Académique Documents
Professionnel Documents
Culture Documents
Multidisciplinary Sciences1
HATTEN S. YODER, JR.
Director Emeritus, Geophysical Laboratory
Carnegie Institution of Washington
HE FIELD OF GEOLOGY is undergoing major transformations as the science is being integrated into other fields. There
are so many exciting developments in the science itself that
only a few examples of new opportunities can be presented here; however, the trends in social issues (particularly environmental concerns),
education, funding, and governmental involvement are alarming and
are having even greater impact on the field of geology.
The bridging programs of geology with physics, chemistry, biology,
and mathematics have been formalized into the disciplines of geophysics (Frbel, 1834), geochemistry (Schnbein, 1838), geobiology (Folquer,
1939; Teilhard de Chardin, 1943), and geomath (Butler, 1941).2 (The
late Preston Cloud, member of the American Philosophical Society,
preferred the title Professor of Biogeology when he joined the faculty
of UCLA in 1965.) Even these fields have been integrated; biogeochemistry, for example, has incorporated the new disciplines in astrobiology,
biomineralogy, and pedogenesis (soil formation).
Geobiology
Astrobiology. The focus on astrobiology arose from the concern that
the anticipated returned samples from Mars will contain new life forms
1 Read
11 November 2000.
terms geomath or geomathematics (Rasmussen, 1952; Griffiths, 1966; Osborne,
1969; Merriam, 1978) have not gained wide recognition, whereas mathematical geology is
preferred (the International Association of Mathematical Geology was founded in 1968).
Computation and modeling permeate all phases of geology. Thermodynamic calculations
have served as a guide and extension of experimentation on the stability of rocks and minerals;
statistics aid in petrographic and geochemical ratio correlation; the analysis of seismic events
depends on wave mechanics; and the thermal history and dating of the earth require differential
equations. These are but a few examples where mathematical skills are mandatory.
2 The
[ 37 ]
38
Figure 1. Citric acid cycle (Cody et al., 2000) illustrating one of the pathways
for generating energy in a living organism
39
realization that inorganic compounds in the human body are wellknown natural minerals in the earth (Skinner, 2000). Some twentyseven minerals in the human body have been described and analyzed
(Table 1). The solid solutions in hydroxyapatite, the principal calcium
phosphate mineral that constitutes bones, are pertinent to the
strength and flexibility of our limbs. The substitution of F for OH in
the mineral greatly increases the strength of bone; that is, fluoroapatite is a critical member of the solid solution. Most familiar is the efficacy of fluoride-bearing toothpaste that is clearly related to apatite
crystal chemistry. Abnormality in bone formation leads to Pagets
disease (high rate of formation) or rickets (low rate of formation).
The nucleation of hydroxyapatite in the organic matrix of collagen
(ossification) is a relatively new area of investigation (Connor, 1983)
involving both mineralogists and organic chemists. A particularly
fascinating set of bones in the ear called otoliths or ear stones are
attached to hair-like nerve fibers that respond to the action of gravity. The clusters of ear stones in four cavities help us maintain our
equilibrium.
Trace-element biogeochemistry. The trace element content of minerals in the human body is another area deserving of study, particularly
in relation to disease (Xia, 1996). For example, excesses of As, Be, Co,
Cr, and V in soils are listed as carcinogenic (Sensi et al., 1999). Trace
element toxicity has been related specifically to digestive, respiratory,
and reproductive functions (Xia, 1996). On the other hand, Se appears
to play a protective role in reducing cancer mortality, although an
excess of Zn or shortage of Mn may reduce the utilization of Se.
Worldwide studies are essential to establish how trace elements in soils
may influence public health.
Geochemistry
The geochemists could use help in visualizing the complex data set
involving the compositions of rocks. Some ten oxides make up 99.9
percent of the earths crust (Table 2A). These combine to make up the
inorganic compounds called minerals, the assemblages of which are
called rocks (Table 2B). By studying these compounds at various pressures and temperatures it is possible for the experimental petrologist to
outline under what conditions these mineral assemblages can be found
in the Earth. Apparatus now exists for investigating all the conditions
to the center of the Earth where T , 4500C and P , 3.5 Megabars
(Xu et al., 1986; Xu and Mao, 2000). By systematically determining
the physico-chemical relations in the binary systems of paired oxides
initially, it is possible to add additional components, thereby approach-
40
Table 1.
