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a) NaF
b) KCl
c) RbCl
22. Inert pair effect is a charecteristic feature of ------------ elements
a) s-block
b) p- block
c) d- block
d) CsI
d) f- block
a) I3
b) F3
c) Br3d) Cl329. During the hydrolysis of interhalogen compound, the larger halogen forms
a) halide ion
b) oxyhalide ion
c) both a and b d) none
30. Which of the following inert gas is not found in air
a) helium
b) neon
c) krypton
d) radon
31. The element which is extremely toxic in boron family is
a) gallium
b) indium
c) thalium
d) boron
32. The compound with garlic taste is
a) P2O3
b) H3PO3
c) PH3
d) P2O5
33.The compound used as souring agent in the preparation of soft drinks is
b) H3PO4
c) H4P2O7
d) P2O5
a) H3PO3
34. The mixture which is used to prevent bends
a) He/Ne
b) Ar/N2
c) Ar/O2
d) He/O2
35.The compound used to prevent knocking is
b) Pb(OH)2
c) Pb(C2H4)4
d)PbO
a) Pb3O4
36. The catalyst used in the manufacture of polythene is
a) V2O5
b) Cr2O3
c) TiCl4
d) Fe2O3
37.The transition metal which shows zero oxidation state in its compound is
a) Sc
b) Cu
c) Ni
d) Os
3+
38. The magnetic moment in BM for Ti is equal to
a) 2
b)8
c) 3
d) 15
39. Which of the following transition metal is attacked by alkali
a) copper
b) zinc
c) silver
d) chromium
40. Aquaregia contains con.HCl and con. HNO3 in the ratio
a) 3: 9
b) 1:3
c) 3 :1
d) 1: 2
41. 18 carat gold contains ---------- parts by weight of copper
a) four
b) eight
c) six
42. The colour of pottasium dichromate in alkaline solution is
v.c.pradeep kumar M.Sc.,M.Phil.,B.Ed.,
P.G.Assistant /chemistry,
Ramakrishna vidyaalaya mat.hr.sec.school,
Villupuram.
d) eighteen
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a) orange red
b) pink
c) yellow
d) colourless
43. In acidic medium,one mole of K2Cr2O7 gives ------------- atoms of oxygen
a) five
b)one
c) three
d) six
44. Bordeaux mixture contains
a) ZnSO4+ H2SO4
b) CuSO4 + lime
c) AgNO3 + lime
d) CuSO4 + NH4OH
45. The oxidation state of Fe in Fe(CO)5 is
a) +3
b)+2
c) +5
d) 0
46. During smelting process of copper pyrites,the matte formed chiefly contains
a) Cu2S+FeS
b) FeSiO3
c) Cu2S +FeO
d)Cu2S +Cu2O
47. Blister copper contains ---------------% impurities
a) 1
b) 2
c) 3
d) 98
48. Gun metal is an alloy containing
a) Cu+Sn
b) Cu+Zn
c) Cu+Sn+Zn
d) Cu+Sn + Ni
49. The metal used for galvanizing iron sheets is
a) copper
b) chromium
c) siver
d) zinc
50. The compound of transition metal which decompose on exposure to light is
b) CuSO4
c) AgNO3
d) ZnCO3
a)AuCl3
51. Which of the following is a ferromagnetic substance
a) Sc
b) Ti
c) Zn
d) Fe
52. Which of the following are also known as rare earth elements
a) s-block
b) p- block
c) d-block
d) f-block
53. Which of the following has the maximum tendency to act as reducing agent
a) Lu
b) Ce
c) Pm
d) La
54. Which of the following hydroxide is most basic
a) La(OH)3
b) Ce(OH)3
c) Nd(OH)3
d) Lu(OH)3
55. The major constituent of mish metals is
a) cerium
b) lutitium
c) lanthanum
d)neodimium
4+
56. The colour of U ion is
a) red
b) yellow
c) green
d) colourless
57. Uranium exhibits maximum oxidation state in
b) UF6
c) UO2Cl2
d) both b and c
a) UO2
58. The existence of an actinide series analogous to the lanthanide series was postulated by
a) Neils Bohr
b) Mary Curie
c) Henry Becquerel
d) Pierre Curie
59. The actinide which is present as an impurity along with lanthanides in monozite sand is
a) Ac
b) U
c) Th
d) Pu
60. Which of the following is called as lattice compounds
a) simple salt
b) a complex
c) double salt
d) all the above
61. Which serves as a lewis acid in a complex compound
a) Central metal ion
b) ligand
c) cation
d) anion
62. The number of Cl- ions formed by [Cr(H2O)5Cl]Cl2.H2O on reaction with AgNO3 is
a) 1
b) 2
c) 3
d)0
63. Geometrical isomers are not possible for--------complex
a) octahedral
b) tetrahedral
c) square planar
d) none
64. The chelating ligand used to form insoluble complex of Nickel is
v.c.pradeep kumar M.Sc.,M.Phil.,B.Ed.,
P.G.Assistant /chemistry,
Ramakrishna vidyaalaya mat.hr.sec.school,
Villupuram.
