Académique Documents
Professionnel Documents
Culture Documents
United States
Environmental Protection Planning and Standards
Research Triangle Park NC 27711
Agency
EPA453/R-93-050a
October 1993
Air
&EPA
EPA-453/R-930050a
Manufacturing Processes at
Kraft, Sulfite, Soda, and Se&-Chemical
Emission
Standards
Division
Mills
ii
Prepared by:
J
/o/ZLh
&eJ&
(Date)
an
Director, 2 mission Standards Division
u. s. Environmental Protection Agency
Research Triangle Park, NC 27711
Bfke
1.
2.
C. Jo
3.
4.
5.
27711
27711
TABLE
OF CONTENTS-
Section
1.0
2.0
3..0
INTRODUCTION
. . . . . . . . . . . . . . . . . . . .
1.1
SCOPE
1.2
DOCUMENT
PROCESS
OF THE
BACKGROUND
ORGANIZATION
DESCRIPTIONS
AND
INFORMATION
l-2
. . . . . . . . . . . . .
l-4
EMISSIONS
DOCUMENT
l-l
ESTIMATES
. . . .
2-l
2.1
INDUSTRY CHARACTERIZATION
. : .........
2.1.1
Pulp Production
............
2.1.2
Paper Production
............
2.2
PROCESSES
AND THEIR EMISSION POINTS ......
2.2.1
The Pulping Process
..........
2.2.2
The Bleaching Process
.........
2-5
2-5
2-22
2.3
BASELINE
EMISSIONS
..........
2.3.1
Summary of Feierai Reguiakon:
2.3.2
Summary of State Regulations
......
2.3.3
Baseline Emission Controls
.......
2.3.4
Baseline Emissions
............
2-30
2-31'
2-31
2-34
2-38
2.4
REFERENCES
2-40
EMISSION
CONTROL
TECHNIQUES
. . . . . . . . . -. . .
INTRODUCTION
3.2
APPLICABLE
CONTROL TECHNIQUES
FOR VENTS
3.2.1
Vent Gas Collection
and Transport
System . . . . . . . . . .
3.2.2
Applicable
Vent Control Devices'
3.4
. . . . . . . . . . . . . . .
3-l
3-l
. .
3-3
. .
. .
.
.
.
.
3-6
3-9
APPLICABLE
CONTROL TECHNIQUES
FOR
WASTEWATER
EMISSION POINTS
. . . .
3.3.1
Wastewater
Collection
!&em
. .
3.3.2
Steam Stripper with Vent Con&oi
. .
3.3.3
Air Stripper with Vent Control
. . .
.
.
.
.
.
.
.
.
3-21
3-21
3-21
3-26
REFERENCES
3-27
M.ODEL PROCESS
ENVIRONMENTAL
4.1
2-l
2-l
2-3
..................
3.1
3.3
4.0
Paae
MODEL
4.1.1
4.1.2
: . . . . . . . . . . . . . . .
4-l
PROCESS UNITS .
. . . . . . . . .
Pulping Model Proceis*Units
. .
. .
Bleaching Model Process Units' . . J . .
4-l
4-2
4-6
iii
TABLE
OF CONTENTS
(Continued)
Section
Pace
4.1.3
5.0
6.0
4.2
CONTROL
4.3
ENVIRONMENTAL
IMPACTS
4.3.1
Air Impacts
4.3.2
Energy Impact:
4.3.3
Water Impacts
4.3.4
Other Impacts
4.4
REFERENCES
ESTIMATED
OPTIONS
in Estimating
.-. . .
..............
4-8
4-9
.
.
.
.
.
.
.
.
.
.
4-11
4-12
4-17
4-20
4-20
4-21
5-l
COSTS
..........
.
Enclosure'&&
...
.
Ductwork and Conv~y&e'C&'
. .
Thermal Incineration
System Co&
. .
Scrubber System Costs
.......
.
Steam Stripping Costs
.......
.
.
.
.
.
.
.
5-l
5-3
5-4
5-7
5-12
5-18
5-21
5-34
6-l
................
CONTROL
5.1
CONTROL
5.1.1
5.1.2
5.1.3
5.1.4
5.1.5
5.2
CONTROL
5.3
REFERENCES
COSTS
OPTIONS
DATABASE. SYSTEM
...........
...........
...........
...........
...........
.............
COSTS
...........
................
FOR ESTIMATING
INPUTS
NATIONAL
IMPACTS
6.1
DATA
. . . . . . . . . . . . . . .
6-l
6.2
CALCULATION
OF NATIONAL EMISSIONS
AND
CONTROL IMPACTS . . . . . . . . . . . . .
6-3
6.3
GENERATION
. . .
6-4
6.4
REFERENCES
. . . . . . . . .
6-5
A-l
B-l
..
C-l
OF SUMMARY
OUTPUT
. . . . :.
APPENDIX
.................
APPENDIX
.........
APPENDIX
......
FILES
.' .......
0'. .........
iv
LIST
OF TABLES
Table
2-l
2-2
2-3
DISTRIBUTION
PROCESSES
MAJOR HAZARDOUS
AIR POLLUTANTS
POINTS......................
EMITTED
FROM
. .
2-4
PROCESS
2-6
2-10
2-4
TYPICAL UNCONTROLLED
EMISSION FACTORS FOR KRAFT
PULPING
FACILITIES
. . . . . v . . . . . . . . . 2-11
2-5
COMPARISON
OF COMMON CHEMICALS
USED IN PULP
BLEACHING
. . . . . . . . . . . . . . . . . . . . 2-23
2-6
MOST
. . . . . . . . .
2-26
2-7
2-27
COMMON
KRAFT
BLEACH
SEQUENCES
2-8
SUMMARY OF TYPICAL
FOR KRAFT BLEACH
UNCONTROLLED
EMISSION
FACTORS
PLANT FACILITIES
. . . . . . . . 2-28
2-9
2-32
2-10
2-11
2-12
2-13
2-14
2-39
PULPING
PROCESS MODIFICATIONS
AND BLEACHING
PROCESS
SUBSTITUTIONS
. . . . . . . .. . . . . . .
3-2
3-4
3-l
3-2
. . . . . 2-35
LIST OF TABLES
(.Continued)
Paae
Table
3-3
3-4
SCRUBBER
3-5
STEAM
. . . . . . .
3-25
4-l
4-3
4-2
PULPING
. . . . . . . . . . .
4-4
4-3
BLEACHING
. . . . . . . . . .
4-7
4-4
SELECTED
CONTROL OPTIONS AND CONTROL TECHNOLOGYEFFICIENCY
. . . . . . . . . . . . . . . . . . .
4-10
4-5
UNCONTROLLED
. .
4-13
4-6
PRIMARY
AIR
. . . . .
4-14
4-7
EXAMPLE
MILL
SECONDARY
4-8
EXAMPLE
MILL
ENERGY
5-l
ELEMENTS
INCLUDED IN CONTROL
FOR VARIOUS POINTS/DEVICES
5-2
5-3
REDUCTION
STRIPPER
MODEL
ESTIMATES
REMOVAL
PROCESS
MODEL
EFFICIENCIES
UNITS
PROCESS
EMISSIONS
IMPACTS
. . . . . . . . . . .
3-5
UNITS
FOR AN EXAMPLE
FOR AN EXAMPLE
MILL
AIR POLLUTION
IMPACTS
FACILITY
IMPACTS
3-20
. . .
4-16
. . . . . . . . . . .
4-19
COST CALCULATIONS
. . . . . . . . . . .
5-2
DESIGN SPECIFICATIONS
FOR VENTING
COMBUSTION
DEVICE . . . . . . . . .
5-5
THERMAL
INCINERATOR
GENERAL DESIGN SPECIFICATIONS
FOR HALOGENATED
VENT STREAMS . . . . . . . . . . .
5-8
DUCTWORK
GENERAL
TO AN EXISTING
DESIGN PARAMETERS
SCRUBBER
SYSTEM
5-14
5-5
DESIGN
FOR STAND-ALONE
5-16
5-6
STAINLESS
5-7
5-23
5-25
5-4
5-8
PARAMETERS
STEEL
COST
FACTORS
vi
SCRUBBER
SYSTEM
. . . . . . . . . . .
. .
5-22
LIST
Table
OF TABLES
(Continued)
Pacre
5-9
5-10
5-11
5-12
5-13
COMPARISON
OF TOTAL CAPITAL INVESTMENT
(TCI) AND
TOTAL ANNUAL COST (TAC) FOR MODEL MILLS WITH
VARYING
CAPACITIES
. . . . . . . . . . . . . . . . 5-33
LIST OF FIGURES
I
Figure
Page
l-3
2-l
Percentage
. .
2-2
2-2
Breakdown
pulping
2-7
2-9
l-1
2-3
2-4
2-5
of wood
pulp
produced
Typical
sulfite pulping process
recovery.....................
by each
process
practicing
chemical
2-18
2-6
Typical
down-flow
3-l
Discrete
burner,
3-2
Packed
3-3
Continuous
4.-l
Example
6-l
National
tower
bleach
thermal
absorption
integrated
air
pollution
impacts
tower
and washer
incinerator
process
steam
estimation
viii
. . 2-24
. . . . . . . .
3-14
. . . . . . . . . .
3-18
stripper
impacts
. . :
2-20
system
. . . .
3-23
. . . . . . . . . . . 4-18
process
. . . . . . . .
6-2
1.0
National
(NESHAP)
under
emission
are
under
authority
amended
This
developed
efforts
used
limitations
is in separate
include
air
emission
options
considered
factors
for establishing
as
(BID)
in the
Effluent
are being
Water
Act.
The U. S.
is coordinating
these
for the air and
industry.
of effluent
documents.
impact
used
mills
and paper
Air Act
NESHAP.
and paper
(EPA)
industry
document
decision-making
information
Clean
and paper
the Clean
integrated
regulations
and paper
and analyses
Agency
air pollutants
information
pulp
under
Protection
to produce
of the
background
for pulp
concurrently
Environmental
information
limitations
for hazardous
112(d)
of the proposed
guidelines
water
of Section
technical
development
standards
development
in 1990.
provides
INTRODUCTION
Technical
guidelines
However,
this BID does
for the process technology
effluent
guidelines
limitations.
The
review
joint
.draft
EPA has
and
air
the technical
and water
regulations.
considered
provided
were
emission
modify
at the public
factors,
the
this
accurate
conclusions
proposed
approach
rule
proposal
meetings
to
to developing
these
incorporated
is technically
documented
of public
on the preliminary
in revising
corrections
the
document
received
information
BID
a number
discuss
of this
comments
conducted
meetings,
into
analyses
were
to
reviewed
Comments and
the BID to ensure
the control
costs,
is based.
in addition
and
document.
and describes
about
control
draft,
were
l-l
the
the Agency's
technologies,
and other
Comments
that
impacts
and data
considered
upon
received
and
which
that
evaluated
to
determine
the
impact
on proposal,
incorporated
into
The
continue
EPA will
the proposal's
with
rule,
SCOPE
1.1
The
public
OF THE
on-site
mills
would
typically
classification
the
document.
Detailed
2611
consists
paper
products,
mills
use
a variety
types
of pulping
not
Chemical
focus
processes
are not
included.
As shown
in Figure
processes
and
chemical
operations
are
discussed
separate
spent
recovery
recovery
include
cooking
operations
and
the production
is not
1-r
in this
of paper
included
in
of the industry,
pulp
from
recycled
to separate
Pulp mills
to pulp wood.
into
common
in this
will
The
the pulping
process
of wood
(not included
l-2
BID;
be evaluated
and pulp
integrated
three
main
and
of the three
pulping
pulping
and semi-chemical
Air emissions
in detail
process
Mechanical
two groups:
recovery.
and
The
and semi-chemical
BID.
the
semi-chemical,
is the most
l-l, chemical
liquor,
Figure
industry
segment
chips.
of this
documents.
Such
and paper).
discussed
mills)
are divided
operations
weak
and paper
about
(mills
included.
pulping
are the
mills
industrial
are chemical,
processes
and
respectively.
industry
of methods
processes.
BID
standard
is designed
processes
pulping
of both pulp
fibers
in the wood
Chemical
wood
that manufacture
process
fibers
in this
development
and integrated
and 2621,
secondary
is also
cellulose
in
mills
of the
of mills
pulping
mechanical.
covers
information
The
which
date
DOCUMENT
or non-integrated
document.
chemical
on the proposed
INFORMATION
of the pulp
segment
(at integrated
the
and data,
in the
fall under
codes
identifies
pulping
document.
comments
be considered
production
an overview
pulping
not
or this
received
document
at pulp
combine
The
will
of this
that
this
comments
BACKGROUND
processes
provides
those
were
NESHAP.
scope
bleaching
analyses
to evaluate
along
of the
other
but they
bleaching.
in this
process
from process
emissions
from
at a later
operations
chips,
covered
evaporation
Chemical
document)
include
of
Pulp Production
(Pulp Mill#
and Integrated Mill8)
I
4
PulP
PrOdWtiOn
PW@r
Produotion
I
I
I
I- -
II
II
I
Process
Operationa
Pulping
Chamlod
Reoowry
I
1
-II
I
-1
Blaaohing
I
. I.
J
L--w-m---
Figure l-1.
the
equipment
strong
spent
The
RAP
emissions,
national
environmental
DOCUMENT
from
the
the Agency's
(HAP)
technologies
and cost
available
and other
Regulatory
impacts
emissions
will
to
impacts
alternatives
from
of
and the
be presented
in
ORGANIZATION
2.0 presents
estimated
units
are
that
on the
were
discussed
bleaching
impacts
vents
are
emissions
shown
from
paper
industry
gives
a brief
environmental
industry
discussed
Development
(Appendix
A),
(Appendix
4.0.
emission
in Chapter
of the data
and cost
base
impacts
The
appendices
Emission
Estimates
above.
Air
regulatory
4.0,
along
process
impacts
with
in Chapter
are discussed
national
The model
RAP emissions
the various
overview
(Appendix
in Chapter
and wastewater
also
the
points,
Control
3.0.
to estimate
and paper
air emission
emissions.
in Chapter
are discussed
for controlling
of the pulp
descriptions,
baseline
developed
industry
options
an overview
process
national
technologies
Data
air pollutant
technologies.
including
industry,
RAP
chemicals
EPA documents.
Chapter
and
cooking
is to document
the demonstrated
these
1.2
BID
hazardous
applying
other
the
liquor.
of this
about
industry,
control
to recover
cooking
purpose
conclusions
this
used
C).
l-4
Costs
for controlling
points
in the pulp
Chapter 6.0
5.0.
developed
to
Process
include
Units
estimate
and paper
Field
and Emission
and
Test
Factors
PROCESS
2.0
This
chapter
DESCRIPTIONS
presents
industry,
focusing
processes
used
character
and distribution
United
emission
2.1
CHARACTERIZATION
The
and paper
pulp
manufacture
pulp,
Converting
(e.g.,
United
they
sulfite)
and paper
mills
the
in the
and their
2.3 describes
baseline
emissions.
and boxes)
pulp
one type
pulp
pulps
process
and a mechanical
(chemical,
of paperboard
using
there
semi-chemical,
or
and paper
industry.
of Water
facilities
in the
facilities
process;
a chemical
for example,
(e.g.,
kraftor
or semi-chemical
and mechanical)
survey
Information),1
and paper
of pulping
that
pulp.
coating
Business
and paper
of these
survey,
from
and
in the pulp
produce
on this
products
Confidential
Many
facilities
565 operating
than
includes
as the piroduction
included
considered
more
may
Based
not
States.
operate
such
on responses
are
are
2.1 describes
processes
or other
containers
are
Based
there
bleaching
unit
industry
paper,
operations
laminating
(which
and
and paper
technologies.
INDUSTRY
products
Section
2.2 discusses
ESTIMATES
of the pulp
pulping
of pulp
and Section
points;
and control
industry.
Section
EMISSIONS
an overview
on the chemical
in the
States;
AND
pulping
process.
processes
operating
in the
industry.
2.1.1
most
Pulp
Production
Although
other
commonly
used
on 1992
pulp
estimates,
are produced
illustrates
States
the
by each
raw materials
can be used,
in the manufacture
approximately
annually
percentage
pulping
of pulp
71.8 million
in the United
of wood
process
pulp
the material
is wood.
tons
States.1
produced
Based
of wood
Figure
2-l
in the United
number
of
so
80
70
60
60
Note: MillsRoduclngMom
Than One PulpType
Are camted Once
For EachType.
40
30
20
10
Figure 2-1.
2-2
;;
mills
of each
document
(kraft,
approximately
wood
pulp
The pulping
type.
soda,
68.4
production
tons
being
considered
Table
2-l shows
the distribution
State
by type
used.2
The
pulp
States
with
Kraft
(including
85 percent
primarily
in the
provides
over
pulp
southeastern
60 percent
in each
process
of chemical
and Georgia.
wood
149 kraft
are
document.
pulping
production
of U.S.
are approximately
by this
for
U.S.
that
concentration
Alabama,
soda)
of total
the highest
are Washington,
There
supported
in this
account
at 161 mills
or semi-chemical
mills
approximately
or 95 percent
of chemical
discussed
and semi-chemical)
sulfite,
million
processes
pulp
pulping
United
accounts
production.lr3.
processes,l
This
States.
of the wood
for
pulp
located
region
in the United
States.3
Figure
pulping
2-l
also
processes
shows
in the United
approximately
4 percent
The majority
of sulfite
northwest,
(spruce,
sulfite
poplar
where
the
and
can
pulping,
are
which
wood
located
species
production.1
in the north'and
in sulfite
pulping
However,
prevalent.
using
16 sulfite
contribute
pulp
used
hardwoods
technology
variety
of wood
given
region
such
2.1.2
Paper
as
species
pulp
approximately
production.lr3
the technology
and,
thus,
There
is no
semi-chemical
can use
a wide
is not restricted
to a
country.
to the
and Allied
on responses
contributes
States
Production
According
were
in the United
of mills.employing
because
of the
processes
which
wood
concentration
pulping
Of paper
U.S.
be produced
of nationwide
geographic
Paper
States,
are more
32 pulping
semi-chemical'
6 percent
fir)
are currently
eucalyptus.4
Approximately
use
mills
softwood
also
there
of total
and
hemlock,
pulp
that
1991
Trades,
produced
to the
Lockwood-Post's
approximately
in the United
1992
EPA Office
2-3
Directory
38.7 million
for Pulp,,
short
States
in 1991.5
of Water
survey,
tons
Based
TABLE
2-l.
DISTRIBUTION
OF CHEMICAL AND SEMI-CHEMICAL
PULP PROCESSES
IN THE UNITED STATESarb
Kraft/soda
Alabama
Alaska
Arizona
Arkansas
California
Florida
Georgia
Idaho
Indiana
Iowa
Kentucky
Louisiana
Maine
Maryland
Michigan
Minnesota
Mississippi
Montana
New Hampshire
New York
North Carolina
Ohio
Oklahoma
.Oregon
Pennsylvania
South Carolina
Tennessee
Texas
Virginia
Washington
Wisconsin
Semi-chemical
16
-2
2
2
7
3
11
13
1
2
11
8
1
3
3
5
2
2
1
7
1
1
7
4
6
3
8
5
12
4
1
3
1
2
1.
2
1
3
1
1
Total
Sulfite
Based on Reference
2.
Mills producing
more than
for each pulp process.
one pulp
2-4
5
5
3
3
2
16
32
process
are
counted
once
integrated
mills
accounted
integrated
mills
for approximately
fiber
mills
for approximately
PROCESSES
2.2
This
emission
AND THEIR
section
points
as well
wood,
section
suggests
supplement
existing
emissions
data
These
any
and
for review
regulatory
analysis.
is given
of this
in Table
digester
diagram
process
operations
air
.system)
will
The
pulping
2.2.1
The
The
kraft,
sulfite,
the
and
industry.
points
scope
to as process
are the
the
area),
coproduct
2-2 provides
operation
and depicts
Chemical
points.
than
be
final
1.0, the
system,
recovery
(other
EPA will
of points
Figure
pulping
in future
the evaporator
documents.
can be divided
for pulping
pulping
group
recovery
Puloins
documentation
sulfite,
production
used
pulp.
points
be-discussed
process
of the
kraft
mills.
emission
referred
process.
and chemical
emission
pulp
processes
bleaching
pulp
in Chapter
the washer
to
into the
process
to points
in this
in this
to'the
incorporation
points.
some
several
provided
with
pulping
from these
be conducted
As discussed
of a typical
recovery
data
associated
mills
has provided
the
secondary
of process
presented
testing
the knotter,
system
and
recovery,
test
Included
system,
evap'orator
Industry
is limited
points.
testing
and for
2-2.
document
oper'ation
flow
of HAP's
emitted
factors
is currently
additional
discussion
semi-chemical
HAP's
further
data.
considered
A list
and
of the emission
that
and
non-
POINTS
a detailed
as the specific
review
10 percent,1
EMISSION
provides
of production,
65 percent.l
for chemical
Industry
and
for 25 percent
process.
and bleaching
the
exact
on the end use
Process
processes
discussed
semi-chemical,
semi-chemical.pulping
These
differences
2-5
document
soda.
Detailed
between
the kraft
and
of the differences
in this
processes
are being
was
and
are
soda,
provided
considered
by
in the
TABLE
2-2.
MAJOR
name
1,4-Dichlorobenzene
2,4,5-Trichlorophenol
2-Butanone
(MEK)
Acetaldehyde
Acetophenone
Acrolein
Carbon
disulfide
Carbon
tetrachloride
Chlorine
Chloroform
Formaldehyde
Hexane
Hydrochloric
Acid
Methanol
Methyl
chloroform
Methylene
chloride
Pkopionaldehyde
Toluene
2-6
EMITTED
FROM
Process Operations
(Covered by this BID)
Chemical Recovery
---.-..e----
-e-
I
I
wood
Preparation
Coproduot
Aooovory
I
*
wood Chips
,
d
Coproduot
Recovery.
Pulping
Area
Weak Black
Liquor Evaporation
and Concentration
I
pulp
-----Jt,
Washing
Area
I
I
f+JlP
f
l-
I
-
I
I
Recovery
Furnace
Smelt
Green Liquor
Praparation
To Wastewater
Treatment Plant
or Condensate
pulp
I
I
-ww
--
-mw
Cooking Uquor
-mm
To Wastewater
Treatment Plant
(a)
I
I
Weak Black
Liquor Storage
I
I
-m
-----
"';l;;l"
-W
I
Strong
Black
Liquor
I
-
Black Liquor
Oxidation with
Direct Contact
Evaporator
(in older mills)
or Concentrator
(in newer mills)
Green
Liquor
I
I
rule;
they
however,
are not
included
specifically
in this
document.
The
remainder
pulping
processes
preparation
through
knots
three
of wood
The
process
and oversize
digestion
process
processes,
such
reuse
goes
process.
three
chips
pulping
the
the chips
steps
chemicals
where
from the
Some
pulping
the spent
chemicals
The remainder
of this
processes
their
are sent
several
recover
with
reduce
through
three
Despite
begin
Wood
and spent
are removed
as kraft,
these
processes
to chemically
then
these
points.
chips.
particles
in the pulping
discusses
pulping
pulp
discusses
emission
into wood
a digestion
a pulp.
section
and their
all
differences,
into
of this
and their
for
section
emission
points.
2.2.1.1
typical
The
kraft
Kraft
pulping
identified.
Table
Process.
process,
Figure
with
2-3 presents
emission
points
shown
presents
emission
ranges
Table
are given
2-4 provides
developed
and
emission
technical
in Figure
screening,
kraft
liquor
solution
cooking
The
the
digestion
and weak
lignin,
black
water,
for the
2-4
Emission
In most
factor
emission
points.
factors
cases,
the
by industry
of the kraft
in June
process
1993
hydroxide
process
lignin
process
liquor,
cooking
breaks
that holds
order
(NCASI
the wood
unbleached
which
is a solution
salts,
2-8
chips
and sodium
down
as shown
washing,
recovery.
wood
produces
hydrolysis
process,
brownstock
and coproduct
involves
of sodium
pulping
deknotting,
recovery,
or digestion
dissolving
in Table
are digestion,
chemical
pulping
points.
stream
650).
components
2-3,
Table
of the emission
B.
supplied
points
characteristics,
in Appendix
as those
key
2-4
presented
bulletin
The
for these
and wastewater
2-3.1r3t6t7
only a summary
shown
factors
of magnitude
in Figure
in Table
the emission
the vent
characteristics
factors
2-3 presents
The
in a white
sulfide.
the wood
fibers
pulp
This
structure by
together.
(brownstock)
of solubilized
and sulphonation
products.*
To Wartswater
12
tz?oz;~
11
h
Turpantins
RcNl~vary
16
5
Ot
wood Chips
l
Digortrr
Syvtem
slow
Tank
I
-
6
Ot
I
-
Knotter
Screens
or Decker
Warher
Oxygen
Delignifioation
I
I
Oxygen
Delignification
Slow Tank
Cooking Liquor
4
15
+
To Wastewater
Treatment Plant
or Condensate Stripper
Iu
\b
10
6
Post Oxygen
Washer
To Storage
or Bleaching
LEGEND
0
-
I
t-
Prooerr Stream
-
Vent Stream
Liquid Stream
ci
To Wastewater
Treatment Plant or
Condensate Stripper
To Tall
Oil Storage
Figure 2-3.
8
2
TABLE
Emission
point
Vent
2-3.
TYPICAL
Emission
point
ID
VENT
AND WASTEWATER
STREAM CHARACTERISTICS
EMISSION POINTS
Emission point
klinimus
capaci tya
(ADT/day)
Haxirmn
capaci tya
(ADT/day)
Average
capaci tya
(ADT/day)
FOR KRAFT
Tellp.b
(c)
Moisture
cantent b
(Xl
Heat
contentd
(Kj/scm)
FL0
rateb
(scWMs
pulp/day)
PULPING
94
1800
720
1.3
82.5
30-99
70
94
1800
720
0.026
112.5
35-70
gas
Wastewater
94
1800
720
0.0026
42.5
3-20
18,400
94
1800
720
0.9
30
NAc
20
Uasher
65
1625
650
0.9
32.5
2-10
40
65
1625
650
0.18
65
15-35
20
Decker/screen
65
1625
720
0.9
NA
NA
0.2
Oxygen delignification
blow tank
498
1300
930
0.026
NA
NA
150
Oxygen delignification
washer and seal tank
498
1300
930
0.18
NA
NA
50
10
Evaporator/hotwelI
65
1625
650
0.0027
112.5
SO-90
21,300
11
Condensate stripper
94
1800
720
0.0027
112.5
NA
WA
12
Turpentine condenser
94
1800
720
0.00257
42.5
IA
18,800
13
65
1625
720
0.000069-0.00763
40
NA
210
14
65
1625
650
0.00274
NA
NA
2,000
15
94
1800
720
0.69-l .4
40
NA
NA
16
Turpentine decanter
underf Low
94
1800
720
0.11
40
IA
IA
17
Evaporator condensates
65
1625
650
4.2-4.9
40
IA
%A
I
a
b
TABLE
2-4.
TYPICAL
UNCONTROLLED
EMISSION
FACTORS
FOR KRAFT
PULPING
Vent
Emission
point ID
Emission point
Digester
relief gas
N
I
=:
Uastewater
'
FACILITIESasb
(Kg/Rg pulp)
Total HAP'
Total VOCc
Methanol
Acetone
TRS
0.1
2.4-4.4
0.0062-0.091
0.0015
2.37-4.02
0.00035-0.00039
4-4.9
0.000240.0003
0.00004-0.0002
2.4-4-O
0.004
2.6-2.7
0.003
0.00006
2.6-2.7
0.1-0.6
0.8-2.6
0.02-0.03
0.005-0.007
NAd
O-026-0.35
1.8-3.4
0.0022-0.15
0.0005-0.033
1.4-2.1
0.2
1.6-5.8
0.18-0.19
0.01-0.04
0.22
0.003-0.005
0.01-0.023
0.002-0.003
0.005-0.007
NA
Oxygen delignification
blow tank
0.019-0.050
0.14
0.05-0.005
0.001
WA
Oxygen delignification
seal tank
washer and
O-24
0.41
0.076
0.073
NA
0.002-0.02
3.1-5.4
0.0014-0.02
0.000007-0.002
3.5
NA
NA
NA
NA
HA
0.004
4.1
0.003
0.0001
2.7
NA
0.006
NA
NA
0.10
10
Evaporator/hotwelI
11
Condensate
12
Turpentine condenser
13
14
0.043-0.1s
0.069-0.15
o-043-0.1
0.0005-0.01
WA
15
0.10-0.62
0.34-l .20
0.1-0.59
0.0012-0.0043
0.33
16
0.51
0.97
0.5
0.004
0.07
17
Evaporator
0.17-3.04
0.17-3.04
0.15-3.0
0.0039-0.01
0.52
18
O-039-0.63
0.11-0.71
0;031-0.62
0.0025-0.001
0.26
stripper
condensates
The
pulp
through
The
and
spent
which
a knotter,
spent
washing
chemicals
process
recovery
slurry
removes
are then
The pulp
oversize
wood
removed
delignification
to remove
deknotting,
brownstock
evaporation,
and
coproduct
Diaester
2.2.1.1.1
may
be a batch
components
completed
in the
discharged
into
Heat
tank.
the
blow
(TRS)
recovery
pulp
quality
ID's
gases
blow
may
tank
be vented
which
comprises
gases
cooking
liquor
is
and pulp
called
are
a blow
is often
to an accumulator
Based
on the total
of the
be incinerated,
part
of
blow
may then
chemical
2).
or condensed
for
for recovering
2.2.1.1.6)
a defibering
to produce
two emission
when
continuous
are
enter
washing
emissions,
in Section
gas emissions
Specifically,
in surges
digesters
blow
digesters,
in Figure
rate.
to pulp
gas
sulfur
or
a higher-
pulp.
digester
constant
tank
prior
blow
(The processes
from.the
or a vapor
reduced
stripped,
are discussed
stage
tank;
system,
After
black
digestion
1 and
digestion,
vess.el typically
concentrations
then
and continuous
shown
to storage
vessel.
of turpentine.
Because
prior
delignification,
from
deknotting
oxygen
system.
may
coproducts
undergoes
and generally
the weak
a low-pressure
and terpene
the
is removed
describe
process,
or similar
for collection.
gases
water
The digester
process
digester,
gases
the
The
tank
recovery
tank
Blow
sphere
system.
in the pulping
and blow
chemical
recovery.
or continuous
digester
lignin
oxygen
wood.
to remove
the pulp
sections
pass
in the
in the
and excess
additional
washing,
the pulp
screened
particles
following
or undigested
from
is then
In some processes,
The
the digester
for reuse
in the decker.
or bleaching.
from
oversize
process.
additional
chemical
Thus,
less
blow
overall
than
those
point
gases
the batch
the digester
digester
differ
blows
emissions
volumes
from
2-12
identifiers
(emission
digester
batch
are
point
releases
its entire
load
are released
of gases
batch
between
from
digesters.
into a
at a
continuous
High-
pressure
gases
primary
condenser
discharges
tank
from
and then
foul
condensate
are recovered
organic
the blow
tank
are typically
sent
to an accumulator.
and blow
and condensed
gas.
The
Vapors
to recover
some
to a
accumulator
from
the
blow
of the
compounds.
Digester
emissions
Figure
relief
gases
(emission
relief
2-3,
condensed
and
point
ID 3).
gases
retained
are alSO
a point
However,
as shown
to recover
of potential
in
of softwoods
turpentine
can be
(see Section
2.2.1.14.7
A wide
reduced
sulfur
digestion
vents,
of volatile
compound
process.
the
blow
emissions
produced
of HAP
15,
2.2.1.1.2
are
fully
broken
defined
as shown
Deknottina
is often
large
pieces
down
in Table
nrocess.
of fiber
The
bundles
digestion.
of pulp
chips
or fiber
bundles)
on a 3/8-inch
Knots
are
for
discarded
further
Two
older
types
which
is being
as waste,
of knotters
releases
phased
washer.10
Emission
The
enclosed,
[emission
step
in'the
in Figure
or wood
that
2-3.
were
not
are generally
is retained
prior
lowers
in Table
second
are
(as-wood
perforated
plate.9
to washing
and are
or returned
in current
vibratory
emissions
out because
which
shown
that
burned,
is the open-top
generated,
are
emissions
to the digester
digestion.
design,
screen,
next
They
fraction
either
underflows,
2-4,
as shown
as the
removed
process
181).
deknotting,
during
from process
by the digestion
is a point
(VOC) and
by the
emissions
condensates)
point
Knots
to HAP
decanter
methanol,
process
are produced
turpentine
(predominantly
kraft
compounds
condensates,
evaporator
ID's
organic
In addition
wastewater
(digester
and
variety
large
the efficiency
factors
One type,
screen.
directly
of the
use.
The vibratory
to the
quantity
atmosphere,
of foam
of the brownstock
for vibratory
screen
knotters
2-4.
type
pressurized,
of knotter
consists
cylindrical,
2-13
of a totally
perforated
an
screen.
rotating
vacuum
foil
in this
and pressure
type
of knotter
Lower
and reduces
foam
buildup.
this
type
of knotter
second
Brownstock
2.2.1.1.3
and knotter
brownstock
is washed
washing
is to remove
recover
sodium
and
industry
of washers
include
horizontal
belt
Washers
black
from
(fresh
the black
oversize
particles
to
during
of washer
Other
pressure
used
All washers
The rinsed
and thickened
type
of
types
washers,
and dilution/extraction.
or recycled)
liquor.
purpose
washer.
to the method
pulp.
called
the pulp
rotary
press,
according
brownstock
of water
recover
washers,
tank
commonly
common
with
system.
contamination
vacuum
clean
the blow
The
from
The most
wash
from
2-3.
and to avoid
is the rotary
washers,
Pulp
liquor
of
associated
it is an enclosed
in Figure
steps.
are
in a process
black
diffusion
differ
liquor
addition
sulfur
processing
'used in the
water
a series
the perforations
emissions
washinq.
with
weak
keeps
because
as shown
washing,
subsequent
which
pulses,
produces
to rinse
pulp
to separate
require
the
the pulp
and
is screened
in a decker
for
(emission
point
or llweaktU
black
to the
liquor
chemical
recovery
A foam
separated
which
up the
Tables
using
foamed
mass.
to the
2-3 and
liquor
tanks.
process.
tanks
and
form
Foam
sent
2-4
centrifugal
force
atmosphere,
(emission
is typically
the
is formed
cooking
process,
piped
ID 6).
2-14
the pulp,
reducing
the
is completed
force
in Figure
The
to the chemical
process.
goes
air trapped
as shown
soap,
are extremely
thereby
or mechanical
point
when
with
that
defoaming
allows
foam
liquors,
"pellets!* on wood
Generally,
This
to capture
If foam remains
in the washing
tank
to vent
used
by the caustic
efficiency.11
foam
black
filtrate
and
to disperse
mass
is typically
in the
saponify
washing
the
tank
the washing
it can
in filtrate
process.
is dissolved
through
hard
is recovered
in
to break
in the
foam
2-3 and
defoamed
recovery
weak
Emissions
entrained
occur
in the pulp
typical
vent
and
characteristics
Tables
2-3 and
digestion
from
a brownstock
of wood
of shower
lower
pulped
in temperature
varies
with
the
Washers
typically
washers
such
require
dilute
and
HAP
Washers
or have
with
these
higher
.step prior
when
used
as a step
chemicals,
can help
chemical
effluent
of the
Vent
oxygen
2-4,
are
These
and vent
consequently,
heat
will
to ambient
will
have
have
belt
washer
air.
Vent
lower
flow
lignin
it may
stage
characteristics
stage
plant
and HAP
Because
2-15
In addition,
the
emission
with
the
the
resulting
recovery
wastewater
are presented
respectively.
use by
is compatible
chemical
for
chlorine
chemical
the pulp.
process. l2
be used
delignification,
with
plant
effluent
to the
also
Oxygen
from
of
as a delignification
to bleaching
in the bleach
delignification
cases
bleach
Treatment
stage.
content).
exposure
therefore,
reduce
can be recycled
stream
washer
or horizontal
however,
prior
recovery
organic.loading
vent
enclosed.
a. lower
conditions.
delignification
kraft
point
digester
washer
washer
in some
to bleaching;
more
the
considerably
than
drum
delisnification
is used
in alkaline
oxygen
limited
the
on the washer.
fully
and,
and
HAP concentrations.
bleaching
removing
not
(and thus
Oxvaen
oxygen
are
content
vacuum
emissions
washers,
and also
of air to capture
as the diffusion
from
with
volumes
of emissions
or continuous),
used
therefore,
large
2.2.1.1.4
pulp
as the rotary
As
of the pulp
brownstock
of enclosure
concentration
enclosed
rates
of the
in
ID.5).
and type
from washers
content
fugitive
such
streams
streams
in moisture
and,
point
or hardwood),
and
type
hooded
moisture
are
Vent
emission
are summarized
(emission
(batch
(softwood
The heat
washer
The
volatilize.
and HAP
are a function
of digestion
as HAP compounds
slurry
the quantity
process,
water.
streams.
liquor
respectively
washer
type
process
characteristics
stream
2-4,
the
production,
and black
of the brownstock
with
type
sy-stem,
is reduced.12
factors
in Tables
for the
2-3
and'
Chemical
2.2.1.1.5
the
kraft
from
pulp
the weak
and
oxygen
The
general
shown
black
steps
(recovery
2-2)
recovery
For
efficient
chemical
solids)
concentration
typically
effect
removed
so that
the vapor
supply
to the
process
containing
of concentrating
emissions
because
from
also
of the
the
and Tables
2-3
produces
oil).
shown
two
pulped.
have
chemical
Large
per kilogram
black
liquor
of
liquor
The water
is
in multiple-
of direct
or
at different
pressures
body
the steam
becomes
phase.
and
2-4
saleable
vaporized
liquor
evaporator
of certain
These
points
(emission
Generally,
the evaporation
recoverv.
resinous
the digester
separator
to remove
any small
wood
from the
condensate
streams
to the -air
are depicted
in Figure
2-3
The
kraft
digester
relief
to reduce
the process
air pollutant
softwoods
condenser
2-16
during
turpentine
from
gases
compounds
point
coproducts:
when
from
are emitted
Hazardous
is recovered
2-3)
emitted
Non-condensible
been
from the
Cooroduct
in Figure
are
and hotwells.
Turpentine
This
is required.
a series
one evaporator
partitioning
2.2.1.1.6
cooking
mechanisms.
that
occur
liquid
black
documents.
a desired
operated
the cooking
vents
(as
evaporator.
basic
HAP's
.evaporator
from
2-3.
inorganic
of water
comprise
air pollutants
by two
water
to achieve
evaporators
next
Hazardous
of excess
the spent
which
evaporators,
contact
of the
of 60 to 65 percent.13
from
indirect
remaining
in future
recovery
evaporated
chemicals
and calcining.
the
(5 to 7 kilograms
are
in Figure
combustion/oxidation/reduction
be discussed
evaporation
washing
or concentration,
evaporation;
will
of water
of cooking
in
and sulfur
brownstock
as shown
and recausticizing
discusses
the
from
are evaporation
element
of sodium
processes,
processes
chemicals,
solids
recovered
(optional),
furnace),
only
amounts
liquor
in the recovery
oxidation
section
is the recovery
delignification
in Figure
liquor
dry
process
An essential
recovery.
gases
content
chips
pulping
process
and soap
relief
such
(tall
gases
(as
as pine
are
are vented
to a
and to a cyclone
or fines.
The
turpentine
and water
The
a decanter.
overflows
removed
other
from
from
Table
the decanter
decanter
(emission
turpentine
decanter
are
separated
which
than
water,
is lighter
to a storage
tank.
overflow
through
During
vents.
at a level
similar
with
the decanting
As shown
ID 16), methanol
point
in
The water
is combined
for treatment.
are emitted
2-4
by the condenser
bottom
condensates
HAP's
process,
turpentine,
the
process
removed
in
is emitted
to that
from
from
the
a decker
or screen.
Tall
oil
Tall
process.
are
can
recovered
reactor,
are not
weak
oils
from
expected
the.digester
from
the
steam
such
and
waste
and to destroy
characteristics
are
not
Emission
the
same
available
sulfite
The
sulfite
basic
coproduct
pulping
are transferred
cooking
pulps
wood
solution.
to take
diagram.
Typical
bases
combustion
The
with
or batch
(emission
absorbed
include
2-17
calcium,
point
stripper
. -
process
the
digester
vent
a
follows
exception
process,
the sulfite
dioxide
vent
practiced
As in the kraft
device,
2-4 presents
sulfite
system
VOC
of the heat
stripping
Figure
from
The VOC-laden
2-3 provides
is not typically
However,
sulfur
for
to remove
to a continuous
using
factors
as the kraft
process.
in the
turpentine
odors.
Table
Process.
liquor.
as from
steam
data
which
the
Condensates
advantage
Sulfite
steps
after
emission
to an existing
time.
process
oil
emissions
it occurs
and steam-stripped
at this
recovery,
with
as well
the VOC.
factor
HAP
striwinq.
for condensate
2.2.1.2
typical
steam
sent
boiler,
a tall
of volatiles
and to reduce
typically
using
and
ID 13).
combined
streams
because
pulping
softwoods
Significant
2-4 provides
evaporator,
as the power
ID 11).
point
the kraft
in resinous
stripped
Table
are often
from
process
2-3.
step
Condensate
is then
content
this
has been
(emission
2.2.1.1.7
recovery,
Figure
process.
point
found
the evaporation
from
liquor
evaporation
be recovered
are.also
as shown.in
black
this
also
of
in the
wood
chips
and cooked
process
chemically
in an acidic
magnesium,
ammonium,
A
I
wood chips
Digester
Syrtem
I
I
I
I
I
1
Blow
Tank
Cooklng Liquor
I
I
ti
A
I
I
A
I
I
I
A
1
A
I
I
Knotter
Washer
I
-1
I-
i
To Wartewater
Treatment Plant
I-~--~
-s-s
-
~~
LEGEND
A
,
.I
Proorra Stream
Vent Stranm
Liquid Stream
I
I
To Wartewater
Treatment Plant
Figure 2-4.
I
Seal
0
Tank
shown
AS
or sodium.
particles
are
is washed
to remove
in Figure
particles,
chemicals
removed
after
in the deknotting
removed
oversize
2-4,
the
spent
digestion,
process
chemicals,
and thickened
in the washing
screened
to remove
process
to remove
excess
may
oversize
water.
then
'The
be recovered
for reuse.
Spent
cooking
be collected
recovered
cost
from
Chemical
sulfite
the
because
process
type
(i.e.,
bases
recovery
economically
of the pollution
general
steps
of sulfite
of base
being
recovered.
this
BID
only
as discussed
focuses
recovery
process
Appendix
C includes
wastewater
a description
to Sections
process
and
mechanical
follows
discussed
similar
in Sections
is also
calcium-based
vary
the process
operation
points,
in further
factors
with
begins
Because
the sulfite
detail.
and vent
for the
and
sulfite
process.
processes,
process
For
refer
semi-chemical
The
to the kraft
pulping
pulps.14
process.
2.2.1.1
The
of the chemical
pulping
chemical
semi-chemical
steps
which
2.2.1.1.5.
Process.
is a combination
a typical
of calcium)
and 2.2.1.1.3.
Semi-Chemical
high-yield
The
washers).
recovery
and washing
process
to produce
the
However,
on process
pulping
the
can be
achieved.
chemical
characteristics
The
feasible,
in Section
of the deknotting
2.2.1.3
stock
may
is not cost-effective.
HAP emission
2.2.1.1.2
red
with
is not discussed
stream
process
chemicals
control
is not practiced
recovery
evaporation,
the washing
because
with
from
In addition,
streams
soluble
recovery
The
the
gaseous
chemical
attractive
removed
and recovered.
of all
makes
liquor
2-5 presents
semi-chemical
or sulfite
and 2.2.1.2,
process
processes
namely,
digestion
and washing.
