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INTERMEDIATE-II YEAR CHEMISTRY


Model Paper-1
Maximum marks: 60

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Time: 3hours

SECTION-A

(10x2=20M)

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NOTE: Answer all questions.

1. What are Frenkel and Schottky defects in crystalline solids ?

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2. What is vant Hoff factor i and how it is related to in the case of a binary
Electrolyte (1:1)?

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3. How is Gibbs free energy related to the emf of the cell mathematically?
2+

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4. Calculate the spin only magnetic moment of Fe (aq ) ion.

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5. What is the role of depressant in froth floatation process?


6. Explain Ferromagnetism with suitable examples.

7. What is condensation polymer? Give example.

8. Write the names and structures of monomers of the following polymers?


i) Bakelite

and

ii) Nylon- 6, 6.

9. How is Ethane converted into bromo ethane?


10. What are ambident nucleophiles? Give an example.

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SECTION-B
Note: Answer any Six of the following.

(6x4m=24marks)

11. What is relative lowering of vapour pressure?


Calculate the mass of a non-volatile solute (molar mass 40g) which should be

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dissolved in 114gm octane to reduce its vapour pressure to 80%.


12. Compare and contrast the phenomenon of physisorption and chemisorption.

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14. Explain the structure of a) XeF2 and b) XeF4

n.

13. Giving examples to differentiate roasting and calcination.

15. What is lanthanoid contraction? What are the consequences of lanthanoid

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contraction?

16. Give the sources of the following vitamins and name the diseases caused by their
deficiency.
b) D

c) E and d) K

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a) A

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17. What are antacids and antihistamines? Give example.


18. Explain (a) Hoffmann bromamide degradation reaction and (b) Gattermann

SECTION-C

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reaction

(8x2=16M)

Note: Answer any Two of the following questions.

19. a) State and explain Nernst equation with the help of a metallic electrode .
b) What is molecularity of a reaction? How is it different from the order of a
reaction? Name one bimolecular and one tri molecular gaseous reactions
20. a) How does SO2 reacts with the following? Give equations.

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i ) Na2 SO3( aq )

ii ) Cl2

iii ) Fe+3 ions

iv) KMnO4

b) Write balanced equations for the following?


a) NaCl is heated with conc. H 2 SO4 in the presence of MnO2

21. a) Give the equations for the preparation of phenol from


a) Cumune

and

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b) Chlorine is passed into a solution of NaI in water.

b) Benzene, conc. H 2 SO4 and NaOH

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b) Complete each synthesis by giving missing starting material, reagent or products.

ii.

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i.

iv.

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iii.

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INTERMEDIATE-IIYEAR CHEMISTRY
Model Paper- 2
Time:3hours

Maximum marks: 60

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SECTION-A
Note: Answer all questions.

(10x2=20M)

1. What is meant by the term coordination number? Give the coordination number of
atoms in a body-centred cubic structure.

n.

2. Calculate the amount of benzoic acid ( C6 H 5COOH ) required for preparing 250 mL

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of 0.15 M solution in methanol.

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3. How is Eo (standard potential) of the cell related to the equilibrium constant Kc


of the cell reaction ?
4. CuSO 4 .5H 2O is blue in colour while CuSO 4 is colourless. Why?
5. What is the role of cryolite in the metallurgy of aluminium?

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6. Classify each of the following as being either a p-type or a n-type semiconductor:


(ii) B doped with Si.

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(i) Ge doped with In

7. What is addition polymer? Give example.

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8. What are the repeating monomeric units of Nylon-6 and Nylon-6, 6?


9. Explain why the alkyl halides though polarare immiscible with water.

10. Write the structures of the following organic halogen compounds.


(i) 2-Chloro-3-methylpentane
(ii) 1-Bromo-4-sec-butyl-2-methylbenzene

SECTION-B
Note: Answer any Six of the following.
11.

(6x4m=24marks)

State Raoults law. Calculate the vapour pressure of a solution containing


9gm of glucose in 162 gm of water at 298K. The vapour pressure of pure water
at 298K is 17.535 mm of Hg.

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12. What are emulsions? How are they classified? Give any two applications of
emulsions.
13. How is alumina separated from silica in the bauxite ore associated with silica?
Give equations.
14. How are xenon fluorides XeF2 , XeF4 and XeF6 obtained?
15. Explain Werners theory of coordination compounds with suitable examples.

18. Complete the following conversions: Aniline to


ii. Cyano Benzene

iii. Benzene and iv. Phenol

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i. Fluoro Benzene

n.

17. What are analgesics and food preservatives? Give example.

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16. Write the structures of maltose and Lactose. What are the hydrolysis products of
maltose and lactose?

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SECTION-C

Note: Answer any Two of the following questions.

(8x2=16M)

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19. a) What is electrolysis? State Faradays First and second laws of electrolysis.
b) Give a detailed account of the collision theory of reaction rates bimolecular

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gaseous reactions.

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20. a) Describe the manufacture of H 2 SO4 by contact process.


b) How does Chlorine react with the following?
b) Iodine

c) H 2 S

d) Na2 S 2O3

a) Acidified FeSO4

21. a) Explain the following with an example.


