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5070/01
CHEMISTRY
Paper 1 Multiple Choice
May/June 2009
1 hour
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An inflated balloon goes down because gas molecules can diffuse through the rubber.
Four balloons are filled with different gases at the same temperature and pressure.
Which balloon would go down quickest?
methane, CH4
nitrogen, N2
oxygen, O2
black
blue
brown
green
red
Black ink can be made by mixing green, red and yellow inks.
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yellow
3
3
The oxidation of ethanol to ethanoic acid is often carried out in the apparatus shown.
condenser
water
ethanol +
oxidising agent
heat
What is the purpose of the condenser?
A
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The diagram shows copper(II) oxide being reduced, by hydrogen, to copper. After reduction is
complete, the burner is turned off but the flow of hydrogen is continued until the tube is cool.
excess hydrogen
dry
hydrogen
copper(II) oxide
burner
Why is the hydrogen allowed to flow through the tube during cooling?
A coin is analysed by dissolving it in nitric acid. To the resulting solution an excess of aqueous
ammonia is added and the mixture is filtered.
A brown precipitate remains in the filter paper and a deep blue solution is obtained as the filtrate.
Which metals does the coin contain?
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17
18
19
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ammonium chloride
carbon dioxide
ethyl ethanoate
sodium chloride
2 g of hydrogen
14 g of nitrogen
32 g of oxygen
44 g of carbon dioxide
11 The equation for the reaction between copper and nitric acid is shown.
vCu + wHNO3 xCu(NO3)2 + yNO + zH2O
v, w, x, y and z are whole numbers.
Which values of v, w, x, y and z balance the equation?
v
Y3Cl
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Y2Cl
YCl
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YCl 2
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13 Which reactions take place during the electrolysis of aqueous copper(II) sulfate with copper
electrodes?
reaction at positive electrode
Cu2+ + 2e Cu
Cu Cu2+ + 2e
4OH 2H2O + O2 + 4e
Cu2+ + 2e Cu
Cu Cu2+ + 2e
2H+ + 2e H2
Cu Cu2+ + 2e
Cu2+ + 2e Cu
14 The diagram shows apparatus used to investigate the conductivity of different solutions.
lamp
platinum
electrodes
solution
Which substance, in aqueous solution of concentration 1 mol / dm3, would cause the lamp to give
the brightest light?
A
ammonia
ethanoic acid
ethanol
sulfuric acid
15 The energy diagram for the reaction between sodium hydroxide and hydrochloric acid is shown.
H+(aq) + OH(aq)
energy
H = 54 kJ / mol
H2O(l)
Which quantity of heat is liberated when 100 cm3 of 1 mol / dm3 hydrochloric acid reacts with
100 cm3 of 1 mol / dm3 sodium hydroxide?
A
0.54 kJ
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2.70 kJ
5.40 kJ
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10.8 kJ
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16 The equation shows a reversible reaction.
N2O4(g)
2NO2(g)
temperature
decreased
decreased
decreased
increased
increased
decreased
increased
increased
X
Y
total
volume
of CO2
0
0
time
experiment 2
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18 What is not an example of oxidation?
A
barium
calcium
copper
potassium
20 Sodium hydroxide solution was added to dilute hydrochloric acid. The pH of the solution in the
flask was measured at intervals until no further change of pH took place.
hydrochloric acid
decrease to 1
decrease to 7
increase to 7
increase to 12
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22 Caesium, Cs, is an element in Group I of the Periodic Table.
Which statements about Caesium are true?
1
1 and 2 only
1 and 3 only
2 and 3 only
1, 2 and 3
23 Elements with the code letters Q and R occupy the positions shown in the outline of the Periodic
Table.
R
Q
QR2
Q2R
Q2R3
Q3R2
3 only
1 only
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1 and 2
2 and 3
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25 In the electrolysis of aluminium oxide to extract pure aluminium a compound called cryolite is first
added to the oxide.
What is the reason for adding the cryolite?
A
to enable the aluminium ions and oxygen ions to move to the electrodes
to prevent the aluminium formed from being oxidised back to aluminium oxide
26 Iron is extracted from its ore haematite, Fe2O3, by a reduction process in the blast furnace.
Which equation for reactions in the blast furnace shows the formation of the reducing agent?
A
CO2 + C 2CO
C + O2 CO2
27 The steel bodies of cars can be protected from rusting by spraying them with zinc.
Why is zinc used?
A
28 Solid Y is insoluble in water. It gives off a gas when heated and also when reacted with dilute
sulfuric acid.
What is Y?
A
copper(II) carbonate
sodium carbonate
sodium nitrate
zinc oxide
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29 What is the ionic equation for the reaction between zinc and aqueous copper(II) sulfate?
A
2
Zn2+(aq) + SO 4 (aq) ZnSO4(s)
ammonia, NH3
hydrogen, H2
nitrogen, N2
carbon dioxide
methane
nitrogen
oxygen
combustion of petrol
photosynthesis
volcanic activity
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34 Carbon dioxide and carbon monoxide are both
A
colourless.
inflammable in air.
35 Which hydrocarbon will burn completely in oxygen to give equal numbers of moles of carbon
dioxide and water?
A
C2H6
C3H6
C4H10
C5H12
aluminium
oxide
ethene
heat
water
action on
aqueous bromine
insoluble
decolourised
insoluble
no reaction
soluble
decolourised
soluble
no reaction
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37 Carbohydrates, proteins, fats and Terylene are macromolecules.
Which element is found in only one of these macromolecules?
A
carbon
hydrogen
nitrogen
oxygen
CH3
CH2
CH
CH2
CH2
CH2
CH3
CH3
CH3
CH3
B
CH3
CH3
CH3
C
CH3
CH2
CH2
CH2
CH3
CH3
CH
CH2
CH3
CH3
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39 Alcohols can be oxidised to form another homologous series of compounds.
What would be the product of the oxidation of propanol?
H
A
O
C
O
H
O
C
H
H
H
and
HO
OH
H
It is a condensation polymer.
It is starch.
It is Terylene.
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BLANK PAGE
5070/01/M/J/09
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Magnesium
Sodium
Calcium
5070/01/M/J/09
Strontium
Key
X = atomic symbol
Actinium
Ac
89
Ra
Radium
88
Fr
Francium
87
Hafnium
72
Lanthanum
57
178
Hf
40
Zirconium
Zr
91
Titanium
139
Yttrium
22
48
Ti
La
39
89
Scandium
21
227
Barium
56
Caesium
45
Sc
226
55
137
Ba
133
Cs
38
Rubidium
37
88
Sr
85
Rb
20
Potassium
19
40
Ca
39
12
24
Mg
23
Na
Beryllium
Lithium
11
Be
II
Li
93
Ta
181
Niobium
Nb
90
58
73
52
96
Mo
184
Protactinium
Thorium
55
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
27
59
28
59
29
64
30
65
Ru
101
Iron
190
Pm
Osmium
Os
Np
93
Neptunium
61
Promethium
76
44
Ruthenium
26
56
Fe
Sm
150
Iridium
Ir
192
Pu
94
Plutonium
62
Samarium
77
45
Rhodium
Rh
103
Cobalt
Co
Eu
152
Platinum
Pt
195
Am
95
Americium
63
Europium
78
46
Palladium
Pd
106
Nickel
Ni
Gd
157
Gold
Au
197
Silver
96
64
Curium
Cm
Gadolinium
79
47
Ag
108
Copper
Cu
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
Dy
162
Thallium
Tl
204
Indium
In
115
Gallium
Cf
98
Californium
66
Dysprosium
81
49
31
70
Ga
Ge
73
Silicon
119
Es
Holmium
Ho
165
Lead
Pb
207
Tin
Sn
99
Einsteinium
67
82
50
32
Germanium
14
28
Si
Carbon
27
Aluminium
13
12
Al
Boron
11
75
Sb
122
Arsenic
As
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
14
Se
79
Sulphur
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
32
Oxygen
16
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
VII
Hydrogen
VI
He
IV
III
1
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
Ce
Tantalum
41
23
Vanadium
51
Group
DATA SHEET
The Periodic Table of the Elements
16
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