In the
digested
the
semi-chemical
with
lignin
and
process,
cooking.chemicals
the wood.
wood
chips
to weaken
Oversize
the
particles
are partially
bonds
between
are removed
from
Wood Chips
I
I
I
Digester
Syrtem
Cooking Liquor
&iP
*
Knotter
I
1
To Wartewatsr
Treatment Plant
I
I
I
I
I
I
1
1 ,-
- -
- ; - -
- -
To Storage
- ,
h)
t!J
0
LEGEND
A
I
I
A
I
I
I
I
Intermediate
A
I
I
------------m-
Spent Liquor
;
To Wastawater
Treatment Plant
To Tail
Oil Storage
is
z
9
mechanical
Based
mills
mills
spent
industry
that
combine
The
process.
on a voluntary
chemical
with
pulping
liquor
liquor
from
is then
survey,
practice
spent
pulp
there
chemical
from
to storage.
are no semiHowever,
recovery.
on-site
an adjacent
sent
semi-chemical
kraft
process
some
process
for chemical
recovery.
There
neutral
sulfite
NSSC
The
(NSCM).
major
kraft/sulfite
wood
pulp
the
rates
essentially
strength
and
discussed
BID
soda
Data
factors
little
processes,
HAP
are dependent
used
HAP
on
to weaken
emission
characteristics
sodium
cooking
hydroxide
Kraft
recovery
for the
2.2.1.1.5.
on process
process
and stream
soda
to the kraft
process
is added
in the
points;
not available.
cooking
2-21
and
2.2.1.1.3,
process
are
process,
the
liquor,
as
discussed,
therefore,
in further
characteristics
are
greater
evaporation,
As previously
is not discussed
of sodium
and washing
2.2.1.1.1
operation
except
to maintain
with
is
are
amount
digestion
begins
process
process,
in the washing
Similar
process
pulping
process
A small
removed
recovered.
soda
pulping
in Sections
Chemicals
for the
The
in the
yield. 16
for vent
sulfur
process
stream
hydroxide.
to the
and
focuses
recovery
and
delignifies
pulping
C includes
to the kraft
used
in Section
only
partially
Process.
are.discussed
chemical
and only
Appendix
Soda
sodium
respectively.
soda
type,
identical
is added
collected
process
and wastewater
chemicals
processes
semi-chemical
semi-chemical
the semi-chemical
wood
The
predominantly
sulfide
sulfite
process.
2.2.1.4
pulp
from
and vent
the
common
the kraft/sulfite
in the wood.
semi-chemical
that
is shorter
production,
factors
and neutral
between
processes
As with
chips.
bonds
The most
difference
pulping
process
emission
(NSSC)
pulping:
process.15
only
digestion
of semi-chemical
semi-chemical
chemimechanical
is the
types
this
the
detail.
and emission
Because
sulfur
compound
emissions
similar
will
to those
The
2.2.2
. The
from
Bleaching
purpose
physical
and
However,. organic
be small.
the kraft
optical
qualities
Two
approaches
of pulps.
One
approach,
chemicals,
such
groups
process
called
brightening,
peroxide,
a product
bleaching)
seeks
to almost
totally
chemicals
to the pulp
depending
of sequences,
produce
stable
methods
paper
that
selective
approach
-(true
residual
lignin
in varying
pulp
delignify
the
a temporary
a high-quality,
paper) I bleaching
remove
bleaching
attack
with
The other
as newspaper).
of
destroy
produces
the
brightness)
uses
that
(such
oxidizing
and
in the chemical
brightness
adding
is to enhance
(whiteness
are used
as hydrogen
Brightening
lignin.
be
process.
of the bleaching
chromatographic
will
Process
pulp.
the
emissions
the
combinations
product.
(such
by
To
as for bond
pulp
must
be
used.
The
most
chlorine
chlorine,
(sodium
common
common
compounds
dioxins,
presently
and hypochlorite
and toward
as chlorine
Table
2-5 provides
these
bleaching
Typically,
separate
stage,
where
bleaching
the
the washer
the
combinations
Two
from
such
dioxide
and
of chlorine
bleaching
in the bleaching
of the basic
and
as
the pulp
the application
of other
less
are ozone
compounds
prompted
caustic
functions
process.
of each
of
chemicals.
the pulp
is treated
as shown
in Figure
bleaching
occurs;
and dissolved
next
effluent
or to be sewered.
have
are
oxygen,
in the industry
the use
a summary
chemicals
to entering
peroxide,
chlorinated
away
agents
hypochlorite.17
used
over
to shift
such
hydrogen
and chloroform
furans,
chemicals
and brightening
and sodium
Concern
industry
tower,
dioxide,
hydroxide),
hydrosulfite.
paper
bleaching
with
2-6.
each
chemical
Each
stage
a washer,
lignins
which
from
Bleaching
of chemical
as wash
processes
stages
called
2-22
water
use
in a
includes
removes
the pulp
which
prior
collects
in other
stages
various
bleaching
sequences.
TABLE
Bleaching
c80mpounds
2-5.
COifPARISON
OF'COMMON
CHEMICALS
PULP BLEACHING
Bleaching
notation
USED
IN
Function
Chlorine
Oxidize
Caustic
(sodium
hydroxide)
Hydrolyze
chlorolignin
solubilize
lignin.
and
Hypochlorite
Oxidize
lignin.
Chlorine
dioxide
Oxidize and,solubilize
lignin.
In amounts with Cl2 protects
against degradation
of pulp.
Oxygen
Oxidize
Hydrogen
peroxide
lignin in
pulps.
Ozone
Oxidize
lignin.
Hydrosulfite
S or Y
and chlorinate
and solubilize
.and solubilize
and solubilize
2-23
lignin.
lignin.
l&in
in
Pulp to
Next Tower
w8dl
Towu
pulp/aldcd
Plant
slwry
vmt to sonlbbu
I
: 00@0
I
Bleaching
ammiod8
LEGEND
Point of Pomible HAP Reieme~
(Souroo ldanMkdon)
Pmoa8stmml
. -
VWltstnm
LlqUM!3tmml
Table
2-6 presents
the most
common
sequences
used
in kraft
bleaching.
Sections
typical
vent
2.2.2.1
bleach
through' 2.2.2.6
Tables
stages.
and wastewater
stream
present
2-7 and
typically
the
emission
order
of magnitude
(NCASI
technical
in the
bleaching
primary
function
delignify
tower
as those
bulletin
the
or stage
process,
that
are water-soluble
aids
in delignifying
stage
During
These
the
these
the
plants
cases,
same
in June
or soluble
stage
1993
stage
The
is to further
pumped
into a
During
2-6.
in Figure
lignin
to form
in an alkaline
before
first
chlorination.
is generally
with
the pulp
The
(C-Stase).
it proceeds
side reactions
produce
and other
phenolics,
as well
chlorination
Tables
tank.
compounds
medium,
which
to the next
chlorinated
as unreacted
stage
2-7 and
chloroform,
tower,
2-8 provide
organics.
chlorine,
the washer,
emissions
may
and
data
for
points.
Extraction
2.2.2.2.
after
chlorination
stage
and
the
pulp.
chlorinated
and
After
remove
excess
largest
amount
stages
The
stages
(E-Stase).
serve
lignin
the extraction
chemicals
of unwanted
(chlorination
The
the extraction
extraction
oxidized
solution.
the
Stase
is typically
remaining
delignified
two
In most
by industry
is typically
emissions,
from
seal
Stase
reacts
bleaching,
byproduct
.be vented
bleach
or stages.18
chlorinated
phenol,
supplied
The pulp
chlorine
this
bleaching
in Table
of the chlorination
similar
from
chlorine,
650).
process
pulp. I8
include
and methanol.
presented
Chlorination
2.2.2.1
vents
The wastewater
chloroform
factors
the typical
for bleaching
kraft
Some of the
respectively.
and methanol.
contains
2-8 provide
on
characteristics
factors,
pulps, and HAP emission
identified
HAP's emitted by bleaching
chloroform,
information
removes
lignin
is removed
and extraction).17
2-25
the
the
in a caustic
the pulp
and solubilized
This
and whiten
by solubilization
stage,
stage
stage.
to bleach
stage
next
is washed
The
lignin.
in these
A portion
to
first
of the
TABLE
2-6.
MOST
COMMON
KBAFT
BLEACH
Number
Bleach
sequencesb
SEQUENCES'
of mills
bleach
sequence
C-E-H
C-E-HE-D
C-EO-HE-H-DE
CD-E-D-E-D
CD-E-H-D
3.
CD-E-Hi-D-E-D
CD-EO-D
CD-EO-H-D
..
with
9
-
CD-EOP-D
DC-EOP-D
DCD-EOP-D
a Bleaching
sequences
performed
at three or more mills are
listed.
Approximately
90 other sequences
are used at one or
two mills for each sequence.
b Key:
C
E
D
H
0
P
CD
EO
EOP
=
=
=
=
=
=
=
=
=
Chlorination
Extraction
Chlorine dioxide
Hypochlorite
Oxygen
Peroxide
Chlorine dioxide substitution
Oxygen added to extraction
stage
Peroxide and oxygen added to extraction
stage
2-26
TABLE
2-7.
TYPICAL
Emission
source
Vent
Uasteuater
VENT
AND WASTEWATER
Emission point
Hinimun
capaci tya
fADT/day)
STREAM
EMISSION
Haximun
capaci tya
fADT/day)
CHARACTERISTICS
POINTS
FOR KRAFT
BLEACH
PLANT
Average
cepaci tya
fAOT/day)
ratell
(scmn/Hg pulp/day)
klilp.b
("c)
Moisture'
content b
co
neat
content d
fKj/scm)
FlO
C-stage tower
90
1500
600
0.024
60
NAC
20
C-stage uasher
90
1500
600
0.362
60
WA
90
1500
600
0.014
60
NA
1900
E-stage tower
90
1500
600
0.024
60
NA
30
E-stage washer
90
1500
600
0.362
60
NA
10
90
1500
600
0.014
60
WA
230
D-stage tower
90
1500
600
0.024
60
NA
0.2
D-stage uasher
90
1500
600
0.362
60
WA
0.2
90
1500
600
0.014
60
NA
0.02
H-stage tower
90
1500
600
0.024
60
WA
0.1
R-stage uasher
90
1500
600
0.362
60
WA
20
90
1500
600
0.014
60
NA
90
1500
600
NA
--
--
-.
90
1500
600
NA'
--
--
-_
filtrate)
Caustic sewer (E-stage filtrate)
z
c
d
Capacities are from References 1 end 3. ADT/day = Air dried short tons/day.
Based on Reference 8. Flowrates are reported at standard conditions of dry gas (21.1'C and 760 mn Hg).
NA = Not available at this time.
The heat content is the heat released based on compounds in the vent stream (reference 6) and is at.standard dry conditions.
TABLE
2-8.
SUMMARY
OF TYPICAL UNCONTROLLED
EMISSION
KRAFT BLEACH PLANT FACILITIES
FACTORS
FOR
Vent
Wastewater
a
b
Emission pointb
Total HAP'
Total VOCc
Chlorine
Chloroform
Methanol
C-stage touer
0.054-0.252
0.008-0.041
0.0009-0.01
0.05-0.21
0.00062-0.029
C-stage washer
0.062-0.647
0.012-0.439
0.0009-0.0113
0.05-0.21
0.009-0.415
0.0084-0.323
0.007-0.32
0.00127-0.0053
0.0067-0.311
E-stage touer
0.013-0.026
0.011-0.026
0.0014-0.01
0-0.003
0.0027-0.0054
E-stage washer
0.031-0.168
0.044-0.091
0.0014-0.01
o-0.003
0.0035-0.078
0.013-0.101
0.023-0.161
0.00009-0.0005
0-0.000076
0.0026-0.029
D-stage tower
0.011-0.036
0.00004-0.018
0.00003-0.02
0.01
0.0000007-0.0002
D-stage washer
0.01-0.06
O.OODl-0.042
D.O0003-0.02
0.01
0.00001-0.003
O.ODOS-0.02
0.00006-0.02
0.000003-0.001
0.0003
0.000008-0.002
H-stage tower
0.088-0.62
0.056-0.119
0.04-0.05
0.01
D.D0049-0.0063
H-stage washer
0.15
0.15
0.04
0.01
0.091
0.074
0.076
0.003
0.0003
0.068
0.12-0.52
O-12-0.53
0.0008-0.005
0.05-0.5
0.042-O-32
D-04-0.32
O.ODD2-0.0023
D-03-0.3
Specific emission factors for these and other compounds are given in Appendix 6. These ranges represent the variability of the emission
factors associated uith the model plants given in Appendix C.
Key: C-stage = Chlorination
1
I
E-stage = Extraction
D-stage = Chlorine dioxide
H-stage = Hypochlorite
Total HAP and WC emission factors are based on the sun of individual HAP and VOC emission factors.
filtrate
from
filtrate
sewered
chlorolignin
stage
precipitation
Emission
tower,
washer,
used
Staae
substitute
chlorine
for total
released
similar
times
basis)
from
tank
HAP,
the
are
shown
in
brightness
When
chorine
points.
oxidizing
dioxide
Chlorine
reaction
dioxide
stage.
dioxide
The
stage
has
(on a pound-per-pound
of cellulose
dioxide
before
all high--
and
bleaching
agent
that
destroys
it also
the
on site
as a gas
in an acidic
vent
factor
and wastewater
data
degradation
stage
(H-Stase).
for the
certain
Hypochlorite
for sulfite
chromophoric
in kraft
to kraft
pulp
sequence
can also
pulps.
2-29
common
is a true
the cellulose
occurs
of the
Another
Hypochlorite
attacks
of hypochlorite
agent
generated
Stase
is hypochlorite.
pulps.
characteristics.21
2-8 provide
stage
intermediate
using
effluent
chlorate
bleaching
application
Consequently,
components.
Hvoochlorite
cellulose
less chlorinated
improved
and emission
stage
however,
chlorine
step has
is typically
2-7 and
in destroying
or hemicellulose.
effluent.
dioxide
of sodium
Tables
2.2.2.4
bleaching
Chlorine
selectivity
of the pulp
characteristics
bleached
(as a
to the chlorination
has a high
into the
dioxide
solution.22
lignin;
stage
dioxide
for nearly
chlorine
delignification
chlorine
is often
- chlorine
chlorine
power
is added
are released
the
usage
is used
degradation
additional
stream
emission
dioxide
without
organics
dioxide
pul~s.2~
Chlorine
lignin
is similar
and
and
in the chlorination
of the chlorine
chlorine
(D-Stase)
Chlorine
stage
greater
than
Stase
or as an additional
dioxide
and has
Dioxide
either
for some
'substitution)
as an
of the solubilized
and seal
(C/D-Staae).
in bleaching,
High
the remaining
factors
and chlorine
Chlorine
Substitution
from
be reused.and
2-8.
2.2.2.3
the
may
to prevent
methanol,
extraction
2.63
stages
compounds.1g
chloroform,
Table
these
groups
to some
pulp,
used
or to produce
However,
extent.
so the
is usually
be used
of
only
semi-
as an effective
the hypochlorite
stage
has
points
been
identified
of chloroform
NCASI
show
that
lower
chloroform
emissions.23
bleaching
sequences
emissions.23
and HAP emission
stage
in Tables
given
Ozone
2.2.2.5
Bleachins
bleaching
is effective
bleaching
and
the
scale
HAP
bleaching
emissions
from
2.2.2.6
Peroxide
stage
Stase
peroxide,
are effective
agents.
Peroxides
are frequently
first
extraction
process.
Peroxides
losses
in the
generate
yield
fewer
this
stage
2.3
BASELINE
This
have
bleaching
agents
in
of the bleaching
lignified
presents
emissions.
national
These
operation
emission
emission
in place
on these
points.
through
and
their
summarize
baseline
stages
of highly
to account
pulp
generally
as bleaching
strength
adjusted
for the
potential
Peroxides,
without
organic
and
measured.
brightness
chapter,
2.3.2
States,
lignin-preserving
used
full-
significant
pulps
and
Emissions
from
EMISSIONS
uncontrolled
regarding
compounds
Another
stage.
in
paper- industry.
regulations
not been
as
not result
one
increase
determined
is only
as well
in the United
or in later
chlorinated
section
estimates
on the
stage
does
organic
fP-Stase).
hydrogen
the
bleaching
havd
is the peroxide
Ozone
delignification
there
this process
stream
respectively.
IZ-Stase).
line operating
have
of chlorinated
Currently
ozone
bleaching
Ozone
or emission
'such as chloroform.24
Staqe
for further
brightening.
formation
2-8,
by
hypochlorite
and wastewater
factors
2-7 and
conducted
without
Vent
characteristics
are
Studies
Significant
from
controls
factors
in the pulp
were
control
level
Federal
and State
provided
and
developed
presented
of applicable
current
level
levels
State
of control
were
and Federal
by many
facilities
2-30
based
in this
of control.
industry.
assumed
emission
information
and paper
points
estimates
Baseline
a review
baseline
Section
regulations.
baseline
The
(NSPS)
of Federal
EPA has
limits
digester
systems,
of
summarizes
the
Federal
points
concentration
affected
Table
for these
the maximum
2-9
processYoperation
emission
rates
on a
basis.
Although
from
and provides
include
systems,
strippers.
regulations
two
that
evaporator
and condensate
standards
established
from points
multiple-effect
washers,
these
the
regulations
pulping
by this
through
the
thereby
reducing
do not
facilities
process,
rule
are achieving
collection
specifically
with
address
new processes
the required
TRS
limits
and combustion
organic
HAP
98 percent.
Summarv
2.3.2
of State
In addition
sources,
existing
sources.
to process
Table
States
are
systems,
facilities
dioxide
in States
are
has
may
additional
provided
Carolina,
that
emission
points
plant
the vents
States
survey
that
condensate
combustion,
chlorine
from
assumed
and
and chlorine
these
reported
stages.
in Table
was
used
if no information
2-10
as a
was
responses.26
Maryland,
2-31
regulations.
on digester
through
This. information
to the regulations
Tennessee,
and
in
in the United
it was
limits
for
specifically
and paper
washers,
some
limits
are summarized
of control,
of control
industry
pertaining
pulp
bleach
control.
determination
In addition
TRS
scrubbing
commented
through
current
these
with
similar
of the facilities
brownstock
in States
Industry
secondary
with
to new and
adopted
points
levels
controlling
limits
have
with
baseline
applies
regulations
60 percent
in States
are
have
emission
evaporators,
strippers
which
States
State
Over
.In determining
facilities
many
operation
2-10.
Resulations
to the NSPS,
modified
North
estimates
performance
The NSPS
brownstock
emission
new source
mills. 25
pulp
emission
least
national
Regulations
developed
for kraft
HAP's
presents
emissions.
Summarv
2.3.1
2.3.4
summarized
in Table
and Michigan
have
2-10,
passed
TABLE
2-9.
Process
unit
limitsb
Method
of control
Kraft digester
system
5 ppm of TRSC
Kraft brownstock
washer system
5 ppm of TRScrd
Multiple-effect
evaporator
system
5 ppm of TRSC
Condensate
system
5 ppm of TRSyc
5 ppm
stripper
New, modified,
or
reconstructed
kraft
digester
system
.a
b
Emission
New Source
Key :
TRS
wm
Performance
=
Total
parts
=
of TRSc
Standards,
40 CFR 60, Subpart BB.
Reduced Sulfur
per million
(by volume, dry basis)
Corrected
to 10 percent oxygen.
Standard
does not apply to facilities
where implementation
has been demonstrated
to be technically
or economically
unfeasible.
2-32
TABLE
2-10.
Process
SUMMARY
unit
Xraft digester
system
OF STATE
REGULATIONS
FOR EMISSIONS
Emission
limitsa
States
5 ppm of TRS
1.2 lb TRS/ton
ADP
Xraft digester
system/multipleeffect evaporators
0.6 lb TRS/ton
20 ppm of,TRS
ADP
5 ppm of TRS
1.2 lb TRS/ton
h)
I
W
W
ADP
FROM
PULPING
regulating
FACILITIES
Method
of control
ME, VA
SC, GA, FL
ID, IN, CA, MS, LA
AL
Combustion
Incineration
Not specified
Incineration
MD
PA
Not specified
Not specified
VA, ME
FL, SC, GA
MS, TN, LA, CA
AL
Combustion
Incineration
Not specified
Not specified
Xraft brownstock
washer
5 ppm of TRS
MEb
CA
Combustion
Not specified
Xraft condensate
stripper
5 ppm
VA, ME
CA, LA
SC
Combustion
Not specified
Incineration
Bleach
3 lb/hr of Cl2
0.2 lb/hr of Cl2
3 lb/hr of clo2
0.1 lb of cl02
ME
GA
ME
GA
Not
Not
Not
Not
0.5 lb TRS/ton
oil
FL
Incineration
9.1 kg TRS/ton
ADP
NH
Not specified
Tall
plant
oil plant
Sulfite
Effluent
a Key:
b After
mills
ponds
1
TRS
wm
ADP
January
of TRS
50 ppm H2S
MT
=
=
=
Cl2
Cl02
H2S
specified
specified
specified
specified
Not specified
I
=
=
=
Chlorine
Chlorine
Hydrogen
dioxide
sulfide
regulations
that
regulations
limit
toxic
by dispersion
achieves
additional
some
controls
into
the baseline
place
to comply
2.3.3
Baseline
and bleaching
vent
all kraft
being
mills
pulping
of kraft
evaporator
systems
A smaller
percentage
well.
Steam
and
and
deckers,
devices
of first
and gas
2-11
relief
of the
turpentine
hotwell
are
vents
are
Much
at kraft
being
As shown
ranges
extraction
in
from
stage
chlorine
absorbers
gases
mills.
mills.
stage
from
vents,
and knotters
vents
and
semi-
decanter
washers
plant
for pulping
emissions
from some
of individual
vents
dioxide
(scrubbers)
are
3.0.
summarizes
25 percent
blow
However,
90 percent
treatment
sulfite,
regulations.
of bleach
processes
kraft,
put-into
used
2-11,
of all sulfite
30 percent
wastewater
Chapter
half
in Chapter
unit
digester
kraft
controlled.
scrubbing
2-13
in Table
of washers,
Combustion
Table
of the
in Tables
and evaporator
at most
to.-approximately
discussed
likely
techniques
as are those
at almost
approximately
pulping
incorporated
air pollutant
In addition,
percentages
vents.
sulfite
noncondensibles,
2-12,
regulations
Some
and
were
are presented
As shown
digesters.
are being
Table
reduction.
control
points
controlled,
controlled
the
as
air concentration
by facilities
toxic
these
from
ambient
evaluation
these
and
controlled
smaller
reported
of existing
nearly
evaporator
these
HAP emission
with
respectively.
chemical
with
facilities,
Although
HAP emissions
control
2-12,
being
the pulping
Emission-Controls
Summaries
are
limit
emissions.
