Revista Boliviana de Qumica

Rev. Bol. Quim. ISSN 0250-5460

Rev. boliv. quim. ISSN 2078-3949

Bolivian Journal of Chemistry

Vol. 32, No. 1, 2015
Abstracts Rsum
INTERACTION OF ISOLEUCINE WITH METAL IONS IN CHEMICAL AND BIOLOGICAL SYSTEMS
PAG. 1

Brij B. Tewari*1, Ashish K. Tiwari2,3

1

Department of Chemistry, Faculty of Natural Sciences, University of Guyana, P. O. Box: 101110,

Georgetown, Guyana

Indian Institute of Technology IIT-Kanpur, Kalyanpur, Kanpur, Uttar Pradesh 208016, Tel. +91 512 259
0151
Kanpur, India

Indian Institute of Technology IIT-Jodhpur, Old Residency Road, Ratanada, Jodhpur, Rajasthan, Jodhpur,
R]ajasthan 342011, India, Tel. +91 291 244 9013, Jodhpur, India

Keywords: Stability constants, paper ionophoretic technique, isoleucine, zinc (II) complexes,
cadmium (II) complexes and iron(II) complexes.

ABSTRACT
The stability constants of Zn2+, Cd2+ and Fe2+ complexes with isoleucine were determined by paper ionophoretic
technique. The present method is based on the movement of a spot of metal ions in an electric field at various
pHs of background electrolyte. A graph of pH versus mobility was used to obtain information on the binary
complexes and to calculate its stability constants. Using this method, the stability constants of binary complexes
metal(II) isoleucine have been determined to be (7.24 0.01, 3.48 0.04); (6.90 0.01, 3.25 0.11) and (6.50
0.03, 2.97 0.07) (logarithm stability constant values) for Zn(II), Cd (II) and Fe(II) complexes respectively at
ionic strength 0.01 Mol L-1 and a temperature of 35C. Spanish title: Interaccin de isoleucina con iones metlicos en sistemas
qumicos y biolgicos.

*Corresponding author: brijtewari2011@yahoo.com

SAPONINS FROM CHENOPODIUM QUINOA WILLD AND CHENOPODIUM

PALLIDICAULE AELLEN AS BIOCONTROLLERS OF PHYTOPATHOGEN FUNGI AND
HEMOLYSIS AGENTS
PAG. 8

Bianca Guzmn, Reynaldo Tenorio, Dora L. Cruz, Christian Espinal, Juan A.

Alvarado, Patricia Mollinedo
Department of Chemistry, Laboratorio de Pruebas Biolgicas, Instituto de Investigaciones en Productos
Naturales IIPN, Universidad Mayor de San Andrs UMSA, P.O. Box 303, Calle Andrs Bello s/n, Ciudad
Universitaria Cota Cota, Tel. 59122792238, La Paz, Bolivia

Keywords: Quantification of Saponins, Quinoa, Canihua.

ABSTRACT
Saponins for its properties as a biopesticide and biocontrol of plant pathogenic fungi, such as Aspergillus and
Fusarium, have the ability to produce red blood cells rupture, which can be measured by the hemolytic index. In
this paper the biocontrol activity of saponins extracted from two species of Chenopodium (Quinoa and canihua)
possible degree of toxicity and eco hemotoxicity, in vitro. We worked with ratings PROINPA samples, extraction
of saponins was carried out in aqueous medium. Growth charts and inhibition show that the M-16 extract
(saponin) has biocotroladora ability on strains Bol RT-1 (Fusarium sPp) and Bull JR-1 (Aspegilius flavus) with
an inhibition at 12 days to 47.6 %, 42% respectively. Ecotoxicity of Daphnia magna show that at a concentration
of 25% w / v saponin extracts are not significantly toxic to the environment, the results of tests of hemotoxicity,
HC50 has a value of 0.58 mg / ml, the RBC hemolysis was performed by quantification of saponins, it is
observed that at a concentration of saponin 0.320 mg / ml (sample 12) A 32. 215% of red cells are lysed, showing
a value not too high toxicity. Sample 16 (saponin) proved to have an efficient inhibitory effect on growth of
Aspergillus flavus and Fusarium spp. is not efficient within a short time, but long term if you could control these
pests, with the added benefit of safe use for protection of the environment as shown in the proof of ecotoxicity
and safe for users as checks haemotoxicity assays.
Original spanish title: saponinas de chenopodium quinoa willd y caihua chenopodium pallidicaule aellen como agente biocontrolador de
hongos fitopatogenos y agente hemolisante.

*Corresponding author: bguzmancondarco@gmail.com

MECHANISTIC VIEWS OF STEREOSELECTIVE SYNTHESIS OF TRI- AND TETRA-SUBSTITUTED
ALKENES, PART II; THE ORGANIC CHEMISTRY NOTEBOOK SERIES, A DIDACTICAL
APPROACH, N 4
PAG. 15

Jos A. Bravo, Jos L. Vila

Department of Chemistry, Laboratorio de Sntesis y Hemisntesis, Instituto de Investigaciones en Productos
Naturales IIPN, Universidad Mayor de San Andrs UMSA, P.O. Box 303, Calle Andrs Bello s/n, Ciudad
Universitaria Cota Cota, Tel. 59122792238, La Paz, Bolivia

Keywords: Organic Chemistry, Stereoselective synthesis, Alkenes, Addition reaction,

Mechanisms of Reactions.

ABSTRACT
This is the complementing part of the previously published: Mechanistic views of stereoselective synthesis of
tri- and tetra-substituted alkenes, part I; The Organic Chemistry Notebook Series, a Didactical Approach, N 3.
As underlined in three previous papers the presentation of synthesis works in a verbal and graphical succinct
manner, needs a didactical approach. Isomerically pure tri- and tetra-substituted alkenes are difficult to obtain as
shown in several publications. We used a series of reactions to synthesize tri- and tetra-substituted alkenes as

reviewed by W. Carruthers, and we have proposed didactical and mechanistic views for the reviewed reactions.
These two latest approaches are included in the synthetic methods reviewed by W. Carruthers with respect to the
Formation of carbon-carbon double bonds. Spanish title: Vistas mecansticas de sntesis estereoselectivas de alquenos tri y
tetrasubstituidos, Parte II, Serie: El cuaderno de notas de qumica orgnica, un enfoque didctico, N4.

*Corresponding author: jabravo@umsa.bo