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Activity 1
1. The relative atomic mass (Ar) of an element is the . mass of one atom of the
. when compared with 1/12 of the mass of an atom of carbon-12.
(ii) How many magnesium atoms will have the same mass as two silver atoms?
[Relative atomic mass: Mg, 24; Ag, 108]
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CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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3. The relative molecular mass (Mr) of a substance is the average of a . of the
substance when compared with 1/12 of the mass of one carbon-12 atom.
5. The term relative molecular mass can only be used for substances that are made up of ....................
For ionic compounds, the term (Fr) is used instead.
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6. The relative formula mass of an ionic compound is calculated by adding up the
of all atoms in its formula.
Example:
(i) Calculate the relative formula mass of sodium chloride.
[Relative atomic mass: Na, 23; CI, 35.5]
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CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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B THE MOLE AND THE NUMBER OF PARTICLES
Learning Outcomes
You should be able to:
define a mole
state the meaning of Avogadro constant
relate the number of particles in one mole of a substance with the Avogadro
constant
solve numerical problems to convert the number of moles to the number of
particles of a given substance and vice versa
Activity 2
1. In chemistry, we use the unit to measure the amount of substance. It has the
symbol
2. One .. is defined as the amount of substance that contains as many particles as the
number of atoms in exactly 12 g of carbon-12. One mole of substance contains
particles.
3. The Avogadro constant, NA is defined as the number of.. in one mole of a substance.
The value of the Avogadro constant is ..
4. 1 mole of atomic substance contains . atoms.
5. 1 mole of molecular substance contains . molecules.
6. 1 mole of ionic substance contains formula units.
7. Relationship between number of moles and number of particles:
Number of moles
x NA
Number of particles
NA
8. Find the number of particles for the substances given the number of moles.
Number of moles
Number of particles
FORM 4 CHEMISTRY
CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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(i) 0.5 mole of carbon
(ii) 0.2 mole of hydrogen gas
Number of moles
FORM 4 CHEMISTRY
CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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Activity 3
1. Molar mass is the mass of one of a substance. It has unit of .
2. The molar mass of a substance is numerically equal to its ,
or
3. The relationship between the number of moles and the mass of a substance:
x Molar mass
Number of moles
Mass (g)
Molar mass
3. Find the mass for the substances given the number of moles.
Number of moles
Mass
Number of moles
FORM 4 CHEMISTRY
CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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(i) 49.2 g of calcium nitrate
(ii) 57.5 g of sodium
(iii) 4.04 g of potassium nitrate
(iv) 70 g of carbon monoxide gas
(v) 4 g of hydrogen gas
(vi) 11.2 g of iron
Learning Outcomes
You should be able to:
state the meaning of molar volume of a gas
relate molar volume of a gas to the Avogadro constant
Activity 4
1. The molar volume of a gas is defined as the ................................ of one ...................................
of the gas.
2. One mole of any gas always has the ........................ under the same temperature and
pressure.
FORM 4 CHEMISTRY
CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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1 mole of
hydrogen
gas, H2
22.4 dm3
at STP
22.4 dm3
at STP
1 mole of
oxygen
gas, O2
22.4 dm3
at STP
1 mole of
nitrogen
gas, N2
x 22.4/24 dm
Molar volume
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Number of moles
Volume of gas
5.
Number of moles
Volume of gas
6.
The
relationships between the number of moles, number of particles, mass and volume of
gases:
Volume (dm3)
Molar
mass
Mass (g)
x Molar
volume
Molar
volume
x NA
Number of moles
Activity 5
1. What is the volume of 12.8 g of oxygen gas, O2, in cm3, at STP?
FORM 4 CHEMISTRY
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[Relative atomic mass: O, 16. Molar volume: 22.4 dm3 mol-1 at STP]
2. How many molecules of carbon dioxide, CO2 are produced when 120 cm3 of the gas is released
during a chemical reaction between an acid and a carbonate at room conditions?
