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Name:______________________

Student ID Number: ____________________

Chemistry 161
Final Exam
Spring 2015
This 120 min exam consists of 50 multiple choice questions.
For each answer, CIRCLE the letter corresponding to the correct answer on the ANSWER
SHEET. You will only be turning in the answer sheet.
You will find a periodic table and a list of constants and conversion factors attached to the end of
the exam.
Programmable/graphing calculators and notes are not allowed in this exam.
Significant Figures must be taken into account on all calculations.

SUGGESTIONS:
Every question is of equal value, do not get stalled on more difficult problems.
There are no penalties for wrong answers. Thus, answer every single question.
If you make corrections, be clear. If the grader has to guess what your answer is, they will guess
that your answer is wrong.
There is no room for cheating. Integrity is hallmark in science and violations of the Student
Conduct Code could result in an expulsion from UH Manoa. It is not worth the risk.
(www.studentaffairs.manoa.hawaii.edu/policies/conduct_code/)

Chem 161 Final Exam Spring 2015, page 1

Name:______________________
1.
a.
b.
c.
d.
e.

Observations Hypothesis  Experiments  Hypothesis  Experiments


Hypothesis  Experiments  Observations Theory  Experiments
Hypothesis  Experiments  Observations  Theory Observations
Observations  Hypothesis  Theory  Hypothesis  Experiments
Theory  Experiments Hypothesis  Observations  Experiments

a.
b.
c.
d.
e.

314 K
41.1 K
-232 K
223 K
496 K

a.
b.
c.
d.
e.

The proton is in the nucleus with neutral charge


The nucleus is roughly 25% of the atoms volume
The electron is a very small mass with positive charge
The proton contains all of the atoms mass and very little volume
The proton contains all of the atoms mass, and all of the atoms volume

a.
b.
c.
d.
e.

118 protons, 50 neurons, 118 electrons


118 protons, 118 neutrons, 50 electrons
50 protons, 68 neutrons, 50 electrons
68 protons, 68 neutrons, 50 electrons
50 protons, 50 neutrons, 50 electrons

a.
b.
c.
d.
e.

transition metal
halide
alkali metal
inner transition metal
alkali earth metal

2.

3.

4.

5.

Chem 161 Final Exam Spring 2015, page 2

Name:______________________

6.
a.
b.
c.
d.
e.

Kr
Br
Se
O
Ne

a.
b.
c.
d.
e.

32.2 x 1023
3.32 x 1024
6.02 x 1023
9.17 x 10-24
91.7 x 10-25

a.
b.
c.
d.
e.

S2Cl2
S2Cl
S2Cl4
SCl
SCl2

a.
b.
c.
d.
e.

CaSO4
CaSO3
(Ca)2SO4
Ca(SO4)2
Ca2(SO4)2

a.
b.
c.
d.
e.

C3H2O5
C4H6O4
C5H10O3
C6H14O2
C7H18O

7.

8.

9.

10.

Chem 161 Final Exam Spring 2015, page 3

Name:______________________
11.
a.
b.
c.
d.
e.

K3PO4 +
K3PO4 +
2K3PO4 +
2K3PO4 +
K3PO4 +

Ca(NO2)2 Ca3(PO4)2 + KNO2


Ca(NO2)2 Ca3(PO4)2 + 3KNO2
Ca(NO2)2 Ca3(PO4)2 + 6KNO2
3Ca(NO2)2 Ca3(PO4)2 + 6KNO2
Ca(NO2)2 Ca3(PO4)2 + KNO2

a.
b.
c.
d.
e.

2.50 M
146 M
4.00 M
0.400 M
0.250 M

a.
b.
c.
d.

SrCl2
Li3PO4
Sr3(PO4)2
LiCl

a.
b.
c.
d.
e.

loss of electrons
increase in oxidation state
Fe2+ Fe3+
gain of oxygen
gain of electrons

a.
b.
c.
d.

Sn2+
Fe3+
Sn4+
Fe2+

12.

13.

14.

15.

Chem 161 Final Exam Spring 2015, page 4

Name:______________________
16.
a.
b.
c.
d.
e.

10.76 psi
706.6 psi
5.661 x 10-2 psi
12.23 psi
3.270 x 104 psi

a.
b.
c.
d.
e.

4.22 L
1.76 L
1.41 L
8.91 L
0.701 L

a.
b.
c.
d.
e.

11.6 atm
0.806 atm
0.154 atm
2.32 atm
1.16 atm

a.
b.
c.
d.
e.

