
30
(D) Zn
(D) PH3
(D) H2S2O7
(D) KI
(D) 0oC
(D) H2S2O3
(D) None
(D) H2O
(D) N2O
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
C
D
D
D
C
A
C
D
C
D
A
A
A
C
C
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
A
C
C
A
A
D
B
C
C
A
A
B
D
A
C
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
D
A
A
A
B
A
D
B
D
C
D
C
D
B
B
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
B
B
B
A
D
A
C
A
C
A
B
D
C
C
A
61
62
63
64
65
66
67
68
69
70
71
31
C
B
B
B
A
C
C
D
B
B
B
O
O
||
||
(43) S2O 72- O S O S O
||
||
O
O
(54) Sulphur -
(1) monoclinic
(2) Rhombic
(3) Plastic
O
F
97
1.48A
F
O
F
32
(2)
(3)
(4)
(B) Phosphine
(B) Chloroform
(B) KClO4
(C) KClO2
(D) KIO3
(7)
(B) Na2S2O3
(D) Cryolite
(C) Ratherlford
(D) Sheele
(9)
(D) Na2SO4
(A) Caliche
(8)
(C) Na2S
(B) Priestley
(B) I2
(D) SO2
(10) Chlorine reacts under various conditions with sodium hydroxide to give
(A) Sodium Chloride
(B) Red
(C) Colourless
(D) Yellow
(C) HBr
(D) HI
(D) Chlorine
(B) HCl
(B) I
(C) Br
(D) Cl
(C) I2
(D) F2
(B) Br2
(B) Cl
(C) Br
(D) I
(B) S2P6
(C) S2P4
(D) S2P5
(B) K2Cr2O7
(C) HNO3
(D) HCl
(22) Aqueous solution of which of following acid can not be kept in bottle of glass
(A) HF
(B) HCl
(C) HBr
(D) HI
(B) Cl
(C) Br
(D) I
(C) HBr
(D) HI
(B) HCl
(26) Fluorine is stronger oxidizing agent than chlorine in aqueous solution. This is attributed to
many factors except.
(A) Heat of dissociation
(B) e-affinity
(27) Mark the element that displaces 3 halogens from their compound
(A) F
(B) Cl
(C) Br
(D) I
(B) Cl
(C) Br
(D) I
(29) Which of following arrangement for 3 halogens Cl, Br, I when placed in order of
increasing e-affinity
(A) Cl, Br, I
(B) I, Br, Cl
(C) Br, Cl , I
34
(D) I , Cl , Br
(B) Br
(C) Cl
(D) F
(C) O3
(D) N2X
(B) CH4
(34) Inisolation of F., a number of difficulties were encounted. Which statement is correct?
(A) Potential required for discharge of F. ions is the lowest.
(B) F. reacts with most glass vessel
(C) F has great affinity for H.
(D) Electrolysis of aqueous HF gives ozonised O2
(35) Chlorin gas is dried over
(A) CaO
(B) NaOH
(C) KOH
(C) Cleansing
(B) Sterilisation
(D) HI & KI
(C) I2O5
(D) I4O9
(D) H - bonding
(B) KI & I2
(B) BrO2
(B) KMnO4
(C) K2Cr2O7
(D) None
(C) HBr
(D) HI
(B) HCl
(47) The halide NaF has high melting point than NaCl , NaBr, & NaI because
(A) Minimum ionic character
(B) Br
(C) Al
(D) Ca
(B) Sn
(C) S
(D) F2
(51) Which one of following in aqueous solution gives a white precipitate with per chloric acid
(A) NaCl
(B) KCl
(C) MgCl2
(D) FeCl3
(52) NOCl is used as a bleaching agent & storilisng agent It can be synthesized by action of
(A) NaCl with H2O
(53) A one litre flask is full of brown bromine vapour intensity of brown colour of vapour will not
decrease a appriciable on adding to flask some of
(A) Pieces of marble
(B) Crystallization
(C) Sublimation
36
(B) Actinides
(57) The compound added to table salt for maintaining proper health is
(A) KCl
(B) KBr
(C) NaI
(D) MgBr2
(B) Cl2
(C) Br2
(D) I2
(B) BCl3
(C)MgCl2
(D) NaCl
(62) Concentrated H2SO4 can not be used to prepare HBr from NaBr because it
(A) reduces HBr
(63) When Fluoride is heated with conc. H2SO4 & MnO2 the gas evolved is
(A) F2
(B) SF
(C) HF
(D) None
(64) Unlike other halogens Fluorine does not show higher oxidation states because
(A) It is highly electionegative
(B) OF2
(C) SF4
(D) O2F2
(C) FeSO4
(D) NH4SO4
(B) CaSO4
(67) Among Cl, Br, I correct order for being oxidized to dihalogen is
(A) I Cl Br
(B) CI Br I
(C) I Br CI
(D) Br I CI
(B) SO 24
(C) S4 O 62
(D) S2 O 62
(C) HBr
(D) HI
(B) HCl
(71) When Cl2 is passed through hot & Conc. Solution of KOH following compound is formed.