These
air concentrations
of
ambient
modeling.
to compliance
process,
air pollutant
surrounding
not specifically
limits
toxic
the maximum
air pollutants
determined
do
limit
the extent
is pretreated
system.
mill
prior
Condensates
turpentine
are pretreated
with
semi-chemical
and air
strippers
3.0.
2-34
from
units
tank
from
to the
approximately
air or steam
blow
mills
wastewater
to discharge
recovery
of the digester
strippers.
to which
and
stripping.
condensates
are pretreated
as
are discussed
in
in
TABLE
2-11.
Percent
Vent
emission
Batch
relief
source
gas
Continuous
relief
Batch
gas
blow
gas
controlled
in industryb
Kraft
Sulfite
Semichemical
97
100
95
33
91
92
88
25
Continuous
blow
Turpentine
vent
decanter
73
NAC
Evaporator
(hotwell
noncondensibles)
88
55
NAc
11
57
38
- 0
Deckers
Knotters
NAc
Washer
screens
Washer
filtrate
Washer
hood
vent
gas
tanks
HAP
2-35
TABLE
2.
Stage
Emission
points
controlled
Bleach lines
controlling
at baselinea
(%)
69
HAP
Assumed
Control
efficiencyb
(%)
Tower
Washer
Seal tank
69
62
First
extraction
Tower
Washer
Seal tank
28
34
51
Hypochlorite
Tower
Washer
Seal tank
18
26
41
First
chlorine
dioxide
Tower
Washer
Seal tank
95
79
92
Second
extraction
Tower
Washer
Seal tank
32
41
59
Second
chlorine
dioxide
Tower
Washer
Seal tank
76
57
76
Chlorination
a Percent controlled
at baseline for individual
bleach stages.
However,
when the level of control is evaluated
on a
sequence
basis, 15 percent of facilities
have all equipment
controlled.
b Control
applied is a scrubber.
TABLE
2-13.
Wastewater
Digester
blow
Turpentine
"Foul"
emission
decanter
evaporator
a
b
plant
of unit processes
controlled
Kraft
SemiChemical
Sulfite
12
underflow
22
NAb
condensates
26
NAb
NAb
condensates
t8Cleantf evaporator
Bleach
source
OF
condensates
wastewater
2-37
mill
known
NAb
was known to
to practice
2.3.4
Baseline
Baseline
adjusted
Emissions
emissions
regulations,
currently
in place.
operation
points
in Table
total
are essentially
TRS,
VOC,
presented
largest
VOC
emissions
Estimated
in the pulp
and
in Table
the
as additional
Estimates
2-14.
2-14.
for the
contributing
included
using
database
developed
for this
emissions
specific
6.0,
regulations
(Tables
reduction
(Chapter
3.0).
purpose
The
on emission
(e.g.,
emission
estimation
respectively.
are based
data
used
2-11
industry
from process
of total
contributors
to total
HAP,
are
methanol
HAP
is
and total
points.
to estimate
process,
including
the models
are given
in Chapter
estimated
baseline
(Appendix
and
4.0
C), mill-
Federal/State
and capture
of the control
2-38
to be
are summarized
production),
and 2-12),
efficiency
known
in the table,
factors
pulp/bleach
Federal
emissions
emission
of the process
emissions
emissions
and VOC
As shown
emissions
Chapter
baseline
HAP
and
controls
for baseline
national
and
State
and paper
15 major
constituent
Descriptions
of current
uncontrolled
efficiency
devices
and
TABLE
2-14.
SUMMARY
Major
Pollutants
(Mg/yr)
-Total
HAP
170,000
Total
VOC
830,000
Total
reduced
350,000
sulfur
120,000
Methanol
Hexane
18,000
Toluene
14,000
Methyl
ethyl
6,000
ketone
Chloroform
3,300
Chlorine
2,800
Formaldehyde
2,100
Acetaldehyde
2,oou
Methylene
1,200
chloride
Propionaldehyde
700
Acrolein
700
60
Acetophenone
Hydrochloric
Methyl
chloroform
Carbon
disulfide
Baked on process
recovery
sources
59
acid
22
8
operation
emission points only
other than evaporation
are not
2-39
(chemical
included).
2.4
REFERENCES
1.
Responses
to the 1990 U.S. EPA National Census
Manufacturing
Facilities
Paper, and Paperboard
308 Questionnaire
and supplements
(Confidential
Information).
1992.
2.
Memorandum
from Wendy Rovansek,
Radian Corporation,
Pulp and Paper Project Team.
Pulp and Paper Mill
Math II.
June 29, 1993.
3.
1991 Lockwood-Post's
Directory
Allied Trades.
San Francisco,
Publications.
1990.
p. 9.
'4.
5.
Ref.
6.
Memorandum
from Greene, D.B.
Radian Corporation,
Shedd, S.A., EPA/CPB.
Heat Release Factors.
September
30, 1993.
7.
Environmental
Pollution Control, Pulp and Paper Industry,
Part I, Air.
U. S. Environmental
Protection
Agency,
Technology
Transfer.
Publication
No. EPA-625/7-76-001.
October
1976.
p. l-4, and
pp. 2-10 through 2-11.
8..
Ref.
5, p. 67.
9.
Ref.
5, p. 89.
10.
Ref.
5, p. 91.
11.
McDonald,
R.G. and J.N. Franklin,
eds.
Pulp and Paper
Manufacture:
The Pulping of Wood.
Second Edition.
Volume
1.
New York, McGraw-Hill
Book Company.
1969.
486.
P-
12.
Ref.
5, p.
164.
13.
Ref.
5, p.
124.
14.
of Pulp,
Section
Business
to
and
4, p. 2.
15.
Ref.
5, p. 40.
16.
Ref.
12, p. 350.
2-40
to
John
17.
Ref.
5, p.
154.
18.
Ref.
5, p.
160.
19.
Ref.
5, p.
170.
20.
Ref.
5, pp.
21.
A comparison
of the Order of
Liebergott,
N., et al.
Addition
of Chlorine and Chlorine Dioxide in the
October 1990.
TAPPI Journal.
Chlorination
Stage.
207.
P*
22.
Ref.
23.
24.
Byrd, Medwich,
Chemical
Pulps
March
Journal,
25.
26.
Responses
to Industry Survey discussed
in the following
J.E. Pinkerton,
National
Council of the Paper
letter:
Industry
for Air and Stream Improvement,
Incorporated
EPA: 15B, and P. Lassiter,
EPA:
(NCASI), to J. Telander,
(Responses
were
claimed
February
11, 1992.
CPB.
confidential
business Information).
5, p.
166 through
167.
158.
of Chloroform
Formation
and
Technical
Bulletin No. 558.
the Paper Industry
for Air
December
1988.' p. 2.
2-41
60,
of affected
Printing
EMISSION
3.0
3.1
chapter
be applied
devices
discusses
to reduce
bleaching
process
are typically
stream
wastewater
stream..
Section
3.2
control
applied
to reduce
techniques
options
that
requirements
commented
that
and
strippers
the
However,
analyses
industry
presented
the methanol
information
based
to date,
provides
data
emission
Industry
has
for scrubbers
are overstated.
chapter
documents
As the
data.
these
comments,
these
data
be considered.
Process
formation
of HAP
by changing
operating
presents
modifications
the
compounds
emission
conditions
a summary
substitutions
and
under
substitutions
in pulping
point
affect
the
and bleaching
or by altering
or process
chemicals
processes
the process
used.1
of the process
modifications
consideration
as candidate
*Table
3-l
and process
control
techniques.
The
oxygen
quantity
thereby
organics
pulping
process
delignification,
of lignin
potentially
formed.
modifications
and
improved
in the pulp
reducing
Appendix
going
(extended
washing)
to the
the quantity
C includes
3-l
in
for
for the
document
on available
to support
or-
are presented
efficiencies
in this
or
(wastewater
NESHAP.
in this
provided
vent
are candidates
removal
presented
3.3
the basis
of the pulp
gas
controls
Section
may provide
reduction
steam
and
Control
point
in the vent
can
and
2.0.
to an emission
of these
that
pulping
in Chapter
HAP's
Details
techniques
from the
discussed
(vent controls)
The
controls).
demonstrated
HAP emissions
points
wastewater
will
TECHNIQUES
INTRODUCTION
This
the
CONTROL
cooking,
reduce
bleach
the
plant,
of chlorinated
emission
factors
for
TABLE
3-l.
Puloina
(modified
Process
Modifications
Extended Cooking
continuous
cook [MCC] and rapid
heating
[RDH])
Oxygen
Improved
Delignification
Brownstock
Washing
Bleachina
Process
Substitutions
Chlorine
Dioxide
Substitution
Elimination
Oxygen/Peroxide
Split
displacement
of Hypochlorite
Use
Chlorine
in Extraction
Addition
Ozonation
a
Reference
1.
3-2
several
of the
discussed
bleach
plant
on reduced
reduction
3.2
modifications
process
in chloroform
This
vents.
Many
pulping
vents
by ducting
bleaching
vents
summary
of the
control
different
lime
kilns
control
and
their
such
bleaching
cooking
liquor.
controlled
combustion
devices
currently
such
of
a
used
to
As
devices
are
currently
evaporator
applicable)
controlled
control
Scrubbing
are also
strategy
and rotary
the scrubber
emission
3-3
followed
points
pulp
to a combustion
pulping
points
that
vents,
enclosed
vacuum
identified
for bleaching
emission
remove
vents,
incineration
For pulping
to generate
streams.
those
and-ducting
and
vents
For pulping
evaluated.
considered;
pulping
believed.to
for the
points,
fugitive
by some
their
is used
in the vent
and
vents,
of the pulping
which
dioxide,
emission
were
than
are controlled
typically
scrubbers
were
by conveyance
3-3 presents
(where
and washers
mills
device,
as knotters
followed
Table
frequently
scrubbing
hooded
control
gases,
and
some
mills.2
and blow
a control
evaluated.
being
pulp
combustion
of their
3-2 presents
currently
in kraft
and
relief
sulfur
currently
were
device
Table
process
some
facilities
and bleaching
to a combustion
control
and most
of the methanol
alone,
are applicable
boilers,
These
To determine
scrubbing
used
by scrubbing.
to recover
pulping
vents
as knotters
is used
vents.
less
vents
the majority
devices
that
and bleaching
currently
and hotwells,
Sulfite
facilities.
pulping
by scrubbing.
digester
decanter
devices
to a combustion
pulping
power
Although
sources
facilities
commonly
noncondensibles
turpentine
from
combustion
the most
to achieve
FOR VENTS
control
emissions
kraft
substitutions
and hypochlorite
TECHNIQUES
presents
HAP
and
generation.
CONTROL
section
for reducing
shown,
substitutions
modifications
use of chlorine
APPLICABLE
their
and
above.
The
focus
process
that
(i.e.,
device
point
vent
off gases
by scrubbing
may
fugitive
washers),
was
are
be
points
enclosure
evaluated.
stream
TABLE
3-2.
PERCENT
OF KRAFT
MILLS
USING
COMBUSTION
CONTROL DEVICESa
Combustion
Emission
Batch
digester
Continuous
Batch
W
I
P
Sources
relief
digester
digester
gas
relief
gas
blow gas
Continuous
digester
blow
Turpentine
decanter
vent
Evaporator
vents
(e.g., noncondensibles,
gas
Lime
kiln
Power
boiler
44
Recovery
furnace
device
Incinerator
Total
26
27
97
63
20
95
68
17
91
47
30
88
49
16
73
68
20
88
hotwells)
5
11
11
Deckers
Knotters
Washer
screens
Washer
filtrate
Washer
hood
Data
taken
tanks
vent
from Reference
2.
TABLE
3-3.
TYPICAL
VENT
CHARACTERISTICS
Capacity rangea
(ADT/day)
Emission point
Batch digester blow gas
Flow rateb
iscmW%
pulp/day)
FOR KRAFT
PULPING
EMISSION
POINTS
Temp.b
(OC)
Moisture
content
(%I
Heat content'=
(Kj/scm)
Enclosure
needed fc$
capture
94-1800
1.3
65-100
30-99
70
No
94-1800
0.026
75-150
35-70
No
94-1800
0.0026
25-60
3-20
18,400
No
94-1800
0.9
20-75
2-10
20
Yes
Washer
65-1625
0.9
20-45
2-10
40
Yes
65-1625
0.18
55-75
15-35
20
No
Decker/screen
65-1625
0.9
20-45
2-10
0.2
Yes
Evaporator/hotwell
65-1625
0.0027
80-145
50-90
21,300
No
Turpentine condenser
94-1800
0.0026
25-60
3-20
18,800
No
l!l
characteristics
and
prior
to routing
point
characteristics
considered
Section
system
that
devices
for pulping
Vent
Gas
must
to alter
control
device.
Typical
the
hoods
employed
and
(i.e.,
safety
Two
methods
are generally
volumetric
an enclosed
rate.
process
the
vent
points
When
washer
device.
in the transport
it reaches
the
and conveyance
or ductwork,
with
system
the prime
equipment
velocity,
type
and will
organic
When
stream.
mover
(if needed),
stream,
and reducing
vent
Hood
hood
depends
gases
or large,
is
of
ambient
flow
device.
such
as a
using
an
to a
is a function
on the creation
to
are examples
hard-piped
efficiency
3-6
point
stream
to a control
and then
the
used
can be hard-piped
may be captured
collection
which
an emission
vent
is diffuse
emissions
affect
the vent
can be hard-piped
streams:
The method
the introduction
and evaporator
point
vent
compound
the vent
a vent,
or well-enclosed
capture
or enclosures.
reducing
an emission
device.
to capture
thereby
that
control
used
and relative
gases
or decker,
enclosure
point
of the vent
Digester
of vent
rate
device,
into
(2) hoods
emission
flow
concentration
air
and
on the
a control
streams
devices.
(1) hard-piping
depends
devices,.vent
before
gas conditioning
fan),
and bleaching
be conditioned
pipe
control
Svstem
to the control
of the capture
or enclosures,
gas to a
streams.
or existing
its characteristics
components
and transport
vent
from pulping
gas may
be
device.
applicable
and Transnort
and transported
the vent
system
vent
emission
should
control
discusses
enclosures
The
gas collection
and bleaching
stand-alone
be captured
needed
table
and convey
3.2.2
HAP emissions
using
Additionally,
are
to capture
Collection
To control
operations
the vent
Section
device.
in this
an appropriate
discusses
is used
points
device.*r3#4
presented
in selecting
3.2.1
which
to a combustion
control
3.2.1
identifies
of an air
of
flow
that
is sufficient
from
the point
to capture
and draw
constant
volumetric
decreases
as the
in flow
enclosure
for pulping
and
used
stainless
vent
when
of the gas
in the pulp
low cost,
Fiberglass
is commonly
and washer
hoods.
The problems
fiberglass
ducting
in the pulp
charge
and
the
used
industry
with
an
by the
Two materials
are
have
the
for venting
bleach
identified
industry
plant
towers
using
its
inability
the buildup
of hydrocarbons
of
resistance.
with
are
fiberglass
advantages
and corrosion
to prevent
absorption
hood
stream.
ducts
light weight,
grounded
A 34-percent
is determined
in the vent
relatively
be electrically
encJosures
capture.
replacinga
used
Fiberglass
steel.
streams.'
material
for ducts
At a
efficiency
vendors,
complete
assumed
of duct
characteristics
commonly
was
with
hood.5
capture
the point
on discussions
reduction
type
hood
between
to achieve
air emitted
flow rate,
distance
can be constructed
The
the air
air
Based
increases.6
the contaminated
to
of static
in its fiberglass
resin.
Stainless
steel
for non-condensible
is the preferred
gas
(NCG) transport
it resists.corrosion
by water
steel
to corrosion
is susceptible
therefore,
not
streams.9
-Ductwork
gas
cooling
freezing
may
that
be insulated
takes
digester
streams
blow
the
control
vent
device.
emission
point,
captured
(such
place
vents,
gases
When
as pulp
to convey
the
vent
desirable
prime
gases.
movers
compounds,
vent
plant
during
industry,
However,
in transport
3-7
is,
gas
of vent
and to prevent
winter.
such
sufficient
the transport
hood
stainless
the amount
in the ducting
the source
washer
Although
bleach
insufficient
or where
systems.8
and
may have
through
of construction
by chlorides
to reduce
in the duct
in the pulp
gas
and sulfur
for conveying
of moisture
Vent
convey
used
material
as those
from
pressure
to
system
pressure
is provided
of emissions
vents),
has
fans must
fans may
systems
to the
by an,
to be
be used
combustible
occur
at any pulp
spark
source
explosive
for explosions
gases
below
their
proof
concentrations
points
In some
lower
such
'(LVHC) streams
the gas
concentration
typical
safety
of the vent
concentration
Steam
systems
ejectors
of sparks
of NCG's
subsequently
potential
with
vented
impact
content
ejectors
are
concentration
or the
control
knockout
gas
the LEL.
lowers
device.
volume
conditioned
the
been
precaution.
in transport
ejectors
and provide
However,
LEL.
the
amount
stream),
LEL,
have
the system
used
may.be
drums,
streams
potential
Steam
and increased
of steam,
Because
which
of the
device,
of vent
is
such
as
streams,
on high-volume,
low-
streams.12
to alter
of the stream
This
on the
on the
on the control
vent
device.
explosive
NCG's.
to the control
(HVLC)
temperature
of the
movers
which
not normally
vent
as prime
from
steam
tank
arrestors
a significant
of this
heat
Vent
steam,
require
vent
be below
as a safety
are preferred
source
would
based
the
depending
design
the
ejectors
steam
the duct
gases,
The
Flame
of turpentine.
into
for handling
however,
storage
greatly
high-concentration
dilution
reduced
varies
allowed
(LEL).lO
25 percent
handling
eliminate
steam
liquor
level. I1
guideline
operation
design
low-volume,.high-concentration
may exceed
streams
incorporated
weak
document
can
to be the
where
designed
limit
in the vent
as with
(e.g.,
systems
can be used;
in this
problems
been.reported
or improper
explosion
of organics
cases,
have
motors
examined
and operating
in transport
maintenance,
to enter
Explosion
from
upsets
and fans
mill,
inadequate
flaws,
gases
Process
gases.
before
it is vented
may be accomplished
or entrainment
the moisture
separators
using
content
to the
condensers,
in the
gas transport
system.
Preheating
stream
may
is controlled
be preheated
enough
of vent
to affect
gases
with
if their
combustion
is only
a combustion
volumetric
performed
when
the
device.
Vent
streams
flow rates
are
in the control
3-8
device.
large
Preheating
is generally
little
only
for
in hardwood
streams
pulping
where
the
LEL.
For this
explosive
incorporated
through
the
discs
explosions.
provide
real-time
observations
Vent
of vent
percent
destroy
may
arresters
of fires
to prevent
venting
also
stream
gases
be used
parameters
of combustible
to
such
compounds
at elevated
dioxide
a wide
fuel
(approximately
gas
has
organic
of vent
First,
if the
100 Btu/scf
stream
compounds
sufficient
oxygen
will
devices
oxidize
have
by at least
a high
enough
ascombustion
content
vent
gas stream
or greater).l6#17
may be used
operate
enough
oxygen
in controlling
has
compound
been
98 percent
the vent
stream
control
devices
to a high
Combustion
stream
are used
devices.
auxiliary
vent
range
These
of sufficient
and water. I4
strategies
combustion
heated
Combustion
of the organic
temperatures.
any VOC
to control
Devices.
structure
in the presence
-documented
Two
that
Devices
Control
the chemical
principle
to carbon
Control
Combustion
temperature
stream
by rapidly
be
in transport
are used
equipment
the
LEL).
by oxidation
under
system
Monitoring
and volume
3.2.2.1
the
transport
Applicable
on the
found
Rupture
during
devices
typically
must
Flame
system.
system.
gas
below
devices
the propagation
to the
3.2.2
are components
processes,
potentially
prevent
damage
(percent
contain
safety
streams
assumed.
arresters
duct
as temperature
that
is
vent
pulping
was
with
be more
is sufficiently
discs
Flame
systems.
softwood
concentrations,
into
rupture
streams
of explosion
and washer
no preheating
vent
compound
and
or streams
therefore
as knotter
concentration
analysis,
ducting
would
processes
turpentine
When
such
streams
the risk
Preheating
low.13
applicable
on HVLC
where
or no turpentine,
sufficiently
and
practiced
gases
with
may
be used
heat
content
as
Secondly,
air
if the
(approximately
20 percent).
Because
combustion
the
control
basic
operating
devices
principle
is similar,
3-9
the
of the various
factors
that
affect
their
destruction
efficiency
are also
destruction
efficiency
temperature
of the combustion
time
of these
of the pollutant
mixing
in the
the hot
times
gases
for
chamber
achieving
range
from
of the combustion
amount
content
the moisture
0.25
and the
content
oxygen, and
residence
98 percent
to 1.5 seconds.18
chamber
of the fuel
of the
the residence
chamber,
at least
The temperature
air,
(or zone),
of the pollutant,
Typical
by combustion.14
efficiencies
and heat
is a function
chamber
generated
incinerators
destruction
devices
in the combustion
combustion
The
similar.
depends
burned,
of the stream,
on the
the percent
and the
excess
amount
of
oxygen.
Applicable
include
lime
combustion
kilns,
incinerators,
and
power
devices
98 percent
or greater.
lime
integral
routed
to these
operation
because
these
and
of process
devices
will
correspond
with
emissions.