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a) en
b) oxine
c) DMG
d) Py
65. The masking agent used to remove a metal ion which would interfere with the analysis of a second
metal ion is
a) en
b) CNc) oxine
d) EDTA
66. If the half life of a substance is 100 sec ,its average life is
a)1.44 sec
b) 50 sec
c)144 sec
d) 100 sec
67. The radioactive decay series finally results in the formation of stable isotope of
a) lead
b) thorium
c) actinium
d) bismuth
68. Nuclear fusion reaction takes place at very high temperature of about
a) 10 K
b) 1010K
c)108 K
d) 10 33 K
69. The isotope used in the detection of eye tumours is
b) 53I131
c) 80Hg197
d) 11Na24
a) 15P32
70. Radio isotopes which are useful in industry and in agriculture is
a) 15P32
b) 27Co60
c) 80Hg197
d) 38Sr90
71. Radio carbon decays by
a) positron decay
b) decay
c) decay
d) none
72. Actinium decay series is known as
a) 4n series
b) 4n+2 series
c) 4n+1 series
d) 4n+3 series
73. In nuclear reactions __________ is / are balanced on both sides
a) mass
b)number of atoms
c) mass number
d) mass & atomic number
74. A fossil will lose half the amount of carbon-14 present in its living state in about
a) 6500 years
b) 5700 years
c) 4700 years
d) 6700 years
75. In radio carbon dating,the age can be determined by knowing the number of _______ particles
emitted per gram per minute
a) +1e0
b)
c)
d) 6C14
76. The wavelength of X-rays is in the order of
a) 108 cm
b) 10-8 m
c) 10-8cm
d) 108 m
77.In Braggs spectromete r method, which of the following are in the ratio 1:2:3
b) sin1: sin2: sin3 c) : :d
d) d1:d2:d3
a) 1: 2: 3
78.In ionic crystals the ions are held by
a) dipole-dipole force
b) coulombic force
c) Vanderwaals force d) all the above
79.The ionic crystal with coordination number equal to four is
a) CsCl
b) FeS
c) ZnS
d) NaCl
80.Elements like silicon and germanium exhibit appreciable conductivity upon addition of impurities as
a) Arsenic
b) Bismuth
c) Boron
d) both a) and c)
81.The crystal used as a three dimentional diffraction grating in Laues experiment is
a) Nickel
b) Zinc sulphide
c) Sodium chloride
d) Cesium chloride
82.The force which occur in all kinds of molecular solids is
a) coulombic force
b) Vanderwaals force c) dipole-dipole force d)all the above
83. The number of cesium chloride units per unit cell of CsCl is
a) 1
b) 2
c) 3
d) 4
84. Glasses are regarded as
a) super cooled liquid
b) amorphous solids c) optically isotropic d) all the above
85. An example for covalent crystals is
v.c.pradeep kumar M.Sc.,M.Phil.,B.Ed.,
P.G.Assistant /chemistry,
Ramakrishna vidyaalaya mat.hr.sec.school,
Villupuram.
