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Abstract
The paper presents investigation of how the usage of bottom ash (BA), granulated blast furnace slag (GBFS), and combination of both
of these materials as ne aggregate in concrete affects the concrete durability. To assess durability characteristics of concrete, durability
tests were conducted and the results were evaluated comparing with reference concrete. Three series concrete were produced. GBFS, BA
and GBFS+BA are replaced the 37 mm-sized aggregate. Five test groups were constituted with the replacement percentages as 10%,
20%, 30%, 40% and 50% in each series. These by-products were used as non-ground form in the concrete. Durability properties of the
concretes were compared in order to study the possible advantages of different replacement ratios. According to results, GBFS and BA
affects some durability properties of concrete positively in case of it is used as ne aggregate. Resistance to high temperature and surface
abrasion are positively affected properties. Capillarity, drying-wetting and freezing-thawing resistance of the concrete can be accepted to
some extent. Properties of by-products and its replacement ratio are controlling the inuence level and direction. Comparison of the
SEM images and test results show that chemical and physical properties of GBFS and BA are the main factors affecting the concrete
durability. It is concluded that it is possible to produce durable concrete by using GBFS and BA as ne aggregate.
r 2006 Elsevier Ltd. All rights reserved.
Keywords: Aggregate; Bottom ash; Concrete; Durability; Granulated blast furnace slag; Replacement
1. Introduction
High consumption of natural sources, high amount
production of industrial wastes and environmental pollution require obtaining new solutions for a sustainable
development. There are also some kinds of studies to
obtain such solutions in the eld of concrete technologies.
In recent years, durability is one of the critical issues to
develop concrete technologies and construct reinforced
concrete structures with long service life due to some
economical and environmental reasons [15]. Huge
amounts of natural sources such as sand, gravel, cement
and water are used in concrete technology. Also, 3 billion
tons of raw materials are used in each year for cement
Corresponding author. Tel.: +90 372 2574010; fax: +90 372 2574023.
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I. Yuksel et al. / Building and Environment 42 (2007) 26512659
2652
Unit
Aggregate
(07 mm)
GBFS
BA
kg/m3
kg/m3
%
%
1930
1950
2.68
11.30
5.00
1052
1236
2.08
10.00
620
660
1.39
12.10
2.40
%
Colour
4.00
Light
yellow
3.00
Light
yellow
7.00
100
0-3 mm
3-7 mm
BA
GBFS
90
80
% passing
70
60
50
40
30
20
10
0
0.01
0.1
1
Sieve size (mm)
10
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Table 2
Chemical composition of GBFS and BA
By-product
SiO2 (%)
CaO (%)
MgO (%)
Al2O3 (%)
Na2O (%)
S (%)
MnO (%)
TiO2 (%)
Fe (%)
P2O3 (%)
GBFS
BA
35.09
57.90
37.79
2.00
5.50
3.20
17.54
22.60
0.30
0.086
0.66
0.604
0.83
0.68
0.70
13.0
0.37
Table 3
Properties of BA
Property
Unit
Value
Loss on ignition
SO3
Cl
45 sieve residue (by weight)
7 day strength activity index
28 day strength activity index
90 day strength activity index
%
%
%
%
%
%
%
1.67
0.08
0.006
25.8
76.9
85.7
100
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Table 4
Mix proportions of concrete specimens (for 1 m3)
Code
Description
Cement
(kg)
Water
(lt)
FA (kg)
Coarse agg.
(37) (kg)
Fine agg.