For
b-3.
average
unscheduled
combustion
were
element
mud
of the
(calcium
temperatures
after
combustion
kiln.
causticizing
encountered
The
1 and
in the
3-10
may
also
the
processes
furnace
data
goes
show
5 percent
down
an
for pulp
these
is an essential
is used
calcium
lime kiln
gases.
per year.
lime kiln
to produce
time,
generate
purposes,
350 days
and
this
vent
Available
as
down
service
its recovery
cycle,
such
During
pulping
be
the normal
shut
that
of
are
may
devices
device
For costing
to operate
carbonate)
with
to control
between
of these
streams
interfering
reserve.
devices.19
Lime
vent
may halt
thermal
furnace
are occasionally
a mill
section
efficiencies
of the processes
downtime
each
and recovery
in combustion
liquor
assumed
3.2.2.1.1
operated,
or maintenance.
shortly
of limited
furnaces,
not be available
example,
f digestion)
devices
upsets
suspension
because
mill
Mill
boilers
interruptions
-However,
recovery
However,
without
process.
power
in this
destruction
boiler,
processes.
of the
lime kilns
power
devices
discussed
Properly
can achieve
kiln,
to mill
boilers,
flares.
combustion
The
devices
to calcine
oxide.
lime
The high
(950 to 1,250oC)
make
it very
efficient
efficiencies
The
reported
lime
as a control
kiln
device
digester
NCG's,
and evaporator
are generally
been
used
vent
these
vent
practiced
to the
applicable
points
HAP-laden
drum)
kiln.
pulp
to the
liquid
(i.e.,
and
entrainment
a potential
the kiln
exhaust
HVLC
processes
(e.g.,
pulp
depending
on the
volumes
of the
if high
vent
is
of explosions
too
lime kiln
may
from
flow
large
rate
to vent
be less
streams.
from venting
condenser,
in sulfur
washers)
levels
gases
HAP
of the
equipment
or knock-out
oxides
compounds
streams
streams
content.
condensate
these
heat
the LEL
system
gas streams
The volumetric
vent
increase
The
LVHC
fuel because
separator,
streams.
as digester
vent
resulting
from
industry
These
is usually
the
pulp
such
of the risk
lime kiln
stream
in the
sufficient
washers
impacts
98 percent.
recovery
stream.13
Therefore,
cross-media
emission
used
in the vent
control
turpentine
exceed
because
with
points
Preheating
for controlling
The
may
present.
by typical
lime
gases.
streams
generally
generated
gases,
to contain
are
turpentine
emission
as supplementary
of turpentine
not
than
demonstrated
blow
demonstrated
However,
the
been
for LVHC
gases,
VOC,
to.,be greater
has
relief
have
in destroying
emissions
in the pulping
may be recycled
back
or sent to wastewater
and characteristics
from
vent
to mill
treatment
of the wastewater
generated.
3.2.2.1.2
coal,
natural
Power
gas,
boiler.
oil,
wood
Power
waste,
boilers,
are designed
to produce
for mill
operations.
Power
than
or equal
temperatures
excellent
(generally
control
destruction
Power
Btu/hr
greater
devices,
than
providing
which
or combination
heat,
boilers
to 150 million
boilers,
steam,
with
fuel-fired
and electricity'
capacities
operate
include
greater
at high -
l,OOOC)
at least
98 percent
as
of VOC.*O
boilers
have
as a control
device
be preferred
over
been
demonstrated
for pulping
the
lime kiln
vent
emission
for burning
3-11
in the pulp
points,
vent
gases
industry
and may
because
they
have
than
the
less
lime
downtime
kiln.*l
The vent
is generally
the
combustion
air needed
may
also
as auxiliary
vented
to the power
relief
LEL,
the
high
and blow
power
gases
at the
would
be below
fuel
credit
moisture
when
and
Power
these
scrubbed
to remove
power
have
boiler
in an accelerated
Information
techniques
existing
to the
kilns
power
recover
stream
may
prior
streams
would
be
to
However,
boilers
to the
the
likely
result
from
is not available.
gas streams
are discussed
identical
first
to an
in Chapter
venting
to those
HAP
The
5.0.
emission
discussed
points
for lime
3.2.2.1.1.
Recovery
of the kraft
the
are
the
of gas conditioning
to power
resulting
with
the
of the boiler.
for venting
device
boiler
3.2.2.1.3
ducted
considered
devices.23
chlorinated
streams
in the
to control
evaluated.
the use
and basis
impacts
in Section
heart
detailing
combustion
cross-media
rate
The
value.
combustion
associated
vent
streams,
the stream's
of the halogens
fully
of to
and TRS,
were
applied
the
instead
fuel
a halogenated
corrosion
for vents
assumptions
gases
plant
may approach
of heating
of venting
not been
as digester
temperatures,
the majority
impacts
streams
of the organics
to.existing
vent
of bleach
introduction
The
streams
such
However,
methanol
some
of combustion
However,
process.
The
have
streams
system,
in the HVLC
bleaching
combustion.
contain
still
po-ints
recovery
fuel penalty
halogenated
such
pulping,
concentrations
as the
gases.
or all of
the stream
and HVLC
turpentine
vent
streams
the heat
boilers
unscrubbed
vented
air to combustion
venting
LVHC
softwood
from
although
of turpentine,
Other
reported
as well
stream,
hood
from
often
boiler.
which
washer
levels
gas volumes
as part
The emission
gases,
and pulp
contain
fue1.22
and blow
evaporator,
used
boiler,
are both
relief
that
by the
boiler
as digester
vent
..
gas stream
serve
larger
furnace.
liquor
chemicals
used
recovery
The recovery
furnace
is the
process,
is used
to
in cooking
and
liquor.
Furnaces
3-12
generally
least
as excellent
serve
a 98 percent
operating
destruction
temperatures
The
recovery
as a control
However,
this
device
combustion
of the
of explosions.
because
water
gases
furnace. l5
furnace
The
would
controlled
vent
in the
Recovery
halogenated
the majority
of venting
The
points
of lime
on the
dioxide
and water
or burners
Although
example
then
sized
temperature
for
by the
the
recovery
and
LEL to those
receive
with
stream
first
may
prior
streams
impacts
are many
the unscrubbed
the bleaching
process.
be scrubbed
to remove
The
to combustion.
to the recovery
resulting
furnace
impacts
have
that
are
similar
to those
3.2.2.1.1.
Thermal
to a high
amount
chamber
combustion
oxidation
to reach
3-13
vent
streams.
stream,
and a
chamber
cornbusting
at the
completion
an
A discrete
chamber.
time
a burner
designs,
3-l.
of hot
in
A thermal
containing
in a premixing
The mixture
to carbon
temperature
incinerator
enough
oxidize
of oxygen.24
in Figure
the mixture
incinerators
enough
VOC-containing
are arranged
the main
HAP
different
mixing.
venting
furnace
incinerator.
an inlet
from
in Section
is shown
inlet
into
to allow
in the
associated
to oxidize
burner,
air
smelt
characteristics
is a refractory-lined
thorough
passes
with
controlled
if heated
incinerator
combustion
controlled
boiler.
principle
used
dual-fuel
gases
for
because
bedin
of a sufficient
there
of turpentine
the
Thermal
operate
incinerator
not preferred
violently
to the recovery
3.2.2.1.4
the presence
levels
points.
moisture
as discussed
kilns,
emission
is generally
vent
in the pulp
evaluated.
cross-media
emission
demonstrated
do not currently
gases
1,000C).15
to remove
of the halogens
fully
exceeding
be conditioned
power
chlorinated
not been
high
The
similar
furnaces
vent
of their
high
streams
a halogenated
However,
ensure
react
have
of VOC because
for HVLC
with
should
may
at
device
vent
furnace
providing
has been
controlling
recovery
devices,
(generally
furnace
industry
risk
control
This
to
gases
chamber
is
elevated
(residence
times
Vent Strwn
Inlet
(21
c
AUXilllsn/
Bumm
TY-)
O@iond Hut
~
/ GL--J
Air
Inlet
(31
(4)
Figure 3-1.
(8;
Combudon
Chmbw
(5)
3-14
that
properly
98 percent
Performance
are common)..
operated
or greater
thermal
destruction
tests
have
incinerators
can
efficiency
for most
in the pulp
industry
voc;15
Incinerators
have
as an applicable
and
emissions,
vent
streams.
that
can
been
control
can
streams
standard
cubic
cubic
feet
minute).
with
a heat
for reducing
with
meters
content
streams
from
burning
supplemental
per minute
However,
the pulp
fuel
rates
gaseous
both
thermal
flow
less than
as vent
to control
single-unit
1,400
per
device
be designed
Package
control
demonstrated
LVHC
and HVLC
incinerators
in the
range
of 14 to
(500 to 50,000
combustion
washers,
stream
100 Btu/scf,
usually
to maintain
standard
of a vent
approximately
exist
such.
requires
the desired
combustion
temperature.4rl5
Incinerators
absorbers
can be used
to reduce
However,
thermal
temperatures
to oxidize
in order
through
absorption
scrubber.25
application
It has
the
the vent
flame
due
gas
entrainment
prior
is practiced
auxiliary
survey
33 percent
with
can
fuel
use
whether
heat
operation
that
that
to remove
also'reported
preheating
none
recovery
with
of the
heat
because
explosions.26
3-15
some
responded
Loss
to
from
of
in the
of the vent
recovery
facilities
and
moisture
Although
be designed
costs,
was
routed
tower
to an incinerator.26
moisture
are
and then
survey
of the mills
separators
to venting
It is not known
incinerators
the
in a literature
higher
compounds.
incinerator
the
been
to excessive
survey. *'
discusses
vents.
requires
as a packed
equipment.
reported
VOC
temperature
such
3.2i3.2.3
the
gas
plant
organic
of absorption
use
gas
their
equipment,
(approximately
survey)
from
with
bleach
of halogenated
streams
to lower
Section
from
the halogenated
exhaust
quenched
mills
HAP emissions
oxidation
The halogenated
in conjunction
to reduce
that
of the risk
responded
of _
to
Cross-media
points
impacts
resulting.from
to an incinerator
from
the gas-conditioning
from
the
vent
nitrogen
carbon
associated
with
condensate
streams
streams
may
the
or sent
volumes
generated.
gases
from
equipment
incinerator
has not been
disposed
and
of,
back
fully
gases
caustic
is typically
sent
moisture
oxides
The
emissions
impact
of
These
processes
(e.g., pulp
depending
is used
brine
generated
hydrocarbons,
evaluated.
scrubber
with
stream
to remove
treatment,
exhaust,
emission
unburned
to mill
If a gas
incinerator
acid
used
exhaust.
to wastewater
neutralizing
liquid
and sulfur
monoxide,
be recycled
washers)
the
and potentially
stream,
oxide,
involve
venting
on
the
to remove
solution,
formed
solution,
must
acid
when
be
to the wastewater
treatment
system.
3.2.2.1.5
which
the
ambient
flares
Flare.
oxygen
air
have
Flares
necessary
shown
of 98 percent
of accepting
fluctuations
and
are
rate
applicable
vent
content
reason,
facilities
devices
such
Gas
sulfur
control
chorine,
plant
absorbers.
dioxide
from
sulfite
hydrochloric
acid,
vent
streams.
Polar
are
also
removed.
This
scrubbers
part
In the
gas mixture
pollutant
and
flow rate
and variable
for proper
as backup
to primary
Gas absorbers
plant
integral
are capable
sufficient
stream
industry
operated,
flow
heat
operation.
systems
at a
combustion
as lime kilns.
recover
methanol
batch,
in the pulp
3.2.2.2
bleach
flares
Flares
However,
in the vent
by the
Properly
in VOC concentration
applications.
in
destruction
or greater.28
for continuous,
is necessary
For this
few
stream
VOC/HAP
devices
is provided
of the flame.
to have
efficiencies
combustion
for combustion
in the proximity
been
are open
because
of the
chemical
absorption
are
sulfite
diffuses
from
pulping
and chlorine
organic
section
pulping
recovery
process,
dissolved
mill
vent
and to
dioxide
such
discusses
scrubbers
in
as
bleach
are an
process.
soluble
into the
3-16
to
vents
compounds
only
components
in the scrubbing
the gas
are used
medium.
caustic
of a waste
The
solution
when
the
liquid
contains
the gaseous
less than
the equilibrium
The difference
component.
concentration
driving
for absorption.2g
force
Figure
tower
3-2 presents
using
compounds
passes
tower,
tower
near
the
to increase
'absorbing
solute
from
mill
the
recovery
from
from
bleach
caustic
caustic
solution.
chilled
water.30
Removal
of the
efficiencies
caustic
as high
chloride
and
Removal
99 percent.
approach
have
thus
lowering
air
the
control
Using
modeling
used
in
and
chemical
(a byproduct
sulfur
vary
fresh
dioxide
based
and
on
and.the
Chlorine
removal
documented
to form
with
sodium
hypochloride.
polar
example,
removal,
compounds
as methanol
the waste
efficiencies
0 to
as chloroform
removal.31
may
treatment
of the
from
as methanol
such
0 percent)
such
range
such
and compounds
from
overall
compounds
compounds
(approximately
atmosphere
the
the
or from
been
reacts
the top
filtrates
solution,
have
For
absorbed
into
chlorine
from
bisulfite
absorbed.
for other
99 percent
back
being
helps
and the
caustic
stage
include
of absorbing
the
tower
solution
absorbers
efficiencies
insignificant
However,
for gas
The
sodium
used
of the
absorbing
operations),
as 99 percent
solution.30
exits
from the
sodium
media
compound
and
flows
absorbing
wash
manufacturing
the type
solution
extraction
liquor,
Other
bottom
is typically
weak
efficiencies
design,
solubility
plant
white
chemical
The
scrubbers
sewer),
process,
some
column
plant
the
to the vapors,
gas phase. 2g
the
containing
soluble.compounds
The absorbing
the
absorption
in the absorber
the
countercurrent
bleach
originates
(i.e.,
between
near
of
actual
provides
stream
material,
The packing
solution.
column,
is introduced
the packing
top.
contact
of the
pulp
through
the
of a packed
The vent
flow.
to be absorbed
between
concentration
a schematic
countercurrent
concentration
volatilize
process,
scrubber
as an
device.
an Advanced
approach,
System
for Process
the scrubber
removal
3-17
Engineering
efficiencies
(ASPEN)
for
(5) ah
Or out
toFldcontrol~
or to Atmosphere
poo&hrJ suppolt
-I-
1
(4)
Absorbing Uquid
with VOC out to Dispowl
or VOCEohmt
Racovcwy
Figure 3-2.
3-18
(1)voc&@
specific
compounds
scrubber
effluent
to approximate
the modeled
were
estimated.31
The emissions
(due to volatilization)
a net emission
scrubber
were
reduction.3l
removal
from
then
Table
efficiencies
the
estimated
3-4 presents
and net
emission
reductions.
The
cross-media
absorbers
with
plant
into
as the
in the
be removed
streams
from
VOC,
HAP
from
gas
condensation
pressure
approximately
are currently
used
to condition
.Organics,
such
digester
blow
of condensers
some
control
streams
The
gases
resulting
wastewater
they
are sent
(e.g.,
pulp
treatment,
vent
to create
(e.g.,
the partial
to its vapor
limited
in the pulp
industry
to
moisture.
be recovered
The
removal
as high
from
efficiency
as 90 percent
in
be ,used as supplemental
content
compounds
from
to the primary
and
remove
LVHC
and HVLC
control
may
be recycled
washers),
steam
stripped,
depending
on the volumes
3-19
air),
unit.32
moisture
streams
when
system
for a single
also
may also
organic
condensate
enough
are typically
condensers.
to lower
In this
from
by removing
can
HAP's
condensation.
explosive
before
processes
using
Condensers
techniques
potentially
gases
as turpentine,
varies,
cases.33
vent
effluent
and volatile
is equal
scfm)
fresh
process.
(saturation)
compound
This
use
scrubber
is non-condensible
(2,000
primarily
the bleach
In a two-component
phase.
flow capacities
57 scmm
with
are separated
at dew point
volatile
Condensers
using
of a brine
facilities
VOC,
Condenser
pressure.
streams
components
gas
operations,
and moisture
occurs
of the
Some
Moisture,
to liquid
one of the
sewered
of the bleaching
vent
using
treatment
4.0.
medium
stage
by lowering
change
where
in Chapter
Condensers.
3.2.2.3
technique,
is typically
scrubbing
extraction
with
is the production
the wastewater
is discussed
caustic
associated
solution
solution
effluent
impact
can
a caustic
This
solution.
impact
device.
back
to mill
or sent
generated.
to
TABLE
3-4.
SCRUBBER
REDUCTION
ESTIMATES
Estimated
Scrubber
Removal
(%)b
Estimated
Reduction
(%)c
Chlorine
99
99
Hioh Solubilitv
Methanol
Acetone
Formaldehyde
2,4,5-Trichlorophenol
Pentachlorophenol
Chlorophenolics
Hydrochloric
Acid
Chlorine
Dioxide
99
75
Medium Solubilitv
Methyl Ethyl'Ketone
Acrolein
Acetaldehyde
Propionaldehyde
Dichloroacetaldehyde
60
35
Low Solubilitv
Chloroform
Carbon Tetrachloride
Methylene
Chloride
Toluene
l,l,l-Trichloroethane
Alpha-Pinene
Beta-Pinene
Chloromethane
p-Cymene
M-w
70
Compound
Classificationa
Average
a
High-solubility
Compounds
are classified
by solubility.
compounds
have solubilities
greater than. or equal to
methanol;
low-solubility
compounds
have solubilities
less
than or equal to chloroform;
medium-solubility
compounds
were between methanol and chloroform.
The volatility
of the speciated
compounds
was evaluated
and
a fraction
emitted was estimated
based on the mass removed
in the scrubber
effluent.
3-20
3.2.2.4
used
in the
pulp
HVLC
vent
APPLICABLE
3.3
generated.
of the
some
streams
from
describes
the
wastewater
to
collection
and
air
to the atmosphere
and
air.34
used
to reduce
HAP
Section
to reduce
system.
Sections
with
Many
ambient
used
strippers
units.
of
to the
devices
points.
are
a series
to treatment
to be emitted
wastewater
compounds
through
are open
control
EMISSION
recovery
HAP
passes
sent
units
techniques
steam
can be -used
and chemical
containing
being
HAP's
discusses
emissions
carbon
FOR WASTEWATER
wastewater
system
of the
section
discuss
bleaching,
before
collection
allow
This
pulping,
units
incineration,
OL TECHNIQUES
Generally,
collection
regenerative
CONT
wastewater
processes,
with
streams.
POINTS
In wood
adsorbers
although
industry,
in conjunction
adsorbers,
control
Carbon
Adsorbers.
3.3.1
HAP
emissions
3.3.2
vent
briefly
from
the
and 3.3.3
control,
respectively.
3.3.1
Wastewater
To reduce
wastewater
system
Collection
HAP
points
that
emissions
strippers)
reduce
amount
using
and
covers
treatment
emissions
3.3.2
Steam
pulping
basic
contact
seals
with
in such
can
a way
as to
be accomplished
on collection
the wastewater
by
system
point
provides
Vent
to the
the best
control
Control
Steam
principle
with
used
in condensate
of wastewater
for vaporization
operations
the HAP-containing
This
are currently
loading
processes.
of steam
the collection
to treatment
between
device
and bleaching
from wastewater.
strippers
operating
2.0,
be designed
air.
or control
Strinoer
compound
distillation
ambient
Hard-piping
of HAP
sulfur
of contact
the
system
Steam
should
and water
components.35
in Chapter
the wastewaters
(including
wastewater
described
conveys
the
System
stripping
wastewater.
of the more
organic
stripping
This
volatile
3-21
streams
involves
to remove
of steam
to reduce
generated
the
and
by the
fractional
compounds.
The
is the direct
contact
organic
organic
provides
compounds.37
heat
the steam
At a pulp
mill,
or it can
be integrated
In the
containing
Heat
column.
injection
packing
steam
the vapor
and water
The vapor
as reflux.
combustion
stripper
reused
that
cools
feed
stream.
in the
process
wastewater
treatment
evaporator
overhead
to the
next
direct
the
sent
the
stripper
Steam
the
been
The
steam
the
greatest
compounds
the
is either
or discharged
to
tank
from
the reflux
case,
into
tank
the
is routed
incorporated
effect
and HAP
emission
to
thesteam
are typically
reductions
characteristics,
as the collection
efficiencies
reported
ranging
in the
design
and
as the
(For a given
3-22
and operation
from
operating
of
systems.
75 to
parameters
performance
(or height
In general,
number
as organic
literature.40
of trays
(SFR).
are highly
and treatment
number
ratio
such
on the removal
packing) increases.
steam,
is also
effect
increases
In this
3-3.
with
device.
stripper
are the
steam-to-feed
efficiency
gases
removal
have
a heat
and preheats
is predominantly
composition,
as well
stripper
99 percent
have
VOC
and
in Figure
which
on wastewater
concentration
in an
3.2.2.39
can be integrated
to a combustion
dependent
through
water)
stripper
A reflux
vent
Achievable
in Section
wastewater
as wash
as shown
effects.
The
incinerated
wastewater
stripped
(i.e.,
stream,
bottoms
stripper.
The
to the-stripper
is then
is passed
the treated
a steam
set,
vapor
stream
stream
operations.
Alternatively,
the
stream
or
partially
back
as described
device,
wastewater
routed
trays
liquid
vapor
is typically
the condensate
with
and
the overhead
industry,
by direct
of the column.38
between
with
exchanger
column
contact
condensed,
treated
to the stripping
wastewater
stripping
are equipped
organics
The
to the
columns
containing
on-site
process,
is pumped
system
effects.
stripping
In the pulp
column
stripping
to provide
phases.
steam
is provided
can be a stand-alone
the evaporator
compounds
of steam
Generally,
into
stand-alone
organic
stripper
of trays
stripper
of organic
of packing)
the
that
and
removal
(height
system,
of
there
will
4
Vent to
Evaporator
Vent to
Control Drvicr
Effect N+ 1 ,
4-
- -
- I
I
I
I
I
I
I
I
8
6
I
Reflux Stream
.
To Wastswater
Treatment or
2.J
W
Reused Wkhin
the Process
Stream From
Evaporator
Effect N + 1
Stripper Feed
Stream
Feed/Bottomr
Heat Exchanger
Reflux Tank
- -
I
1
Vapor Stream
Figure 3-3.
