CHAPTER 4

1.which of the following represents the cubic crystals:

a.KCl,CaF2 and Au
b.SnO2 ,MnO2
c.ZnO, CdS , graphite
d.S, Na2B4O7.10H2O
2.diamond and graphite allotropes of carbon it follows that they
a.give different masses of CO2 when one mole burns completely
b.have different atomic numbers
c.have different arrangement of atoms
d.have different relative atomic masses
3.hydrocarbons which generally have high molecular masses can exist in
a.solid form
b.liquid form
c.vapour form
d.gaseous form
4.instantaneous induced dipole is reacted on an atom by
a.repulsion of electrons of two close shells
b.repulsion of electrons of two close atoms
c.attraction of nucleus on other electrons
d.repulsion of nuclei of two atoms
5.the number of atoms/molecules contained in one face centered cubic unit cell of
mono-atomic substances is
a.2
b.4
c.6

d.8
6.which of the liquid has strong intermolecular forces contained in it
a.diethyl ether
b.ethyl alcohol
c.hydrogen oxide
d.ethylene glycol
7.when water freezes its volume increases because of
a.cubical structure of ice
b.structural arrangements of water molecules
c.change of bond lengths
d.change of bond angles
8.londons forces are present
a.water
b.talcum powder
c.honey
d.kerosene oil
9.diamond is abad conductor because
a.of tight structure
b.high density
c.abscence of free electrons
d.all
10.what is the ratio between strength of covalent bond and dipole dipole forces
a.9:1
b.99:1
c.1:90
d.1:9

11.which one of the molecule has weakest intermolecular forces

a.HCl
b.NH3
c.Cl2
d.H2
12.which one of the following hydride has low boiling point from the hydrides :
a.CH4
b.H2Se
c.PH3
d.H2S
13.vapour pressure does not depend
a.temperature
b.vanderwaal forces
c.volume of the container
d.K.E of particles
14.bubbles in the interior of liquid comes out due to
a.greater external pressure
b.less external pressure
c.greater internal pressure
d.lesser internal pressure
15.what is the difference between the vapour pressure of H2O and diethyl ether at
0C in torr
a.188.2
b.192.2
c.195.2
d.198.2
16.which one of the following is insoluble in polar and non polar solvents

a.CaC2
b.SiC
c.C
d.Al2O3
17.in a crystal the atoms are located at the position of
a.zero P.E
b.infinite P.E
c.minimum P.E
d.maximumP.E
18.the lattice site of I2 contains
a.I
b.I2
c.Id.I3
19.water can boil at 0C when external pressure would be in torr:
a.0
b.8.8
c.4.8
d.20
20.for intermolecular forces there is responsible
a.valence electrons
b.nuclear charge
c.symmetrical electronic cloud
d.total electron cloud
21.if bond energy of H-A bond is 160kj/mol then energy of hydrogen bond in this
sample
a.102kj/mol

b.62kj/mol
c.32kj/mol
d.data unpredictable
22.which of the following factor is not involved in the strength of hydrogen bonding
a.lone pair of electrons
b.polarity
c.electronegativity
d.none
23.a phenomenon which is a necessary evil
a.boiling
b.evaporation
c.surface tension
d.melting
24.a liquid whose thermodynamic property does not depend on intermolecular
forces
a.ethylene glycol
b.acetone
c.mercury
d.none
25.dynamic equilbrium can be establish for water at normal external pressure
a.25C
b.70C
c.100C
d.120C
26.cleavage planes are
a.horizontal
b.vertical

c.inclined
d.parallel
27.ionic solids are brittle due to
a.their hardness
b.crystalline solid
c.layers of alternate ions
d.all
28.graphite shows anisotropy because
a.layered lattice
b.hybridization of C atoms
c.prescence of loose electrons in between layer
d.all
29.the prescence of ionic salt in liquid
a.decreases the viscosity of liquid
b.increases the viscosity of liquid
c.does not effect
d.none
30.in a body centered cubic cell ,an atom at the body of centre is shared by
a.4 unit cells
b.3 unit cells
c.2 unit cells
d.1 unit cell
31.closepacking is maximum in the crystal
a.simple cubic
b.face centerd cubic
c.body centered cubic

d.all
32.in the graphite carbon atoms are hybridized
a.sp2
b.sp3
c.sp
d.vary
33.wax is an example of
a.ionic solid
b.covalent solid
c.molecular solid
d.metalic solid
34.the structure of MgO is similar to NaCl. The coordination number of Mg is
a.2
b.6
c.4
d.8
35.which of the following solid consist of discrete molecules
a.graphite
b.NaCl
c.iron
d.dry ice
36.many metals show superconductivity at
a.very high temperature
b.normal temperature
c.very low temperature
d.50K 100K

37.which of the following has highheat and electrical conductivity

a.ice
b.NaCl
c.Si
d.Li
38.how many Cl ions are present at faces in face centered cubic unit cell
a.1
b.2
c.3
d.4
39.the bond length of crystalline solid is maximum at room temperature in
a.solid state
b. gas state
c. liquid state
d.same
40.transition temperature of allotropic forms than melting point
a.lesser
b.greater
c.equal
d.no relation
41.wax is an example of
a.ionic solid
b.covalent solid
c.molecular solid
d.metallic solid
42.a certain metal crystallizes in a simple cubic structure .at a certain temperature
it arranges to give a body centered structure .in this transition the density of metal

a.decreases
b.increases
c.remain unchanged
d.changes with a definite pattern
43.a pressure cooker reduces cooking time because
a.heat is uniformly distributed
b.boiling point of water increases
c.a large flame is used
d.vapour pressure of liquid decreases
44.nature of I2 crystals are
a.mettalic
b.ionic
c.covalent
d.molecular
45.the number of Clions per unit cell in NaCl
a.2
b.4
c.6
d.8
46.water is awetting liquid it is due to
a.adhesive forces exceed cohesive forces
b.cohesive forces exceed adhesive forces
c.adhesive forces become equal to cohesive forces
d.none
47.following property will decrease with increase of temperature except
Surface tension

b.density
c.viscosity
d.vapour pressure
48.acetone and chloroform are soluble ineach other due to
a.hydrogen bonding
b.dipole dipole interaction
c.london forces
d.all
49.theboiling point increases down the zero group element due to
a.ion dipole forces
b.london forces
c.hydrogen bonding
d.dipole dipole forces
50.evaporation of water is possible at
a.0C
b.100C
c.above100C
d.all temperatures
51.a liquid can be made to boil between its freezing point and
a.transition temperature
b.critical temperature
c.consolute temperature
d.none
52.hydrogen bonding involves in
a.solubility
b.detergent

c.biological molecules
d.all
53.crystalline solids do not have
a.rigidity
b.characteristic geometry
c.compressibility
d.all
54.when external pressure is 23.7torr the boiling water is
a.200C
b.100C
c.98C
d.25C
55.coordination number of Cs in CsCl is
a.2
b.4
c.6
d.8
56.which one of the following liquid has low vapour pressure at 25C
a.water
b.ethyl alcohol
c.acetone
d.diethyl ether
57.water has maximum density at
a.0C
b.2C
c.4C

d.100C
58.which one of the following does not showhydrogen bonding
a.water
b.phenol
c.ethyl alcohol
d.diethyl ether
59.which one of the following crystal has max lattice energy
a.NaF
b.NaCl
c.KCl
d.KBr
60.mettalic structure is
a.highly localized
b.highly delocalized
c.less localized
d.less delocalized