MINERALS IN HUMANS
Carbonates
Calcite
Aragonite
Vaterite
Monohydrocalcite
CaCO3
CaCO3.H2O
Phosphates
Hydroxyapatite
Fluoroapatite
Carbonate-apatite
Monetite
Brushite
Whitlockite
Newberryite
Struvite
Hannayite
Ca10(PO4)6(OH)2
Ca5(PO4)3F
Ca5(PO4,CO3)3(F,OH)
CaHPO4
CaHPO4.2H2O
Ca8Mg(PO4)6
MgHPO4.3H2O
MgNH4PO4.6H2O
Mg2(NH4)2H4(PO4)4.8H2
Halite
Sylvite
NaCl
KCl
Gypsum
Hexahydrate
Epsomite
CaSO4.2H2O
MgSO4.6H2O
MgSO4.7H2O
Whewellite
Weddellite
CaC2O4.H2O
CaC2O4.2H2O
Magnetite
Maghemite
Periclase
Anatase
Fe3O4
g-Fe2O3
MgO
TiO2
Brucite
Mg(OH)2
Urea
CO(NH2)2
Quartz
SiO2
Chorides
Sulphates
Oxalates
Oxides
Hydrates
Organic
Silicates
41
Table 2.
SiO2
Al2O3
CaO
FeO
MgO
Na2O
2.5
2.4
0.9
0.2
0.1
100.0
42
Figure 2A. The binary system SiO2-Al2O3 at one atmosphere (Bowen and
Greig, 1924; Shears and Archibald, 1954)
Cristobalite
Tridymite
Pseudowollastonite
Rankinite
Lime
SiO2
Corundum
Al2O3
CaO?SiO2
3CaO?2SiO2
CaO
Mullite
Anorthite
Gehlenite
3Al2O3?2SiO2
CaO?Al2O3?2SiO2
2CaO?Al2O3?SiO2
43
44
45
way has been one of the great successes in geological research in the
last century.4
The most abundant oxides in the Earths crust are SiO2 and Al2O3.
Figure 2A gives their binary behavior as a function of temperature. In
Figure 2B, CaO has been added to form a ternary system. Its study was
particularly rewarding because it led to an understanding of many
ceramics, and of slag formation in steel making. Another ternary (Fig.
2C) containing MgO-Al2O3-SiO2 is critical to understanding many
basic igneous and metamorphic rocks. To illustrate a four-component
system, the last two ternary diagrams are combined into CaO-MgOAl2O3-SiO2, but only the tie lines of coexisting phases are illustrated
(Fig. 2D). Each of these binary joins and subsidiary ternary diagrams
has been studied. Another way to approach a four-component system
is to take slices at various intervals. One investigator chose a slice at 10
percent MgO, an amount commonly determined in natural rocks, to
investigate the influence of MgO on the system (Fig. 2E). To get at fivecomponent systems, it is customary to combine oxides that form the
end-members of real minerals as the components. The oxides CaO and
MgO are added to SiO2 to form the significant pyroxene end-member
diopside (CaMgSi2O6), and the oxides Na2O and Al2O3 are added to
SiO2 to form the critical mineral nepheline (NaAlSiO4) (Fig. 2F). The
five-component system in Figure 3 is particularly relevant to the
basalts, the most common rock type on the surface of the Earth. A few
attempts have been made to understand a quinary system by projecting
one of the components onto the quaternary system (Fig. 4).
You can see the dilemma of the petrologist: how does one visualize
the even more complex naturally-occurring mineral systems that make
up the rocks observed in the field? Matrices have been applied (Presnall,
1986), but the translation of the matrix into the defining boundary
curves, reaction curves, and eutectics of the phase equilibria system has
not as yet provided a rigorous understanding and appreciation of the
phase relations. Perhaps some of you can give guidance to supplement
the linear algebraic method of representing visually a mineral or a rock
in the natural ten-component system for the Earth.
