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Board of Intermediate Education

Senior Inter - Chemistry
Model Paper (English Version)
Time: 3 Hours

Max. Marks: 60
SECTION - A

Note: 1) Very Short Answer type questions.

10 2 = 20

2) Answer ALL questions.

1.
2.

3.
4.
5.
6.
7.
8.
9.
10.

What are "Tetrahedral holes" and "Octahedral holes"?

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X - rays of wave length equal to 0.134 nm gave a first order diffraction from the
surface of a crystal. The value was found to be 10.5C. Calculate the distance
between the planes in the crystal.
Give the composition of "Brass" and "Nichrome".
What is "Poly Dispersity Index"?

What is "Aspirin"? How it is prepared?

What are "Hormones"? Give two examples.

Give two biological functions of lipids.
What are artificial sweetening agents?

What is "Chloropicrin"? How is it formed from CHCl3?

Complete the following:

Red P4
a) CH3COOH
Cl2

Zn-Hg
b) CH3COCH3
Conc. HCl

SECTION - B

Note: 1) Short Answer type questions.

2) Answer any SIX questions.

6 4 = 24

11.

Define "Molarity". Calculate Molarity and Normality of a dibasic acid solution

(Mol. wt. = 132) having 33g. of the acid in 400 ml.

12.

State Faraday's second law of electrolysis. At 25C, at infinite dilution, Equivalent Conductance of CH3COONa, HCl and NaCl are 91, 426, 126 ohm1 cm2
respectively. Calculate of CH3COOH.

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13.

What is "salt hydrolysis"? What is the nature of aqueous solution of sodium

acetate? Give equation.

14.

What is Catalysis? How is Catalysis classified? Give an example of each.

15.

State Hess law of constant heat summation and give its applications.

16.

How is white Bauxite purified by Serpeck's process?

17.

a) Give the structure of P4O10.

b) What is Nitrolim? How is it prepared?

18.

Give the Werner structures for the following complex compounds

a) CoCl3. 6 NH3

b) CoCl3. 5 NH3

c) CoCl3. 4 NH3

d) CoCl3. 3 NH3

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SECTION - C

2 8 = 16

Note: 1) Long Answer type questions.

2) Answer any TWO of the following.

19.

a) How is Cl2 prepared in Nelson Cell?

b) Give the reactions of Ozone with the following:

i) Hg

20.

ii) SnCl2

iv) H2O2

State Lechatlier's principle and apply it to the following equilibrium.

N2 (g) + 3 H2 (g)

21.

iii) SO2

2 NH3 (g) + Heat energy

Write one method of preparation of Nitro Benzene in the laboratory. What are
the products formed when Nitro Benzene undergoes reduction in
i) Acid Medium

ii) Alkaline Medium

iii) Neutral Medium

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ANSWERS
SECTION - A
1.

What are 'Tetrahedral holes' and 'Octahedral holes'.

Ans: A hole formed between four spheres when they are arranged tetrahedrally are
called 'tetrahedral holes', where as a hole formed between six spheres when they
are arranged octahedrally are called 'octahedral holes'.
2.

X-rays of wave length equal to 0.134 nm gave a first order diffraction from
the surface of a crystal. The value was found to be 10.5. Calculate the
distance between the planes in the crystal.

Ans: n = 2d sin

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n
1 0.134
d = = = 0.3677 nm.
2 sin
2 0.1822

3.

Give the composition of 'Brass' and 'Nichrome'.

Ans: Brass: 60 - 80% Cu,

20 - 40% Zn

Nichrome: 60% Ni, 25% Fe, 15% Cr.

4.

What is 'Poly Dispersity Index'?

Ans: The ratio of weight average molecular weight Mw and the number average

molecular weight Mn of a polymer.

Mw
P.D.I. =

Mn
5.

What is 'Aspirin'? How is it prepared?

Ans: Aspirin is acetyl salicylic acid. It can be prepared by acetylation of salicylic

acid with acetic anhydride.
OH + CH3CO. O. COCH3
OCOCH3
COOH

COOH

CH3COOH

Aspirin
6.

What are 'Hormones'? Give two examples.

Ans: Carbon compounds that transfer biological information from one group of cells
to distinct organs in human body are called hormones.
e.g.: Insulin, Testosterone.

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7.

Give two biological functions of lipids.

Ans: Lipids are energy sources.

8.

Lipids are food reserves.

What are artificial sweetening agents?

Ans: The chemical substances not only controls the intake of calories but also gives
sweet taste.
e.g.: Sucralose, Saccharin.
9.

