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CLASS
CENTRE
NUMBER
INDEX
NUMBER
H2 CHEMISTRY
9647/02
11 September 2012
2 hours
Data Booklet
9647/02/PRELIM/12
Total
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Marks
12
Paper 1
7
40
10
Paper 3
9
80
13
8
Total
72
192
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This document consists of 17 printed pages and 1 blank page.
Planning (P)
Calcium salts are used in many industrial processes. Calcium oxide is used
in the production of cement while calcium nitrate is sometimes used to
accelerate the setting of concrete.
Calcium oxide is a white hygroscopic solid. Calcium oxide can react with
water and as such can cause severe irritation when in contact with skin,
eyes or if inhaled.
Calcium nitrate is also a white hygroscopic solid. Calcium nitrate
decomposes on heating to form the oxide, nitrogen dioxide and oxygen.
(a)
(b)
[1]
Calculate the change in mass of the solid you would expect if 1.00 mol
of calcium nitrate underwent thermal decomposition.
[1]
(c)
9647/02/PRELIM/12
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(d)
[8]
State and explain clearly one precaution you would take to improve
the accuracy of your results.
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[1]
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(e)
Identify one potential safety hazard in this experiment and state how
you would minimise the risk.
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[1]
[Total: 12]
2
Using the following information as well as relevant data from the Data
Booklet, draw a Born-Haber cycle for the formation of TiO 2(s) and
calculate the lattice energy of TiO2(s).
Standard enthalpy change of formation of TiO2(s)
945 kJ mol1
+471 kJ mol1
142 kJ mol1
+844 kJ mol1
[3]
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(b)
804 kJ mol1
394 kJ mol1
+49.9 J mol1 K1
+5.7 J mol1 K1
+223 J mol1 K1
+252 J mol1 K1
+214 J mol1 K1
Using the above information, as well as relevant data from (a) and the
Data Booklet, calculate, for the first step of the Chloride process,
(i)
(ii)
[2]
9647/02/PRELIM/12
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(c)
Using your answers in (b), determine if the first step of the Chloride
process is spontaneous at 2000 K.
[1]
(d)
[1]
[Total: 7]
9647/02/PRELIM/12
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(ii)
(iii)
The numerical value for the Ksp of PbBr2 is 3.9 105. Determine
the concentration of bromide ions in the sample of river water.
[5]
(b)
(ii)
[2]
[Total: 7]
9647/02/PRELIM/12
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E = 0.13 V
E = +1.47 V
(a)
Write the overall equation for the reaction during discharge and
calculate the voltage delivered by the battery.
Equation: .............
[2]
(b)
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[2]
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(c)
(d)
[1]
[1]
[Total: 6]
5
(ii)
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[4]
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10
(b)
(c)
[2]
Fe3+ ions are added to lower the high activation energy so that
the reaction can proceed at a higher rate. Explain why the
activation energy is high for the reaction between the iodide and
peroxodisulfate ions if no Fe3+ ions are added.
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(ii)
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[4]
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11
[Total: 10]
6
(b)
configuration
of
chromium
atoms
[3]
and
Cr ..............................
Cr3+..............................
(c)
[2]
to
aqueous
(ii)
12
chromium(III) nitrate.
............
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(iii)
(iv)
[4]
[Total: 9]
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13
(b)
[2]
(ii)
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[3]
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14
(c)
OH
CH2CH2COOH
IV
OH
NaOH(aq)
heat under
reflux
ethanolic
NaCN
heat under
reflux
CH2CH2Br
CH2CH2CH(OH)CH3
acidified K2Cr2O7(aq),
heat
D
LiAlH4 in
dry ether
OH
III
II
OH
OH
CH2CHO
CH2CH2CH2NH2
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CH=CH2
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15
A:
B:
C:
D:
Step I: .....
Step II:
Step III:
Step IV:
[8]
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16
[Total: 13]
8
OH
dilute HNO 3
Step I
OH
Step II
NH 2
NHCOCH 3
Paracetamol
(a)
[1]
(b)
(c)
[2]
(ii)
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[2]
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17
(d)
(ii)
[3]
[Total: 8]
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18
BLANK PAGE
9647/02/PRELIM/12
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