SRI CHAITANYA IIT ACADEMY

SEC : Sr.IPL-IC

WORK SHEET

SUB : CHEMISTRY

*****************************************************************************************************************

Topic : ATOMIC STRUCTURE

01. The figure given below is for an orbit of He+ ion. The potential energy of this orbit will be

(A) - 13.6 eV/atom

(B) 6.8 eV/atom

(C) - 27.2 eV/atom

(D) - 54.4 eV/atom

02. Electrons with energy 12 eV are shot into a gas of hydrogen atom in the ground state. How
many different wavelengths will be emitted out from this gas sample in Balmer series?
(A)One

(B)Two

(C) Three

D)Zero

03. Electronic configuration of an atom 1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 4s1,

1s

2s

3p

2p

3d

3s

4s

Choose the correct statement regarding this E.C.

(A)It represent the ground state of Cr
(B)It voilet Aubfaue principle
(C)It voilet Hunds rule of maximum multiplicity
(D)It is not a stable E.C.
04.

A metal surface is iradiated by a light of frequency three times the threshold frequency of
metal, the kinetic energy of ejected photoelectron is found to be E.Now the frequency of the
incident light is increased five fold, the kinetic energy of ejected photoelectron is now A x
E. The value of A is

[SR- SPL - CHE_W.S]

SRI CHAITANYA

05. Match the following

Column I
(A)Orbital angular momentum

Column II
2

h
2

(p) d-subshell

(B) mvr nh , n = 1, 2, 3

(q) Classical analogue of angular momentum

(C)Subshell which has degeneracy

(r) P-subshell

(D) N-shell

(s) Number of waves made by electron is 4

06.

07.

08.

09.

AUFBAU PRINCIPLE: The subshell with lowest (n+l) value has less energy and is filled up
first and filling continues in increasing order of energies. If two or more subshells have
same (n+l) value, the subshell with lower value of n is filled up first.
HUNDS RULE OF MAXIMUM MULTIPLICITY : In a sublevel pairing of electrons start only
when all degenerate orbitals are given one electron each having same spin.
PAULIS EXCLUSION PRINCIPLE: In an atom no two electrons will have all the four quantum
numbers same.
While writing electronic configuration above three rules are followed. In general if unpaired
electron exist in (n-1) d sublevel then transition elements, ions and their compounds exhibit
paramagnetic nature and are coloured.

TOPIC : ATOMIC STRUCTURE

:2:

[SR- SPL - CHE_W.S]

10.

The orbital diagram in which the Paulis exclusion principle is violated is

A)

11.

SRI CHAITANYA

B)

C)

D)

The orbital diagram in which the Aufbau principle is violated is

2s
A)

2p

B)

2s

2p

C)

2s

2p

D)

12.

Number of visible lines observed when an electron retruns form 5th orbit to ground state in hydrogen spectrum is _____

13.

A photo sensitive metallic surface has work function by h v0 . If photons of 2hv0 fall on
the surface, the electrons come out with a maximum velocity of 4 106 m / s . If photon
energy is increased to 5hv0 , the maximum velocity of photo electrons will be
A) 2 10 7 m / s

14.

B) 8 10 6 m / s

D) 8 105 m / s

The electron in a hydrogen atom makes a transition n1 n2 where n1 and n2 are the principal quantum numbers of the two states. Assume the Bohr model to be valid the time period
of the electron in the initial state is eight times that in the final state. The possible values of
n and n are
1
2
A) n1 4, n2 2

15.

C) 2 10 6 m / s

B) n1 8, n2 2

C) n1 8, n2 1

D) n1 6, n2 3

3d z2 orbital is designed as abc then sum of a b c is ____

16. Match Column I with Column II

COLUMN-I

COLUMN-II

A)

p) 4s
r

2 dv

B)

q) 5 p y
r

C)

r) 3s
r

D) At least one angular node

s) 6dxy

17. In a hydrogen like atom, two electrons move around the nucleus in circular orbits of radii R
and 4R. The ratio of the time taken by them to complete one revolution is :
a) 1 : 4

b) 4 : 1

TOPIC : ATOMIC STRUCTURE

c) 1 : 8

d) 8 : 7
:3:

[SR- SPL - CHE_W.S]

SRI CHAITANYA

18.

19.

20.

21.

TOPIC : ATOMIC STRUCTURE

:4:

[SR- SPL - CHE_W.S]

SRI CHAITANYA

22.

23.

24.