What is 'Chloropicrin'? How is it formed from CHCl3?

Ans: Nitro Chloroform is is called Chloropicrin. It is formed when CHCl3 reacts with
the vapours of HNO3.
C H Cl3

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+ HO NO2 CCl3NO2 + H2O

10.

Complete the following.

Red P4
a) CH3COOH
Cl2

Zn Hg
b) CH3COCH3
Conc. HCl

Red P4
Red P4
Ans: a) CH3COOH CH2Cl COOH
HCl
+ Cl2
HCl
+ Cl2

ZnHg
b) CH3 C O CH3 CH3CH2CH3 + H2O
H2 H2
Conc. HCl

SECTION - B

11.

Define molarity.

Calculate molarity and normality of a dibasic acid solution (Mol. wt. 132)
having 33 g. of the acid in 400 ml.

Ans: Number of gram moles of solute present in one litre solution is called molarity (M).
Wt. of solute
1000
M =
Gram wt. of solute
Vol. of solution (ml)
33
1000
Molarity (M) = = 0.625 M
132
400
Wt. of solute
1000
Normality (N) =
G.Eq. wt. of solute
Vol. of solution (ml)
33
1000
= = 1.25 N.
66
400

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State Faraday's second law of electrolysis. At 25C, at infinite dilution,
Equivalent Conductance of CH3COONa, HCl and NaCl are 91, 426, 126
ohm1 cm2 respectively. Calculate of CH3COOH.

Ans: When the same quantity of electricity is passed through different cells
containing fused or aqueous electrolytes, connected in series, the mass of substances deposited (or dissolved or liberated) at electrodes are in the ratio of their
equivalent weights.

12.

e.g.: m Cu : m Ag : m H2 = ECu : EAg : E H

CH COOH = C H COONa + HCl NaCl

3
2 5
= 91 + 426 126

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= 391 ohm1 cm2.

13.

What is 'salt hydrolysis'? What is the nature of aqueous solution of Sodium

acetate? Give equation.

Ans: Anion or Cation or both of a salt reacts with water to give OH ions or H ions
or both is known as salt hydrolysis. The nature of sodium acetate solution is
alkaline, as it under goes anionic hydrolysis.

CH3COO + H2O CH3COOH + OH

Kw
Kh =
Ka

14.

What is Catalysis? How is Catalysis classified? Give an example of each.

Ans: The phenomenon of changing the rate of a reaction by a substance (without

consuming) is known as Catalysis.
1) Homogeneous catalysis: The catalysis in which the catalyst and the
reactants are in the same phase.
NO (g)

e.g.: 2 SO2 (g) + O2 (g)

2 SO3 (g)

2) Heterogeneous catalysis: The catalysis in which the catalyst and reactants

are in different phases.
Fe (s)
e.g.: N2 (g) + 3 H2 (g)

15.

2 NH3 (g)

State Hess law of constant heat summation and give its applications.

Ans: The heat of the reaction remains same whether the reaction takes place in a
single step or many steps.

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1
e.g.: C (graphite) + O2 (g) CO (g); H = 110.5 K.J.
2
1
CO (g) + O2 (g) CO2 (g); H = 283.0 K.J.
2

C (graphite) + O2 (g) CO2 (g); H = 393.5 K.J.

Applications: Lattice energy or electron affinity can be calculated.

Heat of transformation can be calculated.

16.

How is white Bauxite purified by Serpeck's process?

Ans: The powdered white Bauxite (containing SiO2) is mixed with coke and heated
in N2 gas. The reactions occurred are

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SiO2 + 2 C Si + 2 CO

Al2O3 + 3 C + N2 2 Al N + 3 CO

Al N on hydrolysis gives Al(OH)3

Al N + 3 H2O Al(OH)3 + NH3

Al(OH)3 is filtered, washed and ignited to get pure Al2O3

1200C
2 Al(OH)3 Al2O3 + 3 H2O

17.

a) Give the structure of P4O10

b) What is Nitrolim? How is it prepared?

Ans: a) Four Oxygen atoms are surrounded by each P atom.

O

P
O

O P

PO

O
O
O
b) The mixture of Calcium Cyanamide and graphite is called Nitrolim. It is
formed when CaC2 reacts with N2 at 1273 1373 K.
1273 1373 K
CaC2 + N2 CaCN2 + C
(graphite)

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18.

Give the Werner structures for the following complex compounds.

