Regd No:

Total No. of Questions -21

Total No. of printed Pages -2
CHEMISTRY, PAPER -II
(English Version)
Time : 3 Hours

Max.Marks:60

Note : Read the following instructions carefully :

Answer all the questions of section A. Answer any Six questions of section B and any Two
questions from section C
1. In section -A questions from sr.no 1 to 10 are Very Short Answer type. Each question carries
2 marks. Every answer may be limited to two or three sentences. Answer all these questions
at one place in the same order.
2. In section - B, questions from sr.no 11 to 18 are Short Answer Type. Each

question carries

four marks. Every answer may be limited to 75 words.

3. In section C, questions from sr.no 19 to 21 are of Long Answer Type. Each question carries
8 marks. Every answer may be limited to 300 words.
4. Draw labeled diagrams wherever necessary for questions in section B and Section C
SECTION -A
Note : Answer all the questions
1. Give the complete name for PHBV. How it is useful?
2. What is insulin?
3. What is Cholesterol?
4. What are artificial sweetening agents? Give one example.
5. What is Brownian movement?
6. What is emulsifying agent? Give one example.
7. Define anti-histamines. Give one example.
8. Give the composition and uses of Nichrome.
9. Define order of reaction
10. Write Hell Volhard Zelinsky reaction with equation.

SECTION B
Note : Answer ANY SIX questions.
11. Explain Schottky and Frenkel defects in solids.
12. State and explain Raoults law.
13. State Faradays laws of Electrolysis.
14. How is bauxite purified by serpecks process?
15. Give balanced equations and principle involved in the manufacture of Nitric acid by Ostwald
process?
16. Calculate the EAN of the following central metals in their respective complexs
a) [Cu(NH3)4](OH)2

b) K4[Fe(CN)6]

17. Explain a) clemensen reduction

b) williamsons synthesis
18. Define Molality. How many grams of Na2CO3 should be dissolved in 250 grams of water to
prepare 0.1 m solution
SECTION C
19. a) Give any three oxidation reactions of Ozone with chemical equations
b) How chlorine is prepared and write their chemical properties
20. Write the preparation method of Nitro-Benzene. Explain any three reduction properties of
Nitro-benzene with equations
21. a) State Kohlrauschs law of independent migration of ions with example.
c) Calculate equivalent conductivity for CaCl2 and MgSO4 from the given data
-

Ca+2= 119.0 s cm2 mol-1, Cl = 76.3 s cm2 mol-1

2-

Mg+2= 106.0 s cm2 mol-1, SO4 = 160.0 s cm2 mol-1

Regd No:

Total No. of Questions -21

Total No. of printed Pages -2
CHEMISTRY, PAPER -II
(English Version)
Time : 3 Hours
Note : Read the following instructions carefully :

II

Max.Marks:60

Answer all the questions of section A.

Answer any six questions of section B and any two questions from section C
1. In section -A questions from sr.no 1 to 10 are Very Short Answer type. Each question carries
two marks. Every answer may be limited to two or three sentences. Answer all the questions
at one place in the same order.
2. In section - B, questions from sr.no 11 to 18 are Short Answer Type. Each

question carries

four marks. Every answer may be limited to 75 words.

3. In section C, questions from sr.no 19 to 21 are of Long Answer Type. Each question carries 8
marks. Every answer may be limited to 300 words.
4. Draw labeled diagrams wherever necessary for questions in section B and Section C
SECTION -A
Note : Answer all the questions
1. Define order of reaction
2. Give the composition of Brass
3. What is PHBV? How is it useful to man?
4. Give the deficiency disease caused by A,D,E,K Vitamins.
5. Give two biological functions of lipds
6. What are antibiotics? Give two example
7. What are food preservatives? Give example
8. What is williamsons synthesis? Give equation
9. Write HVZ reaction with equation.
10. The reactant A is reduced to Azobenzene with LiAlH4. What is A? Give equation?

SECTION B

II. Answer any SIX of the following questions

11.What is doping? What are n-type and p-type semiconductors?

