Académique Documents
Professionnel Documents
Culture Documents
ENGLISH
ESPAOL
FRANAIS
DEUTSCH
ITALIANO
PORTUGUS
Page 1 of 3
SVENSKA
POLSKI
ESK
ROMN
MAGYAR
TRKE
Quick Login
HOME
E-mail:
Password:
Key Benefits
How it Helps
Fact Sheet
Multiuser
FAQ
Contact
Order Now
Font size
Print page
INFO
News
Quick Tour
Articles
FREE AREA
PowerDemo Online
Free Download
SUBSCRIBERS AREA
Login
Abstract:
Shape memory alloys (SMAs) are metals which exhibit two very unique properties, pseudo-elasticity
and the shape memory effect.
Because these materials are relatively new, some of the engineering aspects of the materials are
still not well understood. Many of the typical engineering descriptors, such as Young's modulus and
yield strength, do not apply to shape memory alloys since they are very strongly temperature
dependent. On the other hand, a new set of descriptors must be introduced, such as stress rate and
amnesia.
Shape memory alloys (SMAs) are metals which exhibit two very unique properties, pseudo-elasticity
and the shape memory effect. Arne Olander first observed these unusual properties in 1938, but not
until the 1960s were any serious research advances made in the field of shape memory alloys.
Search by
The basic phenomenon of the shape memory effect was widely reported a decade later by Russian
metallurgist G. Kurdjumov and also by Chang and Read. However, presentation of this property to the
wider public came only after the development of the nickel-titanium alloy (Nitinol) by Buehler and
Wang. Since then, research activity in this field has been intense, and a number of alloys have been
investigated, including Ag-Cd, Au-Cd, Cu-Zn, Cu-Zn-AI, Cu-AI-Ni, Cu-Sn, Cu-Au-Zn, Ni-AI, Ti-Ni, Ti-NiCu, Ni-Ti-Nb, Ti-Pd-Ni, In-Ti, In-Cd and others. The most effective and widely used alloys include Ni-Ti,
Cu-Zn-Al, and Cu-Al-Ni.
Crystallography of shape memory alloys have been studied for the last four decades. Because these
materials are relatively new, some of the engineering aspects of the materials are still not well
understood. Many of the typical engineering descriptors, such as Young's modulus and yield strength,
do not apply to shape memory alloys since they are very strongly temperature dependent. On the
other hand, a new set of descriptors must be introduced, such as stress rate and amnesia.
SMAs are useful for such things as actuators which are materials that change shape, stiffness,
position, and other mechanical characteristics in response to temperature or electromagnetic fields.
The potential uses for SMAs especially as actuators have broadened the spectrum of many scientific
fields. The diverse applications for these metals have made them increasingly important and visible to
the world.
The alloys that exhibit so-called shape memory can undergo surprisingly large amounts of strain and
then, upon temperature increase or unloading, revert to their original shape. Ni-Ti based shape
memory alloys have to date provided the best combination of materials properties for most commercial
applications. However they are very expensive compared with Cu-based shape memory alloys. In
many applications, Cu-based alloys provide a more economical alternative to Ni-Ti. Cu-Zn based
shape memory alloys have actually been used and Cu-AI based shape memory alloys have shown
promise.
The two unique properties described above are made possible through a solid state phase change that
is a molecular rearrangement, which occurs in the shape memory alloy. The two phases, which occur
in shape memory alloys, are martensite and austenite. Martensite is the relatively soft and easily
deformed phase of shape memory alloys, which exists at lower temperatures. The molecular structure
in this phase is twinned which the configuration is shown in the middle of Figure 1. Upon deformation
this phase takes on the second form shown in Figure 1, on the right. Austenite, the stronger phase of
shape memory alloys, occurs at higher temperatures. The shape of the Austenite structure is cubic, the
structure shown on the left side of Figure 1. The undeformed martensite phase is the same size and
shape as the cubic austenite phase on a macroscopic scale, so that no change in size or shape is
visible in shape memory alloys until the martensite is deformed.
i Full text
j
k
l
m
n
j Headings
k
l
m
n
j Keywords
k
l
m
n
j Abstracts
k
l
m
n
Figure 1: Microscopic and macroscopic views of the two phases of shape memory alloys
The temperatures at which each of these phases begin and finish forming are represented by the
following variables: Ms, Mf, As, Af. The amount of loading placed on a piece of shape memory alloy
increases the values of these four variables as shown in Figure 2. The initial values of these four
variables are also dramatically affected by the composition of the wire (i.e. what amounts of each
element are present).
The shape memory effect is observed when the temperature of a piece of shape memory alloy is
cooled to below the temperature Mf. At this stage the alloy is completely composed of martensite
which can be easily deformed. After distorting the SMA the original shape can be recovered simply by
heating the wire above the temperature Af. The heat transferred to the wire is the power driving the
http://nonferrous.keytometals.com/default.aspx?ID=CheckArticle&NM=207
04.12.2008
Page 2 of 3
138
molecular rearrangement of the alloy, similar to heat melting ice into water, but the alloy remains solid.
The deformed martensite is now transformed to the cubic austenite phase, which is configured in the
original shape of the wire.
The transition temperature varies for different compositions from about -50C to 166C. In the
martensite phase, Nitinol can be bent into various shapes. To fix the parent shape (as it is called), the
metal must be held in position and heated to about 500C. The high temperature causes the atoms to
arrange themselves into the most compact and regular pattern possible resulting in a rigid cubic
arrangement known as the austenite phase. Above the transition temperature, Nitinol reverts from the
martensite to the austenite phase which changes it back into its parent shape. This cycle can be
repeated millions of times.
Pseudo-elasticity occurs in shape memory alloys when the alloy is completely composed of austenite
(temperature is greater than Af). Unlike the shape memory effect, pseudo-elasticity occurs without a
change in temperature. The load on the shape memory alloy is increased until the austenite becomes
transformed into martensite simply due to the loading.
Terms of Use | Key Benefits | How it Helps | Fact Sheet | Multiuser | FAQ | Contact | Order Now
Home | Site Map
http://nonferrous.keytometals.com/default.aspx?ID=CheckArticle&NM=207
04.12.2008
Page 3 of 3
http://nonferrous.keytometals.com/default.aspx?ID=CheckArticle&NM=207
04.12.2008