47. 5 L
29.7 L
47.4 L
48.2 L
27.5 L

a.
b.
c.
d.
e.

H2
HCl
N2
Cl2
SO2

17.

18.

19.

20.
1

# of particles

2
3
4
5

velocity

Chem 161 Final Exam Spring 2015, page 5

Name:______________________

21.
a.
b.
c.
d.
e.

Avagadros Law
Boyles Law
Charless Law
Daltons Law
Einsteins Law

a.
b.
c.
d.
e.

Lead (CS = 0.128 J/gC)


Silver (CS = 0.235 J/gC)
Iron (CS = 0.449 J/gC)
Water (CS = 4.18 J/gC)
Sand (CS = 0.840 J/gC)

22.

23.

a. -177.9 kJ

b. -355.8 kJ

c. 457.0 kJ

d. 177.9 kJ

e. -457.0 kJ

24.
a.
b.
c.
d.
e.

radio waves
microwaves
gamma waves
ultraviolet radiation
XRAY

a.
b.
c.
d.
e.

4, 3, 2
4, 2, -3
3, 1, 0
3, 0, 1
3, 3, -2

25.

Chem 161 Final Exam Spring 2015, page 6

Name:______________________
26.

a.

b.

c.

d.

e.

27.
a.
b.
c.
d.
e.

1s22s22p63s23p64s23d104p2
1s22s22p63s23p64s24p2
1s22s22p63s23p64s24d104p2
1s22s22p63s23p64s23d12
1s22s22p63s23p64s22d104p2

28.

a.
b.
c.
d.
e.
29.
a.
b.
c.
d.
e.

Po
Cs
Te
C
Rn

a.
b.
c.
d.
e.

Ca
Rb
Fr
Ge
F

30.

Chem 161 Final Exam Spring 2015, page 7

Name:______________________

31.

a.

2-

b.

2-

c.

2-

d.

2-

e.

2-

32.

a. Na2+ F

2-

b. Ca3+ O

c. Ca+ F

2-

1-

d. Na1+ F

1-

e. Mg2+ I

2-

33.
H
H

a.

H
S

b.

H
S

c.

H
S

d.

H
S

e.

34.
H

a. H

b.

C
Cl

c.

d.

e.

C
H

d. H

H
C

C
H

35.

a. H

b. H

c. H

e.

Chem 161 Final Exam Spring 2015, page 8

Name:______________________
36.
a.
b.
c.
d.
e.

-2
-1
0
+1
+2

a.
b.
c.
d.
e.

0
1
2
3
4

CH3
+

H3C

CH3

37.

O
O

38.
F

a.

b.

c.

F
F

S
F

F
+

d.

F
+

e.

F
F

39.
a.
b.
c.
d.
e.

1 single bond, 3 lone pairs


2 single bonds, 2 lone pairs
3 single bonds, 1 lone pair
1 triple bond, 1 lone pair
4 single bonds

40.
H
H
C

a.

C
H

C
C

C
N

b.

C
H

C
N

c.

H
C

C
H

C
N

C
C

d.

H
C

e.

3-

C
H

3-

3-

Chem 161 Final Exam Spring 2015, page 9

Name:______________________
41.

a.

b.

c.

d.

e.

42.
a.
b.
c.
d.
e.

linear
bent
trigonal planar
tetrahedral
octahedral

a.
b.
c.
d.
e.

trigonal bipyramidal
see-saw
trigonal pyramidal
T-shaped
trigonal planar

a.
b.
c.
d.
e.

BrH
CH4
NH3
H2O
CH2O

a.
b.
c.
d.
e.

square planar
trigonal pyramidal
tetrahedral
bent
T-shaped

43.

44.

45.

Chem 161 Final Exam Spring 2015, page 10

Name:______________________
46.
a.
b.
c.
d.
e.

HO

#1
#2
#3
#4
#5

HO

5
3

HO

O
2

H
1

47.

a.

b.

c.

d.

e.

48.

a.
b.
c.
d.
e.

H22Ne2
He22+
F22Li22-

a.
b.
c.
d.
e.

0
1
2
3
4

a.
b.
c.
d.
e.

6
11
2
41
10

49.

