MATERIAL SAFETY DATA SHEET

EME SALT
ChemWatch Material Safety Data Sheet (REVIEW)
CHEMWATCH 4922-89
Date of Issue: Mon 15-Jul-2002

PRODUCT NAME
EME SALT

STATEMENT OF HAZARDOUS NATURE

CONSIDERED A DANGEROUS SUBSTANCE ACCORDING TO DIRECTIVE
67/548/EEC, POINT 4; AND
HAZARDOUS ACCORDING TO OSHA 29 CFR 1910.1200 (USA).

SUPPLIER
Company:
Kota Minerals and Chemicals Sdn Bhd
Address:
No.1-1, Block C1, Dataran Prima, Jalan, PJU1/41
Petaling Jaya
Selangor Darul Ehsan, 47301
Malaysia
Telephone: (+60) 3 7880 6118
Telephone: +019 239 2056
Emergency Tel: +019 326 8425

HAZARD RATINGS
Flammability: 1
Toxicity:

Body Contact: 2
Reactivity:

Chronic:

SCALE:

Min/Nil=0

Low=1

Moderate=2

High=3

Extreme=4

PRODUCT USE
Lubricant for water-based drilling fluids.

SYNONYMS
Kota Minerals
fatty acids, esters with polyol and triethanolamine
KOTA MINERALS AND CHEMICALS SDN. BHD.

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Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME
R CODE
fatty acids, C16-18 and C18-unsaturated, triethano None

INT HAZ
None

EC NO: 270-279-3 CAS RN: 68424-19-1

fatty acids, esters with polyol

Not
spe

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
RISK
May produce discomfort of the eyes and skin*.
* (limited evidence).

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS
SWALLOWED
Although ingestion is not thought to produce harmful effects (as classified
under EC Directives), the material may still be damaging to the health of the
individual, following ingestion, especially where pre-existing organ (e.g liver,
kidney) damage is evident. Present definitions of harmful or toxic substances
are generally based on doses producing mortality rather than those producing
morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce
nausea and vomiting. In an occupational setting however, ingestion of
insignificant quantities is not thought to be cause for concern.
EYE
Limited evidence exists, or practical experience suggests, that the material may
cause eye irritation in a substantial number of individuals and/or is expected
to produce significant ocular lesions which are present twenty-four hours or
more after instillation into the eye(s) of experimental animals.

KOTA MINERALS AND CHEMICALS SDN. BHD.

%
Not
spe

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SKIN
Limited evidence exists, or practical experience predicts, that the material
either produces inflammation of the skin in a substantial number of individuals
following direct contact, and/or produces significant inflammation when applied
to the healthy intact skin of animals, for up to four hours, such inflammation
being present twenty-four hours or more after the end of the exposure period.
Skin contact is not thought to have harmful health effects (as classified under
EC Directives); the material may still produce health damage following entry
through wounds, lesions or abrasions.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a
minimum
and that suitable control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Primary route of exposure is usually by skin contact / eye contact
As with any chemical product, contact with unprotected bare skin; inhalation of
vapour, mist or dust in work place atmosphere; or ingestion in any form, should
be avoided by observing good occupational work practice.

Section 4 - FIRST AID MEASURES

SWALLOWED
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
Seek medical advice.
EYE
KOTA MINERALS AND CHEMICALS SDN. BHD.

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If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye
and moving the eyelids by occasionally lifting the upper and lower lids.
If pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
INHALED
If fumes or combustion products are inhaled remove from contaminated area.
Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
FIRE FIGHTING
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Avoid spraying water onto liquid pools.
Do not approach containers suspected to be hot.
KOTA MINERALS AND CHEMICALS SDN. BHD.

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Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of
containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
Mists containing combustible materials may be explosive.
Other combustion products include carbon dioxide (CO2) and aldehydes
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result
HAZARD: Rags wet / soaked with unsaturated hydrocarbons / drying oils auto
oxidise; may generate heat and in-time smoulder and ignite. Oily cleaning rags
should be collected regularly and immersed in water.

Section 6 - ACCIDENTAL RELEASE MEASURES

MINOR SPILLS
Clean up all spills immediately.
Slippery when spilt.
Wipe up.
Place in clean drum then flush area with water.
MAJOR SPILLS
Slippery when spilt.
Minor hazard.
Clear area of personnel.
Alert Fire Brigade and tell them location and nature of hazard.
Control personal contact by using protective equipment as required.
Prevent spillage from entering drains or water ways.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
Wash area and prevent runoff into drains or waterways.
If contamination of drains or waterways occurs, advise emergency services.
KOTA MINERALS AND CHEMICALS SDN. BHD.

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Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING
Limit all unnecessary personal contact.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
When handling DO NOT eat, drink or smoke.
Always wash hands with soap and water after handling.
Avoid physical damage to containers.
Use good occupational work practice.
Observe manufacturer's storing and handling recommendations.
Polymerisation or oxidation of the unsaturated bonds may occur.
SUITABLE CONTAINER
Polyethylene or polypropylene container. Packing as recommended by
manufacturer
Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers
STORAGE REQUIREMENTS
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well ventilated area.
DO NOT allow to freeze.
Store away from incompatible materials.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storing and handling recommendations.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS
None assigned. Refer to individual constituents.
ODOUR SAFETY FACTOR (OSF)
KOTA MINERALS AND CHEMICALS SDN. BHD.