(A) KCl
(B) KClO3
(C) KClO2
(D) KClO4
(B) HBr
(C) HClO3
(D) HCl
(C) KI2
(B) KI2
(D) KI3
(79) When Cl is passed over dry slaked lime at room temperature, main reaction product is,
(A) Ca(ClO2)2
(B) CaCl2
(C) CaOCl2
(D) Ca(OCl2)2
(C) HBr
(D) H2S
(B) NaClO2
(C) NaClO3
38
(D) None
(B) ClO2
(C) Cl2O6
(D) Cl2O7
(C) I2
(D) Cl2
(B) F2
(85) Electrolysis of a liquid resulted in formation of Hydrogen at cathode & Cl2 at anode.
Liquid is
(A) Pure water
(B) HOI
(C) HOIO2
(D) HOIO3
(87) Manufacture of Bromine from sea water, the mother liquor containing bromides is treated
with
(A) CO2
(B) Cl2
(C) I2
(D) SO2
(88) Formula of some fluorides are given. Which of them will combine with fluorine?
(A) IF5
(B) NaF
(C) CaF2
(D) SF5
(C) Br
(D) I
(B) F
(90) A solution of HCl in water is good conductor while gaseous Hydrogen chloride is not .
This is because
(A) Water is good conductor of electricity
(C) Gas can not conduct electricity but water can (D) None of these
(91) Bleaching action of bleaching powder is due to liberation of
(A) Chlorine
(92) What products are expected from disproportion reaction of hypochlorous acid.
(A) HClO3 & Cl2O
(93) Mixture of conc. HCl & HNO3 made in 3:1 ratio contains
(A) ClO2
(B) NOCl
(C) NCl3
(D) N2O4
(C) Br
(D) F
(C) Hydrolysis
(C) P
(D) S.
(B) I
(B) Reduction
(B) C
39
(B) Na
(C) F
(D) I.
(C) Cl
(D) All
(A) Cl
(100) Which of following sequence is correct with refrence to oxidation number of iodine
(A) I2 < ICl < HI < HIO4
(C) Hg(CN) Cl
(D) Hg [Hg(CN)2Cl2]
(B) KBr
(C) CaCl2
(D) AgF
(B) SO2
(C) ClO2
(D) SiO2
(C) CCl4
(D) Alcohol
(B) CCl4
(C) C2H5Cl
(D) C2H6
(B) CaO
(C) CaO(Cl).
(D) CaCl(OCl)
(B) CaCO3
(C) CaSO4
(D) Ca(OH)2
(109) Which is formed when F reacts with hot & conc. Sodium Hydroxide.
(A) O2
(B) O3
(C) NaO
(D) HF.
(B) Cl2
(C) CrOCl2
(D) CrO2Cl2
(112) Amongst LiCl , RbCl , BeCl2 & MgCl2 , max. & min. ionic character will be shown by
(A) LiCl , MgCl2.