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a) ice
b) diamond
c) sodium chloride
d) copper
86. In a fcc arrangement,the corner atoms are A type and those at face centres are B type. The
simplest formula of the compound is
a) AB2
b)A3B8
c)AB3
d) AB4
87. The standard entropies of either elements or compounds at any temperature above 00K is
a) zero
b) positive
c) negative
d) infinite
88. Which of the following will not obey Troutans rule
a) CCl4
b) H2S
c) CHCl3
d) H2O
89. Standard free energies of formation of elements are taken as
a) unity
b) zero
c) infinity
d) none
90.In an equilibrium reaction forward reaction is favoured when
a) Q> Kc
b) Q = Kc
c) Q< Kc
d) none
91. In an equilibrium reaction,if the number of moles of gaseous products are lesser than the number
of moles of gaseous reactants,then
a) Kp > Kc
b) Kp < Kc
c) Kp = Kc
d) none
92. For the dissociation of PCl5 reaction, the degree of dissociation (x) is proportional to
a) P
b) 1/P
c) 1/V
d) Both a and c
93. The optimum temperature maintained in contact process is nearly
b) 300-5000C
c) 400-4500C
d) 700-12000C
a) 500-5500C
+
2Cr3+ + 3I2 + 8H2O is
94. The rate equation for,
2HCrO4 + 6I + 14H
r = k [HCrO4] [I]2 [H+]2 ,the order of the reaction is
a) 1
b) 2
c) 3
d)5
95. For the decomposition of H2O2 reaction,the progress of the reaction is followed by titrating equal
volumes of reaction mixture against standard
a) NaOH
b) HCl
c) KMnO4
d) all the above
96. In acid catalysed hydrolysis of ester,the rate of the reaction is followed by titrating the reaction
mixture against standard
d) all the above
a) NaOH
b) HCl
c) KMnO4
97.The number of moles of water present in 1 litre is
a) 18
b) 1
c) 55.55
d) 1000
98. Keeping the concentration constant,when measured at a temperature 10 K greater than the initial
temperature,the rate becomes
a) Same
b) two times greater c) two times lower
d) ten times greater
99. For Arrhenius equation ,a plot of log k against 1/T gives a straight line with slope equal to
a) Ea/ R
b) Ea/2.303 R
c) Ea/2.303 R
d) -2.303 Ea/R
100. Higher the value of Ea, the rate of the reaction is
a) higher
d) moderate
c) slower
d) zero
101. The time required to complete 1/u th fraction is independent of
a) rate constant
b) initial concentration
c) halflife period
102.Which of the following gases are adsorbed more easily
a) hydogen
b) oxygen
c) chlorine
103. Which of the following process is homogeneous catalysis
a) Habers process b) Contact proces
c) Ostwalds process
v.c.pradeep kumar M.Sc.,M.Phil.,B.Ed.,
P.G.Assistant /chemistry,
Ramakrishna vidyaalaya mat.hr.sec.school,
Villupuram.
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104. The oxidation of sodium sulphite by air is retarded by
a) Glycerine
b) As2O3
c) alcohol
d) H2S
105.In the oxidation of oxalic acid by KMnO4,the auto catalyst is
b) KMnO4
c) MnSO4
d) H2SO4
a) K2SO4
106.The catalytic poison used in contact process is
a) Mo
b) As2O3
c)H2S
d) V2O5
107.The intermediate formed in the catalytic oxidation of SO2 to SO3 in lead chamber process is
a) NO
b) O2
c) NO2
d) SO
108. The promoter used in Boschs process for the manufacture of hydrogen is
a) Nickel