[Molar volume: 24 dm3 mol-1 at room conditions. Avogadro constant: 6.02 x 1023 mol-1]
3. What is the mass of 0.6 dm3 of chlorine gas, CI2, at room conditions?
[Relative atomic mass: CI, 35.5. Molar volume: 24 dm3 mol-1 at room conditions]
4. A sample of nitrogen gas, N2 has a volume of 1800 cm3 at room conditions. What is the mass of the
sample and how many molecules of nitrogen gas, N2 are in it?
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5. 1.12 dm3 of hydrogen gas, H2 and 1.12 dm3 of oxygen gas, O2 are mixed together in a closed container
at STP. What is the total number of molecules in the container? What is the total mass of the gases in
the container?
E CHEMICAL FORMULAE
Learning Outcomes
You should be able to:
state the meaning of chemical formula
state the meaning of empirical formula
state the meaning of molecular formula
determine empirical and molecular formula of substances
compare and contrast empirical formula with molecular formula
solve numerical problems involving empirical and molecular formulae
write ionic formulae of ions
construct chemical formulae of ionic compounds
state names of chemical compounds using IUPAC nomenclature
use symbols and chemical formulae for easy and systematic communication in the field
of chemistry
Activity 6
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FORM 4 CHEMISTRY
CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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1. A chemical formula is a representation of a chemical substance using letters for
and subscript numbers to show the .. of each type of atoms that are present in the
substance.
2.
The letter H
shows the
symbol of
...
atom
H2
Molecular formula
H2O
C2H4
C6H6
C6H8O6
Simplest ratio of
atoms of elements
H:O=2:1
C:H=1:2
C:H=1:1
C:H:O=3:4:3
12
Empirical formula
H2O
CH2
CH
C3H4O3
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8. To determine the molecular formula of a compound, we need to know the ..
and . of the compound.
Activity 7
1. 1.08 g of aluminium combines chemically with 0.96 g of oxygen to form an oxide. What is the empirical
formula of the oxide? [Relative atomic mass: O, 16; Al, 27]
Element
Mass of element(g)
Number of moles of
atoms
Ratio of moles
Simplest ratio of
moles
Empirical formula
2. Copper (II) iodide contains 20.13 % copper by mass. Find its empirical formula.
[Relative atomic mass: Cu, 64; I, 127]
Element
Mass of element(g)
Number of moles of
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atoms
Ratio of moles
Simplest ratio of
moles
Empirical formula
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FORM 4 CHEMISTRY
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5. 8.5 g of hydrogen peroxide contains 0.5 g of hydrogen. If the molar mass of hydrogen peroxide is 34
34 g mol-1, find its molecular formula.
[Relative atomic mass: H, 1; O, 16]
6. Ethanoic acid is an important ingredient of vinegar. The empirical formula of this acid is CH2O. Given
that its molar mass is 60 g mol-1, find its molecular formula.
[Relative atomic mass: H, 1; C, 12; O, 16]
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Activity 8
1. Ionic compounds consist of .. and
2. To construct the chemical formulae of ionic compounds, we need to know the formulae of cations
and anions.
3.
Cation
Formula
Anion
Sodium ion
Fluoride ion
Potassium ion
Chloride ion
Silver ion
Bromide ion
Hydrogen ion
Iodide ion
Ammonium ion
Hydroxide ion
Nitrate ion
Calcium ion
Ethanoate ion
Magnesium ion
Manganate(VII) ion
Aluminium ion
Oxide ion
Zinc ion
Carbonate ion
Barium ion
Sulphate ion
Iron(II) ion
Thiosulphate ion
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Formula
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Iron(III) ion
Chromate(VI) ion
Lead(II) ion
Dichromate(VI) ion
Lead(IV) ion
Phosphate ion
Tin(II) ion
Tin(IV) ion
Chromium(III) ion
17
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5. Construct the chemical formula for each of the following ionic compounds:
Ionic compound
Chemical compound
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Activity 9
1. Chemical compounds are named systematically according to the guidelines given by the International
Union of Pure and Applied Chemistry (IUPAC).
