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Edexcel IAL
Chemistry
Advanced
Unit 5: General Principles of Chemistry II
Transition Metals and Organic
Nitrogen Chemistry
Sample Assessment Material
Time: 1 hour 40 minutes
Materials required for examination
Data Booklet
Question Leave
Number Blank
Section
A
Section
B
Section
C
Total
ACQUIRE INSTITUTE
Edexcel IAL in Chemistry
Turn over
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blank
SECTION A
Answer ALL the questions in this section. You should aim to spend no more than 25
minutes on this section. For each question, select one answer from A to D and put a
cross in the box ( ). If you change your mind, put a line through the box ( ) and then
mark your new answer with a cross ( ).
Each of the questions or incomplete statements in this section is followed by four
suggested answers, A, B, C and D. Select the BEST answer in each case.
1.
Q1
(Total 1 mark)
2.
positive
negative
Q2
(Total 1 mark)
3. The standard electrode potential for the electrode system based on the equation below is
+1.51 V.
MnO4(aq) + 8H+(aq) + 5e U Mn2+(aq) + 4H2O(l)
Which of the following statements about the electrode system is correct?
A
Q3
(Total 1 mark)
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4.
Hr
Ssystem
Ssurroundings
Stotal
Q4
(Total 1 mark)
5.
Methanoic
acid
+1
+2
+1
+2
2
(1)
(b) How many moles of methanol react with one mole of dichromate(VI) ion, Cr2O72?
A
3
(1)
Q5
(Total 2 marks)
6.
Which of the following will not act as a ligand in the formation of complexes?
A
C6H5NH2
CH3NH2
NH4+
NH3
Q6
(Total 1 mark)
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7.
1s2 2s2
Q7
(Total 1 mark)
8.
X, Y, and Z are three different compounds from the list below. X and Y react together to
form an ester. X and Z also react to give the same ester as X and Y, but less readily.
Compound Y could be
A
propanoyl chloride
propanoic acid
propan-1-ol
propanal
Q8
(Total 1 mark)
9.
Butan-1-ol
Butan-2-ol
2-methylpropan-1-ol
2-methylpropan-2-ol
Q9
(Total 1 mark)
Use this space for any rough working. Anything you write in this space will gain no
credit.
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10. When the colourless liquid chlorobenzene is shaken with bromine water, the chlorobenzene
becomes a yellow orange colour. What is the interpretation of this?
A
Q10
(Total 1 mark)
11. What class of organic compound has a characteristic smell and gives a solution in water
with a pH of about 10?
A
arene
amine
aldehyde
carboxylic acid
Q11
(Total 1 mark)
12. Which chemical term best describes what happens, when butylamine is added to a solution
of a copper(II) salt?
A
precipitation
redox
proton transfer
complex formation
Q12
(Total 1 mark)
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polyester
detergent
protein
Q13
(Total 1 mark)
Q14
(Total 1 mark)
15. The rate equation for the reaction between aqueous sodium hydroxide and
2-chloro-2-methylpropane is
Rate = k[2-chloro-2-methylpropane]
The first step in the mechanism of this substitution reaction is
A
Use this space for any rough working. Anything you write in this space will gain no
credit.
Q15
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blank
16. When hydrogen cyanide, HCN, is added to ethanal, CH3CHO, the resulting solution has
no effect on the plane of polarisation of plane polarised light.
This is because
A
Q16
(Total 1 mark)
non-polar molecules
linear molecules
Select from AD, the similarity between each of the compounds below.
(a) Benzene, C6H6 and cyclohexane, C6H12
A
B
C
D
(1)
(b) Hydrogen cyanide, HCN, and carbon dioxide, CO2
A
B
C
D
(1)
(Total 2 marks)
Q17
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Benzene, C6H6
Glycine, NH2CH2COOH
Propene, CH3CHCH2
Propanone, CH3COCH3
Use this space for any rough working. Anything you write in this space will gain no
credit.
Leave
blank
Q18
(Total 4 marks)
19. Select, from AD, the type of interaction which best describes the bonding between
(a) adjacent polymer chains in CH
[
]n
2CH2
A
dative covalent
London forces
ion-dipole
ionic
(1)
dative covalent
London forces
ion-dipole
ionic
(1)
(Total 2 marks)
TOTAL FOR SECTION A: 25 MARKS
Q19
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Answer ALL the questions. Write your answers in the spaces provided.
1.
[Ar] .......................................................
(3)
(iii) State what you would see when dilute sodium hydroxide is added to a solution
containing hexaaquachromium(III) ions, until it is present in excess.
................................................................................................................................
................................................................................................................................
................................................................................................................................
(2)
(iv) Give the equations for the reactions taking place in (iii).
................................................................................................................................
................................................................................................................................
(2)
(b) (i) Give the structural formulae of an organic compound that can be oxidised by
potassium dichromate(VI) in dilute sulphuric acid and of an organic product of the reaction.