TOPIC : ATOMIC STRUCTURE

:5:

[SR- SPL - CHE_W.S]

SRI CHAITANYA

25. Column-I

Column-II

(A) Probability denisty of electron in

(P) Principal quntum number(n)

hydrogen like atom

(B) Shape, Size and Orientation of hydrogen

(Q) Azimuthal quantum number(l)

like atomic orbitals

(C) A hydrogen like one-electron wave

(R) Magnetic quantum number (m)

function obeying pauli principle

(D) Orbital angular momentum of the

(S) Spin quantum number (s)

electron in hydrogen like atomic orbital

26. Assertion (A) : The graph plotted between K.E and frequency of absorbed photon is given by
K.E. of
Photo electron

o
frequency

Reason (R) : Photo electric effect explains particle like behaviour of elecrons.
(A) A is true, R is true; R is a correct explanation for A
(B) A is true, R is true; R is NOT a correct explanation for A
(C) A is true, R is false

(D) A is false, R is true

27 .The mass of a proton is 1836 times more than that of the mass of an electron. If a sub-atomic
particle of mass ( m ') 207 times the mass of electron is captured by the nucleus, then the first
ionisation potential of H_____
(A) Decreases
(C) Remains the same

TOPIC : ATOMIC STRUCTURE

(B) Increases
(D) May increase (or) decrease

:6:

[SR- SPL - CHE_W.S]

SRI CHAITANYA

28. n orbit no; z at no; rn, z radius Vn, z velocity ; Tn, z Time period of revolution,

K n, z kinetic energy of the electron.

Column-I (of single electron species)

Column-II (ratio)

(A) r2,1 : r1,2

(P) 9 : 1

(B) V1,3 : V3,1

(Q) 8 : 1

(C) T1,2 : T2,1

(R) 16 : 1

(D) K1,2 : K 2,1

(S) 1 : 32

29. Calculate the number of waves made by a Bohr electron in one complete revolution when it is
present in third orbit.
30. A single electron ion has ionisation energy equal to 217.6 eV. What is the total number of protons present in one ion of it
a) 2
b) 5
c) 4
d) 9
31. Assertion (A) : Two orbitals with same value of l but different values of M l will ahve same
number of angular nodes.
32

.If the shortest wave length of H - atom in Lyman series is x, Then longest wave length in Balmer
series of He+ is
a)

9x
5

b)

36x
5

c)

x
4

d)

5x
9

33. The photoelectron emitted by irradiation of a metal surface by a light of frequency 3.2 X 1016 Hz
has KE twice that of the photoelectron emmitted by irradiation of the same metal surface by a
light of frequency 2.0 X 1016 Hz. Calculate work function of the irradiation process in 1015 Hz.

34

1,0
.Given the wave function of an orbital of hydrogen atom;
a3 / 2
0

r / a
e 0 , the most

probable distance of the electron present in the orbital from the nucleus is ;
a) a0.e-2r

b) a0

1

35. Given the wave function; 1,0
a3/2
0

c) (3/2)a0

d) 2a0

r/a0
e
. Then the most probable dis

tance of the electron from the nucleus in the ground state of a hydrogen atom
is;
a) a 0.e -2r
b) a0
c) (3/2)a0
d) 2a0

TOPIC : ATOMIC STRUCTURE

:7:

[SR- SPL - CHE_W.S]

SRI CHAITANYA

36. The Schrodinger wave equation for hydrogen atom is

3/2
1 Z
/2
2
radical
where a0 and Z are the constant
1 8 12 e

16 4 a0

2Zr
in which answer can be expossed and a then correct option is
0
a
0
2Z

A) The minimum positions of radical nodes from the nucleus is

B) The minimum positions of radical nodes from the nucleus is
C) The maximum position of radical node from the nucleus is
D) The maximum position of radical node from the nucleus is

37.

a
0
Z
3a
0
Z

4a
0
Z

Select the correct statements :

a) Angular momentum of all s-electrons is same
b) For n = 2 there may be four sub sub shells and may contain a maximum of 8 electrons.
c) M orbit can accomodate a maximum of 18 electrons
d) The energy of 4s-subshell is less than that of 3d-subshell

01) B (02) D (03) BCD (04) 7 (05) A r ; B q ; C pr ; D prs (06) B

(07) A (08) 8 (09) D (10) B (11) B (12) 3(13) B(14) AD (15) 5(16) (17) C (18) 4

(19) C (20) ABD (21) AD(22) A - Q ; B - R ; C - S ; D - P (23) D (24) B

(25) A - P,Q,R; B - P,Q,R; C - P,Q,R,S; D - Q (26) A (27) C (28) A - Q; B - P; C - S; D - R

(29) 3 (30) C (31) A(32) A (33) 8 (34) B (35)B (36) (37) ABCD

TOPIC : ATOMIC STRUCTURE

:8: