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The propellant used in the solid rocket booster of a space shuttle is a mixture of aluminium
and compound X. Compound X contains chlorine in an oxidation state of +7. Which of the
following could be compound X?
A
NH4Cl
N2H5Cl
NH4ClO3
NH4ClO4
Disproportionation occurs when an element is both oxidised and reduced in a reaction. Which
named element does not disproportionate in the reaction shown?
Element
Carbon
Nitrogen
Sulphur
Chlorine
A
B
C
D
Reaction
H2C2O4 H2O + CO + CO2
H2O + 2NO2 HNO3 + HNO2
2FeSO4 Fe2O3 + SO2 + SO3
3ClO- ClO3- + 2Cl-
In an experiment, 25.0 cm3 of a 0.10 mol dm-3 solution metallic salt reacted exactly with 12.5
cm3 of 0.10 mol dm-3 aqueous sodium sulphite. The half equation for the oxidation of the
sulphite ion is shown below.
SO32- (aq) + H2O (l) SO42- (aq) + 2H+ (aq) + 2eIf the original oxidation number of the metal in the salt was 3, what would be the new oxidation
number of the metal?
A 0
B 1
C
2
D
4
25.0 cm3 of a solution of M2O5 of concentration 0.100 mol dm-3 is reduced by sulphur dioxide to
a lower oxidation state. To reoxidise M to its original oxidation number required 50.0 cm 3 of
0.0200 mol dm-3 potassium manganate (VII) solution. To what oxidation number was M
reduced by sulphur dioxide?
A
+2
+3
+4
+5
The Winkler method is used to determine the amount of dissolved oxygen in a sample. In this
procedure, oxygen reacts with Mn2+ under alkaline conditions to produce a precipitate of
MnO(OH)2.
2Mn2+ (aq) + O2 (aq) + 4OH (aq) 2MnO(OH)2 (s)
The precipitate is then dissolved in acid and reacted with iodide, forming iodine and Mn2+.
MnO(OH)2 (s) + 2 (aq) + 4H+ (aq) I2 (aq) + Mn2+ (aq) + 3H2O (aq)
Finally, the amount of iodine produced is determined by reaction with thiosulphate.
I2 (aq) + 2 S2O32- (aq) 2I- (aq) + S4O62- (aq)
When a sample of water was analysed using the Winkler method, a total of 0.60 mol of
thiosulphate was used in the reaction. What was the mass of oxygen present in the original
sample?
A
1
D
4.8 g
2
C
9.6 g
3
C
4
C
19.2 g
38.4 g
5
A
H2 Chemistry 9647
Cr2O72- + 6Fe2+
(acidic medium)
[2]
Cl2 ClO -
+ Cl -
(alkaline medium)
[2]
[1]
25.0 cm3 of a solution containing ethanedioic acid and sodium ethanedioate required 14.75
cm3 of 0.100 mol dm-3 sodium hydroxide solution for neutralisation and 32.00 cm3 of 0.0205
mol dm-3 KMnO4 solution for oxidation in acidic conditions at 60oC. Find the concentration of
the ethanedioic acid and the sodium ethanedioate in the solution.
[6]
Acid-base titration:
H2C2O4 (aq) + 2NaOH (aq) Na2C2O4 (aq) + 2H2O (l)
Amount of NaOH required
[]
[]
[1]
Redox Titration:
16 H+ (aq) + 5 C2O42- (aq) + 2 MnO4- (aq) 2 Mn2+ (aq) + 10 CO2(g) + 8 H2O (l)
[1]
Amount of KMnO4
[]
H2 Chemistry 9647
Which one of the following particles has the correct number of electrons and neutrons?
particle
number of electrons
number of neutrons
10
19
Br+
34
44
18
16
19
79
D
2
2-
Which one of the following corresponds to the configuration of the three electrons of the
highest energy for one of the elements in Group III?
1s2 2s1
2s1 2p2
3p3
4s2 4p1
A
B
C
D
3
Which of the following particles will have half-filled p orbitals on losing an electron? Given that
14
16
7N and
8O.
A
B
C
D
N
N
O+
O
The proton number of an element X is 32. Which of the following shows the correct order for
the successive removals of electrons from their orbitals to form X4+ ion?
first
second
third
fourth
4s
4s
4pX
4py
4pX
4py
4s
4s
4pX
4pX
4s
4s
4py
4py
3d
3d
The first seven ionisation energies (in kJ mol1) of an element Y are as follows:
1
D
2
D
3
B
4
B
5
D
3
H2 Chemistry 9647
(a)
[3]
beam
source
+
(b)
(i)
On the same diagram, draw the path of deflection for the 2H+ nucleus.
(ii)
Account for the shape of the path of deflection for the 2H+ nucleus.
m/e ratio of 2H+ = 2
m/e ratio of 1H+ = 1
or
charge / mass =
charge / mass = 1
[1]
[2]
[1]
Draw the occupied orbitals found in nitrogen. Name the orbital shapes.
Note:
Shape:
[3]
1s orbital
ACJC Chemistry Department (2014)
H2 Chemistry 9647
Figure below shows the energy required to remove eight electrons, one at a time, from an
atom of element Q.
log10 (I.E.)
(a) (i) To which group in the Periodic Table does this element Q belong?
[1]
Group V
(ii) What is the electron arrangement in the outer shell of Q?
2
[1]
ns np
[1]
[1]
The no. of protons is constant while the no. of electrons decreases. The attraction
experienced per remaining electron by the constant positive charge of the nucleus increases.
(c) Why is the energy difference between the removal of the 5 th and the 6th electrons much
larger than the energy difference between the removal of the 4 th and the 5th electrons?
[1]
The 4th and the 5th electrons are in the same outermost principal quantum shell, while the 6 th
electron is in the next inner quantum shell, hence nearer to the nucleus (stronger attraction
of the electron by the nucleus, so needs more energy to remove electron).
(d) Write the full electronic configuration of the element in Period 4 that could be the element
Q.
[1]
Group V: Arsenic
As: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p3
33