Académique Documents
Professionnel Documents
Culture Documents
B.E./B.Tech.DEGREEEXAMINATION, NOVEMBERIDECEMBER
2006.
Fourth Semester
Chemical Engineering
CH 242 -
PTrySICAL CHEMISTRY
PARTA-(10
x2=Z}marks)
N.
1.
co
m
Molarconductance
va
Concentration Specificconductance
9.82 f)-1 cm-l
0. 1 I\I
aa
na
1M
Write dorrynthe cell and the half cell reactions in the following reaction.
Zn + HrSOn-+ ZnSOa +Hz
3.
Draw the free enerry profile diagrams for an exothermic and endothermic
reaction based on the activated cornplex theory.
4.
5.
ww
w.
2.
7.
8.
9.
10.
11.
(a)
(i)
co
m
(ii)
Or
(ii)
Explain Hydrogenelectrode.
(i)
(ii)
N.
va
L 2 , (a)
( 10)
(i)
(6)
( 10)
aa
na
(b)
(8)
w.
i,
3.45 x 10-5 at 25"C and
pentoxide (Nzos -+NrOn *]or)
2'
4.87 x 10r at 65.C. Calculate the activation energy for the reaction.
(6)
13.
(a)
(i)
(8)
(ii)
(8)
(i)
(ii)
Draw a representative
system and interpret
ww
(b)
Or
(10)
Or
s 9086
(b) (i)
(ii)
L4.
(a)
(8)
(16)
Or
(b)
15. (a)
(r2)
(i)
(ii)
(r,
(ii)
' (8)
(8)
Or
What are photochemical reactions? How do they differ from dark
(4)
reactions?
(ii)
co
m
(i)
aa
na
va
N.
(b)
ww
w.
s 9086