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5070/11
CHEMISTRY
Paper 1 Multiple Choice
May/June 2012
1 hour
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1
A student measured the rate of reaction between calcium carbonate and dilute hydrochloric acid.
A graph showing the volume of gas produced against time is shown.
volume
/ cm3
time / seconds
Which apparatus was used to measure the variables shown on the graph?
chromatography paper
beaker
spot of mixture
liquid
be placed so that the spot is just below the level of the liquid.
C2H4
H2
H2O
N2
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4
The addition of dilute acid to a solution containing the anion Q and the subsequent use of
limewater can be used to identify the anion Q.
What is Q?
a carbonate
a chloride
an iodide
a sulfate
property
HCl
NaCl
Pb
Pb
HCl
NaCl
HCl
Pb
NaCl
NaCl
HCl
Pb
X2Y3
X3Y2
XY3
XY4
Which ion reacts with aqueous ammonia to give a precipitate that dissolves in an excess of
ammonia?
A
Al 3+(aq)
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Fe2+(aq)
Fe3+(aq)
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Zn2+(aq)
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8
15.0 cm3 of 1.0 mol / dm3 potassium hydroxide just neutralise 20.0 cm3 of a solution of nitric acid.
What is the concentration of the acid?
A
It contains 6 neutrons.
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12 The diagram shows an apparatus used to compare rates of diffusion.
At which labelled position did a white deposit of ammonium chloride form?
A
source of
hydrogen
chloride gas
source of
ammonia
gas
14 In terms of electrons, what happens when potassium combines with iodine to form a compound?
A
The potassium atoms each lose one electron and the iodine atoms each gain one electron.
The potassium atoms each gain one electron and the iodine atoms each lose one electron.
Cu(s) Cu2+(aq) + 2e
Cu2+(aq) + 2e Cu(s)
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16 The combustion of methane is exothermic. The equation is given below.
CH4 + 2O2 CO2 + 2H2O
What can be deduced from the fact that the reaction is exothermic?
A
18 Copper(II) carbonate powder was heated. The loss in mass was plotted against time as shown
on the graph.
0.4
0.3
loss in mass / g
0.2
0.1
0
0
10
time / min
0 to 2 min
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2 to 4 min
6 to 8 min
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8 to 10 min
7
19 In which equation is the underlined element reduced?
A
20 A sample of air was bubbled into water. The pH of the water slowly changed from 7 to 6.
Which gas in the sample caused this change?
A
carbon dioxide
carbon monoxide
nitrogen
oxygen
lead sulfate
silver nitrate
sodium carbonate
zinc chloride
22 The following statements about dilute sulfuric acid are all correct.
1
Addition of Universal Indicator shows that the solution has a pH value of less than 7.0.
1 and 2
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1 and 3
2 and 4
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3 and 4
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23 Pieces of material are placed in turn between P and Q in the incomplete electrical circuit shown.
P
Q
bulb
aluminium
diamond
magnesium
zinc
1 and 2 only
1 and 4 only
2 and 3 only
3 and 4 only
C + CO2 2CO
C + O2 CO2
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26 An atom of which element gains three electrons when it forms an ion?
A
aluminium
iron
nitrogen
silicon
in Group II
in Group III
calcium
1 and 2
1 and 3
2 and 4
3 and 4
2.
copper
3.
potassium
4.
silver
X Y
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30 Three different beakers are set up as shown.
1
2
rod of
metal Z
3
rod of
metal W
aqueous
metal W
salt
rod of
metal X
aqueous
metal X
salt
aqueous
metal Y
salt
least
reactive
31 Which gases are formed during the production of aluminium by electrolysis of molten aluminium
oxide?
A
32 Which pair of gases could be removed from the atmosphere using calcium carbonate?
A
CO2 and O3
CO and SO2
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33 In which parts of a motor car do the reactions, shown in the equations, take place?
N2 + O2 2NO
engine
engine
engine
exhaust
exhaust
engine
exhaust
exhaust
NH2
HOOC
NH2
HO
NH2
HO
OH
How many of these monomers would react with the molecule below to form a polymer?
HOOC
COOH
35 For which molecules are the empirical and molecular formulae the same?
1. methanoic acid, HCO2H
2. ethanoic acid, CH3CO2H
3. propanoic acid, C2H5CO2H
4. butanoic acid, C3H7CO2H
A
1, 2 and 3 only
1 and 3 only
2 and 3 only
2, 3 and 4 only
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37 A 10 cm3 sample of a gaseous hydrocarbon is completely burnt in oxygen. The total volume of the
products is 70 cm3. All gas volumes are measured at room temperature and pressure.
Which equation represents the combustion of the hydrocarbon?
A
38 The boiling points of the alcohols increase as their relative molecular mass increases.
Which alcohol has the highest boiling point?
A
butanol
ethanol
methanol
propanol
paraffin
polyethene
protein
sugar
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40 Compound Q reacts with bromine to form the compound shown.
Br
Br
Which is compound Q?
A
Br
Br
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BLANK PAGE
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BLANK PAGE
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Magnesium
Sodium
Calcium
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Strontium
Key
X = atomic symbol
Actinium
Ac
89
Ra
Radium
88
Fr
Francium
87
Hafnium
72
Lanthanum
57
178
Hf
40
Zirconium
Zr
91
Titanium
139
Yttrium
22
48
Ti
La
39
89
Scandium
21
227
Barium
56
Caesium
45
Sc
226
55
137
Ba
133
Cs
38
Rubidium
37
88
Sr
85
Rb
20
Potassium
19
40
Ca
39
12
24
Mg
23
Na
Beryllium
Lithium
11
Be
II
Li
93
Ta
181
Niobium
Nb
90
58
73
52
96
Mo
184
Protactinium
Thorium
55
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
27
59
28
59
29
64
30
65
Ru
101
Iron
190
Pm
Osmium
Os
Np
93
Neptunium
61
Promethium
76
44
Ruthenium
26
56
Fe
192
Sm
150
Iridium
Ir
Pu
94
Plutonium
62
Samarium
77
45
Rhodium
Rh
103
Cobalt
Co
Eu
152
Platinum
Pt
195
Am
95
Americium
63
Europium
78
46
Palladium
Pd
106
Nickel
Ni
Gd
157
Gold
Au
197
Silver
96
64
Curium
Cm
Gadolinium
79
47
Ag
108
Copper
Cu
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
Dy
162
Thallium
Cf
98
Es
Holmium
99
Einsteinium
67
Ho
165
Lead
207
Tin
Pb
Californium
66
119
Sn
Tl
82
50
32
Germanium
Ge
73
Silicon
204
Indium
In
115
Gallium
Dysprosium
81
49
31
70
Ga
14
28
Si
Carbon
27
Aluminium
13
12
Al
Boron
11
75
Sb
122
Arsenic
As
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
14
Se
79
Sulfur
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
32
Oxygen
16
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
VII
Hydrogen
VI
He
IV
III
1
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
Ce
Tantalum
41
23
Vanadium
51
Group
DATA SHEET
The Periodic Table of the Elements
16
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