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The arsenic compound usually used is an oxide, As2O3. In the remedies it is called by its
Latin name Arsenicum album (white arsenic). The oxide is prepared industrially by roasting
arsenic-containing ores such as arsenopyrite, FeAsS, in air. The other products formed are
iron(III) oxide and sulfur dioxide.
(a) (i)
(ii) Give an equation for the industrial production of As2O3 from FeAsS.
As2O3 is moderately soluble in water; one dm3 of a saturated solution at 25 C contains
20.6 g. When dissolved in water, the oxide reacts to form arsenous acid, H3AsO3.
(b) (i)
Given that spectroscopy shows all the hydrogen atoms in H3AsO3 to be in the same
environment, suggest a structure for the acid. What is the geometry around the
arsenic atom?
(ii) Give an equation for the formation of arsenous acid from As2O3.
(iii) Calculate the concentration of the arsenous acid in mol dm3 in the saturated
solution.
In homeopathy, a 'decimal-scale' is often used to specify the dilution of a given sample: D1
(sometimes labelled 1X) means the sample has been diluted 1 part in 10. D2 (or 2X) means
the sample has been diluted 1 in 10, then 1 part of that solution has been further diluted 1 in
10 again to give a 1 in 100 dilution. A D6 (or 6X) solution has repeated this process six
times to give a final dilution of 1 in 106.
Arsenicum album is often sold as a D30 preparation. Let us assume that the initial stock
solution before dilution was the saturated solution containing 20.6 g dm3 of As2O3.
(c) (i)
Calculate the mass (in g) of As2O3 present in a 100 cm3 glass of the D30 Arsenicum
album remedy.
2
(ii) Given that 0.1 g of As2O3 is usually fatal, calculate the volume (in m3) of the D30
solution that would be needed for a fatal dose of As2O3. Also express your answer
as a fraction of the volume of the Earth (approximately 1.08 1012 km3).
(iii) The preparations are usually sold in one ounce bottles (1 ounce = 28 cm3).
Calculate how many bottles of the D30 solution need to be bought in order, on
average, to include one atom of arsenic.
Another 'remedy' is Muriaticum acidum which is actually diluted hydrochloric acid. This is
available in various dilutions up to the extremely 'potent' D2000 preparation.
Assuming the original stock solution before dilution was 1.0 mol dm3, what is the
concentration of HCl in the following preparations?
(d)
What is the pH of pure water at room temperature? Calculate [H+] for pure water.
(ii) Calculate the pH of the 1.0 mol dm3 stock solution and the five dilutions from
part (d). Give your answers to one decimal place.
Whilst homeopathy deals with extremely dilute solutions, at the other extreme, high
concentrations are limited by solubilities and, ultimately, the densities of materials.
(f)
(g)
Given that the density of pure water is 1.0 kg dm3, calculate the concentration of
pure water in mol dm3.
At high concentrations of acids, the above equations for pH are no longer valid. Not
realising this, one popular science book has erroneously quoted the strongest acid (a boroncarbon cluster compound) as having a pH of 18.
(h)
Keeping track of the functional group level can be a useful way of understanding a large
number of organic reactions.
In every one of the reactions in this question,
no carbon-carbon bonds are broken or formed.
During oxidation reactions, the functional group level will be found to increase as new CE
bonds are formed at the expense of CH bonds.
During reduction reactions, the functional group level is found to decrease as new CH
bonds are formed at the expense of CE bonds.
During hydrolysis reactions, the functional group level of every carbon remains the same,
but the addition of water (hydro) may be used to split (lyse) functional groups, and / or
replace some bonds to electronegative atoms with new bonds to oxygen. Different
hydrolysis reactions may require different conditions with some only taking place at a
significant rate with acid or alkali present.
4
(a)
Each of the following ten reactions takes place with a single reagent. Classify each
one as either an oxidation, a reduction, or a hydrolysis reaction. Simply tick the
appropriate box for each in the answer booklet.
A honey bee
(b)
(c)
The scheme below contains a number of mystery organic compounds RZ. Draw
the structures for the compounds RZ.
Each carbon atom in all of the molecules RZ is bonded to exactly one other
carbon atom.
Mg
12
24.31
Ca
20
40.08
Sr
38
87.62
Ba
56
137.34
Ra
88
Na
11
22.99
19
39.102
Rb
37
85.47
Cs
55
132.91
Fr
87
+Actinides
*Lanthanides
89
Ac+
57
138.91
La*
39
88.91
Pa
91
Th
90
232.01
93
Np
61
94
Pu
Ir
Pt
46
106.4
Pd
Cm
97
Bk
66
162.50
98
Cf
Tl
99
Pb
Er
100
Fm
Te
34
78.96
Se
16
32.06
8
16.00
16
101
Md
69
168.93
84
Yb
102
No
85
Lu
103
Lr
86
Rn
54
131.30
Xe
36
83.80
Kr
18
39.95
Ar
10
20.18
Ne
2
4.003
71
174.97
At
53
126.90
35
79.904
Br
17
35.45
Cl
9
19.00
17
70
173.04
Po
52
127.60
Tm
83
208.98
Bi
51
121.75
Sb
33
74.92
As
15
30.97
7
14.01
15
68
167.26
82
207.2
67
164.93
Es
Sn
32
72.59
Ge
14
28.09
Si
6
12.01
14
50
118.69
Ho
81
204.37
Dy
80
200.59
Hg
49
114.82
In
Cd
48
112.40
31
69.72
Ga
13
26.98
Al
5
10.81
13
30
65.37
Zn
12
65
158.93
Tb
79
196.97
Au
64
157.25
96
Ag
29
63.55
Cu
11
47
107.87
Gd
78
195.09
Am
95
Ni
10
28
58.71
63
151.96
Eu
77
192.2
62
150.4
Sm
76
190.2
Os
45
102.91
Rh
27
58.93
Co
92
238.03
60
144.24
59
140.91
58
140.12
Ru
26
55.85
Fe
44
101.07
Pm
75
186.2
Re
43
Tc
25
54.94
symbol
atomic number
mean atomic mass
Mn
Pr
Nd
74
183.85
42
95.94
Mo
24
52.00
Cr
Ce
73
180.95
Ta
Hf
72
178.49
41
92.91
Nb
23
50.94
40
91.22
Zr
22
47.90
21
44.96
4
9.01
3
6.94
Ti
Sc
Be
Li
He
1
1.008
18