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A 0.5 m3 rigid tank contains regrigerant-134a initially at 200 kPa and 40%
quality., Heat is now transferred to the refrigerant until the pressure
reaches 800 kPa. Determine (a) the mass of refrigerant in the tank and (b)
the amount of heat transferred. Also, show the process on a P-v diagram
with respect to the saturation lines.
The mass of refrigerant may be found from the initial state using the equation that m
= V / v where V = 0.5 m3 and v is found from the temperature and the quality. Since
we are given an initial quality, x1 = 40%, we know that we are in the mixed region.
The specific volume is found from the specific volumes of the saturated liquid and
vapor, which are found in Table A-12 on page 843: vf(200 kPa) = 0.0007532 m3/kg
and vg(200 kPa) = 0.0993 m3/kg. We then find the initial specific volume as follows.
3
(0.4) 0.0993 m 3 0.04017 m 3
v (1 x ) v f xv g (1 0.4) 0.000753 m
kg
kg
kg
With this specific volume, we then find the refrigerant mass as follows:
0.5 m 3
V
m
v 0.04017 m 3
= 12.45 kg
kg
To compute the heat transfer we apply the first law, Q = U + W. We assume that
there is no volume change in the rigid tank. If there is no volume change, no work
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The final state has the same specific volume as the initial state (0.04017 m 3/kg,
because of the constant volume process) and a given pressure of 800 kPa. From the
superheat table, A-13, on page 845, we see that the specific volume of 0.04017
m3/kg occurs at a pressure of 800 kPa (0.8 MPa) between 140 oC and 150oC. The
internal energy at the final state is found by interpolation.
u 348.09 kJ
358.15 kJ
348.09 kJ
kg
m 3 0.03997 m 3 349.84 kJ
0
.
04017
3
3
kg
kg
kg
kg
0.04113 m
0.03997 m
kg
kg
kg
Problem 4-12
1,200
Pressure (kPa)
1,000
2
800
600
400
200
1
0
0
0.05
0.1
0.15
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0.2
4.13E A 20 ft3 rigid tank contains saturated regrigerant-134a vapor at 120 psia.
As a result of heat transfer from the refrigerant, the pressure drops to 30
psia. Show the process on a P-v diagram with respect to the saturation
lines, and determine (a) the final temperature, (b) the amount of
refrigerant that has condensed, and (c) the heat transfer.
The solution of this problem is similar to the previous one. It is a constant volume
process so that the work is zero and the heat transfer equals the change in internal
energy. The P-v diagram for this problem is shown below. The process starts at the
saturated vapor line at 120 psia and as heat is removed, some refrigerant condenses,
moving the process into the mixed region.
Problem 4-13E
160
140
Pressure (psia)
120
100
80
60
40
20
0
0
0.5
1.5
2.5
3.5
Path
Since the final state is in the mixed region, we know that the final temperature is the
saturation temperature at the final pressure of 30 psia. From table A-12E on page
892, we find that the final temperature, Tsat(30 psia) = 15.38oF.
The amount of refrigerant that has condensed is the total mass minus the mass that
is vapor at the final state. This is m x2m. We can find the total mass from the
specific volume at the initial state and the total volume of the container: m = V/v 1,
where v1 is the volume of the saturated vapor, vg, at the initial pressure of 120 psia.
From Table A-12E, we find that vg(120 psia) = 0.3941 ft3/lbm, so that the total mass is
given by the following equation.
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20 ft 3
V
v 0.3941ft 3
50.75 lb m
kg
The specific volume at the final state is the same as the initial specific volume, so we
can find the quality at this final state from the saturated liquid and vapor specific
volumes taken from Table A-12E.
0.3941 ft
0.01209 ft
v vf
lb m
lb m
0.2499
v g v f 1.5408 ft 3 0.01209 ft 3
lb m
lb m
lb
lb
lb m
m
m
The heat transfer can now be found from the first law.
Q = U + W = m(u2 u1) + W = (50.75 lbm)(105.05 36.02) Btu/lbm + 0 = 3,507
Btu.
4.20
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Wresistor Wpaddle = m(u2 u1) + Pm(v2 v1) =m[(u2 + P2v2) (u1 + P1v1)] = m(h2 h1)
We can find the mass from the initial state where we know V1 = 5 L and v1 = vf(P1 =
150 kPa). Using Table A-5 on page 832 to find vf, we compute the mass as follows.