50.
H3C

CH3

CH3

CH3

H3C

CH3

CH3

CH3

H3C

CH3

Chem 161 Final Exam Spring 2015, page 11

Name:______________________

Chem 161 Final Exam Spring 2015, page 12

Name:______________________
List of constants and conversions
2.54 cm = 1 in.
1 lb = 453.6 g = 16 oz
1 L = 1.057 qt
1 mL = 1 cc = 1 cm3
1 qt = 4 cups = 2 pints = 0.25 gal
1 atm = 14.7 psi = 760 mmHg =760 torr = 101.325 kPa
1 cal = 4.184 J
1 kWh = 3.60 x 106 J
TK = TC + 273
TF = 1.8 (TC) + 32o
23
NA = 6.02210
M = mol/L
PV = nRT
R = 0.08206 (L atm)/(mol K)
qrxn = -qcal
Cs = J/(g oC)
Hrxn = qrxn = mCsT
= c/ = h/(mv)
E = h
h = 6.62610-34 Js
En = -2.1810-18 J(1/n2)
pH = -log(H+)
Ka = [H3O+][A-]/[HA]
+
-24
p = 1.67310 g = 1.007 amu
n = 1.67510-24 g = 1.008 amu
e = 9.11010 -28 g = 0.00055 amu
c = 3 x 108 m/s

Some common polyatomic ions


Hydroxide, OH
nitrate, NO3
sulfate, SO42
chlorate, ClO3
hypochlorite, ClO
phosphate, PO43
acetate, C2H3O2

cyanide, CN
ammonium, NH4+
perchlorate, ClO4
chlorite, ClO2
carbonate, CO32
chromate, CrO42
permanganate, MnO4

Unit Prefixes
giga(G)
mega(M)
kilo(k)
deci(d)
centi(c)
milli(m)
micro()
nano(n)
pico(p)
femto(f)

= 109
= 106
= 103
= 10-1
= 10-2
= 10-3
= 10-6
= 10-9
= 10-12
= 10-15

Soluble Ions (Exception)


1. Li+, Na+, K+, NH4+ (none)
2. NO3, C2H3O2 (none)
3. Cl, Br, I (Ag+, Hg22+, Pb2+)
4. SO42 (Ca2+, Sr2+, Ba2+, Pb2+, Ag+)
Insoluble Ions (Exception)
_
2
+
+
+
+
3
2
PO4 , CO3 , S , OH (Li , Na , K , NH4 )

Chem 161 Final Exam Spring 2015, page 13

4.003

He

9.012

Be

10.81

12.01

14.01

16.00

19.00

18

Neon

20.18

Ne

10

Li

17

Fluorine

Helium

6.941

16

Oxygen

39.95

Ar

15

35.45

Cl

Nitrogen

14

32.06

Carbon

13

30.97

Boron

Si

12

28.09

Beryllium

26.98

Al

83.80

Kr

24.31

79.90

Br

Mg

78.96

Se

22.99

74.92

As

36

30

72.59

Ge

Argon
29

69.72

Ga

35

28

65.39

Zn

Chlorine

27

63.55

Cu

34

26

58.69

Ni

Sulfur

25

58.93

Co

33

24

55.85

Fe

Phosphorus

23

54.94

Mn

32

22

52.00

Cr

Silicon

21

31

20

Magnesium

50.94

Aluminum

19

Sodium

Ti

54

Krypton

47.88

53

Bromine

44.96

52

Selenium

Sc

51

Arsenic

40.08

50

Germanium

Ca

49

Gallium

48

Zinc

131.3

Xe

47

Copper

126.9

46

127.6

Te

Nickel

121.8

Sb

45

118.7

Sn

Cobalt

In

44

114.8

Iron

112.4

Cd

43

107.9

Ag

Manganese

106.4

Pd

42

102.9

Rh

Chromium

101.1

Ru

41

(98)

Tc

86

Xenon

Vanadium

95.94

Mo

85

Iodine

40

92.91

Nb

84

Tellurium

Titanium

91.22

Zr

83

Antimony

39

82

Tin

Scandium

88.91

81

Indium

38

Sr

80

Cadmium

Calcium

87.62

79

Silver

37

85.47

Rb

78

(220)

Rn

Palladium

(210)

At

77

(209)

Po

Rhodium

209.0

Bi

76

207.2

Pb

Ruthenium

Tl

75

204.4

Technitium

200.6

Hg

74

197.0

Au

Molybdenum

Pt

73

195.1

Niobium

Ir

72

192.2

Zirconium

190.2

Os

57

186.2

Re

Yttrium

183.9

56

180.9

Ta

Strontium

174.9

Hf

55

138.9

118

Radon

La

117

Astatine

137.3

116

Polonium

Ba

115

Bismuth

132.9

114

(294)