Ans:

a) CoCl3. 6 NH3

b) CoCl3. 5 NH3

c) CoCl3. 4 NH3

d) CoCl3. 3 NH3

a)
Cl
H3N

NH3

Co+3

b)
NH3

H3N
Cl

Cl

Co+3

NH3
Cl

Cl
H3N

NH3

Cl

H3N

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NH3

c)

NH3

Cl

H3N

d)

NH3

Co+3

H3N

Cl

H3N

Cl

NH3

Co+3

Cl

NH3

Cl

SECTION - C

19.

NH3

Cl

NH3

a) How is Cl2 prepared in Nelson Cell?

b) Give the reactions of Ozone with the following.

i) Hg

ii) SnCl2

iii) SO2

iv) H2O2

Ans: a) Nelson Cell consists perforated "U" shaped

steel tube having thin lining of asbestos inside
acts as cathode. Brine solution (aqueous NaCl) is
taken in this steel tube as an electrolyte. A
graphite rod suspended in this solution acts as
anode.

This "U" shaped tube is placed in iron tank.

Steam is passed from bottom to clear pores and keep
the substances hot. On passing electricity, Cl2 is liberated at anode. Na+ ions pass through pores and reacts
with steam to form NaOH & H2.

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Reactions in the cell:
2 NaCl 2 Na+ + 2 Cl- (Ionization)
At Anode: 2 Cl- Cl2 + 2 e- (oxidation)
At Cathode: 2 H2O + 2 e- 2 OH- + H2 (reduction)
2 Na+ + 2 OH- 2 NaOH
NaOH is collected in catch basin and concentrated further.
b) (i) O3 reacts with Hg to give mercurous oxide.
2 Hg + O3 Hg2O + O2 (Tailing of mercury)
(ii) Ozone oxidises SnCl2 to SnCl4
3 SnCl2 + 6 HCl + O3 3 SnCl4 + 3 H2O

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(iii) Ozone oxidises SO2 to SO3
3 SO2 + O3 3 SO3

(iv) O3 reduces H2O2 to H2O

H2O2 + O3 H2O + 2 O2.

20.

State Lechatlier's principle and apply it to the following equilibrium.

N2 (g) + 3 H2 (g)

2 NH3 (g) + Heat energy

Ans: "If a system at equilibrium is disturbed either by change in concentration,

temperature or pressure, then the equilibrium shifts towards the direction in
which that effect nullified or minimised".
Effect of pressure:

Increase of pressure: A high pressure (200 atm) is favoured as equilibrium

shifts in forward direction (from more number of moles side to less number of
moles side) and gives more NH3.
Decrease of pressure: If pressure is decreased, equilibrium shifts in backward
direction, i.e. dissociation of NH3 takes place.

Effect of Temperature:

Increase of Temperature: An optimum temperature 725 - 775 K favours

forward reaction to give more NH3.
Decrease of temperature: It is exothermic reaction, decrease of temperature
favours, but rate of reaction is slow. Practically optimum temperature is used to
get more NH3.

Effect of Concentration:
Addition of N2 & H2: Favours forward reaction, equilibrium shifts in forward
direction to give more NH3.

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Removal of N2 & H2: Equilibrium shifts in backward direction, dissociation of
NH3 takes place.
Addition of NH3: Equilibrium shifts in backward direction, dissociation of
NH3 takes place.
Removal of NH3: Favours forward reaction, equilibrium shifts in forward
direction to give more NH3.
Optimum conditions:
Pressure: 200 atm (High pressure)
Temperature: 725 K - 775 K (Optimum temperature)
Concentration: Addition of N2 & H2, removal of NH3

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Catalyst: Finely powdered iron.
Promoter: Mo

21.

Write one method of preparation of Nitrobenzene in the laboratory. What

are the products formed when Nitrobenzene undergoes reduction in
i) Acid medium

ii) Alkaline medium

iii) Neutral medium.

Ans: Preparation: Benzene on Nitration below 60C gives Nitrobenzene.

Conc. H2SO4
C6H5 H + HO NO2 C6H5NO2 + H2O
< 60C

Properties:

i) In acid medium, it is reduced to aniline.

NH2

NO2

Zn
+ 6 (H) O + 2 H2O
HCl

ii) In alkaline medium, it is reduced to hydrazo benzene.

O

NO2 + 10 (H) + O2 N

Zn
O
Alc. KOH

NN

+ 4 H2O

H H
iii) In neutral medium, it is reduced to N-phenyl Hydroxyl amine.
NO2
O

NHOH
Zn
+ 4 (H) O + H2O
HCl

Prepared by A.N.S. Sankara Rao

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