b) Chromic oxide
c) ferric oxide
d) Molybdenum
109.Which of the following is a crystalloid
a) gelatin
b) sugar
c) albumen
d) glue
110. An example for aerosol type of colloid is
a) cloud
b) haze
c)mist
d) all the above
111. Silver chloride can be converted into sol by adding
c)NaOH
d) KOH
a) HCl
b) H2SO4
112.The colour of As2S3 sol is
a) red
b) black
c)yellow
d) colourless
113. Electrodialysis method is not applicable for impurities like
a) urea
b) sugar
c)HCl
d) both a and b
114.The colloid used in curing kalazar is
a) argyrol
b)milk of magnesia
c) colloidal gold
d) colloidal antimony
115.An example for W/O type emulsion is
a) milk
b) butter
c) vanishing cream
d) all the above
116. The emulsifying agent used to stabilise O/W type emulsion is
a) lampblack
b) long chain alcohols
c) protiens
d) all the above
117. Emulsions can be broken into constituent liquids by
a) heating
b) freezing
c) centrifuging
d) all the above
118.An example for semiconductors is
a) benzene
b) glass
c) cobalt oxide
d) none
119.The enthalpy of neutralisation of a strong acid by strong base is equal to
a) 57.32 kJ/mol
b) 22.0 kJ/mol
c) -47 kJ/mol
d) -57.32 kJ/mol
120. Which of the following shows abnormal colligative properties
a) sugar
b)urea
c) NaCl
d) all the above
121.For strong electrolytes,the degree of dissociation() is equal to
a) 0.1
b) 0
c)1.0
d) infinite
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125.The quantity of electricity needed to deposit 1 gm equivalent of Al3+ is
a) 1F
b) 2F
c) 3F
d) 0.5F
126. The degree of dissociation of AgCl is reduced by adding
a) NaF
b) NH4OH
c) NaCl
d) CH3COONa
127.The value of ionic product of water at 298 K is
a) 10 14 mol2dm-6
b) 10 -7 mol2dm-6
c) 10 -14 mol2dm-6
d) 10 7 mol2dm-6
128.Which of the following is not a buffer solution
a) CH3COOH+ CH3COONa b) NH4OH+NH4Cl
c) H2SO4 +Na2SO4
d) none
129.For a buffer solution having equimolar amounts of acid and salt
a) pH= pKa
b)pH = pOH
c) pH = 1
d) pKa = 0
130. The pH of buffer containing equimolar amounts of acetic acid and sodium acetate is
a) 1.0
b) 14.0
c) 4.77
d) 0
131.The pH range of phenolpthalien indicator is
a) 6.8-8.4
b) 3.1-4.4
c) 4.4 6.2
d) 8.3 10
132. The suitable indicator for the titration of CH3COOH Vs NH4OH is
a) methyl orange
b) phenolpthalien
c) phenol red
d)none
133.The carbinol name of sec-butyl alcohol is
a) dimethyl carbinol b) isopropyl carbinol
c) ethyl methyl carbinol
d) trimethyl carbinol
134. The alcohol which is called wood spirit is
a) methyl alcohol
b) ethyl alcohol
c) benzyl alcohol
d) phenol
135. When alcohols are converted to alkyl chlorides by thionyl chloride in presence of pyridine,the
reaction belongs to
b) SN2
c) SNi
d) none
a) SN1
136. In breath analysis test the oxidation state of chromium in potassium dichromate changes from
a) III to IV
b) VI to III
c) III to VI
d) IV to III
137.The alcohol which does not answers iodoform test is
a) ethanol
b) methanol
c) isopropyl alcohol
d) none
138. Denatured spirit is ethanol containing
a) 95% methanol
b) 5% water
c) 5% methanol
d) 95% water
139. Diols are isomeric with
a)di ethers
b) aldehydes
c) hydroxy ethers
d) both a) and c)