.
.
Steam
d; uP$J
P
be a maximum
additional
An
number
of trays
removal
will
increase
stripping
will
flow through
of organics
increase
heat
is provided
additional
water
is also
volatilized.
is also
normally
rate
beyond
the column.
additional
in the steam
height)
which
no
be achieved.)
the vapor-to-liquid
the
(packing
flowing
when
the ratio
This
phase.
the steam
of
increases
Because
rate
is increased,
Therefore,
an increase
by an increase
accompanied
in the overhead
stream.41
on responses to an industry
Based
used
for controlling
pulping
used
compound
removed
HAP
These
removals
Fr's
the
streams
The Kremser
a relationship
wastewater
wastewater.
to generate
survey,
between
Henry's
average
is
equation
the
Law
was
fraction
constant
are summarized
SFR
of
at an
in Table
range
3-5.
from
90
to 99 percent.42
Steam
strippers
to reduce
TRS
and chemical
Typically,
from
and
the blow
evaporators.
stripped
used
turpentine
Liquid
streams
involve
wastewater
impacts
of nitrogen,
be emitted
being
associated
Criteria
the
fossil
vent
fuel burning
generated
from
feed
and must
analysis,
no auxiliary
stripper
this
overheads
stream
offsets
vent
the fuel
because
required
temperature.23
3-24
be
use of steam
and stripped
sulfur
required
dioxide,
will
to
Sludges _.may be
be disposed.
For this
is necessary
stream
may also
and particulates)
the stripper.
fuel
the
(i.e.,
to operate
tanks
and the
gases
stream
streams
sewered.
with
pollutants
carbon monoxide
from
process
any gas-conditioning
the organic-laden
stream.
system,
from vent
before
industry
or condensates.
to condensate
recovery
from
pulp
in pulping
wastewater
moisture
organics
in the
loading
is applied
tank,
cross-media
strippers
also
evaporator
to remove
used
compound
stripping
to remove
The
oxides
organic
recovery
steam
equipment
are currently
for burning
the heat
to bring
the steam
content
of.
to combustion
TABLE
3-5.
HAP
STEAM
STRIPPER.REMOVAL
EFFICIENCIES
Removal
Compound
Efficiencya
Acetaldehyde
99
Acrolein
99
2-Butanone
99
(MEK)
Formaldehyde
99
Methanol
90
Propionaldehyde
99
Total
Reduced
Sulfur
94b
(TRS)
Removal
efficiency
is based on a steam-to-feed
1.5 pounds of steam per gallon of wastewater.
(Reference
42)
Removal
efficiency
for TRS is based on the average removal
efficiencies
for hydrogen
sulfide, dimethyl disulfide,
dimethyl
sulfide, and methyl mercaptan.
3-25
ratio
of
Air
3.3.3
Strioner
Another
wastewater
stripping
volumes
control
is air
of air
rate
phase.43
The
combustion
for reducing
stripping.
through
overhead
The underlying
equilibrium.
the contaminated
resulting
of the organic
vent
HAP
emissions
principle
stream
for air
By forcing
large
water,
air-water
the
in an increase
compounds
from
into
is then
in the
the vapor
sent
to a
device.
Although
recovery
Control
technique
is increased,
transfer
in the
Vent
is vapor-liquid
interface
industry
with
air
strippers
to reduce
condensate
TRS
be effectively
emissions,
streams
operations,
have
from
been
the organic
the blow'tank,
and evaporators
controlled
employed
in the pulp
concentrations
turpentine
are generally
too high
by an air stripper.
3-26
'I
to
3.4
REFERENCES
1.
Summary of Technologies
for the Control and Reduction
of
Chlorinated
Organics from the Bleach Chemical Pulping
Subcategories
of the Pulp and Paper Industry.
Protection
Agency, Office of Water
u* s. Environmental
April 27,
Washington,
D.C.
Regulations
and Standards.
1990.
pp. 20, 22, 25 through 27, 43, 54, and 63.
2.
Responses
to Industry Survey discussed
in the following
National Council of the Paper
J.E. Pinkerton,
letter:
Industry
for Air and Stream Improvement,
Incorporated
EPA: 15B, and P. Lassiter,
EPA:
(NCASI), to J. Telander,
(Responses were claimed
February
11, 1992.
CPB.
confidential
business information).
3.
Environmental
Pollution
Control,
U.S. Environmental
Part 1, Air.
Publication
Technology
Transfer.
October
1976. p. l-4.
4.
Memorandum
from Greene, D.B., Radian Corporation,
Heat Release Factors.
Shedd, S.A., EPA/CPB.
September
30, 1993.
5.
Industrial
Committee
on Industrial
Ventilation.
Ann Arbor, Michigan,
Ventilation.
19th Edition.
p. 4-l.
1986.
Brothers
Incorporated.
Air Pollution
Alley.
Boston, PWS Engineering.
to
Edwards
Control:
1986.
6.
7.
-
Memorandum
from Greene,
and Paper NESHAP File.
costs.
July 21, 1993.
8.
Collection
and Burning of Kraft Non-Condensible
Gases Current Practices,
Operating
Experience,
and Important
Technical
Bulletin
Aspects
of Design and Operation.
No. 469.
New York, National
Council of the Paper
August 29,
Industry
for Air and Stream Improvement,
Inc.
1985.
p. 40.
9.
An Investigation
of Corrosion
in Particulate
Control
Equipment.
U. S. Environmental
Protection
Agency, Office
Publication
Washington,
DC.
of General Enforcement.
February
1981.. p. 38.
No. EPA-340/l-81-002.
10.
Ref.
F.C.
8, p. 41.
3-27
11.
Fourth Edition.
OAQPS Control Cost Manual.
Protection
Agency, Office of Air
u. s. Environmental
Quality Planning and Standards.
Research Triangle Park,
January 1990.
Publication
No. EPA 450/3-90-006.
NC.
3-26.
P*
12.
Ref.
8, p. 42.
13.
Ref.
8, p. 51.
14.
Hazardous
Air Pollutant
Emissions
from Process Units in
the Synthetic
Organic Chemical Manufacturing
Industry-Background
Information
for Proposed Standard.
Volume lB,
Control Technologies.
U. S. Environmental
Protection
Office of Air Quality Planning and Standards.
Agency,
Research
Triangle Park, NC.
EPA-453/D-92-Ol.66.
November
1992.
pp. 2-8 and 2-9.
15.
Memorandum
from Farmer, Jack R., EPA/CPB to Ajax,
Thermal Incinerators
and Flares.
al., EPA/CPB.
August 22, 1980.
16.
Ref.
17.
Memorandum
from Pandullo, R.F., Radian Corporation,
to
Barbour,
W., Radian Corporation,
Evans, L., U.S. EPA, et
al.
Summary of April 11 Meeting to Discuss Thermal
Incinerator
Cost Issues.
April 27, 1990.
18.
Ref.
19.
Telecon.
Bagley, C.J., Radian Corporation,
J
Hartford
Steam Boiler, July 19, 1993.
P¢
Downtime.
20.
Ref.
14, p. 2-18.
21.
Ref.
8, p. 56.
22.
Memorandum
from Seaman, J.C., Radian Corporation,
to
Project
File.
Control of Pulping Vent Streams in an
Existing
Combustion
Device.
September
29, 1993.
23.
Memorandum
from Greene, D.B.,
Project
File.
Fuel Penalty.
24.
Ref.
14, p. 2-7.
25.
Ref.
14, p. 2-10.
26.
Ref.
8, p. 59.
27.
Ref.
8, p. 60.
28.
Ref.
14, p. 2-6.
B., et
8, p. 50
14, pp.
3-28
with Halt,
Discussion
of
Radian Corporation,
October 8, 1993.
to
29.
30.
Ref.
14, PP*
2-48
and 2-49.
31.
Memorandum
from Olsen, T.R., Radian Corporation,
Model Scrubber Removal
Shedd, S.A., EPA/CPB.
September
17, 1993.
Efficiencies.
to
32.
Ref.
33.
Control Technologies
Air and
Handbook.
Office of Research
Protection
Agency,
EPA/625/6-86/014.
34.
Industrial
Wastewater
Volatile Organic Compound
Information
for BACT/LAER
Emissions --Background
U. S. Environmental
Protection
Agency,
Determinations.
Research Triangle
Park, NC.
Control Technology
Center.
January
1990.
p. 3-2
Publication
No. EPA-450/3-90-0.04.
and 3-3.
35.
Ref.
34, p. 4-20.
36.
Ref.
34, p. 4-22.
37.
Ref.
34, p. 4-3.
38.
Ref.
34, p. 4-4.
39.
Ref.
8, p.'30.
40.
Ref.
34, p. 4-14.
41.
Ref.
34;p.
42.
Memorandum
from Fortier, G.E., Radian Corporation,
to
Design Steam-to-Feed
Pulp and Paper NESHAP Project File.
Ration of a Steam Stripper in Pulp Mills and Development
September
3, 1993.
of Fraction
Removed Values.
43.
Ref.
14, p. 2-33.
for Hazardous
Air Pollutants
Energy Engineering
Research
Laboratory
U. S. Environmental
and Development.
Research Triangle Park, NC.
September
1986.
p. 27.
4-13.
34, p. 4-18.
3-29
4.0
This
chapter
developed
pulp
MODEL
the
industry,
and the
controls
and that
options
are
techniques
likely
the
currently
Section
impacts
to estimate
national
emissions.
MODEL
This
model
environmental
in Section
PROCESS
models
were
of control
emission
in estimating
2.0).
washing
processes,
evaporation
applicable).
bleaching
The
and
the units
The
emission
for an example
4.3,
developed
were
control
mill
are
respectively.
as chemical
models
used
document
represents
delignification
area
processes
represents
to analyze
4-l
the
impacts
the
were
divided
in
the pulping
recovery
has commented
and
analysis,
(as discussed
as well
Industry
of the
of
of how these
emissions
of this
areas
bleaching
of the development
national
area
process.
and bleaching
air,
and how
pulping
oxygen
The
include
description
the scope
bleaching
Chapter
the MACT.
units
within
and
exist
Control
future.
process
a discussion
and a brief
options.
pulping
that
control
options
units
points
impacts
presents
used
are
UNITS
section
process
units
in analyzing
the model
operations
presented
these
impacts.
bleaching
and
in the
evaluated
and
options
process
emission
for these
4.1 describes
for pulping
4.1
being
were
of processes
to be constructed
set of demonstrated
that
were
on the
of applying
Model
of the types
that
impacts
options
impacts
PND
units
and cost
facility.
water,
process
control
environmental
environmental
used
emission
descriptions
are
the model
environmental
to an example
parametric
into
defines
to analyze
selected,
The
and
through
(where
the chemical.
that
the pulping
environmental
and
cost
impacts
within
test
the pulp
program
manner
the
do not
final
model
all data
development
for review
bleaching
Section
model
4.1.3
briefly
4.1.2.
assignment
of pulping
and bleaching
pulp
within
industry
.emissions
4.1.1
and
control
Puloina
air emission
parameters
Table
4-l
nature
potentially
digestion
the
control
Eighteen
vent
model
total
uncontrolled
HAP
of individual
(TRS)
other
HAP
organic
emission
emission
(e.g.,
Appendix
flow
C.
were
(e.g.,
and,
B and
emissions.
an effect
on
pulping
affect
the
therefore,
(e.g.,
washer
and
therefore,
developed
Table
type,
flow rate
affect
and
of
the
were
emission
(VOC),
and total
are presented
18 model
process
stream
and concentration)
4-2,
The
reduced
units.
sum
process
HAP,
in Appendix
unit
from the
for both
Speciated
the
model
factors.
developed
factors
points.
in Table
each
H.AP emission
and wastewater
shown
to characterize
4-2 describes
factors
emission
for these
stream
As
HAP
have
the concentration
compound
compounds
rate
to
to determine
capacity)
parameters
used
in Appendices
that
formed
and,
were
affect
production
uncontrolled
factors
point
vent
units
emission
and wastewater
volatile
national
data
parameters
streams
area. I,2
process
to
streams.
and presents
vent
Other
affect
point
units
evaluated
process
of the HAP
process)
of these
pulping
of these
emitted.
emission
were
parameters
and pulp
and quantity
process
as presented
data
seven
Some
type,
the
model
and sourcetest
These
identifies
wood
process,
is discussed
Units
of the pulping
emissions.
and
discusses
for estimating
factors,
2.0.
which
HAP
Process
literature
C and Chapter
units
pulping
impacts.
Model
Existing
develop
the
into
of the
4.1.1,
process
in a timely
incorporation
in Section
in Section
mills
and
conducting
Development
is discussed
of the
to the EPA
alternatives.
units
process
of emissions
is currently
provided
be considered
regulatory
the variability
Industry
industry.
and
will
represent
total
sulfur
for each
In addition,
characteristics
are presented
the total
in
uncontrolled
HAP
4-2
TABLE
Process
Chemical
Wood
process
Coproduct
Capacity
process
Kraft/soda
Sulfite
Semichemical
Batch
Continuous
Vacuum drum
Improved washinga
type
Additional
parameters
Softwood
Hardwood
type
Washer
Process
characteristics
pulping
Digestion
4-l.
delignification
recovery
Oxygen
delignification
Turpentine
Tall oil
Pulp
production
Horizontal
belt, diffusion,
and baffle
affected
emissions
in a similar manner
versus open or hooded).
4-3
washer
(i.e.,
capacity
systems
enclosed
TABLE 4-2.
Model
process
unit
Pulping
type
Digestion
type
Wood
type
Chemical
recovery
Washer
type
P-l
Kraft
Batch
Hard
Kraft
P-2
Kraft
Batch
Soft
P-3
Kraft
Continuous
P&4
Kraft
P-5
Oxygen
delignification
(Yes or No)
Uncontrolled
HAP emission
factora
Rotary
drum
No
5.02
Kraft
Rotary
drum
No
1.99
Hard
Kraft
Improved
washing
No
4.90
Continuous
Hard
Kraft
Rotary
drum
No
5.05
Kraft
Continuous
Soft
Kraft
Improved
washing
No
1.94
P-6
Kraft
Continuous
Soft
Kraft
Rotary
drum
No
2.26
P-7
Sulfite
NDb
Soft
Sulfite
Rotary
drum
No
1.51
P-8
Sulfite
NDb
Hard
Sulfite
Rotary
drum
No
4.46
P-9
Semichem/
kraft
NDb
Soft
Kraft
Rotary
drum
No
1.64
P-i0
Semichem/
kraft
NDb
Soft
suifite
Rotary
drum
No
' 1.05
P-11
Kraft
Continuous
Hard
Kraft
Improved
washing
Yes
5.16
P-12
Kraft
Continuous
Soft
Kraft
Improved
washing
Yes
2.23
TABLE 4-2.
Model
process
unit
Pulping
type
Digestion
type
Wood
type
Chemical
recovery
Washer
type
P-13
Kraft
Batch
Hard
Kraft
P-14
Kraft
Batch
Soft
P-15
Sulfite
Batch
P-16
Suifite
P-17
.P-18
Oxygen
delignification
(Yes or No)
Uncontrolled
HAP emission
factora
(kg/W pulp)
Improved
washing
Yes
5.13
Kraft
Improved
washing
Yes
1.96
Hard
Sulfite
Rotary
drum
Yes
4.68
Batch
Soft
Sulfite
Rotary
drum
Yes
1.75
Kraft
Batch
Hard
Kraft
Improved
washing
No
4.87
Kraft
Batch
Soft
Kraft
Improved
washing
No
1.67
a Includes emissions from vent and wastewater streams (See Appendix C for model process
unit emission factors by individual emission point and compound).
b ND = Not defined.
emission
factors
the model
factor
vary
process
that
units.
most
factors
softwood
emission
available
data,
other
previous
is wood
kg HAP/Mg)
capacity,
type,
being
have
little
for
the
with
hardwood
greater
parameters
Model
Process
than
Based
effect
on total
process
units
pulping
model
process
The bleaching
to have
the most
were
developed
units
process
effect
in a similar
described
in the
characteristics
on HAP emissions
are wood
HAP
From
process
units
units
for hardwood
both
the
caustic
bleach
vents
vent,
bleaching
sewer
of these
twelve
model
the bleaching
model
process
HAP emission
represent
factors
six bleaching
for softwood,
plant
total
and wastewater.
and
sewer.
with
variations
emission
factors
Similar
factors
other
Speciated
stream
decrease
4-6
from
vents
include
for each
points-include
in Table
range
4-3,
from
the
the
0.56
to
the hardwood
higher
than
those
in HAP emissions
of all chlorine
HAP and total
characteristics
4-3
emissions
vent
to pulping,
are generally
the elimination
compounds.
plant
seal tank
the greatest
chlorinated
in Table
The process
As shown
HAP emission
factors
However,
and
vent,
of pulp.
through
bleach
The wastewater.
emission
softwood.
presented
uncontrolled
and acid
kg HAP/MS
achieved
models
factors
washer
stage.
bleaching
data,
uncontrolled
and six
emission
total
process
tower
to
use.
The model
represent
each
the total
The twelve
emissions
to characterize
4-3 describes
model.
in chemical
2.11
developed
and presents
sequences
the
of available
were
Table
for each
of
emissions.
a review
area.lr2
on.
Units
model
section.
determined
pulping
of pulp
emissions.
Bleaching
as the
than
emissions
factors
Bleachina
manner
to 5.16 kg HAP/Mg
(4.46 to 5.16
process
4.1.2
1.05
Other
affects
emission
pulping
from
and
VOC
for each
emission
emission
for
is
TABLE 4-3.
Model
process
unit
B-l
B-2
B-3
B-4
B-5
B-6
B-7
B-8
B-9
B-10
B-11
B-12
Wood
type
Bleaching
sequence
(% c102 substitution)a
Hard
Soft
Hard
Soft
Hard
CEHD (0%)
CEHD (0%)
CEDED (0%)
CEDED (0%)
CdEDED (10w)~
CdEDED (10~)~
CdEDED (high)c
CdEDED (high)c
CdEDED (100%)
CdEDED (100%)
O-Ed
O-Ed
Soft
Hard
Soft
Hard
Soft
Hard
Soft
Uncontrolled
HAP
emission factor
(kg/W
pulp)
1.98
1.30
1.75
1.06
2.11
1.04
1.67
1.45
1.66
1.45
0.56
0.59
= Chlorine
C
for chlorine
Cd
= Chlorine dioxide substituted
= Chlorine dioxide
D
= Hypochlorite
H
= Extraction
E
= Oxygen/ozone
0
A low substitution
range is 10 to 50 percent substitution.
Less than 10 percent is considered
to have the same
emissions
as 0 percent substitution.
A high substitution
range is 50 to 90 percent substitution.
Greater than 90 percent is considered
to have the same
emissions
as 100 percent substitution.
The totally chlorine
free model bleaching
sequence is used
in conjunction
with oxygen delignification
in the pulping
model process units.
Key:
4-7
point
Appendix
process
Process
Units
units
are presented
in
C.
Use
4.1.3
model
of Model
in Estimatins
National
Emissions
were
and
To estimate
emissions
constructed
using
12 model
the
of the U.S.
(discussed
in Chapter
production
information
pulp
model
mill
assembled
and
sequence)
was used
location
State
was
used
units
individual
Section
were
mills
estimated
process
based
on the
Because
a mill
baseline
Pulping
to pulp
contain
more
than
for each
facility.
A pulping
multiple
units
models
digesters.
were
were
aggregated
in the
presented
assigned
data
at
emissions
only,one
one pulping
and bleach
a specific
washer,
but
4.1.1
4-8
were
facility
as
In other
could
model
and 4.1.2.
and bleach-line
base.
or
lines
washer.
in Sections
the whole
industry
and bleaching
on a pulp
the
model
The pulping
to represent
industry
with
contained
how
within
in Tables
evaluated
line
lines
and bleaching
mills
pulp
each
summarizes
individual
words,
from
models.
presented
associated
type,
levels
and bleaching
process,
digesters
washing
control
discusses
bleaching
the
type,
Geographic
4.1.3.1
assigned
could
information
mills.
Assisnment.
criteria
of each
to individual
4.1.3.2
units.were
location
model
and Section
these
contains
appropriate
to pulping
Model
that
digestion
assigned
using
4.1.3.1
units
and
to assign
to determine
regulations.
process
were
bleaching
type,
pulping
to approximate
Production
States.
mills
A database
wood
and
18 model
designed
6.0) was
capacity,
pulping
were
industry.
in the United
model
composition
pulp
(including
bleach
The
mills
level,
of the
processes.
of these
structure
wood
combinations
bleaching
distribution
on a national
process
These
basis,
for each
contain
and then
facility
Estimating
4.1.3.2
for model
process
unit
the
assigned
multiplying
production
or baseline
points,
or Federal
the
control
vents
device
were
(sulfite
assumed
was
99 percent
on the
were
removal
pollutants
assumed
99 percent
process
the
same
emissions
manner
details
pulp
and
paper
4.2
CONTROL
applies
streams.
Due
reductions,
such
points
HAP's,
plant
points
HAP's,
in Section
baseline
a 70 to
depending
of individual
0 to
depending
3.2.2.2
emissions
streams
on
for a
were- summed
Chapter
emissions.
for baseline
were
achieving
achieving
option
applies
and
controls
in this
in
2.0
in the
document.
two options
to pulping
apply
to
wastewater
are currently
requirements,
Table
and
being
evaluated
4-4 describes
specific
each
emission
points
applies.
option
and
conveyance
mills), assuming
vents,
streams.
control
as a power
cost
options
wastewater
control
the
are discussed
to all pulping
no control
the
collection
options
to the high
for bleaching
The
reduction
bleach
individual
on the basis
control
vents,
to which
from
or scrubbing
industry.
bleaching
option,
HAP
3.0, process
by a scrubber
the total
by
OPTIONS
Four
option
technology
as discussed
State
or documented
wastewater
as for uncontrolled
provides
One
present
of specific
estimated
in Chapter
Applicable
unit
the documented
of individual
efficiency
To obtain
unit,
with
by a steam stripper
to be controlled
absorbers.
were
organic
Applicable
present.
on the pollutants
gas
emissions
of the assumed
efficiency
removal
by the process
by applicable
to use combustion
to be controlled
by
required
As discussed
applied.
calculated
control
and a 98 percent
mills);
emissions
reported
emissions
in place.
assumed
efficiency
were
efficiency
were
factors
baseline
uncontrolled
reduction
points
emission
controls
regulations,
adjusting
emission
emission
If the mill
capacity.