BeCl2
(D) MgCl2,
(B) AgCl
(D) None
(115) Which of following is present as an active ingredient in bleaching powder for bleaching action
(A) CaCl2
(B) CaOCl2
(C) Ca(OCl)2
(D) CaO2Cl
(C) Cl2O6
(D) ClO4
(C) HBr
(D) HI
(B) Cl2O
(B) HCl
(118) When KBr is treated with concentrated H2SO4 redish brown gas evolved, gas is
(A) Mixture of Br & HBr
(C) Bromine
Answer Key
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
B
A
D
A
C
B
B
A
A
D
A
A
D
C
A
B
D
D
D
A
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
D
A
D
A
B
B
A
A
B
C
C
A
D
A
D
A
D
B
B
D
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
B
C
D
A
B
D
B
A
D
C
B
C
A
C
B
A
C
D
D
D
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
B
B
C
B
A
B
C
A
C
A
B
A
A
D
B
A
A
D
C
A
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
A
A
D
B
C
C
B
A
B
B
C
D
B
A
B
A
A
C
A
D
41
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
B
D
A
C
B
B
D
D
A
B
D
B
B
C
C
C
A
C
(2)
(3)
Iodine has the least affinity for water and is only slightly soluble in it . However it is dissolved
I2 + I
I3 (Complex)
(4)
2KClO3 + I2 2KIO3
(5)
(6)
The acidic strength of oxy acids decreases down wards in a group. The correct order of acidic
C strength of oxy - acids of Halogens is HClO4 > HBrO4 > HIO4
(7)
Carnellite is KCl. Mg Cl2.6H2O. The mother liquor remain after crystallisation of KCl from carnellite
contains about 0.25% of Bromine as MgBr2 or KBr.
(9)
+ Cl2
A more electronegative halogen can displace less acid because of lowest bond dissociation Energy.
Cold
(10) 2NaOH(dil) + Cl2
NaCl + NaClO + H2O. Sod. Hypochlorite.
heat
6NaOH(conc) + 3Cl2
5NaCl + NaClO3 + 3H2O Sodium chlorate.
(12) HF is weakest acid. Since it is on able to give H + ions which are trapped in H - Bonding.
(69) 2Na2S2O3 + I2 2NaI + Na2S4O6
(70) HF is liq. Because of int . molec. H - Bond
(71) 6KOH + 3Cl2 5KCl + KClO3 + 3H2O
(72) Cl2 + 2NaBr 2NaCl + Br2
(73) HClO H+ + ClO(74) Br2 + 2KI I2 + 2KBr
(75) 2NaCl + 2H2O 2 NaOH(aq) + Cl2(g) + H2(g)
(76) I2 + 10HNO3 2HIO3 + 10NO2 + 4H2O
(77) MnO 2 + 4HCl MnCl2 + 2H 2 O + Cl2
(4 )
(2 )
42
H2O
(90) HCl
H (ag ) Cl
43
Cl
(107) CaCl(OCl)
Ca
O
Cl
44
(2)
(4)
(D) Haematite
(D) Is diatomic
(D) Ramsay
(C) Helium
(D) Xenon
(C) Methane
(D) Xenon
(7)
(C) Rectile
(A) Monoatomic
(A) Argon.
(6)
Molecules of noble gas do not posses vibrational energy bec. Noble gas is
(A) Rayleigh
(5)
(3)
(B) Argon
(8)
Monazite is source of
(A) He
(9)
(B) Kr
(C) Ar
(D) Ne.
(B) Beryllium
(C) Aluminium .
45
(D) Krypton.
(16) Which of following noble gas does not have octate of e - in outer most shell.
(A) Ne
(B) Rn
(C) Ar
(D) He
(B) 2%
(C) 3%
(D) 4%
(B) Ne
(C) Ar
(D) Xe.
(A) XeO6
(B) H XeO 4
(C)
XeO 4
(D) Xe.
(B) He
(C) Ar.
(D) Rn
(C) N2.
(D) Argon.
(B) O2
(B) He
(C) Ar
(D) Kr
(C) Kr & Ne
(D) Ar & Xe
(B) Ar & Ne
(B) Rutherford
(D) Dorn
(B) Reducing
(C) Un reactive
(C) Xe
(D) Ne
(B) He
46
(B) Duterium .
(C) He
(D) Krypton
(C) SF4
(D) CF4
(C) 18
(D) 8
(D) 1S2
(B) Ar
(C) Ne
(D) He
(B) XeO
(C) XeO2
(D) Xe
(B) HeF4
(B) 2
Answer Key
1
2
3
4
5
6
7
8
9
10
B
B
A
D
C
B
A
A
A
B
11
12
13
14
15
16
17
18
19
20
B
D
A
C
A
A
B
A
D
A
21
22
23
24
25
26
27
28
29
30
D
D
B
D
C
A
C
C
B
D
31
32
33
B
D
A
Hints
(26) all the xenon fluorides are strongly oxidizing
(27) XeF2, XeOF2, XeF4, XeOF4, XeF6, XeO3
2
(28) 1H 1H 2He