(i) Reimer-Tiemann reaction

(ii) Williamson ether synthesis.

b) Describe the following.


(i) Acetylation and

(ii) Aldol condensation

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INTERMEDIATE-II YEAR CHEMISTRY


Model Paper- 3
Time: 3 hours

Maximum marks: 60

NOTE: Answer all questions.

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SECTION-A
(10x2=20M)

1. Explain Paramagnetismwith suitable example.

mass.
3. What are primary and secondary batteries?

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n.

2. Calculate the mole fraction of H 2 SO4 in a solution containing 98% H 2 SO4 by

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4. How do transition elements exhibit catalytic activity?


5. Give the composition of the following alloys.
i) German silver

ii)Bronze

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6. How do you distinguish between Crystal lattice and unit cell?


7. What is PHBV? How is it useful to man?

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8. What is Ziegler-Natta catalyst? Give its use?

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9. Write the isomers of the compound having formula C4 H 9 Br .

10. How is Toluene converted to benzyl alcohol?

SECTION-B

Note: Answer any Six of the following

(6x4=24marks)

11. Define Osmotic pressure.


If the osmotic pressure of glucose solution is 1.52 bar at 300K, what would be its
concentration if R=0.0831 bar/mol/k.
12. What is catalysis? How is catalysis classified? Give two examples for each type
of catalysis.

13. Explain the purification of sulphide by froth floatation method.


14. Explain the structures of a) XeF6 and b) XeOF4
15. Why do the transition metal ions exhibit characteristic colours in aqueous
solution? give example.
16. What are hormones? Give one example for each.

17. Explain the following terms with suitable example.


(i) Cationic detergents

(ii) Anionic detergents

(ii) Sandmeyer reaction

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(i) Carbylamine reaction

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18. Write short notes on the following.

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i) Steroid hormones ii) Poly peptide hormones and iii) Amino acid derivatives

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SECTION-C

Note: Answer any Two of the following questions.

(8x2=16M)

19. a) Give the applications of Kohlrauschs law of independent migration of ions.

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b) Explain the following terms with suitable examples

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i) activation energy of a reaction

ii) order of reaction

20. a) How is ozone prepared? How does it react with the following?
ii) KI

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i) PbS

iii) Hg

b) Write the names and formulae of the oxo acids of chlorine and give their

structures.

21. a) Explain the acidic nature of phenol and Compare with that of alcohols.
b) Describe the following.
a. Cannizzaro reaction

and

b. Decarboxylation

INTERMEDIATE-II YEAR CHEMISTRY


Model Paper- 2
Maximum marks:60

SECTION_A

NOTE: Answer all questions.

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Time-3hours

(10x2=20M)

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number of atoms in a body-centred cubic structure.

n.

1. What is meant by the term coordination number? Give the coordination

2. Calculate the amount of benzoic acid ( C6 H 5COOH ) required for preparing

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250 mL of 0.15 M solution in methanol.

3. How is Eo (standard potential ) of the cell related to the equilibrium constant

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Kc of the cell reaction ?

4. CuSO 4 .5H 2O is blue in colour while CuSO 4 is colourless. why?

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5.What is the role of cryolite in the metallurgy of aluminium?

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6. Classify each of the following as being either a p-type or a n-type


semiconductor:

(ii) B doped with Si.

(i) Ge doped with In

7. What is addition polymer ? Give example.


8. What are the repeating monomeric units of Nylon-6 and Nylon-6,6?
9. Explain why the alkyl halides though polarare immiscible with water?

10. Write the structures of the following organic halogen compounds.


(i) 2-Chloro-3-methylpentane
(ii) 1-Bromo-4-sec-butyl-2-methylbenzene

SECTION-B
Answer any Six of the following

(6x4m=24marks)

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NOTE:

11. State Raoults law. Calculate the vapour pressure of a solution containing

9gm of glucose in 162 gm of water at 298K. The vapour pressure of pure water at

n.

298K is 17.535 mm of Hg.

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12. What are emulsions? How are they classified? Give any two applications of
emulsions.

silica? Give equations.

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13. How is alumina separated from silica in the bauxite ore associated with

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i

14. How are xenon fluorides XeF2 , XeF4 and XeF6 obtained?
15. Explain Werners theory of coordination compounds with suitable examples.

ak

16. Write the structures of maltose and Lactose. What are the hydrolysis

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products of maltose and lactose?


17. What are analgesics and food preservatives? Give example.

18. Complete the following conversions: Aniline to

i. Fluoro benzene

ii.cyano benzene

iii. Benzene and

iv. Phenol

SECTION-C
NOTE: Answer any Two of the following questions.

(8x2=16M)

19.a) What is electrolysis? State Faradays First and second laws of electrolysis.
b) Give a detailed account of the collision theory of reaction rates bimolecular

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gaseous reactions

b) How does Chlorine react with the following?


c) H 2 S

d) Na2 S 2O3

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a) Acidified FeSO4 b) Iodine

n.

Describe the manufacture of H 2 SO4 by contact process.

20. a)

21. a) Explain the following with an example.

b) Describe the following

(ii) Aldol condensation

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(i) Acetylation and

(ii) Williamson ether synthesis.