Uncontrolled
Emissions.
boiler
for pulping
vent
to an existing
or lime kiln
a 98-percent
organic
4-9
emission
combustion
points
is
device
(or scrubbing
for sulfite
reduction.
As discussed
TABLE
Option
4-4.
SELECTED
CONTROL OPTIONS
Costing basis
Control
efficiency
(% reduction)
Process
area
Emission
8ource
Emission points
.
Combustion:
capture and
conveyance to an
existing
combustion device
Individual
conveyance of
vents with
combined
combustion
Scrubbing
Combined and
individual control
of vents
o-9oc
Bleaching
Vent
.
.
.
Combustion
followed by
scrubbing
Combined and
individual control
of vents
98/9gCId
Bleaching
Vent
.
.
.
Steam stripper
w/air emissions
control device:
conveyance to an
existing
combustion device
Combined and
individual control
of,wastewater
streams
80-9ge
Pulping
Wastewater
Evaporator
OP
I
P
0
100/98a
Pulping
Vents
.
.
a
b
C
d
e
condensates
Evaporator, surface
condenser
condensates
Turpentine recovery
underflow
1
reduces
With sources requiring enclosure, a 100 percent capture efficiency is assumed. Combustion
(All sources requiring capture are footnoted with "b".)
captured organice by 98 percent.
Emission point8 may require enclosure because they are hooded or partially open to the atmosphere.
The emissions reduction for this control technology is variable and dependent on the solubility of the
compound in the scrubbing medium and the volatility of the organic HAP's present.
Ninety-eight percent reduction of organice/
percent reduction of acid gases.
The removal efficiency and emissions reduction for this control technology is variable and dependent
on the volatility of the organic HAP's present.
in Chapter
some
existing
pulping
vent
vents
for this
Capture
hooded
these
3.0,
streams
option
existing
is also
necessary
or partially
complete
was
control
incinerator
applied
to
(Combustion
of
is possible,
devices
for those
were
emission
but
selected.).
points
to the atmosphere
assumed
option
scrubbing
70 percent
emission
ducting
which
reduction
that
are
(washers,
As discussed
to be achieved
points
the
control
in Chapter
with
option
only
of 75 percent.3
bleaching
vent
emission
by caustic
for organics
and
3.0,
enclosure
hydrochloric
acid.
The
control
of
is collection
generation,
steam
handling
stripping
reduction.
conveyed
Chapter
The
dependent
wastewater
design
device.
total
option
However,
HAP
for
98 percent
reduction
for chlorine
wastewater
and
emission
at the point
of
an 80 to 99 percent
organic
combustion
steam
points
and
stripper
are assumed
to be
device.
As discussed
in
stripper
control
of the HAP's
efficiency
present
is
in the
stream.
This
example
then
system,
the
for
vent
collection
from
volatility
ENVIRONMENTAL
applying
streams
reduction
incineration
to achieve
for pulping
overheads
on the
is thermal
reduction
to achieve
the
control
is
of
first,
an average
in an enclosed
to an existing
3.0,
points
of wastewater
stream
to a combustion
A third
points
average
for bleaching
the vent
scrubbing
option
emission
and 99 percent
achieves
99 percent
vent
a weighted
option
off-gas
reduction
followed
achieves
is scrubbing
scrubber
control
for bleaching
for organics
A second
chlorine.3
section
the
if not
IMPACTS
presents
control
facility.
preliminary
most,
facilities.
combustion
open
being
points.
caustic
4.3
at most
and deckers).
capture
One
this
are currently
in a stand-alone
knotters/screens,
these
controls
draft
all,
the environmental
options
These
discussed
impacts
BID based
have
on internal
of the comments
4-11
impacts
in Section
been
provided
4.2 to an
revised
review,
of
and
from
the
address
by industry.
The
,_
.p
/
/
.,
example
with
facility
batch
sequence
model
HAP
rotary
digestion,
bleach
plant
emissions
emissions
for the
entire
baseline
HAP
baseline
emissions
relief,
No other
cornbusted.
baseline
example.
As discussed
emissions
and
considered
section
application
secondary
Section
air
the
Air
section
air
from
directly
Table
mill,
its digester
are
assumed
for this
in estimating
control
national
levels
Water
impacts
control
were
on this
and
Section
options.
impacts
for
options
the primary
control
and other
and 4.3.4,
on the
attributed
resulting
fuel
of vent
4.3.2
impacts
respectively.
and secondary
air
of all control
options,
Primary
example
pulp
of HAP,
increased
from steam
option.
criteria
generation
cornbusted in the
mill.
to the control
are the
pollutant
for steam
incinerator,
Secondary
stripping,
and
from
streams.4
4-6 presents
by control
the primary
the reduction
evaluated
auxiliary
combustion
4.1,
presents
4.3.3
4.2,
include
impacts
emissions
were
in Section
impacts
emissions
that
noncondensibles
defined
impacts.
presents
resulting
discussed
air
These
4-5.
Imoacts
This
impacts
in Table
analysis.
of these
in Sections
and total
emissions,
the environmental
4.3.1
impacts
energy
are described
4.3.1
presents
as
to uncontrolled
baseline
impacts,
of the previously
mill;
presents
control
tons
as a total
assuming
in Section
air-dried
as well
controls
in a plant-specific
This
example
estimated
uncontrolled
points
points,
and evaporator
gases,
and a CEHD
are presented
emission
are presented
were
facility
C as pulping
1,000
HAP emissions
emission
emissions
blow
pulps
In addition
mill.
washing,
of the total
that
for bleaching
drum
pulping
Bl.)
mill
uncontrolled
hardwood
in Appendix
a summary
for this
The
per day.
total
model
4-5 presents
emissions
vacuum
(designated
PI and bleaching
Table
is a kraft
selected
option
primary
air
(as presented
4-12
impacts
in Section
4.2).
The
TABLE 4-5.
Line
No.
Process
Type
a
b
c
d
Line
Capacity
(ADTPD)
Assigned
model process
unitb
Total uncontrolled
HAP emission factor
(kg/W ~ulp)~
Total
uncontrolled
HAP emissions
(W/yr) c
Baseline
HAP
emissions
(W/W
d
Pulping
1000
Pl
4.39
1400
1360
Bleaching
1000
Bl
1.98
630
630
6.37
2030
1990
Total Mill
P
I
P
w
Kraft hardwood pulping with batch digestion rotary vacuum drum washing and a CEHD bleach
plant.
Definition of pulping and bleaching models and total uncontrolled HAP factors as
presented in Tables 4-2 and 4-7.
HAP Emissions (Mg/yr) = capacity (air dried tons/day) * HAP emission factor
(kg/Mg pufp)*(Mg/l.l,tons) * (Mg/lOOO kg) * (350 days/yr).
Assumes dlgester relief and blow gases and evaporator noncondensibles are being
cornbusted at baseline.
TABLE 4-6.
Emission
Source
TYPO
Pulping
Vents
Bleaching
Vents
Pulping
Wastewater
a
P
I
!G
b
C
d
e
f
4
h
i
j
Baseline Emissions
(Mg/yr)a.
HAP
voc
TRS
160
1160
570
550
420
1200
1300
270
Emission Reduction
(%)
Emission
Reductionb (Mg/yr)
HAP
voc
TRS
HAP
voc
TRS
Collection and
CombustionC
Scrubbinge
98skd
98%d
98%d
150
1090
520
70%f
70%f
NA
380
290
NA
Incineration
and Scrubbingg
Steam
strippingi
98-99%h
98%h
NA
540
410
NA
90%j
90%j
94%j
1080
1200
250
Baseline emissions assume control of digester relief and blow gases and evaporator
noncondensibles using a combustion device with 98 percent efficiency. Emissions
calculated from uncontrolled emission factors for an example 1000 ton/day kraft hardwood
pulp mill with batch digestion, rotary vacuum drum washing, and a CEHD bleach plant
using the following equation:
Emissions (Mg/yr) = 1000 (air dried tons/day) * (Uncontrolled emission factor +
l-O.98 * Emission factor for baseline controlled points
[kg/Mg air dried pulp]) * (Mg/l.l
tons) * (Mg/lOOO kg) * 350
(days/year)
Emission reductions represent additional emission reductions beyond the baseline control
level.
Assumes capture and combustion of emissions from digester blow tank, digester relief
gases, brownstock washer, brownstock foam tank, evaporator vent knotter,
deckers/screens, and weak black liquor storage.
Combustion reduces captured organics by 98%.
Assumes tower, washer, and seal tank vents from all four stages are scrubbed.
Percent emission'reduction as follows: 99% chlorine, 99% Hcl, 70% methanol, 70% average
for other HAP.
Assumes tower, washer, and seal tank vents from all four stages are incinerated and
scrubbed.
98% reduction of organics/99% reduction of acid gases.
Assumes digester blow condensates and evaporator foul condensates are steam stripped.
Percent emission reduction as follows: 90% methanol, 99% MEK, 94% TRS, 90% average for
other HAP.
table
and
presents
TRS
from
uncontrolled
pulping
control
options
streams
and
options
selected,
were
same
for these
in Table
the pollutant
for total
impacts
from
steam
were
estimated
required
and wastewater
control
efficiencies
VOC,
and TRS,
vary
from
as shown
nitrogen
based
including
oxides
stripper
combustion
fuel. 4
.as auxiliary
estimated
based
vents
requiring
added
to the
requirements,
devices
from
on the amount
combustion
the
the
device
addition
vent
were
in criteria
vent
of pulping'vents,
dioxide
effect
reduced
result
offsets
to be
was
sulfur
in the
moisture
in additional
to these
the
on-site
assumed
impact
the additional
will
streams
on the fuel
were
dioxide
of total
vent
for existing
streams
sulfur
to be
from the
All HVLC
air
of organics
streams
impacts
of fuel
determined
streams).
Although
control.
secondary
increase
of sulfur
LVHC
The
carbonmonoxide,
The
no significant
while
requirements,
in
to be generated
combustion
as combustion
with
used
values.4r5
the exception
devices,
for
Annual
the amount
overheads,
to be used
of steam
estimated
and the
with
(with
combustion
4-7,
streams.
option.4
the steam
negligible
assumed
the greatest
on calculating
associated
steam
in Table
were
on literature
impacts
impacts
for this
based
air pollution
wastewater
sulfur
to generate
The
used
vent
the pulping
production
.pollutants
usage
total
As shown
occur
of 63 Mg/yr
123 Mg/yr
were
removal
HAP,
4-6.
secondary
mill. 4
example
stripping
impacts
and
calculated
4-7 presents
secondary
steam
reductions
VOC
table.
Table
the
emission
are presented
70 to 99 percent
in the
vents,
Estimated
wastewater.
fuel
combustion
associated
fuel
requirements.6
Scrubbing
no impact
followed
secondary
bleach
on secondary
by scrubbing
air pollution
plant
vent
streams
air emissions;
of these
vent
impacts,
4-15
was
assumed
however,
streams
resulting
incineration
will
from
to have
result
in
the combustion
TABLE
Emission Source
Type
EXAMPLE MILL
SECONDARY
AIR
POLLUTION
Emissions
Control Optiona
IMPACTS
(Mg/yr)blc
PM
SO2
co
NO,
vocd
Pulping Vents
Collection and
Combustione
67
Bleaching Vents
Scrubbing
Pulping
Wastewater
P
I
!ii
4-7.
El
C
d
e
f
4
Incineration and
Scrubbingf
1.7
0.3,
23
310
Steam Strippingg
.2
27
20
Sources being controlled are defined explicitly in Tables 4-5 and 4-6.
Reference 4.
Criteria pollutapt emissions calculated for an example 1,000 tons/day kraft
hardwood pulp mill with batch digestion, rotary drum washing and a CEHD bleach
plant.
VOC generated from the control devices.
Includes SO2 resulting from incineration of TRS from pulping vents not controlled
at baseline: washer vent and washer foam tank vent. These are HVLC vents routed
to a power boiler assumed to be equipped with a venturi scrubber achieving
90 percent SO2 emissions reduction.
Criteria pollutant emission rates ignore any potential emission reduction of PM or
SO2 emissions that might occur as a result of scrubbing.
Includes SO2 resulting from incineration of TRS from wastewater streams not
controlled at baseline: digester blow and evaporator foul condensates. The
resulting steam stripper overheads are routed to a power boiler assumed to be
equipped with a scrubber achieving 90 percent SO2 emissions reduction and
90 percent PM emission reduction.
In addition,
secondary air impacts from the combustion of auxiliary fuel is
included.
is
not shown).
4.3.2
Enersv Impacts
The control options evaluated require additional energy
in a similar manner.
requirements.
4-17
Particulate
Matter
HAP
voc
TRS
Sulfur
Dioxide
Y//////1
2.1
28
94
Figure 4-1.
Carbon
Monoxide
Oxides of
Nitrogen
TABLE 4-8.
Emission
Source Type
P
I
=f
Control OptionC
Electricity
WBtu/Yr)
Auxiliary
fuel
(natural gas)
WBWyr)
Auxiliary
fuel required
for steam
generation
(mBtu/Yr)
Total
Pulping Vent
Collection and
Combustion
3,900
NAd
NA
3,900
Bleaching Vent
Scrubbing
9,500
. NAd
NA
9,500
Incineration and
Scrubbing
9,500
NA
1,060,OOO
Steam Stripping
3,000
Pulping
Wastewater
1,050,000'
NAd
290,000
293,000
6
E
:
Reference 4.
Energy impacts calculated for an example 1,000 ton/day kraft hardwood pulp mill with
batch digestion, rotary vacuum drum washing and a CEHD bleach plant.
Sources being controlled are defined explicitly in Table 4-6.
Additional fuel required from the moisture (above ambient combustion air) in these
vent streams is offset by the fuel value of the vent streams.
NA = Not applicable.
The greatest
and
Water Impacts
The water impacts associated with the control options
discussed
contribute
approximately
wastewater
loading reductions.
consequently,
4.3.4
Other Impacts
Other impacts considered for the control options
discussed
levels.
4-20
will occur from fans and pumps used to transport the vent
streams and wastewater streams to the'control devices.
No
Any waste
from steam strippers or scrubbers should be
manageable
significant
irreversible
No
No
4-21
4.4
REFERENCES
1.
2.
3.
4.
5.
6.
7.
4-22
to
to
(Section 5.z).
identified
in previous chapters.
CONTROL COSTS
This section presents the methodologies
used to determine
Sections
5-l
TABLE 5-l.
Emission point
Enclosure
Ductwork/
conveyance
Combustion
devices"
scrubberb
Steam
stripperC
Puloino vents
Digester relief gas
Digester
blow gases
Knottets
Pulp washers
Deckers/screens
Tower vents
Washer vents
Oxygen delignification
tank
blow
Oxygen delignification
washer vent
Bleachinu vents
pulpinq wastewater
I
a
b
:
streams
d
t
X
1
For pulping vents, existing combustion devices were assumed to be applicable; however, stand-alone
incinerators were considered for bleaching vents. The vent gas from the wastewater steam strippers
was assumed to be combusted in an existing combustion device.
Scrubbers were considered for bleach plant vents in two control options: as the primary control
device; and as a secondary control following incineration.
Including collection and transport of wastewater to steam stripper.
The overheads from the steam stripper are conveyed to an existing combustion device.
5.1.1
Enclosure Costs
AS shown in Table 5-1, the emission points that will
enclosures
require
(model washers,
approximate
An
for each enclosure at a typical (i.e., 1000 ton per day) mill.
Additional
panel
additional
It was
assumed that screens, knotters, and deckers each exist as
single units, and require a single enclosure.
For mills with
larger capacities,
the purchased
equipment cost.
investment
approximately
5.1.2
Ductwork
Affectina Cost.
analysis, it was
with transition
pieces.
5-4
TABLE 5-2.
Specification
Item
Design and
cost
references
8 inchesa
20 to 40 inches
of water
1,000 feeta
2a
Duct length
Number of elbows per 100 feet
of duct
Fans per duct
2,5
6
16 gauge
of steel
5-5
and
an incinerator
It
is insignificant.
Electricity
electricity
requirement
The
vent gas flow rate and the estimated pressure drop through the
duct system and- a cost of electricity of $0.04 per kilowatt-hr
($O.O4/kW-hr).ll
Maintenance
labor
costs.12
The annualized capital charges include capital recovery
charges as well as taxes, insurance., administrative,-and
overhead charges.
As
5.1.3.1
Affectins
halogenated
combustion
ductwork,
incinerator
General thermal
incinerator
sufficient-to
support combustion.14
5-7
Therefore,
TABLE 5-3.
Item
Specif ication
98 percent or greater
destruction of VOC
Minimum
incinerator capacitya
500 scfm
Maximum
incinerator capacity
50,000 scfm
Incinerator
temperature
1.00 set
Supplemental
fuel requirement
5-8
in the heat
bleach plant
the temperature
(chlorine).
If
were to drop below the acid dew point temperature for these
In cases such as
vent streams, acid gases would condense.
bleaching vents steams where heat is not recovered, the annual
fuel costs would be higher than for cases where heat recovery
is practiced,
The destruction
temperature,
concentration
Since these
parameters
5-9
Thermal oxidation of
Auxiliary
for start-
up of the unit.
chamber.18
The reference temperature
(i.e., it is
These assumptions
requirements
in a
separate document.19
5.1.3.2
costs.
Equipment
are based on data provided by various
in the 500
within 30 percent.
where:
EC
QToT
equipment cost.
conveyance
Section 5.1.2.
Installation
purchased
instrumentation,
Direct and
indirect installation costs for thermal incinerators have been
incorporated
capital investment
equipment
cost.
5.1.3.3
cost.
The total
is estimated at 1.61 times the purchased
operating
charges.
respectively.
5-11
shift.
Maintenance
maintenance
labor costs.
The annualized
in previous sections.
administrative
bleach plant vent streams, without incineration (i.e., stand(However, based on recent industry
alone scrubbers).
comments,
stand-alone
sections.
5.1.4.1
Affectins
Post-Incineration
Costs.
major equipment:
ductwork,
and fan.
organics.
absorption process and that both the gas and liquid streams
The liquid-to-vapor flow ratio is calculated from
are dilute.
the inlet and outlet gas and liquid stream flow rates and is
assumed to be constant through the scrubber.
The column diameter was estimated based on mass transfer
equations in the literature, 24,25,26,27,28,29,30
using characteristics
liquid
and an
For this
of design procedures
is presented in Chapter 9 of
the OCCM.32
The height of the packed column was calculated by
determining
Costs.
scrubber
TABLE 5-4.
Values
Parameters
Waste gas flow rate entering
absorber
2,000 OFa
Pollutant
HCl
in waste gas
liquid
Packing type
a
SCRUBBER
99 percent
(molar basis)
5-14
solution
(sodium hydroxide).
in chlorine.
Table 5-5.
stand-alone
memorandum.1g
The
The
15 feet of packing.19
and
stand-alone)
the OCCM.34
tower,
was used in the cost analysis for the tower, after conversion
to 4th Quarter
1991 dollars:
EC = (115,$/ft2) * (S,ft2)
where:
EC
S
=
=
D
HT
=
=
The cost for the column packing was based on the packing
volume.
5-15
TABLE 5-5.
Values
Parameters
Waste gas flow rate entering
absorber
Temperature
stream
140 OF
Pollutants
of waste gas
in waste gas
Cl28
cw2,
HCl, Methanol,
Chloroform
Chlorine removal efficiencya
99 percent
Scrubbing
liquid
(molar basis)
Packing type
Packing height
15 feet
Column height
27 feet
5-16
The methodology
for
calculating
instrumentation,
5.1.4.3
indirect operating
charges.
(sodium hydroxide
[NaOH])
recovery
energy required
the pressure
electricity
insurance,
exception
5.1.5
Though
information
Institute/National
Stream Improvement
.(Industry has
recently commented that the questionnaire was misinterpreted
and that a lower percentage of mills use integrated steam
strippers.)
evaporator
upgrades,
evaporator
system.
Affectinq
sensitive parameter
adjustments
stand-alone
The
(low) pressure
effects.
the approximated
greater.
5.1.5.2
The capital costs for the steam stripper system are based on
the following equipment components:
Reflux tank (for integrated system);41
Flame arrestor;J4
Pumps;45 and
Feed Preheater.46
All costs are for carbon steel construction except for sieve
trays and pumps.
be constructed
The purchased
components,
wastewater
sales
for comparison
streams
constructed
of a corrosion-resistant
material.
Equipment
costs for stainless steel were estimated from the carbon steel
costs, using a factor for conversion from carbon steel cost to
304.stainless steel cost. Table 5-6 presents the stainless
__
steel cost factor for each equipment component.
5.1.5.3 Development of Steam Stripper Annual Costs.
The
electrical
for the pumps is calculated using design flow rates for each
pump and assuming a developed head of approximately
37 meters
For
wastewater
approximately
system.40
$4.02/Mg.=
labor costs,
administrative
in
TABLE 5-6.
Equipment component
Reference
1.7
42
Reflux tank
2.4
45
46
Feed preheater
5-22
TABLE 5-7.
Option
'Jl
I
h)
W
Flow rate
(scfm)
HAP cont.
WI ($)
TAC
(S/yr)
Brownstock washera
Brownstock foam tank
Knottera
Deckers/screensa
Weak black liquor
storage tank
34,900 scfmb
300 ppmv
1,920,000
429,000
51,400 scfm
150 ppmv
860,000
287,000
51,400 scfm
150 ppmv
4,320,OO
3,840,OOO
1,500
gal/min
1,350
PPmw
3,500,000
1,900,000
Emission points
Combustion of
pulping vents:
capture (enclosures
where necessary)
and conveyance to
an existing
combustion device
Scrubbing of
bleaching vents
(combined vents)
l
l
l
l
l
l
Combustion of
bleaching vents
followed by
scrubbing (combined
vents)
Steam stripping of
pulping wastewater
(combined streams)
followed by
conveyance to an
existing combustion
device
l
l
I
I
Emission points that require enclosures.
it The flow rate for sources requiring enclosures was 29,000 scfm with a concentration of 150
ppmv (after enclosure installation) and for enclosed sources, the flowrate was 5,900 scfm
with a concentration of 1,000 ppmw.
including
Tables 5-8 to 5-12 for the example 1000 ton per day (TPD)
facility.