Social Issues
A plethora of socially oriented issues involves the environment, hazards, resources, climatology, archeology, and agriculture. Concern for
4 The systematic investigation of these systems was undertaken initially at the U.S.
Geological Survey in 1880 and transferred to the Geophysical Laboratory of the Carnegie
Institution of Washington after its establishment in 1905. Most of the high-temperature and
high-pressure research has since been carried out there (Yoder, 1994).
46
akermanite
diopside
enstatite
forsterite
K-mel
Ks
La
Lc
potassium melilite
kalsilite
larnite
leucite
Mo
Sa
Qz
Wo
monticellite
sanidine
quartz
wollastonite
47
these problems has had a dramatic effect on the field of geology. The
most persistent concerns are related to the environment.
Environment. To accommodate the demands of the job market,
some universities have abandoned traditional courses in the field of
geology and substituted courses on the environment. Unfortunately,
that subject is being taught without the substantive geophysics, geochemistry, geomathematics, and geobiology courses needed for a
meaningful understanding of the problem. For example, only a few
geology departments teach fluid dynamics, that is, fluid flow and mass
transport in porous media. Sophisticated computer codes in fluid
dynamics are now available to account even for the heterogeneity of
natural rock formations, and have been successfully applied to oil and
gas reservoirs. These same codes can be applied as well to the flow of
contaminants in water reservoirs, chemical spills, radioactive waste
storage leaks, and effluents from industrial plants. It is obvious that
those problems require knowledge of the entire range of interdisciplinary sciences.
Everyone is well aware of the growing world population, which is
now more than six billion, the need for raising the standard of living of
the developing nations, and the demands of new technologies. We are
asked to achieve these goals, without impacting the environment! A
reasonable compromise will have to be devised to minimize the environmental effects arising from the advance of civilization. Incidentally,
environmentalists can take note of a new process being studied at the
Los Alamos National Laboratory, which reduces emissions from the
burning of coal to almost zero without significant reduction of energy
yield (Lackner, 2000).
Resources. The economies of the world are wholly dependent on
minerals, yet there is little appreciation that these resources are not
renewable and are not infinite (Yoder, 1982). The U.S. already imports
more than 70 percent of its annual requirements of each of about two
dozen major elements of minerals. As lower grades are mined, larger
volumes will be removed (Fig. 5); the problem is to find ways to process low-grade ores using the least amount of energy. The impact of
mining on the environment, condemned by many in spite of reclamation, is still less than the impact of a coast-to-coast federal superhighway! The relative values of mineral resources vs. transport accessibility
vs. farm land vs. natural preservation have yet to be weighed. At
present rates of consumption, it is estimated that all reserves of antimony will run out in twenty-six years, followed by tin, sulfur, bismuth,
and zinc in ninety years (Table 3, Steady State Life Column). These
numbers will be cut in half if the production is increased only 2 percent
in accord with population growth. These are indeed critical and strate-
48
gic elements, yet Congress has voted to sell off our stockpiles! According to the Stockpile Report to the CongressFiscal Year 1999
(Oliver, 2000), the National Defense Stockpile has sold almost a half
billion dollars worth of materials and has neither acquired nor
upgraded any of the commodities annually since 1995. Recycling, substitutes, reductions in demand, and new technologies are not going to
resolve the ultimate consequences of the accelerated use of non-renewable resources.5
The problem is not only being ignored, but further exacerbated by
the closing of the U.S. Bureau of Mines in 1995. The U.S. Geological
Survey was assigned the Bureaus responsibilities of assembling the statistics on mineral commodities, but has closed down its own basic
research programs on ore deposits. A geochemical census, strongly
advocated by the U.S. Geological Survey, has not been supported as it
5 Recognition of this looming catastrophe is not new. Almost fifty years ago the policy
report Resources for Freedom, the Paley Report (1952), was published expressing concern
that the rate of consumption of minerals surpassed the discovery of new deposits. The future
security of the nation was in jeopardy in the view of the commissioned study. Some twentyfive years ago a presentation was sponsored by the American Geological Institute at the
White House in which the prospects of mineral shortages were again spelled out. Next came
the Club of Rome (Meadows et al., 1972) conclusion that population growth and
consumption of resources would produce profound changes in our lifestyle by the middle of
this century. A few years later the Dahlem Workshop (McLaren and Skinner, 1987) projected
increased costs of minerals and increased usage of minerals would lead to changing patterns
in at least fifty years. All these warnings have been ignored and the principal issues of debate
are now on the environmental impact of mining and the sustainability of the present way of
life for future generations.