140. The molecular formula for stearic acid is
b) C17H35COOH
c) C15H31COOH
d) C16H33COOH
a) C17H33COOH
141.Glycerol reacts with metallic sodium at high temperature to give
a) monosodium glycerolate b)disodium glycerolate c) trisodium glycerolate
d)all the above
142.Glycerol forms mesoxalic acid with
a) con HNO3
b) FeSO4/H2O2
c) bismuth nitrate
d) KMnO4
143.Glycerose is a mixture of glyceraldehyde and
a) mesoxalic acid
b) tartronic acid
c) dihydroxy acetone
d) oxalic acid
c) cresols
d) both b) and c)
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a) phenyl benzoate
b) benzyl acetate
c) phenyl acetate
d) benzyl benzoate
146.The compound used in the treatment of asthma is
a) phenyl benzoate
b) benzyl acetate
c) phenyl acetate
d) benzyl benzoate
147.The IUPAC name of Pyrogallol is
a) 1,2,3 trihydroxy benzene b)1,2,4 trihydroxy benzene c)1,3,5 trihydroxy benzene d) none
148. The compound which dissolves in sodium hydroxide but not in sodium bicarbonate is
a) ethyl alcohol
b) benzyl alcohol
c) phenol
d) acetic acid
149. Phenols are stronger acids than
a) alcohols
b) mineral acids
c) carboxylic acids
d) carbonic acids
150.Which of the following is most acidic
a) p-nitro phenol b) phenol
c) p-cresol
d) p-amino phenol
151.The main product obtained in the reaction of phenol with PCl5 is
a) C6H5Cl
b) POCl3
c) (C6H5O)3PO
d) HCl
152.Bakelite is a polymer of phenol and
a) methanal
b) ethanol
c) formic acid
d) none
153.The number of ether isomers posible for a compound with molecular formula C3H8O is
a) 1
b)3
c) 2
d)4
154.The intermediate formed in the reaction of alkyl halides with dry silveroxide is
a) R-O-X
b) R-O-Ag
c) AgX
d) R-O- R
155. Ethers do not react with
a) acids
b) alkalies
c) Sodium
d) all the above
156. Which of the following is used as a solvent for Grignard reagent
a) alcohol
b)water
c) ether
d) all the above
157. The alkyl halide formed in the reaction of HI with C2H5-O-CH3
a) C2H5I
b) CH3I
c) both a and b
d)none
158.The reagent used in Ziesels method is
a) KMnO4
b) PCl5
c) BF3
d) HI
159.Ziesels method is used to detect which of the following groups in alkaloids
b) Oc) OCH3
d) all the above
a) CH3
160. Which of the following is used as a medium in the preparation of Grignard reagent
a)CH3 O C2H5 b) C2H5 O CH3
c) C2H5 O C2H5
d) C3H7 O C2H5
161.Which is not formed in the reaction of anisole with HI
a) phenol
b) methyl iodide
c) iodobenzene
d)none
162. Pyridoxal an aldehyde is derived from
a) vitamin D
b)vitamin B12
c) vitamin K
d)vitamin B6
163.Aldehydes are functional isomers of
a) ketones
b) carboxylic acids
c) unsaturated alcohols
d) both a and c
164.The product in Rosenmund reduction in the absence of BaSO4 is
a) acid chloride
b) aldehyde
c) primary alcohol
d) ketone
165.Which of the following cannot be prepared by Rosenmund reduction
a) acetaldehyde
b) formaldehyde
c)benzaldehyde
d) none
166.The reaction used to locate the position of double bond is
a) Haloform reaction
b) hydrolysis
c) oxidation
167. Which of the following is least reactive carbonyl compound
v.c.pradeep kumar M.Sc.,M.Phil.,B.Ed.,
P.G.Assistant /chemistry,
Ramakrishna vidyaalaya mat.hr.sec.school,
Villupuram.
