PAPER? M2 (Single Correct Choice Type) 1. The complex showing a spin-only magnetic moment of 2.62 B.M. is A) Ni(CO), B) [NiCL]> C) Ni(PPhs), D) INUCN) I> 2. The species having pyramidal shape is A) SO, B) BYF, ©) S10. D) OSF, 2 (1) NaOH/Bry 3. In the reaction nc—_S—& = the structure of the i Cc) HWWeXy p-NH ep o 4. The compounds P, @ and S 00H och, 7 Ho" c Q were separately subjected to nitration using HNO,/H,SO, mixture. The major product formed in each ease respectively, 1s ocH, A) _ ON OCH; B) c) D)5, The packing efficiency of the two-dimensional square unit cell shown below is A) 39.27% B) 68.02% ©) 74.05% D) 78.54% Mere Ly 6. Assuming that Hund’s rule is violated, the bond order and magnetic nature of the diatomic molecule B, is A) 1 and diamagnetic —C) 1 and paramagnetic B) 0 and diamagnetic —_D) O and paramagnetic SECTION - II \(Integer Type) 7. The total number of diprotic acids among the following is HPO, HySO4 HgPO3 HCO3 HyS907 HBO; HPO, H,CrO4 H)S03 8. Total number of geometrical isomers for the complex [RhCI(CO}(PPh,)(NHg)] is 9. Among the following, the number of elements showing only one non-zero oxidation state is oO, Cl. . NP, Sn, Tl. Na, Ti 10. Silver (atomic weight = 108 g mol"}) has a density of 10.5 g cm. The number of silver atoms on a surface of area 10-)? m? can be expressed in scientific notation as y x 10, The value of x is 11. One mole of an ideal gas is taken from a to b along two paths denoted by the solid and the dashed lines as shown in the graph below. If the worl done along the solid line path is w, and that along the dotted line path is w, then the integer closest to the ratio wy/w, 1s p 2 faumy?® oo oo 05 10 18 20 26 30 28 40 45 50 55 90SECTION — III) (Paragraph Type) Paragraph for Questions 12 to 14. ‘Two aliphatic aldehydes P and @ react in the presence of aqueous KyCOs to give compound R, which upon treatment with HCN provides compound S. On acidification and heating, S gives the product shown below HC on HC7 Th \o So 12. ‘The compounds P and Q respectively are CHy cu, CH. H KSC. as ot Ne and ee and A) Hc Y OS ea oO o=d p=o c) mem en t cH on 14. The compound $ is me Hl B) He ~H ch on onParagraph for Questions 15 to 17. The hydrogen-like species Li?* is in a spherically symmetric state S, with one radial node. Upon absorbing light the ion undergoes transition to a state Sy. The state S, has one radial node and its energy is equal to the ground state energy of the hydrogen atom. 15. The state S; is A) Is B) 2s Cc) 2p D) 3s 16. Energy of the state S; in units of the hydrogen atom ground state energy is A) 0.75 B) 1.50 C) 2.25 D) 4.50 17. The orbital angular momentum quantum number of the state S, is A)O B)1 cj) 2 D) 3 SECTION - IV) (Matrix Type) 18, Match the reactions m Column I with appropriate options in Column I. Column I Column II AY Opn + Chon “OE Oy p) Racemic mixture eon so, B) uc-b—-cx, = éueu, q) Addition reaction r) Substitution reaction D) w—>-a Batt s) Coupling reaction t) Carbocation intermediate 19. All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate options listed In Column IL Column I Column IT A) (CH,),SiC1, Pp) Hydrogen halide formation B) XeF, q) Redox reaction c) Cl, r) Reacts with glass D) vcl, s) Polymerization t) O, formationUES EB eis hey or) (SECTION —I_ (Single Correct Choice Type) 20. For r =0, 1, ... 10, let A B, and C, denote, respectively, the coefficient of 3 im the expansions of (1+%)19, (14)20 and (1+n)90, Then 19 > Ay BioBy - Cio Ar) = Is equal to MEWS FA SM—Sera) 8 DI Cio Bro 21. Let S , 4}. The total number of unordered pairs of disjoint subsets of S is equal to A) 25 B) 34 ©) 42 D) 41 22. Let f be a real-valued function defined on the interval (-1, 1) such that e* fag =2+ J At? +1dt, for al xe (-1,1), and let £1 be the inverse ftmction of f a Then (f7)' (2) is equal to aa BA ot p) 2 Us| 2 de 23. If the distance of the point P(1, -2, 1) from the plane x + 2y -2z = o, where @ > 0, is 3, then the foot of the perpendicular from P to the plane is 4 41 1210 B) (5: | a (e3 3] ‘Two adjacent sides of a parallelogram ABCD are given by ® AB =2i+10)+11kand AD =-1+2j+2k The side AD is rotated by an acute angle u in the plane of the parallelogram so that AD becomes AD’. If AD’ makes a right angle with the side AB, then the cosine of the angle o. is given by viz B) — ° 2 5 5 D) olan a5 = A) 4a 25. A signal which can be green or red with probability 4 and= respectively, is received by station A and then transmitted to station B. The probability of each