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(i) Reimer-Tiemann reaction

INTERMEDIATE-IIYEAR CHEMISTRY
Model Paper-2
Time-3hours

Maximum marks:60

(10x2=20M)

n.

NOTE: Answer all questions.

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SECTION_A

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1.What are Frenkel and Schottky defects in crystalline solids ?

2.. What is vantHoff factor i and how it is related to in the case of a binary

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uc

electrolyte(1:1).?

3. How is Gibbs free energy related to the emf of the cell mathematically?

sh
i

4. Calculate the spin only magnetic moment of Fe 2+ (aq ) ion .

ak

5.What is the role of depressant in froth floatation process?


6.Explain Ferromagnetism with suitable examples.

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7.What is condensation polymer? Give example

8.Write the names and structures of monomers of the following polymers?


and

ii) Nylon- 6,6.

i) Bakelite

9..How is Ethane converted in to bromo ethane ?


10.What are ambident nucleophiles? Give an example.

SECTION-B
NOTE:

Answer any Six of the following

(6x4m=24marks)

11. What is relative lowering of vapour pressure?


Calculate the mass of a non-volatile solute (molar mass 40g ) which should be

co
m

dissolved in 114gm octane to reduce its vapour pressure to 80%.


12. Compare and contrast the phenomenon of physisorption and chemisorption.

at
io

14. Explain the structure of a) XeF2 and b) XeF4

n.

13. Giving examples to differentiate roasting and calcination.

15. What is lanthanoid contraction? What are the consequences of lanthanoid

ed
uc

contraction?

16. Give the sources of the following vitamins and name the diseases caused by
their deficiency
b) D

c) E and d) K

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i

a) A

18. Explain

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17. What are antacids and antihistamines? Give example.


(a) Hoffmann bromamide degradation reaction and (b)

SECTION-C

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Gattermann reaction

(8x2=16M)

NOTE: Answer any Two of the following questions.

19.a) State and explain Nernst equation with the help of a metallic electrode .
b) What is molecularity of a reaction? How is it different from the order of
a reaction?

Name one bimolecular and one tri molecular gaseous reactions

20. a) How does SO2 reacts with the following. Give equations
i ) Na2 SO3( aq )

ii ) Cl2

iii ) Fe+3 ions

iv) KMnO4

b) Write balanced equations for the following?


a) NaCl is heated with conc. H 2 SO4 in the presence of MnO2
b) Chlorine is passed into a solution of NaI in water.
21. a) Give the equations for the preparation of phenol from
and

b) Benzene, conc. H 2 SO4 and NaOH

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a) Cumune

b) Complete each synthesis by giving missing starting material, reagent or

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n.

products.

Ii.

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i.

iv.

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sh
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iii.

INTERMEDIATE-II YEAR CHEMISTRY


Model Paper- 3
Time-3hours

Maximum marks:60
SECTION_A
(10x2=20M)

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NOTE: Answer all questions.


1. Explain Paramagnetismwith suitable example.

n.

2. Calculate the mole fraction of H 2 SO4 in a solution containing 98% H 2 SO4 by

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mass.

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uc

3. What are primary and secondary batteries?

4. How do transition elements exhibit catalytic activity?


5. Give the composition of the following alloys.
ii)Bronze

sh
i

i) German silver

ak

6. How do you distinguish between Crystal lattice and unit cell?

w
.s

7. What is PHBV? How is it useful to man?


8. What is Ziegler-Natta catalyst? Give its use?

9. Write the isomers of the compound having formula C4 H 9 Br ?

10. How

is Toluene converted to benzyl alcohol ?

SECTION-B
NOTE:

Answer any Six of the following

(6x4=24marks)

11. Define Osmotic pressure.


If the osmotic pressure of glucose solution is 1.52 bar at 300K, what would be

co
m

its concentration if R=0.0831 bar/mol/k.


12. What is catalysis? How is catalysis classified? Give two examples for each
type of catalysis.

at
io

14. Explain the structures of a) XeF6 and b) XeOF4

n.

13. Explain the purification of sulphide by froth floatation method.

solution? Give example?

ed
uc

15. Why do the transition metal ions exhibit characteristic colours in aqueous

16. What are hormones? Give one example for each.

ii) Poly peptide hormones and

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i

i) Steroid hormones

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iii) Amino acid derivatives

17. Explain the following terms with suitable example

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.s

(i) Cationic detergents

(ii) Anionic detergents

18. Write short notes on the following

(i)Carbylamine reaction

(ii) Sandmeyer reaction

SECTION-C
NOTE: Answer any Two of the following questions. (8x2=16M)
19.a)Give the applications of Kohlrauschs law of independent migration of ions.
b)Explain the following terms with suitable examples
ii) Order of reaction

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i) Activation energy of a reaction

20.a)How is ozone prepared? How does it react with the following?


iii) Hg

n.

i) PbS ii) KI

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b)Write the names and formulae of the oxo acids of chlorine and give their
structures

b) Describe the following

and

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a. Cannizzaro reaction

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21.a)Explain the acidic nature of phenol and Compare with that of alcohols.

b. Decarboxylation