Uuo

Lead

Uus

113

Lv

(294)

Thallium

Uup

(293)

112

Fl

(288)

Mercury

(289)

111

Uut

Flerovium

Gold

(286)

110

Cn

Ununtriium

Platinum

Rg

(285)

109

Ds

(281)

Iridium

Mt

(281)

108

(278)

Osmium

Hs

Meitnerium

107

(269)

Rhenium

Bh

Hassium

106

(270)

Tungsten

Sg

Bohrium

105

(269)

Tantalum

Db

Seaborgium

104

(268)

Hafnium

Rf
Dubnium

89

(267)

Lanthanum

Ac
Rutherfordium

88

227.0

Barium

Ra
Actinium

87

Fr
226.0

Pr

59

144.2

Nd

60

(145)

Pm

61

150.4

Sm

62

152.0

Eu

63

157.3

Gd

64

158.9

Tb

65

162.5

Dy

66

164.9

Ho

67

167.3

Er

68

168.9

Tm

69

173.0

Yb

70

175.0

Lu

71

Ununoctium

Radium

58

140.9

Ununpentium Livermorium Ununseptium

(223)

140.1

103

(262)

Lr

Lutetium

No

102

(259)

Ytterbium

Md

Nobelium

101

(258)

Thulium

Fm

Mendeleevium

100

(257)

Erbium

Es

Fermium

99

(252)

Holmium

Cf

Einsteinium

98

(251)

Dysprosium

Bk

Californium

97

(247)

Terbium

Cm

Berkelium

96

(247)

Gadolinium

Am

Curium

95

(243)

Europium

Pu

Americium

94

(244)

Samarium

Np

Plutonium

93

237.0

Promethium

Neptunium

92

238.0

Neodymium

Pa

Uranium

91

231.0

Praseodymium

Th

Protactinium

90

232.0

Lawrencium
Thorium

Cerium

Ce

Darmstadtium Roentgenium Copernicium

Francium

Cesium

Cs

Rubidium

Potassium

39.10

Na

11

The Periodic Table of the Elements

Chem 161 Final Exam Spring 2015, page 14

Lithium

Hydrogen

1.008

Name:______________________

Name:______________________

Answer Sheet
1.

a.

b.

c.

d.

e.

26.

a.

b.

c.

d.

e.

2.

a.

b.

c.

d.

e.

27.

a.

b.

c.

d.

e.

3.

a.

b.

c.

d.

e.

28.

a.

b.

c.

d.

e.

4.

a.

b.

c.

d.

e.

29.

a.

b.

c.

d.

e.

5.

a.

b.

c.

d.

e.

30.

a.

b.

c.

d.

e.

6.

a.

b.

c.

d.

e.

31.

a.

b.

c.

d.

e.

7.

a.

b.

c.

d.

e.

32.

a.

b.

c.

d.

e.

8.

a.

b.

c.

d.

e.

33.

a.

b.

c.

d.

e.

9.

a.

b.

c.

d.

e.

34.

a.

b.

c.

d.

e.

10.

a.

b.

c.

d.

e.

35.

a.

b.

c.

d.

e.

11.

a.

b.

c.

d.

e.

36.

a.

b.

c.

d.

e.

12.

a.

b.

c.

d.

e.

37.

a.

b.

c.

d.

e.

13.

a.

b.

c.

d.

e.

38.

a.

b.

c.

d.

e.

14.

a.

b.

c.

d.

e.

39.

a.

b.

c.

d.

e.

15.

a.

b.

c.

d.

e.

40.

a.

b.

c.

d.

e.

16.

a.

b.

c.

d.

e.

41.

a.

b.

c.

d.

e.

17.

a.

b.

c.

d.

e.

42.

a.

b.

c.

d.

e.

18.

a.

b.

c.

d.

e.

43.

a.

b.

c.

d.

e.

19.

a.

b.

c.

d.

e.

44.

a.

b.

c.

d.

e.

20.

a.

b.

c.

d.

e.

45.

a.

b.

c.

d.

e.

21.

a.

b.

c.

d.

e.

46.

a.

b.

c.

d.

e.

22.

a.

b.

c.

d.

e.

47.

a.

b.

c.

d.

e.

23.

a.

b.

c.

d.

e.

48.

a.

b.

c.

d.

e.

24.

a.

b.

c.

d.

e.

49.

a.

b.

c.

d.

e.

25.

a.

b.

c.

d.

e.

50.

a.

b.

c.

d.

e.

Chem 161 Final Exam Spring 2015, page 15

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