station 3 receiving the signal correctly is +. If the signal received at station B is green, a then the probability that the original signal was green is 6 20 9 BF ° $3 pb) 2 ala A)26, SECTION - II | (Integer Type) Two parallel chords of a circle of radius 2 are at a distance J3+1 apart. If the chords tan =, where k > ©, then the value of [kis (Note : [i] denotes the largest integer less than or equal to I] subtend at the center, angles of . Consider a triangle ABC and let a, b and ¢ denote the lengths of the sides opposite to vertices A, B and C respectively. Suppose a = 6. b = 10 and the area of the triangle is 15V3. If ZACB is obtuse and if r denotes the radius of the incircle of the triangle, then 1? is equal to Let f be a function defined on R (the set of all real numbers) such that f(x) =2010(x-2009)(x-2010)?(x- 2011) («- 2012). for allx € R. If g 1s a function defined on R_ with values in the interval (0, 00) such that fix) =m (¢ (3). forallxe R, then the number of points in R at which g has a local maximum is Let ay, Ag, Ag... » Ay, be real numbers satisfying a,=15, 27-2a,> 0 and a, = 2a, 1 - a,» fork = 3, 4,..., 11. ta2+.ta2, ll If 90, then the value of is equal to30. Let k be a positive real number and let Qk wk wir Oo aki vk 2k 1 -2k | na B-l1-2k 0 2K |. -WKe Mk 1 -vk -2k 0 If det (adj A) + det(adj B) =10%, then [k] is equal to INote : adj M denotes the adjoint of a square matrix M and [kl denotes the largest integer less than or equal to kj. SECTION - III) (Paragraph Type) Paragraph for questions 31 to 33. Consider the polynomial f[x)=1+ 2x + 3x? + 4x3. Let s be the sum of all distinct real roots of f(x) and let t = |s| 31. The real number s lies in the interval 4) (-$) B) (ou. 32. The area bounded by the curve y the interval 3 eign ; A) (5°) B) (erie) ©) (9.10) 33. The function f(s) Is A) increasing in (- |] and decreasing In ( B) decreasing im {-t,- 1 al and increasing in ( C) increasing in (-t. 0 D) decreasing in (-t, t) Paragraph for Questions 84 to 36. ‘Tangents are drawn from the pomt P(3, 4) to the ellipse touching the ellipse at points A and B.34. The coordinates of A and B are A) (3.0) and ©, 2) _8 2v161 O18 15 Jose 2) 35. The orthocenter of the triangle PAB is ai(s8) 36. The equation of the locus of the point whose distances from the point P and the line AB are equal, is A) 9x? + y?_ Gxy - 54x - 62y + 241 =0 B) Oy? + 6xy - 54x + 62y- 241 =0 C) 9x? + Sy? — Oxy - 54x - 62y - 241 =0 D) x? +y? - Qxy + 27x + 31y- 120=0 SECTION - IV) (Matrix Type) 37. Match the statements in Column-I with those in Column-IL (Note: Here z takes values in the complex plane and Im z and Re z denote, respectively, the imaginary part and the real part of z.] Column I A) The set of points z satisfying ke-alz[=fe+il2| is contained in or equal to B) The set of points z satisfying |z+4] + |2-4] =10 Is contained in or equal to C) If |w| = 2, then the set of points 1 2=W-= is contained in or equal to D) If [wl] = 1, then the set of points Ll, Z=Ww+— is contained in or equal to w Column IL 4 p) an ellipse with eccentricity 5 q) the set of points z satisfying Im z = 0 1) the set of points 2 satisfying |Im 2| <1 s) the set of points z satisfying [Re z| < 2 t) the set of points z satisfying |88. Match the statements in Column-I with the values in Column-IL. Column I Column IT A) A line from the origin meets the lines p)-4 lat PandQ respectively. If length PQ = d, then d? is B) The values of x satisfying tan”! (x + 3) — tan” (x — 9) = sin} qo C) Non-zero vectors 4,bandé satisfy (6 -4).(6 +8) =0and 2|+é |=|b-a|. If A=ub+46, then the possible values of | are na D) Let f be the function on [-z,x] given by ox x £0) = 9 and fos) = sin} |/sin|> | tor x0. s) 5 rn 2 Sadx The value of = Jfts) dx is nm on u6 eeepc (Single Correct Choice Type) 39. A Vernier calipers has 1 mm marks on the main scale. It has 20 equal divisions on the Vernier scale which match with 16 main scale divisions. For this Vernier calipers, the least count is A) 0.02 mm B) 0.05 mm c) 0.1 mm D) 0.2mm 40. A hollow pipe of length 0.8 m Is closed at one end. At its open end a 0.5 m long uniform string is vibrating in its second harmonic and it resonates with the fundamental frequency of the pipe. If the tension in the wire is 50 N and the speed of sound is 320 ms-1, the mass of the string is A) 5 grams B) 10 grams C) 20 grams D) 40 grams41. A biconvex lens of focal length 15 cm is in front of a plane mirror. The distance between the lens and the muror is 10 cm. A small object