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3/16/2015

Law&Sea| H2S.Purging

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OilCargoesWithHighH2SContentLastupdated12Aug2014
HydrogenSulfide(H2S)isaverytoxic,corrosiveandflammablegas.Ithasaverylowodourthresholdandadistinctive
odourofrotteneggs.
InternationalSafetyGuideforOilTankersandTerminals,5thedt.,ICS,OCIMF,IAPH,section2.3.6(ISGOTT).
Tankers

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Definition

H2SPurging?
Bydefinition,purgingontankersisan operationofintroductionofinertgasintoatankalreadyintheinertcondition
withtheobjectoffurtherreducingtheexistingoxygencontentand/orreducingtheexistinghydrocarbongascontenttoa
levelbelowwhichcombustioncannotbesupportedifairissubsequentlyintroducedintothe tank.
Definitions
Purging. The introduction of inert gas into a tank already in the inert condition with the object of further
reducing the existing oxygen content and/or reducing the existing hydrocarbon gas content to a level below
whichcombustioncannotbesupportedifairissubsequentlyintroducedintothetank.
Introductionofairinshipstanksusuallyrequiredwhenitisnecessarytogasfreeemptyfromcargotanks,i.e.toremove
toxic, flammable and inert gases and increase the oxygen content to 21% by volume after washing. Due to combustible
nature of hydrocarbon gas its mixture with air can be ignited when hydrocarbon content in air is more than 2% by
volume.Topermanently (emphasis mine) reduce the hydrocarbon content to 2% or less and to ensure that, during the
subsequent gas freeing operation, no portion of the tank atmosphere is brought within the flammable range the tanks
shouldfirstbepurgedwithinertgas.
Thus,insimplewordspurgingisanoperationofpermanentreplacementofhydrocarbongasinemptycargotanksbyinert
gastoreduceriskofcombustionandsubsequentventilationwithair.
Quasipurgingwhichisusuallyproposedbythecharterersisakindofventilationofverysmallempty volumes of loaded
tankstotemporarybringH2Scontentdown.Introductionofinertgasintoloadedtanksdoesnotdisplaceordilute(asin
caseofpurgingdescribedabove)H2S,butratherblowsoutvapoursofH2S.Sofarasspeedofinterchangeofgasesin
tankortanksexceedsspeedofH2Svaporisation,contentofH2Sdecreases,butH2Scontentrisesagainassoonasthis
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Law&Sea| H2S.Purging

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Subchapters
I.SafetyAspects
II.PracticalAspects
III.RecommendedProcedures
IV.LegalAnalysis
V.H2SPurging?

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