V
V1
5L
m 1
kg
0.001 m 3
4.748 kg
L
Since the paddle wheel and resistance work are inputs, these are negative. Thus the
values of Wresistor and Wpaddle are EIt and 300 kJ, where E is the voltage that we want
to find. The enthalpy at the initial state is simply h f at 150 kPa. The enthalpy at the
final state is the enthalpy of a mixture with a quality of 50% at the same 150 kPa
pressure. We thus have h1 = hf(150 kPa) = 467.11 kJ/kg, where we use Table 1-5 for
the saturation data. Using the same table and the value of x2 = 50% we find h2 as
follows.
Substituting the work terms and enthalpy and mass into our first law gives an
equation for the unknown voltage.
Wresistor Wpaddle = EIt + 300 kJ = m(h2 h1) = (4.748 kg)(1580.4 467.11) kJ/kg
Combining the numerical data gives an equation for the work done by the resistor.
EIt = 4988 kJ = 4988 kWs
We can solve this to find the voltage applied to the resistor.
4.22
4988 kW s
4988 kW s 1 m 1000 V A
= 230.9 V.
I t
(8 A)( 45 m ) 60 s
kW
A piston-cylinder device initially contains steam at 200 kPa, 200 oC, and 0.5
m3. At this state a linear spring (F x) is touching the piston but exerts no
force on it. Heat is now slowly transferred to the steam causing the
pressure and the volume to rise to 500 kPa and 0.6 m3, respectively. Show
the process on a P-v diagram with respect to the saturation lines and
determine (a) the final temperature, (b) the work done by the steam, and
(c) the total heat transferred.
The path for this process is shown in the diagram below. The initial point of the path is (P1,
V1) = (200 kPa, 0.5 m3); the final point is (P2, V2) = (500 kPa, 0.6 m3).
P2
P
P1
V
V1
V2
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The work is the area under the path which is the area of a trapezoid: W = (P 1 + P2)(V2
V1)/2. Using the values of pressure and volume given in the problem allows us to
find the work.
P1 P2
( 200 500) kPa
kJ
(V2 V1 )
0 .6 m 3 0 .5 m 3
35 kJ
2
2
kPa m 3
The heat transfer is given by the first law: Q = U + W = m(u2 u1) + W. We have to
find the values of u1 and u2 from the property tables for water. In addition, we can
find the mass from the initial volume, V1 = 0.5 m3, and the initial specific volume, v1.
At the initial state of P1 = 200 kPa and T1 = 200oC, we find the following properties in
the superheat table, Table A-5 on page 834: v1 = 1.0803 m3/kg and u1 = 2654.4 kJ/kg.
We can then find the mass as follows.
V1
0.5 m 3
m
v1 1.0803 m 3
0.463 kg
kg
From this system mass, we can compute the specific volume at the final state where
V2 = 0.6 m3.
v2
3
V2
0.6 m 3
1.296 m
kg
m
0.463 kg
At the final pressure of 500 kPa, the specific volume, v2 = 1.296 m3/kg occurs
between temperatures of 1100oC and 1200oC in Table A-6 on page 834. Interpolating
between these two points gives the temperature and internal energy at the final
state.
u 4256.3 kJ
kg
4466.8 kJ
1.3596 m
kg
kg
4256.3 kJ
1.2672 m
kg
kg
1200 o C 1100 o C
1.296 m 3 1.2672 m 3 1131o C
T 1100 C
3
3
`
kg
kg
1.3596 m
1.2672 m
kg
kg
o
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4.24
kJ
150 kJ
kPa m 3
The mass is found from the initial volume of 0.5 m3 and the initial specific volume
which is the specific volume of a saturated vapor at 200 kPa. This is found from Table
A-5 on page 833.
V1
V1
0501 m 3
m
0.5645 kg
kg
Since the mass is constant and the volume doubles, the final specific volume is twice
the initial specific volume: v3 = 1.7714 m3/kg. The final state with this specific
volume and a pressure of 300 kPa is found in the superheat tables, Table A-6 on page
834, to occur at a temperature between 800oC and 900oC. The final temperature is
found by interpolation.
900o C 800o C
1.7714 m 3 1.6499 m 3 878.9 o C
T 800 C
3
3
`
kg
kg
1.8041m
1.6499 m
kg
kg
o
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The initial internal energy for the saturated vapor state is found from Table A-5, u 1 =
ug(200 kPa) = 2529.5 kJ/kg. The internal energy at the final state is found by an
interpolation similar to the one used for the temperature.
u 3662.9 kJ
kg
3854.2 kJ
1.8041 m
kg
kg
3662.9 kJ
1.6499 m
kg
kg
`
The heat transfer is found as follows:
Q = m(u3 u1) + W = (0.5645 kg)(3813.8 2529.5)kJ/kg + 150 kJ = 875 kJ.
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