(03) (kg)
GBFS (kg)
R
C 10
C 20
C 30
C 40
C 50
Reference
10% GBFS
20% GBFS
30%GBFS
40% GBFS
50% GBFS
350
350
350
350
350
350
167
167
167
167
167
167
35
35
35
35
35
35
1120
1120
1120
1120
1120
1120
720
648
576
504
432
360
0
72
144
216
288
360
0
0
0
0
0
0
2.45
2.45
2.45
2.45
2.45
2.45
K10
K 20
K 30
K 40
K 50
10%
20%
30%
40%
50%
350
350
350
350
350
167
167
167
167
167
35
35
35
35
35
1120
1120
1120
1120
1120
648
576
504
432
360
0
0
0
0
0
72
144
216
288
360
2.45
2.45
2.45
2.45
2.45
CK5
CK 10
CK 15
CK 20
CK 25
5% GBFS 5% BA
10% GBFS 10% BA
15% GBFS 15% BA
20% GBFS 20% BA
25% GBFS 25% BA
350
350
350
350
350
167
167
167
167
167
35
35
35
35
35
1120
1120
1120
1120
1120
648
576
504
432
360
36
72
108
144
180
36
72
108
144
180
2.45
2.45
2.45
2.45
2.45
BA
BA
BA
BA
BA
BA (kg)
Chem.
adm. (kg)
35.0
30.0
25.0
C series
K series
CK series
20.0
0
10
20
30
Replacement ratio (%)
40
50
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Fig. 3. Cracks on specimens due to high temperature (800 1C), (a) reference concrete, (b) C40 concrete, (c) K40 concrete.
7
6.49
6
Loss in strength (%)
6.49
6.36
6.04
6.18
5.51
4.92
4.59
4.91
4.92
4.77
4.11
4
3.60
3.31
3
2.29
2.19
C series
K seris
CK series
1
0
10
20
30
40
50
dryingwetting cycles. According to test results, dryingwetting effect accelerates the strength decreases for all three series
of concrete. The porous structure of by-product replaced
concrete is effective in these decreases. As the replacement
ratio increases, the structure of hardened concrete is getting
more porous. The microstructure assessments are supported
this idea. Therefore decrease of compressive strength should
be encountered as a normal state. C series are the most
negatively effected series in three series. The differences
between chemical compositions and shapes of GBFS and BA
can be considered as a second reason for the strength losses.
For example, the amount of CaO content is very different for
GBFS and BA (Table 2). More CaO ingress into the concrete
occurs in C series. When CaO reacts with water, heat is
brought out into the open and volume expansion occurs. It is
possible that Ca(OH)2 transforms to CaCO3 during drying.
Also, additional internal vapour pressure occurring due to
evaporation of absorbed free water with respect to temperature change during dryingwetting cycles. This can be said as
another reason of the strength losses.
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55
50
45
40
35
C-ref before drying-wetting cycles
K-ref before drying-wetting cycles
CK ref before drying-wetting cycles
C after drying-wetting cycles
K after drying-wetting cycles
CK after drying-wetting cycles
30
25
0
10
20
30
40
50
4.5
4
3.5
3
2.5
2
C-series
K-series
CK series
1.5
1
0
10
20
30
40
50
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14
13
12
11
10
C series
K series
CK series
Allowable limit value
8
0
10
15
20
25
30
35
40
45
50
4. Conclusions
In this study, the effects of BA and GBFS, as ne
aggregate in concrete without no pre-processes at various
replacement ratios, to concrete durability are investigated.
As a general result, GBFS and BA affects durability
properties of concrete positively when it is used as
ne aggregate. Mainly, properties of the replaced byproduct and the replacement ratio are controlling the
inuence level and direction.
High-temperature affects the concrete types which
contain GBFS or/and BA ne aggregate replacement like
reference concrete even if for the 50% replacement.
Amount of surface cracks also decrease when these byproducts are used. So, it is possible to replace GBFS and
BA with ne aggregate in concrete exposing high temperature.
Compressive strength loss due to freezingthawing effect
decreases for low replacement ratio (1030%). Therefore
durability against freezethaw cycles increases for these
replacement levels. Compressive strength loss starts to
increase after this level. After all, it is still on the same level
as well as in reference concrete for the maximum level of
replacement (50%). Therefore GBFS or BA replaced
concretes have better durability than reference concrete.
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2658
Fig. 8. (a) SEM micrograph of reference concrete specimen, (b) SEM micrograph of C30 concrete specimen, (c) SEM micrograph of K30 concrete
specimen.
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