49
Table 3. Comparison of 1997 world production and reserve base for new
material added to the economy.3
Abundant Commodities
Iron
Sulfur
Aluminum
Potassium
Silicon
Magnesium
Bromine
Scarce Commodities
Phosphorous
Copper
Zinc
Manganese
Chromium
Lead
Titanium
Nickel
Tin
Molybdenum
Antimony
Vanadium
Tungsten
Cobalt
Silver
Bismuth
Mercury
Gold
1997
World
Production
World
Reserve Base
SteadyState Life
550,000
54,000
23,000
20,000
3,200
3,000
470
110,000,000
3,500,000
5,600,000
14,000,000
immense
immense
immense
200 yr.
65
240
700
18,000
11,000
7,800
7,500
3,600
2,900
2,400
1,100
200
130
124
35
32
27
15
3.5
3.0
2.3
4,300,000
1,500,0002
710,0002
11,000,000
2,300,000
350,0002
360,000
140,000
12,000
12,000
3,600
27,000
3,300
9,000
1,7002
260
240
1902
240 yr.
140
91
670
640
120
150
130
60
92
29
770
100
330
110
74
80
83
% in
Average
Rock1
4.8
0.026
8.3
2.09
28
2.33
0.00025
0.12
0.0050
0.0081
0.10
0.0077
0.0013
0.53
0.0061
0.00016
0.00011
0.000045
0.012
0.00012
0.0018
0.0000065
0.00000029
0.000008
0.00000035
All production and reserve base data are in thousands of metric tons of the pure element and are rounded to two
significant figures. Neither recycled scrap nor stockpile contributions are included here.
1 Data for average continental crust from Lee and Yao (1970). Some abundant rock types may contain 10 to
100, or even more, times more than the average for some elements.
2 Data from Singer (1995) for World Discovered Resources.
3 Barton (2000).
has been in South Africa. Only 53 percent of the U.S. has been mapped
geologically at a scale of 1 inch 5 4 miles, a scale not adequate for the
discovery of high-grade element concentrations. Furthermore, plans
for three-dimensional mapping by drilling have been made but not
implemented. The oil companies were briefly fascinated with the mining business. More than half of all domestic copper companies are
in the hands of oil companies. On the other hand, they have closed
the research laboratories of the companies they absorbed (Atlantic-
50
51
rate that exceeds the recharge rate. Attempts to capture the natural
supplies have resulted in antagonism between those who believe dams
on the rivers are the solution and those who object to their effect on
the ecological evolution of the environment. There are about seventyfive thousand dams in the U.S., of which two hundred have been dismantled, and only a few thousand are being considered for removal
because of the sediment release problem. Some 60 percent of the
worlds largest 227 rivers have been dammed, diverted, or channelized,
and half of the worlds wet lands have been lost during the twentieth
century (Revenga et al., 2000). Alternative solutions require energy,
already in short supply. Water quality is indeed at the forefront of
worldwide concerns. According to UNESCO, more than one billion
people do not have access to clean and drinkable water (Matsuura,
2000).
In brief, a national plan to reduce the conflicts that will eventually
emerge in the struggle to acquire the limited accessible resources of the
world should include the following steps:
1. Fulfill the goals of the strategic and critical mineral stockpiles,
public and private, as soon as possible, by exchange, barter, or
private investment, and maintain them as needs change.
2. Insure that the Emergency Mobilization Preparedness Board
has contingency plans for meeting material shortages from
alternative sources, through substitution, recycling, conservation, and technological redesign, and by elimination of nonessential uses.
3. Ascertain the reasons for the demise of the mining industry in
the U.S. and take the necessary actions to sustain at least a
readily expandable and steady domestic mining industry.
4. Encourage each state to undertake an assessment of elements
in surficial natural materials and at depth through drilling
with appropriate sampling techniques.