12.Give Nernst equation. Calculate the electrode potential of the following single
electrode Cu++(C=0.01 M)/Cu; (Eo = +0.337V)
13.What is emulsion? How are emulsions classified? Give examples
14.Write about a) roasting b) calcination
15.Draw Werners structures of the following
a) CoCl3.6NH3
b) CoCl3.5NH3
c) CoCl3.4NH3
d) CoCl3.3NH3
16. Give the reactions of ozone with the following and give equations
i.
PbS
ii. SnCl2/HCl
iii) Moist KI
iv) BaO2
17. How does ethyl alcohol react with the following? Write equations
i.
Metallic Na ii. CH3COOH iii) CH3MgI iv) con H2SO4 at 170oc
18. Define molality. How many grams of Na2CO3 should be dissolved in 250 grams of
water to prepare 0.1 m solution
SECTION C
III. Answer any Two of the following questions
19. A. Define rate of reaction. Explain the factors which influence rate of reaction
B. A current of 10 amp is passed through molten AlCl3 for 96.5 seconds. Calculate the
mass of Al deposited at cathode ( At.wt Al=27)
20. a. How is Cl2 obtained in laboratory? How does it react with a) cold dil NaOH b) KI
b. How is ozone prepared from oxygen? Explain its reactions
21. a. Explain sandmayer reaction carbylamines reaction
b. Explain cannizzaro reaction and decarboxylation

Regd No:

Total No. of Questions -21

Total No. of printed Pages -2

CHEMISTRY, PAPER -II

(English Version)
Time : 3 Hours

III
Max.Marks:60

Note : Read the following instructions carefully :

Answer all the questions of section A.
Answer any Six questions of section B and any Two questions from section C
1. In section -A questions from sr.no 1 to 10 are Very Short Answer type. Each question carries
2 marks. Every answer may be limited to two or three sentences. Answer all these questions
at one place in the same order.
2. In section - B, questions from sr.no 11 to 18 are Short Answer Type. Each

question carries

four marks. Every answer may be limited to 75 words.

3. In section C, questions from sr.no 19 to 21 are of Long Answer Type. Each question carries
Eight marks. Every answer may be limited to 300 words.
4. Draw labeled diagrams wherever necessary for questions in section B and Section C
SECTION -A
Note : Answer all the questions
1. State Raoults law.
2. Calculate the Spin Only magnetic moment of Fe+2 ion?
3. How is change in gibs energy related to the e.m.f of a galavanic cell?
4. Give two examples for gaseous first order reactions?
5. Ammonia is a good complexing agent- with an example
6. What is tailing of mercury? How is it removed?
7. What is the difference between Buna-N and Buna-S?
8. What is Biodegradable polymer? Give one example of a biodegradable polyester?
9. What are enantiomers
10. How do you covert aniline to p-bromoaniline?

SECTION B
11. Derive Braggs equation?
12. Define mole fraction. Calculate the mole fraction of sodium hydroxide in 10%(w/w) NaOH
solution
13. What is catalysis? How is catalysis classified? Give two examples for each type?
14. Explain the purification of sulphide ore by froth floatation method?
15. What are hormones? Give an example for each of the following
a. Steroid hormones b. Polypeptide hormones c. amino acid derivate
16. Write short notes on a. analgesics and b. food preservatives
17. Explain Werners theory of coordinate compounds with suitable examples?
18. Explain a. Aldol condensation b. coupling reactions
SECTION C
19. A. State and explain Kohlrauschs law of independent migration of ions?
B. What is rate equation? How is it obtained? Write rate equations for the following
i. 2 NO (g) + O2 (g) 2NO2 (g) ii. CHCl3 + Cl2 CCl4 + HCl
iii. CH3COOC2H5 + H2O CH3CHOOH + C2H5OH
20. A. What are inter-halogen compounds? Give some Examples to illustrate the definition how
they are classified?
B. Explain the shape of XeOF4 on the basis of VSEPR Theory?
21. A. Explain the acidic nature of phenols and compare it with that of alcohols?
B. Give the structures of A,B and C in the following reaction
C6 H5N2Cl ---------------- A ---------- --- B ------------ C