Material Safety Data Sheet

MANAJEMEN LAB
Material Safety Data Sheet

(MSDS)
AYA SOFIA
4311413083
KIMIA/002
UNIVERSITAS NEGERI SEMARANG

2014

Dithizone MSDS
Product Name: Dithizone
Synonym: Diphenylthiocarbazone
Chemical Formula: C13H12N4S
Hazards Identification
Hazardous in case of eye contact (irritant), of ingestion. Slightly hazardous in case of skin contact (irritant), of
inhalation.
CARCINOGENIC EFFECTS
: Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS
: Not available.
DEVELOPMENTAL TOXICITY : The substance is toxic to kidneys, mucous membranes. Repeated or prolonged
exposure to the substance can produce target organs damage.
First Aid Measures

Eye Contact
Skin Contact
Inhalation
Ingestion
: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.
: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the
contaminated skin with running water and non-abrasive soap. Cover the irritated skin with an
emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.
: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
: Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the
victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Fire and Explosion Data

Flammability of the Product
: May be combustible at high temperature.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product
in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE : Use DRY chemical powder.
LARGE FIRE : Use water spray, fog or foam. Do not use water jet.
Accidental Release Measures

Small Spill
Large Spill
: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish
cleaning by spreading water on the contaminated surface and dispose of according to local and
regional authority requirements.
: Use a shovel to put the material into a convenient waste disposal container. Finish
cleaning by spreading water on the contaminated surface and allow to evacuate through the
sanitary system.
Handling and Storage

Precautions:
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue
under a fume hood. Ground all equipment containing material. Do not breathe dust. Avoid contact with eyes Wear
suitable protective clothing If you feel unwell, seek medical attention and show the label when possible.
Storage:
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed.
Keep in a cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away
from strong oxidizing agents.
Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Physical ,Chemical Properties, Stability and Reactivity Data

Physical state and appearance : Solid. (Solid crystalline powder.)
Odor
: Not available.
Taste
: Not available.
Molecular Weight
: 256.32 g/mole
Color
: Blue. (Dark.)
pH (1% soln/water)
: Not applicable.
Boiling Point
: Not available.
Melting Point
: Decomposes. (168C or 334.4F)
Critical Temperature
: Not available.
Specific Gravity
: Not available.
Vapor Pressure
: Not applicable.
Vapor Density
: Not available.
Volatility
: Not available.
Odor Threshold
: Not available.
Water/Oil Dist. Coeff.
: Not available.
Ionicity (in Water)
: Not available.
Dispersion Properties
: See solubility in water, methanol.
Solubility
: Soluble in methanol. Insoluble in cold water.
Stability
: The product is stable.
Instability Temperature : Not available.
Conditions of Instability : Not available.
Corrosivity
: Non-corrosive in presence of glass.
Special Remarks on Reactivity : Not available.
Special Remarks on Corrosivity: Not available.
Polymerization
: No.
Toxicological Information
Routes of Entry
: Eye contact. Ingestion.
Toxicity to Animals
: Not available.
Chronic Effects on Humans
: The substance is toxic to kidneys, mucous membranes.
Toxic Effects on Humans
: Hazardous in case of ingestion. Slightly hazardous in case of skin contact

(irritant), of inhalation.
Ecotoxicity
: Not available.
Toxicity of the Products : The products of degradation are more toxic.
of Biodegradation
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Methyl red MSDS
Product Name: Methyl red
Synonym: C.I. Acid Red 2; Benzoic
Acid, 2-((4-dimethylamino)phenyl)azo)-; 2Carboxy-4'-(dimethylamino)azobenzene; 4'Dimethylaminoazobenzene-2-carboxylic acid; C.I. 13020;
C.I. Red 2; o-((p-(Dimethylamino)phenyl)azo)benzoic acid;
p-(Dimethylamino)phenyl)azo)benzoic acid; Methyl Red,
Neutral
Chemical Name: 2-((4(Dimethylamino)phenyl)azo)benzoic acid
Chemical Formula: C15-H15-N3-O2
Potential Acute Health Effects
:Hazardous in case of ingestion. Slightly hazardous in case of

skin contact (irritant), of eye contact (irritant), of inhalation.
Potential Chronic Health Effects:

CARCINOGENIC EFFECTS
: 3 (Not classifiable for human.) by IARC.
MUTAGENIC EFFECTS : Mutagenic for bacteria and/or yeast.
TERATOGENIC EFFECTS
: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance
may be toxic to liver. Repeated or prolonged exposure to the substance can
produce target organs damage.
First Aid Measures

Eye Contact
Skin Contact
Inhalation
Ingestion
:Check for and remove any contact lenses. In case of contact, immediately flush
eyes with plenty of water for at least 15 minutes. Get medical attention if irritation
occurs.
: Wash with soap and water. Cover the irritated skin with an emollient. Get
medical attention if irritation develops.
: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention.
: Do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If large quantities of this material are
swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt
or waistband.

Flammability of the Product
: May be combustible at high temperature.
in
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: As with most organic solids, fire is possible at elevated temperatures or by
contact with an ignition source.

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading
water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and allow to evacuate through the sanitary system.

Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,
evaporate the residue under a fume hood. Ground all equipment containing material. Do not breathe dust. Wear
suitable protective clothing. If you feel unwell, seek medical attention and show the label when possible. Keep away
from incompatibles such as oxidizing agents, reducing agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Gloves.
Physical , Chemical Properties ,Stability and Reactivity Data

Physical state and appearance: Solid. (Crystals solid or Powdered solid.)
Odor
: Odorless.
Taste
: Not available.
Molecular Weight
: 269.3 g/mole
Color
: Violet or Red. Bluish-purple.
pH (1% soln/water)
: Not applicable.
Boiling Point
: Not available.
Melting Point
: 179C (354.2F) - 182 C
: Not available.
Specific Gravity
: Not available.
Vapor Pressure
: Not applicable.
Vapor Density
: 9.3(Air = 1)
Volatility
: Not available.
Odor Threshold
: Not available.
Water/Oil Dist. Coeff
.: Not available.
Ionicity (in Water)
: Not available.
: Not available.
Solubility
: Insoluble in cold water, hot water. Soluble in very hot acetone, benzene,
chloroform, acetic acid, alcohol, lipids. Slightly soluble
in petroleum ether.
Stability
Instability Temperature : Not available.
Conditions of Instability : Excess heat, incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, reducing agents.
Corrosivity
Special Remarks on Reactivity: Not available.
Polymerization: Will not occur.
Routes of Entry
: Inhalation. Ingestion.
Toxicity to Animals
: Not available.
Chronic Effects on Humans
: Mutagenic for bacteria and/or yeast. May cause damage to the following
organs: liver.
Toxic Effects on Humans
: Hazardous in case of ingestion. Slightly hazardous in case of skin contact

(irritant), of inhalation.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic). May cause cancer based on animal test data. No adequate data found for
humans.
.
Ecotoxicity: Not available.

Curcumin MSDS
Product Name: Curcumin
Catalog Codes: SLC5503
Synonym: Brilliant Yellow S; 1,7-Bis(4-hydroxy-3methoxyphenyl)1,6-heptadiene-3,5-dione; Tumeric Yellow
Chemical Formula: C21H20O6
Potential Acute Health Effects:
Hazardous in case of eye contact (irritant), of ingestion. Slightly hazardous in case of skin contact (irritant), of
inhalation.
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least
15 minutes. Get medical attention.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if
irritation develops.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.

Flammability of the Product: May be combustible at high temperature.
Fire Hazards in Presence of Various Substances:
Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of
shocks.
in presence of static discharge: Not available.
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading
water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and allow to evacuate through the sanitary system.

Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,
evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe
dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested, seek medical advice immediately and
show the container or the label. Keep away from incompatibles such as oxidizing agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24C
(75.2F).

Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Physical , Chemical Properties ,Stability and Reactivity Data

Physical state and appearance
: Solid.
Odor
: Not available.
Taste
: Not available.
Molecular Weight
: 368.39 g/mole
Color
: Orange. Orange-Yellow
pH (1% soln/water)
: Not applicable.
Boiling Point
: Not available.
Melting Point
: 183C (361.4F)
: Not available.
Specific Gravity
: <1 (Water = 1)
Vapor Pressure
: Not applicable.
Vapor Density
: 13 (Air = 1)
Volatility
: Not available.
Odor Threshold
: Not available.
.: Not available.
Ionicity (in Water)
: Not available.
: Not available.
Solubility:
Very slightly soluble in acetone. Insoluble in cold water, diethyl ether.
Stability
Conditions of Instability
: Excess heat, incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity
Special Remarks on Reactivity
: Orange -Yellow tumeric will hold shade better than lemon-yellow
when exposed directly or indirectly to sunlight.
Polymerization: Will not occur.
Routes of Entry: Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): >2000 mg/kg [Mouse].
Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
Other Toxic Effects on Humans:
Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of inhalation.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic). It produced sister chromatid exchange in bone marrow of mice at 25
mg/kg, induced micronuclei at 73,600 mcg/L in a human embryo, and DNA inhibition in human HeLa cell [RTECS
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation. No adverse effects expected. No information found
on absorption through skin. Eyes: Dust may cause eye irritation. No adverse effects expected. Inhalation: Dust may
cause respiratory tract irritation. No adverse effects expected. No information found on absorption through lungs.
Ingestion:
Ingestion of small amounts during normal industrial handling is not likely to be harmful. Ingestion of large doses
may cause gastrointestinal tract irritation (upset). It is poorly absorbed from the gut. Chronic Potential Health
Effects: no information found other than it lowered serum and liver cholesterol levels in rats and that it may affect
genetic material. The toxicological properties of this substance have not been fully investigated.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.