5. Expand data-collecting agencies concerned with the mineral
production of the world and post professional mineral attachs
in principal supply nations.
6. Maintain and provide for continual economic evaluation of
pilot plants for the development of alternative recovery methods
of strategic elements from unconventional source minerals.
7. Organize a consortium of agencies for mapping the oceanic
areas of the Exclusive Economic Zone, and accelerate the geological mapping of the continental U.S. by expanding the U.S.
and state geological surveys.
8. Develop a prime-minerals, land-use policy, setting aside lands
52
53
54
References
Barton, P. B. 2000. Minerals: Building blocks of civilization. U.S. Geol. Survey Reports
(in press).
Bowen, N. L., and J. W. Greig. 1924. The system: Al2O3-SiO2. Jour. Amer. Ceram. Soc.
7.4: 23854.
Brown, W. 1966. Crystal growth of bone mineral. Clin. Orthoped. 44: 20515.
Butler, M. M. 1941. Geomath. Casper, Wyo.: General Engineering Co., 29 pp.
Claudy, N. H. 1999. Directory of Geoscience Departments, 19992000. American
Geological Institute publication. 634 pp., http://www.agiweb.org.
Cody, G., R. M. Hazen, J. A. Brandes, H. J. Morowitz, and H. S. Yoder, Jr. 2001.
Geochemical roots of autotrophic carbon fixation: Hydrothermal experiments in
the system citric acid - H2O - (6FeS) - (6NiS). Geochim. Cosmochim. Acta 65.20:
355776.
Connor, J. M. 1983. Soft tissue ossification. Springer-Verlag, 145 pp.
Folquer, H. 1939. Geobiologia. Universidad Nacional de Tucumn publication, Inst.
Miner. y Geol. 259.
Frbel, J. 1834. Entwurf eines Systems der geographischen Wissenschaften I. Mittheilungen aus dem Gebiete der Teoretischen Erdkunde 1: 135.
Griffiths, J. C. 1966. Future trends in geomathematics. Mineral Ind. 35. 5: 18.
Hazen, R. M. 2001. Emergence and the origin of life. In Fundamentals on life: Proceedings of the Workshop on Life, ed. G. Palyi. Modena, Italy (Rome: Accademia
Nazionale di Scienze, Lettere ed Arti Press), in press.
Keith, M. L., and J. F. Schairer. 1952. The stability field of sapphirine in the system
MgO-Al2O3-SiO2. Jour. Geol. 60.2: 18186.
Lackner, K. S. 2000. Could fossil energy fuel the next century? Paper read at the American Philosophical Society, November 2000.
Lee, T., and G. L. Yao. 1970. Abundance of chemical elements in the earths crust and
its major tectonic units. Internat. Geol. Rev. 12.7: 77886.
McLaren, D. J., and B. J. Skinner. 1987. Resources and world development. New York:
John Wiley and Sons, 939 pp.
Matsuura, K. 2000. UNESCO embarks on major fresh water initiative. EOS, Trans.
Amer. Geophys. Union 81.38: 434.
Meadows, D. H., D. L. Meadows, J. Randers, and W. W. Behrens. 1972. Limits to
growth; a report for the Club of Romes project on the predicament of mankind.
New York: Potomac AssociatesUniversity Books, 205 pp.
Merriam, D. F. 1978. Geomathematics: Past, present, and prospects. Syracuse University Geology Contribution 5, 74 pp.
Oliver, D. 2000. Strategic and critical materials report to the Congress, Department of
Defense Annual Report, 54 pp., http://www.drms.dla.mil.
Osborn, E. F., and A. Muan. 1960. Phase equilibrium diagrams of oxide systems. Plate
1: The system CaO-Al2O3-SiO2, Amer. Ceram. Soc. Special Publication. Columbus, Ohio.
Osborne, R. H. 1969. Undergraduate instruction in geomathematics. Jour. Geol. Educ.
17.4: 12024.
Paley, W. S. 1952. Resources for Freedom. Washington: U.S. Government Printing
Office, 5 vols., 818 pp.
Presnall, D. C. 1986. An algebraic method for determining equilibrium crystallization
and fusion paths in multicomponent systems. Amer. Mineral. 71: 106170.
