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1
The experiment is set up as shown and left until there is no further change.
water
purple crystal of
potassium manganate(VII)
What is observed?
A student adds aqueous sodium hydroxide or aqueous ammonia to aqueous solutions of four
different metal compounds.
2+
ions?
solution
add a few
drops of
NaOH(aq)
add excess
NaOH(aq)
add a few
drops of
NH3(aq)
add excess
NH3(aq)
ppt
ppt dissolves
ppt
ppt dissolves
ppt
ppt dissolves
ppt
ppt
ppt
ppt
no ppt
no ppt
no ppt
no ppt
no ppt
no ppt
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3
3
A sample of a pure compound is heated until it is completely molten and the compound is then
allowed to cool until it is completely solid again.
The graph shows how the temperature of the compound changes with time.
temperature
R
S
time
When are liquid and solid both present?
A
P to Q and R to S
P to Q
Q to R
R to S
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4
4
A beaker of nitrogen is inverted over a porous pot containing carbon monoxide as shown.
The water level does not change.
beaker
nitrogen
carbon monoxide
porous pot
water
The gas particles are too large to pass through the porous pot.
an alloy
a hydrocarbon
a metal oxide
a salt
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5
7
conducts electricity
T
o
Substance X has a melting point higher than 500 C. It is insoluble both in water and in organic
solvents. It conducts electricity when both solid and molten.
What is X?
copper
mercury
poly(ethene)
sodium chloride
3
How many moles per dm of gaseous carbon dioxide are there if 4.4 g occupies 500 cm ?
3
0.1 mol / dm
0.2 mol / dm
2.2 mol / dm
8.8 mol / dm
10 Which reactions take place during the electrolysis of aqueous copper(II) sulphate with copper
electrodes?
reaction at positive electrode
A
B
2+
Cu
Cu Cu
4OH 2H2O + O2 + 4e
Cu Cu
2+
+ 2e
Cu Cu
2+
+ 2e
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2+
+ 2e Cu
Cu
2+
+ 2e
+ 2e Cu
2H + 2e H2
Cu
2+
+ 2e Cu
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6
11 The heat-reflecting shields of some space rockets are gold-plated, using electrolysis.
Which electrodes and electrolyte would be used to gold-plate the heat shield?
negative electrode
positive electrode
electrolyte
carbon
heat shield
gold compound
gold
heat shield
copper compound
heat shield
carbon
copper compound
heat shield
gold
gold compound
the energy needed to break the bonds is greater than that released on forming new bonds.
the energy needed to break the bonds is less than that released on forming new bonds.
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13 Which reaction profile shows the fastest exothermic reaction?
A
energy
energy
reaction pathway
reaction pathway
energy
energy
reaction pathway
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8
14 In two separate experiments, a substance is decomposed and the gas evolved is collected.
The graph shows the total volume of gas collected against time for each experiment.
experiment 2
volume
of gas
collected
experiment 1
time
Which graph shows how the speed of reaction varies with time in each experiment?
B
speed of
reaction
1
speed of
reaction
speed of
reaction
time
time
speed of
reaction
2
1
1
2
time
time
15 A colourless gas is passed into each of three different solutions. The results are shown in the
table.
solution of
potassium iodide
acidified potassium
dichromate(VI)
acidified potassium
manganate(VII)
result
stays colourless
orange to green
purple to colourless
an acid
an alkali
an oxidising agent
a reducing agent
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16 Chlorine can be manufactured by using the reversible reaction between hydrogen chloride and
oxygen.
4HCl(g) + O2(g)
2H2O(g) + 2Cl2(g)
H is negative
adding a catalyst
17 Which pair of substances produce a precipitate when their aqueous solutions are mixed?
A
At
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Cs
5070/01/M/J/05
Li
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10
20 Elements X and Y are in Group VII of the Periodic Table.
X is a liquid at room temperature. Y is a solid at room temperature.
1
1 only
2 only
3 only
1, 2 and 3
21 Metal M will displace copper from aqueous copper(II) sulphate solution, but will not displace iron
from aqueous iron(II) sulphate solution. M is extracted from its oxide by heating the oxide with
carbon.
What is the order of reactivity of these four metals?
least reactive
most reactive
sodium
metal M
iron
copper
sodium
iron iron
metal M
copper
copper
metal M
metal M
sodium
copper
iron
sodium
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22 The diagram shows the electrolytic production of aluminium.
waste gases
carbon
anodes
(+ve)
cathode
(-ve)
What is the physical state of the aluminium oxide and aluminium during this process?
aluminium oxide
aluminium
liquid
liquid
liquid
solid
solid
liquid
solid
solid
24 Alloys are usually harder than the metals from which they are made.
Which difference between the metals explains the greater hardness of alloys?
A
atomic radii
densities
electrical conductivities
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25 Which gas cannot be removed from the exhaust gases of a petrol powered car by its catalytic
converter?
A
carbon dioxide
carbon monoxide
hydrocarbons
nitrogen dioxide
carbon dioxide
methane
nitrogen
oxygen
result
What is compound X?