2. For ionic compounds, the name of the cation comes first, followed by the name of the anion.
Cation
Anion
Name of ionic compound
Sodium ion
Chloride ion
Calcium ion
Carbonate ion
Barium ion
Sulphate ion
Certain metals can form more than one type of Thus, Roman numerals are
3.
are used in their naming to distinguish the different types of ions. For example, iron can form 2
cations, namely iron(II) ion and iron(III) ion. Thus, the names of the compounds formed by these
ions with chlorine would be . and
4. For simple molecular compounds, the more element is written last and is added with
an ide. The name of the .. element is maintained. For example, a molecular compounds
consisting of hydrogen and chlorine is given the name .
5. Greek prefixed are used to show the .. of atoms of each element in a compound.
Prefix
MonoDiTriTetraPenta-
Meaning
1
2
3
4
5
Example
Carbon monoxide
Sulphur dioxide
Sulphur trioxide
Carbon tetrachloride
Phosphorus pentachloride
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FORM 4 CHEMISTRY
CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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F
CHEMICAL EQUATIONS
Learning Outcomes
You should be able to:
Activity 10
1. Chemical equation is a precise . of a chemical reaction.
2. The chemical equation can be written in word, but it is more convenient and quicker to use
3. The starting substances are called .. They are shown on the left-hand side of
the equation.
4. The new substances formed are called .. They are shown on the right-hand
side of the equation.
C (s) + O2 (g)
CO2 (g)
Reactants
Product
. in a chemical reaction. This means that the number of atoms before and after a
chemical reaction are the Therefore, a chemical equation must be
.
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(iv) Ammonia gas reacts with oxygen gas to yield nitrogen monoxide gas and water.
(v) Silver nitrate solution is added to calcium chloride solution. Silver chloride precipitate and calcium
nitrate solution are produced.
..
(vi) When solid zinc carbonate is heated, it decomposes into zinc oxide powder and carbon dioxide gas.
.
7. Chemical equations give us the following qualitative information:
(i) ............................
(ii)
8. Quantitatively, the .. in a balanced equation tell us the exact of
reactants and products in a chemical reaction.
2H2 (g)
+
O2 (g)
2 molecules
1 molecule
or
or
2 mol
1 mol
2Cu(NO3)2 (s)
2 formula units
or
2 mol
2H2O (l)
2 molecules
or
2 mol
2CuO (s) + 4NO2 (g) + O2 (g)
2 formula units 4 molecules 1 molecule
or
or
or
2 mol
4 mol
1 mol
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CHAPTER 3: CHEMICAL FORMULAE AND EQUATIONS
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Activity 11
1. Copper(II) oxide, CuO reacts with aluminium according to the following equation.
3CuO (s) + 2Al (s)
Calculate the mass of aluminium required to react completely with 12 g of copper(II) oxide, CuO.
[Relative atomic mass: O, 16; Al, 27; Cu, 64]
2. A student heats 20 g of calcium carbonate, CaCO3 strongly. It decomposes according to the equation
below.
CaCO3 (s)
CaO (s) + CO2 (g)
If the carbon dioxide produced is collected at room conditions, what is its volume?
[Relative atomic mass: C, 12; O, 16; Ca, 40. Molar volume: 24 dm3 mol-1]
22
FORM 4 CHEMISTRY
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3. Hydrogen peroxide, H2O2 decomposes according to the following equation.
2H2O2 (l)
Calculate the volume of oxygen gas, O2 measured at STP that can be obtained from the decomposition
of 34 g of hydrogen peroxide, H2O2.
[Relative atomic mass: H, 1; O, 16. Molar volume: 22.4 dm3 mol-1 at STP]
Find the volume of carbon dioxide released as STP if 42 g of ethene is burnt completely.
[Relative atomic mass: H, 1; C, 12. Molar volume: 22.4 dm3 mol-1 at STP]
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FORM 4 CHEMISTRY
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5. 16 g of copper(II) oxide, CuO is reacted with excess methane, CH4. Using the equation below, find
the mass of copper that is produced.
[Relative atomic mass: O,16; Cu, 64]
4CuO (s) + CH4 (g)
What is the mass of zinc needed to produce 2.4 dm3 of hydrogen gas at room conditions?
[Relative atomic mass: Zn, 65. Molar volume: 24 dm3 mol-1 at room conditions]
24