55
Prince, A. T. 1954. Liquidus relationships on 10% MgO plane of the system lime-magnesia-alumina-silica. Jour. Amer. Ceram. Soc. 37.9: 40208.
Rait, J. R. 1949. Basic refractories: Their chemistry in relation to their performance.
Iron and Steel 22: 18793.
Rankin, G. A., and H. E. Merwin. 1918. The ternary system MgO-Al2O3-SiO2. Amer.
Jour. Sci., 4th ser. 45: 30125.
Rankin, G. A., and F. E. Wright. 1915. The ternary system CaO-Al2O3-SiO2. Amer.
Jour. Sci., 4th ser. 39: 179.
Rasmussen, W. C. 1952. Yield of ground-water reservoirs calculated by geomathematical analogy. Proc. 25th Ann. Conf. MD-Del. Water Sewage Assoc. Washington,
D.C., pp. 4262.
Revenga, C., J. Brauner, N. Henninger, K. Kassen, and R. Payne. 2000. Plot analysis of
global ecosystems: Freshwater systems. Washington, D.C.: World Resources Institute Pub., 59 pp. http://www.wri.org/wri/wr2000.
Ronov, A. B., and A. A. Yaroshevsky. 1969. Chemical composition of the earths crust.
In The earths crust and upper mantle, ed. P. J. Hart. Amer. Geophys. Union
Monograph 13: 3757.
Schairer, J. F., and H. S. Yoder, Jr. 1960. The nature of residual liquids from crystallization, with data on the system nepheline - diopside - silica. Amer. Jour. Sci., Bradley
Volume, vol. 258A: 27383.
Schnbein, C. F. 1838. Ueber die Ursache der Farbenvernderung, welche manche
Krper unter dem Einflusse der Wrme erleiden. Poggend. Ann. Physik chem. 45:
281.
Senesi, G. S., G. Baldassarre, N. Senesi, and B. Radina. 1999. Trace element inputs into
soils by anthropogenic activities and implications for human health. Chemosphere
39.2: 34377.
Shears, E. C., and W. A. Archibald. 1954. Almino-silicate refractories: Some observations on their chemistry. Iron and Steel 27: 6166.
Singer, D. A. 1995. World class base and precious metal depositsA quantitative analysis. Econ. Geol. 90: 88104.
Skinner, H.C.W. 2000. Minerals and human health. In Environmental Mineralogy, ed.
D. J. Vaughan and R. A. Wogelius, vol. 2, chap. 11, pp. 383412.
Teilhard de Chardin, P. 1943. Geobiologie et Geobiologia. Geobiologia 1: 18.
Tilling, R. I. 1987. Eruptions of Mount St. Helens: Past, present, and future. U.S. Geol.
Survey Report. Washington: U.S. Government Printing Office, 46 pp.
Xia, Y.-M. 1996. Trace elements in health and disease. Biomed. Environ. Sci. 8.2-3:
13036.
Xu, J.-a., H.-k. Mao, and P. M. Bell. 1986. High-pressure ruby and diamond fluorescence: Observations at 0.21 and 0.55 terapascal. Science 232: 140406.
Xu, J.-a., and H.-k. Mao. 2000. Moissanite: A window for high-pressure experiments.
Science 290: 78385.
Yoder, H. S., Jr. 1965. Diopside-anorthite-water at five and ten kilobars and its bearing
on explosive volcanism. Carnegie Instn. Wash. Year Book 64: 8289.
Yoder, H. S., Jr. 1982. Strategic minerals: A critical research need and opportunity.
Proc. Amer. Philos. Soc. 126.3: 22941.
Yoder, H. S., Jr. 1990. Potassium-rich rock diversity and experimentally determined
contiguity. Ann. Rpt., Director of the Geophysical Laboratory, Pub. No. 2200, pp.
7680.
Yoder, H. S., Jr. 1994. Development and promotion of the initial scientific program for
the Geophyscial Laboratory. History of Geophysics, Amer. Geophys. Union 5: 21
28.
Yoder, H. S., Jr., and C. E. Tilley. 1962. Origin of basalt magmas: An experimental
study of natural and synthetic rock systems. Jour. Petrol. 3: 342532.