A
ammonium carbonate
ammonium nitrate
calcium carbonate
calcium nitrate
0.5
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1.5
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13
29 Ammonium sulphate is an important fertiliser.
During which stage in the manufacture of ammonium sulphate does a reaction with water occur?
sulphur
stage
A
sulphur
dioxide
stage
B
sulphur
trioxide
stage
C
stage
D
sulphuric
acid
ammonium
sulphate
30 The diagram shows the colours of the indicators, methyl orange and methyl red, at different pH
values.
pH
colour of
methyl orange
red
yellow
colour of
methyl red
red
yellow
pH
W and X
X and Y
C Y and Z
Z only
31 The diagram shows some of the stages in the manufacture of ammonium sulphate.
From which connecting pipe would a major leak most increase the pH value of rain?
nitrogen
and
hydrogen
pipe A
reaction
vessel
ammonia
pipe B
reaction
vessel
SO2+O2
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reaction
vessel
SO3
pipe D
ammonium
sulphate
reaction H SO
2
4
vessel
pipe C
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14
32 Which graph shows the changes in pH as an excess of hydrochloric acid is added to aqueous
sodium hydroxide?
A
14
pH
pH
0
volume of acid added
14
pH
14
14
pH
0
volume of acid added
result
What is compound X? A
aluminium chloride
B
aluminium sulphate
calcium chloride
calcium sulphate
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34 Which property of the alkanes does not increase as relative molecular mass increases?
A
boiling point
flammability
melting point
viscosity
35 What is the structure of the product of the reaction between butene, CH3CH2CH=CH2, and
bromine, Br2?
A
CH2BrCH2CH2CH2Br
CH2BrCH2CHBrCH3
CH3CHBrCH2CH2Br
CH3CH2CHBrCH2Br
36 Which formula represents a compound that will react with sodium carbonate to give off carbon
dioxide?
A
CH3OH
HCO2CH3
CH3CO2H
CH3CO2C2H5
C
H
O
C
O
H
C
H
H
O
C
O
H
What are the similarities and differences between the two compounds?
similarities
differences
molecular formulae
reactions
molecular formulae
structures
molecular formulae
structures
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38 In which of the following are all the compounds members of the same homologous series?
A
CH4
C2H6
C3H6
CH4
C2H6
C3H8
C2H4
C3H6
C4H10
C3H4
C3H6
C3H8
CH3
C2H5
C6H5
and
O
n
B
O
C
C
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n
5070/01/M/J/05
HO
OH
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Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
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Group
I
III
II
IV
VI
VII
He
Hydrogen
Helium
1
7
11
12
14
16
19
20
Li
Be
Ne
Lithium
Beryllium
Boron
23
24
Na
Mg
Sodium
Magnesium
11
Nitrogen
Oxygen
Fluorine
Neon
10
27
28
31
32
35.5
40
Al
Si
Cl
Ar
Aluminium
12
Carbon
13
Silicon
14
Phosphorus
Sulphur
16
15
Chlorine
17
Argon
18
39
40
45
48
51
52
55
56
59
59
64
65
70
73
75
79
80
84
Ca
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Kr
Potassium
19
Calcium
20
Scandium
Titanium
21
22
Vanadium
23
Chromium
24
85
88
89
91
93
96
Rb
Sr
Zr
Nb
Mo
Rubidium
Strontium
37
38
Yttrium
Zirconium
39
40
Niobium
41
Manganese
25
Molybdenum
42
Iron
26
Tc
Technetium
43
Cobalt
27
Nickel
28
Copper
29
Zinc
30
Gallium
31
Germanium
32
Arsenic
33
Selenium
34
Bromine
35
Krypton
36
101
103
106
108
112
115
119
122
128
127
131
Ru
Rh
Pd
Ag
Cd
In
Sn
Sb
Te
Xe
Ruthenium
44
Rhodium
45
Palladium
46
Silver
47
Cadmium
48
Tin
Indium
50
49
Antimony
51
Tellurium
52
Xenon
Iodine
54
53
133
137
139
178
181
184
186
190
192
195
197
201
204
207
209
Cs
Ba
La
Hf
Ta
Re
Os
Ir
Pt
Au
Hg
Pb
Bi
Po
At
Rn
Caesium
Barium
Lanthanum
Hafnium
Tantalum
Tungsten
Rhenium
Osmium
Iridium
Platinum
Gold
Mercury
Tl
Lead
Bismuth
Polonium
Astatine
Radon
55
56
57
226
Fr
Ra
Ac
Radium
Actinium
88
73
74
140
141
144
Ce
Pr
Nd
Cerium
Key
X
b
76
78
77
79
80
81
82
83
84
85
86
89
75
227
Francium
87
72
Thallium
58
Neodymium
60
232
X = atomic symbol
b = proton (atomic) number
Praseodymium
59
90
Pm
Promethium
150
152
157
159
162
165
167
169
173
175
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
Samarium
62
61
Europium
63
Gadolinium
64
Terbium
65
Dysprosium
66
Holmium
67
Erbium
68
Thulium
69
Ytterbium
70
Lutetium
71
238
Th
Pa
Np
Pu
Am
Cm
Bk
Cf
Es
Fm
Md
No
Lr
Thorium
Protactinium
Uranium
Neptunium
Plutonium
Americium
Curium
Berkelium
Californium
Einsteinium
Fermium
Mendelevium
Nobelium
Lawrencium
91
92
93
94
95
96
97
98
99
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
100
101
102
103
20
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University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES), which is itself a
department of the University of Cambridge.
UCLES 2005
DATA SHEET
The Periodic Table of the
Elements