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OSF=0.77 (fatty acids, C16-18 and C18-unsaturated, triethanolamine)
Exposed individuals are NOT reasonably expected to be warned, by smell,
that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class
A

B
C
D

OSF
550

Description
Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
26-550 Idem for 50-90% of
persons being distracted
1-26
Idem for less than 50% of
persons being distracted
0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
<0.18 Idem for less than 10% of
persons aware of being
tested

INGREDIENT DATA

FATTY ACIDS, C16-18 AND C18-UNSATURATED, TRIETHANO:

TLV TWA: 10 mg/m3 (Value for particulate matter containing no asbestos and
<1% crystalline
silica,Inhalable fraction) [ACGIH]
TLV TWA: 3 mg/m3 (Value for particulate matter containing no asbestos and
<1% crystalline
silica,Respirable fraction) [ACGIH]
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m3
Particulate (insoluble or poorly soluble *) Not .Otherwise Specified (P.N.O.C)
KOTA MINERALS AND CHEMICALS SDN. BHD.

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TLV TWA: 10 mg/m Inhalable particulate
TLV TWA: 3 mg/m3 Respirable particulate
OEL-Sweden, United Kingdom: 10 mg/m total dust, 5 mg/m respirable
dust
These "dusts" have little adverse effect on the lungs and do not produce toxic
effects or organic disease. Although there is no dust which does not evoke
some
cellular response at sufficiently high concentrations, the cellular response
caused by P.N.O.C.s has the following characteristics:
the architecture of the air spaces remain intact,
scar tissue (collagen) is not synthesised to any degree,
tissue reaction is potentially reversible.
Extensive concentrations of P.N.O.C.s may:
seriously reduce visibility,
cause unpleasant deposits in the eyes, ears and nasal passages,
contribute to skin or mucous membrane injury by chemical or mechanical
action,
per se, or by the rigorous skin cleansing procedures necessary for their
removal. [ACGIH]
This limit does not apply:
to brief exposures to higher concentrations
nor does it apply to those substances that may cause physiological impairment
at lower concentrations but for which a TLV has as yet to be determined.
This exposure standard applies to particles which
are insoluble or poorly soluble* in water (or, preferably, in aqueous lung fluid
(if data is available) and
have a low toxicity (i.e.. are not cytotoxic, genotoxic, or otherwise chemically
reactive with lung tissue, and do not emit ionizing radiation, cause immune
sensitization, or cause toxic effects other than by inflammation or by a
mechanism of lung overload)
* Notice of intended change

PERSONAL PROTECTION

EYE
Safety glasses with side shields; or as required, Chemical goggles. Contact
KOTA MINERALS AND CHEMICALS SDN. BHD.

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lenses pose a special hazard; soft lenses may absorb irritants and all lenses
concentrate them.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear.
OTHER
Overalls.
Eyewash unit.
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.

ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas. Air contaminants generated in the workplace possess varying
"escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectively remove the contaminant.
Type of Contaminant:
solvent, vapours, degreasing etc.,
evaporating from tank (in still air)
aerosols, fumes from pouring
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling,

Air Speed:
0.25-0.5 m/s (50-100 f/min)
0.5-1 m/s (100-200 f/min.)

1-2.5 m/s (200-500 f/min)

2.5-10 m/s (500-2000 f/min.)

KOTA MINERALS AND CHEMICALS SDN. BHD.

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high speed wheel generated dusts
(released at high initial velocity into
zone of very high rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range
1: Room air currents minimal or
favourable to capture
2: Contaminants of low toxicity or of
nuisance value only
3: Intermittent, low production.
4: Large hood or large air mass in
motion

Upper end of the range

1: Disturbing room air currents
2: Contaminants of high toxicity
3: High production, heavy use
4: Small hood - local control only

Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.
Molecular Weight: Not applicable
Boiling Range (OC): Not available
Melting Range (OC): Not available
Specific Gravity (water=1): 0.995
Solubility in water (g/L): Immiscible
pH (as supplied): Not available
pH (1% solution): Not available
Vapour Pressure (kPa): Not available
Volatile Component (%vol): Not available
Evaporation Rate: Not available
KOTA MINERALS AND CHEMICALS SDN. BHD.

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Relative Vapour Density (air=1): Not available
Flash Point (OC): 230
Lower Explosive Limit (%): Not available
Upper Explosive Limit (%): Not available
Autoignition Temp (OC): Not available
Decomposition Temp (OC): Not available
State: Liquid

APPEARANCE
Amber liquid with a faint odour; does not mix with water.
Viscosity: 120 mm2/s @ 40 deg C.

Section 10 - CHEMICAL STABILITY AND REACTIVITY

INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Product is considered stable and hazardous polymerisation will not occur.

Section 11 - TOXICOLOGICAL INFORMATION

KMC EME Salt
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
FATTY ACIDS, C16-18 AND C18-UNSATURATED, TRIETHANO:
Not available. Refer to individual constituents.

Section 12 - ECOLOGICAL INFORMATION

Biodegradable.

Section 13 - DISPOSAL CONSIDERATIONS

Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Management Authority for disposal.
Bury residue in an authorised landfill.
Recycle containers if possible, or dispose of in an authorised landfill.
KOTA MINERALS AND CHEMICALS SDN. BHD.

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Section 14 - TRANSPORTATION INFORMATION

Shipping Name: NONE
Hazard Class: None
UN/NA Number: None
ADR Number:
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO: None

Section 15 - REGULATORY INFORMATION

SAFETY
Keep away from combustible material.
Avoid contact with skin.
Wear eye/ face protection.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.

Section 16 - OTHER INFORMATION

RISK
R8

Contact with combustible material may cause fire.

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Mon 15-Jul-2002
Print Date: Mon 7-Jul-2003

KOTA MINERALS AND CHEMICALS SDN. BHD.

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