is kept at a distance of 20 cm from the lens. The final image is A) virtual and at a distance of 16 cm from the mirror B) real and at a distance of 16 cm from the mirror C) virtual and at a distance of 20 cm from the mirror D) real and at a distance of 20 cm from the mirror 42. A block of mass 2 Kg is free to move along the x-axis. It is at rest and from r= 0 onwards it is subjected to a time-dependent force Fi) in the x direction. The force F(t) varies with tas shown in the figure. The kinetic energy of the block after 4.5 seconds is Fall 4N A) 4.500 B) 7.503 ©) 5.06.5 D) 14.06 3 43, A tiny spherical of! drop carrymg a net charge q is balanced in still air with a sins vertical uniform electric field of strength ——*10° vm). When the field is switched off, the drop is observed to fall with terminal velocity 2 x 10-3 m 1 and the density of Given g = 9.8 m s~, viscosity of the air = 1.8 x 10° Ns m“ oil = 900 kg m™, the magnitude of q is A) 16x 1012C B) 3.2x10C OC) 48x10#C —_D) 8.0 x 101°C 44. A uniformly charged thin spherical shell of radius R carries uniform surface charge density of ‘oper unit area. It is made of two hemispherical shells, held together by pressing them with force F (see figure), Fis proportional toSECTION - II) (Integer Type) 1 45. A diatomic ideal gas is compressed adiabatically to 55 of its initial volume. In the initial temperature of the gas is T, (in Kelvin) and the Mnal temperature is aT,, the value of ais 46. At time (= 0, a battery of 10 V is connected across 2ma ae pots A and B in the given cireuit. If the capacitors MW, have no charge initially, at what time (in seconds) does © a the voltage across them become 4 V ?. a Www 2Ma 2uk Make : ¢n 5 = 1.6, ¢n3 = 1.11 45. A diatomic ideal gas is compressed adiabatically to a of its initial volume. In the initial temperature of the gas is 7; (in Kelvin) and the final temperature is aT,, the value of a is 47. Image of an object approaching a convex mirror of radius of curvature 20 m along its optical axis is observed to move from 7 m to 2 m in 30 seconds. What is the speed of the object in km per hour ? * 48. A large glass slab (t1=5/3) of thickness 8 cm is placed over a point source of light ona plane surface. It is seen that light emerges out of the top surface of the slab from a circular area of radius Rem. What is the value of R? 49. To determine the half life of a radioactive element, a student plots a graph of an (a) aN it) versus t. Here x is the rate dt of radioactive decay at time ¢ If the number of radioactive nuclei of this element decreases by a factor of p after 4.16 years, the value of p is SECTION - Ill] (Paragraph Type) Paragraph for questions 50 to 52. When liquid medicine of density © is to be put in the eye, it is done with the help of a dropper. As the bulb on the top of the dropper is pressed, a drop forms at the opening of the dropper. We wish to estimate the size of the drop. We first assume that the drop formed at the opening is spherical because that requires a minimum increase in its surface energy. To determine the size, we calculate the net vertical force due to the surface tension T when the radius of the drop is _R. When this force becomes smaller than the weight of the drop, the drop gets detached ftom the dropper. en50. If the radius of the opening of the dropper is r, the vertical force due to the surface tension on the drop of radius R (assuming r <x10” kg, is close to 3 A) 2.410790 m B) 19x10!m —C) 1.3%1010m D) 4.4x104 mSECTION - IV] (Matrix Type) 56, Two transparent media of refractive indices J, and yg have a solic lens shaped transpar material of refractive index Jay between them as shown in figures in Column Tl. A traversing these media is also shown in the figures. In Column I different relationsh between }y.}2 and Ag are given. Match them to the ray diagrams shown in Column Column 1 A) F< Pe B) Wl > Bo ©) Be =H D) Bo > Hs Column I P) g y 3) 0 ty) ‘)57. You are given many resistances, capacitors and inductors. These are connected to variable DC voltage source (the first two circuits) or an AC voltage source of 50 Hz frequenc (the next three circuits) in different ways as shown in Column I. When a current (steady state for DC or rms for AC) flows through the circuit, the corresponding voltage V and V5. (dicated in circuits) are related as shown m column I. Match the two Column I A) 1#0.V, is proportional to T B) 1#0,V,>V, ©) Vj=0.V,=V D) I #0,V> is proportional to 1 Column II ee erred P) em) Sue ts <4, Q 9 pwns