d)ozonolysis
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a) H-CHO
b)R-CHO
c)R-CO-R
d) R-O-R
168.Aldol on heating forms
a) acrolien
b)cinnamaldehyde
c) crotonaldehyde
d) allyl alcohol
169. A cyanohydrin of a compound X on hydrolysis gives mandelic acid. The X is
a) HCHO
b) CH3CHO
c) (CH3)2 CO
d) C6H5CHO
170. The electron source used in Clemmenson reduction is
a) mercury
b) zinc metal
c)HCl
d) aldehyde
171.The intermediate formed in Wolff kishner reduction is
a) alkanes
b)hydrazine
c) ketone
d) hydrazone
172.The compound used as a hypnotic under the name hypnone is
a)acetone
b)benzophenone
c)acetophenone
d)acetaldehyde
173.The compound which does not form addition product with sodium bisulphite is
a)acetone
b)benzophenone
c)acetophenone
d)acetaldehyde
174.Which of the following is obtained from Laurel oil
a) C3H7COOH
b) C11H23COOH
c) C4H9COOH
d) CH3COOH
175.The acid which undergo intermolecular dehydration is
a) formic acid
b)succinic acid
c) acetic acid
d) all the above
176.The stable product formed when formic acid reacts with PCl5 is
b)HCOCl
c)C6H5COCl
d) HCl+CO
a) CH3COCl
177.The reagent used to convert CH3COOH CH3-CH3 is
a) LiAlH4
b) H2/Ru
c) HI/P
d) NaOH/CaO
178. The acid used in the treatment of gout is
a) acetic acid
b) oxalic acid
c) salicylic acid
d) formic acid
179.The acid which undergo haloform reaction is
a) acetic acid
b) formic acid
c) lactic acid
d) salicylic acid
180.The acid which is used as urinary antiseptic is
a) acetic acid
b) formic acid
c) benzoic acid
d) salicylic acid
181.Which is the most reactive derivative of carboxylic acid
a) ester
b) amide
c) acid chloride
d) acid anhydride
182.Which of the following compound is used as soldering flux
a) acetyl chloride b) acetamide
c) methyl acetate
d) acetic anhydride
183. Which of the following does not exhibit tautomerism
b) (CH3)2CH-NO2
c) CH3-NO2
d) (CH3)3C-NO2
a) CH3CH2-NO2
184. Nitro alkanes are functional isomers of
a) Amines
b) alkyl nitrites
c) Alkyl cyanides
d) Aldehydes
185.Which of the following is insoluble in NaOH
a) 2-nitro propane
b) Nitro ethane c) 1-nitro propane
d) 2-nitro 2-methyl propane
186.Which of the following is a stronger base
a) methyl amine
b) Dimethyl amine
c) Benzyl amine
d) Trimethyl amine
187.Which of the following gives secondary amines on reduction
a) Nitro methane b) methyl cyanide
c) Acetamide
d) methyl isocyanide
188. The electron deficient species formed during Hoffmann bromamide reaction is
a) Carbene
b) diazonium ion
c)Nitrene
d) Carbonium ion
v.c.pradeep kumar M.Sc.,M.Phil.,B.Ed.,
P.G.Assistant /chemistry,
Ramakrishna vidyaalaya mat.hr.sec.school,
Villupuram.
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189.The compound which has fishy odour is
a) Nitrobenzene
b) Nitriles
c) Amines
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a) starch
b) glucose
c) inulin
211.Cellulose on boiling with dil.H2SO4,gets completely hydrolysed to
a) D-glucose
b) L-fructose
c) d- fructose
212.In protiens amino acids are linked through ----------linkage
a) pepdide
b) amide
c) glycosidic
213.In acidic solution an amino acid exists in the form of
a)cation
b) zwitter ion
c) anion
214.Which of the following is a phospholipid
a) wax
b) fat
c) cephalin
215.Which lipid is involved in the organisation of cell structure
a) cephalin
b) lecithin
c) glycolipid
216.Which lipid has been implicated in the process of blood coagulation
a) cephalin
b) lecithin
c) glycolipid
d) cellulose
d) L- glucose
d) ester
d) neutral molecule
d) all the above
d) fat
d) fat
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ANSWER KEY
Q.NO
ANS
Q.NO
ANS
Q.NO.
ANS
Q.NO
ANS
Q.NO
ANS
Q.NO
ANS
Q.NO
ANS
25
49
73
97
121
145
26
50
74
98
122
146
27
51
75
99
123
147
28
52
76
100
124
148
29
53
77
101
125
149
30
54
78
102
126
150
31
55
79
103
127
151
32
56
80
104
128
152
33
57
81
105
129
153
10
34
58
82
106
130
154
11
35
59
83
107
131
155
12
36
60
84
108
132
156
13
37
61
85
109
133
157
14
38
62
86
110
134
158
15
39
63
87
111
135
159
16
40
64
88
112
136
160
17
41
65
89
113
137
161
18
42
66
90
114
138
162
19
43
67
91
115
139
163
20
44
68
92
116
140
164
21
45
69
93
117
141
165
22
46
70
94
118
142
166
23
47
71
95
119
143
167
24
48
72
96
120
144
168
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ANS
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ANS
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ANS
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174
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