................................................................................................................................
................................................................................................................................
................................................................................................................................
(2)
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(ii) Both dichromate(VI) ions and manganate(VII) ions need hydrogen ions in order
to act as oxidising agents in titration experiments.
Explain, by calculating E cell values, whether hydrochloric acid could be used to provide the H+ ions
for these oxidations.
Cr2O72 + 14H+ + 6e
Cl2 + 2e
MnO4 + 8H + 5e
3+
2Cr + 7H2O
E = +1.33 V
2Cl
E = +1.36 V
2+
Mn + 4H2O
E = +1.51 V
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................................................................................................................................
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................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
(4)
(iii) When aqueous alkali is added to an aqueous solution containing dichromate(VI)
ions, the following change takes place
Cr2O72 + 2OH 2CrO42 + H2O
Explain in terms of oxidation numbers why this is not a redox reaction.
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
(1)
(Total 15 marks)
Q1
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2.
NO2
Step 1
N2+Cl
NH2
Step 2
Step 3
Compound X
(4)
(b) Give the reagents for Step 2 and state the type of reaction occurring.
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
(2)
(c) Give the reagents and temperature for Step 3 and name the product, compound X.
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
(3)
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OH
Compound X
Outline an experiment you could perform to show that this reaction is first order with respect to compound
X.
You should:
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
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3.
A firm claims that their iron tablets contain 10 mg of Fe2+ per tablet. A chemist wishes to
check this by titration using potassium manganate(VII) and dilute sulfuric acid.
Fe2+(aq) U Fe3+(aq) + e
MnO4(aq) + 8H+(aq) + 5e U Mn2+(aq) + 4H2O(l)
(a) Why is the acid necessary?
.......................................................................................................................................
.......................................................................................................................................
(1)
(b) How many moles of Fe2+ react with one mole of MnO4?
.......................................................................................................................................
(1)
(1)
(ii) Use your answer to (i) to calculate the volume of 0.010 mol dm3 potassium
manganate(VII) solution that would be needed to react with one tablet.
(2)
(iii) Is this a suitable volume to verify the integrity of the firms claim? How would
you alter the experiment to obtain a more suitable volume?
................................................................................................................................
................................................................................................................................
................................................................................................................................
(1)
*(d) The recommended consumption of Fe2+ per day is 14 mg. The tolerable upper level
of consumption of Fe2+ per day is 45 mg.
The 10 mg iron tablets produced by a pharmaceutical company contain between
9 and 11 mg of Fe2+.
Discuss whether or not this range of iron content is acceptable.
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
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.......................................................................................................................................
(2)
(Total 8 marks)
Q20
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4.
O
H2COCR
O
HCOCR
O
H2COCR
(1)
(b) R can be a saturated hydrocarbon chain or the cis isomer of an unsaturated hydrocarbon chain.
(ii) At room temperature, saturated fats are generally solids whereas unsaturated fats
are generally liquids.
Suggest a reason for the difference in melting temperatures.
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
(2)
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(c) (i) Complete the equation below for the alkaline hydrolysis of a fat.
O
H2COCR
O
HCOCR +
3NaOH
O
H2COCR
(2)
(ii) State an important use of the reaction in (c)(i).
................................................................................................................................
(1)
(d) Describe simple chemical tests (other than the use of indicators) to distinguish
between each of the following pairs of compounds.
Include the reagents used and an observation for each substance.
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(e) (i) Propanone and hydrogen cyanide, in the presence of cyanide anions, react to
form (CH3)2C(OH)CN.
Give the mechanism for this reaction.
(4)
(ii) Explain what happens to the rate of the reaction in (e)(i) if the pH of the solution is lowered.
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
(2)
(Total 20 marks)
Q4
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5.
(a) The apparatus below was used to measure the standard emf of the cell formed from
Fe3+/Fe2+ and Cu2+/Cu half-cells.
copper
1 mol dm3
Cu2+(aq)
salt
bridge
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(v) Write the ionic half-equations for the reactions occurring in each half-cell.
................................................................................................................................
................................................................................................................................
................................................................................................................................
(2)
(vi) Write the equation which represents the overall cell reaction.
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
(1)
(b) The cell below was set up. Copper is the negative electrode. The solution in the right
hand beaker contained a suitable electrolyte and phenolphthalein. After some time the solution turned
pink.
copper
oxygen
1 mol dm3
copper(II)
sulphate
solution
Write the ionic half-equation for the reaction at the oxygen electrode which caused the phenolphthalein
to turn pink.
.......................................................................................................................................
.......................................................................................................................................
(2)
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3
2CuI + I2
The iodine produced was reduced by 16.50 cm3 of 0.100 mol dm3 of sodium thiosulphate solution.
2S2O32 + I2
S4O62 + 2I
(3)
(Total 15 marks)
TOTAL FOR PAPER: 75 MARKS
END
Q5