Eugenol MSDS
Product Name: Eugenol
Synonym: Hydroxy-1-methoxy-2-allyl-4-benzene
Chemical Formula: C10H12O2
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in
case of skin contact (permeator).
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS: Not available.
TOXICITY: Not available. The substance is toxic to lungs, the nervous system, mucous membranes. Repeated or
prolonged exposure to the substance can produce target organs damage.
First Aid Measures

Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin
with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover
the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before
reusing.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Ingestion:
Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible
indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight
clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation.
Seek immediate medical attention.

Flammability of the Product: May be combustible at high temperature.
Flash Points: OPEN CUP: 104C (219.2F).
in presence of static discharge: Not available.
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the sanitary system.

Precautions:
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue
under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/
vapour/spray. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory
equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin
and eyes
Storage:
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed.
Keep in a cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away
from strong oxidizing agents.

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station
location.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Physical and Chemical Properties

Odor
Taste
Molecular Weight
Color: Colorless.
pH (1% soln/water)
Boiling Point
Melting Point
Specific Gravity
Vapor Pressure
Vapor Density
Volatility
Odor Threshold
Ionicity (in Water)
Solubility
: Liquid.
: Not available.
: Not available.
: 164.2 g/mole
: Not applicable.
: 253.2C (487.8F)
: -7.5C (18.5F)
: Not available.
: 1.055 (Water = 1)
: 0.03 mm of Hg (@ 20C)
: Not available.
: Not available.
: Not available.
: Not available.
: Not available.
: Not available.
: Insoluble in cold water.
Stability and Reactivity Data

Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Polymerization: No.
Routes of Entry: Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 1930 mg/kg [Rat].
Chronic Effects on Humans: The substance is toxic to lungs, the nervous system, mucous membranes.
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact
(permeator).
arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: May decompose on exposure to moist air and water.

Ferric Ammonium Sulfate, Saturated,Aq.Sol. MSDS
Product Name: Ferric Ammonium Sulfate,
Saturated,Aq.Sol.
Chemical Name: Ferric Ammonium Sulfate, Saturated,
Aq.Sol.
Chemical Formula: Not applicable.
Very hazardous in case of eye contact (irritant), of ingestion. Hazardous in case of skin contact (irritant), of
inhalation. Noncorrosive for skin. Non-sensitizer for skin. Non-permeator by skin. Inflammation of the eye is
characterized by redness, watering, and itching.
Very hazardous in case of eye contact (irritant), of ingestion. Hazardous in case of skin contact (irritant), of
inhalation. Noncorrosive for skin. Non-sensitizer for skin. Non-permeator by skin.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to kidneys, liver. Repeated or prolonged
exposure to the substance can produce target organs damage.
First Aid Measures

Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,
keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin
with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold
water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing,
perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Neutralize the residue
with a dilute solution of sodium carbonate. Finish cleaning by spreading water on the contaminated surface and
allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.

Precautions:
Do not breathe gas/fumes/ vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment If
you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes
Storage:
No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure
that it is
not necessary to strain to reach materials, and that shelves are not overloaded.

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure Limits:
Ferric ammonium sulfate dodecahydrate TWA: 1 (mg/m3) from ACGIHConsult local authorities for acceptable
exposure limits.
Physical and Chemical Properties

Odor
Taste
Molecular Weight
Color
pH (1% soln/water)
Boiling Point
Melting Point
Specific Gravity
Vapor Pressure
Vapor Density
Volatility
Odor Threshold
Ionicity (in Water)
Solubility
: Liquid.
: Not available.
: Not available.
: Not applicable.
: Not available.
: Acidic.
: The lowest known value is 100C (212F) (Water).
: Not available.
: Not available.
: Weighted average: 1.38 (Water = 1)
: The highest known value is 17.535 mm of Hg (@ 20C) (Water).
: The highest known value is 0.62 (Air = 1) (Water).
: Not available.
: Not available.
.: Not available.
: Not available.
: See solubility in water.
: Easily soluble in cold water.
Stability and Reactivity Data

Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Polymerization: No.
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Not available.
Chronic Effects on Humans: The substance is toxic to kidneys, liver.
Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of inhalation. Non-corrosive for
skin. Nonsensitizer for skin. Non-permeator by skin.
arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.

Material Safety Data Sheet

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