The
Points
presented
in
(i.e.,
are
Two potential
Vents
(as discussed
5-24
TABLE 5-8. COSTS FOR MODEL MILL PULPING VENTS NOT REQUIRING ENCLOSURES
USING AN EXISTING COMBUSTION DEVICEa
Cost component
Component cost
($1
Total cost
($1
Equipment costs:b
Ductwork
19 in. diameter
1000 ft. length
20 elbows
50,000
Fan
16 in. diameter
17 hp
5,900 scfm
1,000
Knockout drum
2 ft. diameter
5 ft. height
0.25 in. thickness
1,000
Flame arrestor
19 in. diameter
Rupture disc
10 discs
3.02 * PEC
32,000
9,000
93,000
281,000
83,000
I
a Includes brownstock washer foam tank and weak black liquor storage tank with a
flowrate of 5,900 scfm.
b It was assumed that equipment costs are given as purchased equipment costs.
Cost component
Equipment costs:b
Ductwork
Component cost
($1
249,000
44 in. diameter
1000 ft. length
20 elbows
Fan
44 in. diameter
50 hp
29,000 scfm
6,000
Knockout drum
5,000
. Flame arrestor
Rupture disc
Purchased equipment cost
(PW
Total capital investment
WI 1
TCIduct
TCIenclosure
TCI
Total cost
(9
45 in. diameter
10 discs
Sum of equipment costs
3.02 * PEC
5 enclosuresC
111,000
43,000
414,000
1,250,OOO
385,000
1,635,OOO
TCIduct + TCIenclosure
TACduct
TACenclosure
TAC
58,000
TACduct + TACenclosure
I
346,000
Cost component
Component cost
($1
Total cost
($1
Equipment costs:
Scrubber column
15 ft. diameter
27 ft. height
Packing
Pump
Fanb
187,000
53,000
9,350
7,600
ul
I
td
4
74,000
(EC)
330,000
1.18 * EC
390,000
2.20 * PEC
860,000
(TCI):
TCI
287,000
a Based on tower, washer,, and seal tank vents from C, D, E, and H stages.
b Detailed equipment size and cost procedures for ductwork are presented in
Table 5-8.
TABLE 5-11.
COSTS FOR CONTROL OF MODEL MILL BLEACHING VENT STREAMS USING AN INCINERATOR
FOLLOWED BY A SCRUBBERa
Cost component
Component cost
($1
Total cost
($1
Equipment costs:b
Incinerator = EC
1 incinerator
51,400 scfm
132,000
1.18 (EC)
156,000
TCIincinerator
1.61 * PEC
250,000
TC1duct to incinerator
1 duct
1000 ft. length
48 in. diameter
20 elbows
2,830,OOO
TCIduct to scrubber
300 ft length
48 in. diameter
6 elbows
595,000
TCIscrubber
15 ft. diameter
27 ft. height
650,000
TCI
TCIincinerator + TCIduct to
incinerator + TC1duct to
&rubber + TC1scrubber
4,320,OOO
I
TABLE 5-11.
COSTS FOR CONTROL OF MODEL MILL BLEACHING VENT STREAMS USING AN INCINERATOR
FOLLOWED BY A SCRUBBER (Concluded)
Cost component
Component cost
Total cost
TACincinerator
650,000
TACduct to incinerator
TAcdUCt to scrubber and
scrubberb
TAC
370,000
TACincinerator + TACduct to
incinerator + TACduct to
scrubber and scrubber
3,840,OOO
s:
a Based on tower, washer and seal tank vents from C, D, E, and H stages.
b Detailed equipment size and cost procedures for duct are presented in Table 5-8 and for
scrubber in Table 5-10.
TABLE 5-12.
Cost component
Component cost
($1
Total cost
($1
Equipment costs:
ul
I
W
0
Feed preheater
49,000 ft2
680,000
Tray column
11 ft diameter
29 ft height
150,000
17,000
1 per line
0.16 ft. diameter
113
100,000
Pumps (nonintegrated
only)
EC (integrated)
99,000
950,000
EC (nonintegrated)
930,000
1,100,000
Auxiliary
. .pipinga
. .+. sales
tax + instrumentation
1,100,000
TABLE 5-12. COST FOR CONTROL OF MODEL MILL PULPING WASTEWATER STREAMS
USING A STEAM STRIPPER (Concluded)
,
Cost component
Component cost
($1
Total cost
($1
2.2 * PEC
2,500,OOO
TCI, (nonintegrated)
2.2 * PEC
2,500,OOO
TCI (duct)
TCI
3,200,OOO
3,500,000
O=67(TCIintegrated)b +
0*33(TC1nonintegrated +
TCIduct)
W
P
250,000
2,900,000
,73,000
TAC (integrated)
780,000
13,400,000
720,000
TAC (nonintegrated)
TAC (duct)
TAC
0067(TACintegrated)~ +
, 0.33(TACn onintegrated +
TACduct)
1,900,000
I
a Auxiliary piping is included here to account for the combination of wastewater streams
and vapor vent lines for wastewater holding tanks.
b Costs are based on weighted ratio of the cost of an integrated steam stripper and a
stand-alone steam stripper (0.67 and 0.33, respectively).
presented
in Table 5-13.
medium
5-32
TABLE 5-13.
COMPARISON OF TOTAL CAPITAL INVESTMENT (TCI) AND TOTAL ANNUAL COST (TAC)
FOR MODEL MILLS WITH VARYING CAPACITIES
Emission Point
Combustion of
pulping vents not
requiring enclosures
Combustion of
pulping vent8
requiring enclosures
Scrubbing of .
bleaching ventea
l
l
l
VI
I
W
I*)
Steam stripping of
pulping wastewatet
followed by
conveyance of vent
stream to an
existing combustion
110,000
350,000
$1,600,000
450,000
$2,100,000
290,000
330,000
Sl,lOO,OOO
83,000
210,000
$1,000,000
160,000
58,000
Brownstock washer
Knotter
Deckers/screens
400,000
TCI
TAC
TCI
280,000
170,000
Combustion of
bleaching vents
followed by
scrubbinga
TAC
TCI
TAC
860,000
410,000
$2,63O,OOO
$2,670,000
$3,800,000
$4,300,000
$7,500,000
$7,OOO,OOO
$1,620,000
$1,900,000
$3,500,000
$2,300,000
S4,600,000
840,000
a The bleaching vent emission points controlled included those points in a CEBD sequence (i.e, 3 points for each stage,
totaling 12 vents).
I
I
I
5.3
REFERENCES
1.
2.
3.
4.
5.
6.
7.
8.
9.
Ref. 8, p. 3-52.
16.
11.
12.
13.
14.
5-34
15.
16.
Ref. 9, p. 3-8.
17.
18.
19.
20.
Ref.
21.
Ref. 8, p. 3-47.
22.
Ref. 8, p. 2-25.
23.
Ref. 8, p. 2-29.
24.
Perry's
Perry, R.H., D.W. Green, and J.O. Maloney.
New York,
Sixth
Edition.
Chemical Engineers' Handbook.
1984.
p.
3-78.
McGraw-Hill Book Company.
25.
26.
27.
28.
29.
30.
Ref. 8, p. 9-65.
31.
Industrial Control
Buonicore, A.J., and L. Theodore.
Volume I. Cleveland,
Equipment for Gaseous Pollutants.
OH, CRC Press, Inc., 1975. PP* 74, 105, and 106.
32.
8,
5-35
33.
36.
Telecons.
medium.
37.
Telecons.
Brown, H.P., Radian Corporation - Research
Triangle Park, NC, with Rovansek, W., Radian. Corporation
- Herndon, VA. Wastewater Treatment Costs.
January 13, 1993.
38.
39.
40.
41.
42.
43.
44.
Telecon.
Oakes, D.
45.
to
Scrubbing
5-36
46.
5-37
6.0
The
database
calculated
discusses
and fuel use, and the generation of summary output tables for
these joint air and water control impacts.
'6.1
DATA INPUTS
As described in previous chapters, extensive data
gathering
the pulp and paper industry with regard to processes and their
emissions
basis.
A database containinginformation
mill-specific
(e.g., capacity,
wood type) on each pulping and bleaching line for all mills
considered
national
database
contains confidential
therefore,
(This mill-specific
6-l
,
I
Emission
Factors
I
I
Industry
Characterization
(Model Mills)
1
Calculate Uncontrolled
Air Emissions
t
Assi n
BasePne
Controls
c
I
Ca~~l~i~~rr
1
Identify
Air Control
Options
L-
a
-
Water b
Control
options
m
Water b
Control
Impacts
Involvesreassignmentof model
processunits if water control .
optionsrequireprocess
modification
t
Emissions & Control Impacts
costs
Water
Process
Ii
3
3
emission factor.
database is produced
(made up of
and a
of
in the database.
As described
impacts for
factors multiplied
by mill-specific
6-3
line capacities)
by
assigning
The
point, were then summed for each process line and mill.
National emissions were estimated by summing emissions from
all individual mills.
National air control impacts (emissions, emissions
reductions,
(Environmental
Taking into
for each
Because the
add-on controls may be applied to multiple emission points
within a mill, control costs were not calculated by emission
point; but instead were calculated by line or by mill.
is, depending
That
device, multiple
device together
accounting
6.3
GENERATION
These output
air emissions and emissions
6-5
6.4
References
1.
2.
3.
4.
6-6
APPENDIX A
FIELD TEST DATA
APPENDIX A
FIELD TEST DATA
A.1
INTRODUCTION
The EPA conducted a field test program to gather air
emissions
emission factors.
Testing was
Testing
and wastewater.
Additional
site.
The information
from the field test reports and are in units of lb/hr for gaseous
measurements
the measured
discussed
A.2
Conversion of
in Appendix B.
TEST DATA
A.2.1
because
Site 1.
it is considered to be representative
A-l
and
paper
potentially
produces kraft pulp from both hardwood and softwood chips. The
pulp is used to produce uncoated, white free-sheet paper for copy
machines, manuals, brochures, printing, business forms, and
The mill also produces bleached pine and hardwood
envelopes.
market pulp, approximately 20 percent of which is in the form of
baled pulp. An overview of the processes at the site are
presented
in Figure A-l.
(50 percent).
Figures A-2 and A-3 present the hardwood and softwood pulping
processes.
digester pulping lines and the pine chips are cooked in one
continuous
digester.
Each
each digestion
line.
direct-contact
The steam and condensible gases are condensed in the directcontact accumulator
The noncondensib>e
the accumulator.
accumulator
from
with evaporator
stripped.
After the blow tanks, hardwood pulp flows to a knotter which
removes undigested
brownstock
washing system.
3-stage
r-l
WOOd
Prepuation
soRwoo
HUdWOOd
HUdwOOd
Wood
Prrpudlon
Wood
Prepumtlon
b
& i
8%
Oigoston
Oigosmm
& $zZ*~
I .I
t2iX
vfzr
pup
. ug!!z
/tA
-we
t
szl t ~cbrnlcd*
w- we. --A Liquor
it%
,+,
,+
w
9..
Figurr
A-l.
General
qgy
0
Q
.-.
Process
A-3
Diagram
for-Site
Nrr(
____________-__-------------------------,
I
I
I
&
10
5
%l
I
I
I
I
a
2
J$i
y
I
t,
I
1
:
.
.
I
s
5 0
*:.......-...,
i
I...
ii
...
:-o
4.
.
$ *..:a*-taf
I
3
_f
P
Ic
3
;g
21
4
d
1
2+
I
7 ner
.m8
n!
1
a
,
11
t
t
I
@
...m z
; !I
II-*oil
c;
A-4
4
k
Itc
4 1. L8
!I-,e,
11
i B4
4
%%
I4
42
cn
u10
:
%
k
z
-4
2
2
80
..
A
it
%
-4
a
5:
2%
hf
vJ
I
.
i aa
:a
:a i
CO,....
8%
iv
;g
05
\
1
51
f
.
.................
I2
%
41
l
4
-
El4
I I I'
4 1,
I I
I I.
-_------
-----m-m
I IL---------
I I I
III
9
iii
; I I
I I I
III
i1111-
I
.---'
Ll
I
I
I
I
I
I
4
z/---13
.:
4 <I
m
d
I
I
I
I
I
I
I
A-S
s
8
1
I
washed, pressed,
plants.
The pulp
and the liquor mixture flow from the second vessel to a two stage
diffusion washer.
tower countercurrent
lignin.
hardwood brownstock
washer are collected
process.
soap is skimmed
VtilO
EtmctmWkRW
VtilO
__ _. _. . . - . . . . . . . . - - .
...&-,
- ....
l-l
....... ......................
WbI
*&-&).I...m
.I :
:: *
L
2:
cm- .- :: :
(
:: :
sz
. ........)
rlsi
8rlppdload-
....................................
:-
............
.............
. .
-:
:
:
i
i
;
!
:
:
.
:
.
.
.
:
:
.
:
I
:
:
:
.
:
:
:
4.
. ..__._____._..........
Figure A-4.
.'.
t.2miMwl~Dlr
________..._._._.
Sllumr
(Na2C03) and
in the causticizing
The evaporator
process.
system condensates form two streams, one with
section.
is sent to a rectifier.
The vapor exiting the rectifier consists primarily of
methanol and is routed to the lime kiln.
condensates
The bleaching
The 3-stage
(C/D) 'stage,an
sequence consists
of chlorine/chlorine
A-8
dioxide
0
sLI cc=
33
..1
0
a+
a% 4>7
z
5
%
;;4..
i&T
33
33
:
:
*
.
i
I
LYJ ....
4
,.___......._.._.
................ p-.0
B
i : #,
s..............!I.
h
d
0
I
:
I
I
I
.
i
,
I
i
.
I
:
-_----e-----------
,d
I
8
I
,I.
A-9
production.
The objectives
characterize
bleaching
Other
constituent
measurement
locations.
methods
Process
of the facility.
Table A-l.
Location
Identifier
..
Hardwood Plant
Vent into hardwood bleach plant scrubber
Hardwood D stage vent/wash and tower seal tank
HVl
HVlA
softwood Plant
0, delignification blow tank ven-t
Vent into bleach plant scrubber
Combined vent from EOwasher/filtrate
tank
SVl
sv4
sv5
at
Site
Measurement Points
COMPOUND
SVl
sv2
sv4
0.0784
0.0124
HVl
HVlA
NA
NA
Acetone*
0.0554
Acetoneb
0.0912
0.00904
0.01004
NA
NA
Acrolein
NA
4. 01E-4C
0.000441d
NA
NA
NA
NA
MeK
MeKb
0.000567
0.00296
0.00289
0.0160
6.29e-4'
1.82e-4'1
NA
NA
NA
0.795
0.0435
NA
NA
2.16
0.0747
0.0260
NA
NA
HCLf
NA
0.0288
NA
NA
NA
Ch'
a-pineneg
N'A
0.212
NA
NA
NA
0.116h
2.17e-6'
NA
NA
NA
B-pinene'
0.0617h
7.15e-5'
NA
NA
NA
or.600
0.476
0.377
Chloroformb
Methanolb
THCj
4.320
0.863
D
- Obtained using EPA Method 0011.
b 2 Obtained using NCASI Methanol method.
. c - Value below detection limit of method.
d
- Estimated value below calibration limit.
c - Value. below quantitation limit.
f
- Obtained using EPA Method 26A.
I - Obtained using EPA Method 0010.
II- Estimated value above quantitation limit.
i
- Estimated value below quantitation limit.
j - Obtained using EPA Method 25A.
NA - Not applicable
.
A-12
TABLE A-3.
Location
0
SP5
SP6
SP7
SP8
SP9
WW6A&B
WW7
WW8
SP3
SP4
HP2
HP3
SPl
SP2
A-13
HP1
WWl
WW2
WW3
WW4
Site 2.
at this facility.
(NSSC)
Approximately
2153 tons
from hardwood.
in Figure A-6.
cook.
A-14
Pulp
TaMa M.
Muund
Conetitumt 8Zxwmntaclonm
.t 5ltmt (ug/nU
Measurement Points
M8hyl*elfi lmmm (a)
*kemd Cl
cubondl~
(*)
(0)
Chlommdum
bw5
0.145
sP3
0.745
SP4
5.03
HP2
0.W
HP3
0.155
HP1
15.24
0.542
4.41
0.410
0.127
O.po
0.252
ox)31
0.017
0.13
0.00s
O.OP
0.410
0.213-
0.103
0.30
0.105
5B.4
0.011
22.0
0.042
<15x)
0.045
35.3
0.033
257
0.014
175.2
t.001
0.002
0.075
0.023
0.02
0.04
eo.02
0.13
X0.03
<0.02
0.57
<0.02
<0.02
eo.02
0.55
<on4
CO.03
0.77
0.14
0.05
075
455
535
0.05
2.712
010
4M
501
435
a5
30.1
0.52
0.53
10.2
w
(4)
~~
w
Dbhbmmc.mnlmb
tn
(0
2.4-DMbrophmd
0
r-kuloxy-l-~-t--w
tirrr*
0
4.5-okhbtcr~moykY&
sowam
t.1
1.W
44.2
4.45
3,247
5,374
.63,tt5
3,530
22
23a
2.73
4.3
12.5
104
aso
0.01
0.152
0.544
13.1
33.3
37.a
15
13.4
67.6
53.8
115
50.5
1340
31.1
0.5
120
310
155
37.3
203
m
(0)
58.3
13.2
4.15
30
3s
<0.02
0.57
0.04
0.043
13.087
t.433
12.4
*Tm
M
AmmdcLumm
0.4
0.072
0.332
(0
Dlmho~
2.40
(fj
Phhbhh
(0
TtWddum
*hod
T.h*llanm
15.2
1.40
0.151
12.5
Dlmmhy(dlmulnIb (a)
w
VAV4I
275
0.6
-*lo
EbnxobDddm
*pl--
ww3
7.m
10.4
~-0
2.4.CTfkhbqh.d
w--
574
I~oa
NW-2
3.97
13s
(a)
D~bf-bphm
5llowrw (a)
Nltl&
345
o.tu
wt
0.52
chbd&
filcyl=#
m
HD*uundcDdd
54.5
5Pt
0.038
437
4.01
bb
Tdurw
W
l.l.l-Trkh)ocatitta
Dlmhyi
ww7
0.023
24.3
(a)
(a)
hw-
wwa
0.300
275
(0)
bdalm-
5Po
0.37
SP2
0.305
SP5
0.410
co.02
(e)
chb4Tb-m (c)
Chbdder (d)
2.euumm
sn
o.cu3
u**y*rw-
n+hucu
203
SP5
0.407
53.0
Acmldn (*)
chbmbfm
sP5
0.722
3.57
2.05
o.to4
(I)
DlmhyttiMldo
Total VO -vMal
1.75
0
@pm) Q)
l-obhlmdudnQ~ootl.
b.
Cbmlmd
u&g
NtXSWe5mnol.
txakhbmbmJmMty(mchlblm.
c-CbhllmdudngM
dObmld
udng
MMmd
25A.
l.camlndumhgM5rNqDlmlpm
I - obulnd UJng MS270 lmlpr
g - Cbrnlrld Udng Mdhod 260.
lS=
570
to4
MO
eutral
LmW
Sulftte
occ PIent
CxcBa
woodhpwoIion
1
occpl
F3
I &A
2carnuas
u
. .g
w
t
2w
0
z
w
ToGnnlQaed
L(dirrmprobdlar
h-
*
I
ToaMtidm
1
I
I
I
I
I
ok
II
'-
5f 13
I
I?r
i
I
I
*-----------------
I
I
I
c--
Y--
Cd
.I
il
... .
. ..
. ...
.
.. :.
. ..._.....
.... ..... .
.. ... ... ..
..... ..
. .... .
. .. .
..w
%
8 10
mI
%.I1
I
I
I
I
I
1
i
I
I
I
I
I
Ii
II
r!
--
>
-1
I
Dilrwdcmdc
)
ToN3KhSmBu
=2
0
L
ii&
I
t
a
---I,
Figure A&8.
brownstock
digesters
is washed
thickened
in a decker.
secondary refining,
is combined with
spent pink liquor from the NSSC screw presses, and sent to an
evaporation
After evaporation, a
portion of the black liquor is oxidized and then burned in the
recovery furnaces.
The
slurry formed in the slaker is agitated in a causticizing tank to'
form white liquor and lime mud.
in the slakers.
Condensible
Turpentine
is decanted
f3twmsiocrcw~(No.7w~~l
4
1;
loi--;
nd
'I.
.
fjJpy=w
:
,~""""""'
i.
i
u
1.
:
I
1
I
I
/
,
//
EvrFmrplor-.
115RwxmyFe-*
a 110du
oiI
t
I
:
I-0
ti
I
I
- I
I
I
I
I
-1
:
I
I
-l-e
Ez-
&
f-f%-
&
1
I -0
tl
usEN
-v--e_
w*
-s--e-
*e..
t_
To
Figure A-9.
.. L
7
=I
..-in
Fi*re
A-10.
AL
~gppggjy~
=z
L
Y
II
t.
I4
I1qlr
Washing at Site 2
-TZy$y
RakKhon
-
-.
AJP
Noncondensible
evaporators,
digesters,
collection system.
The bleaching sequence at Site 2 is CEHD (chlorination with
approximately
chlorine dioxide tower and washer and the foam tower are vented
to a caustic scrubber.
hypochlorite
The
and blow tank offgas condensates, acid sewer, caustic sewer, and
bleach plant scrubber effluent.
characterization
of
air emissions
substitution,
listed in Table A-5 along with the identifier for each location.
A summary of the average vent emissions of identified
constituents is given in Table A-6.
Process stream samples were collected at a number of
.'locations throughout
the plant.
GC/ECD.
The relative
!1
I- 1s
-0 2f I
-------------
1,
!I
II E
:- _,i_&--:---I
B
51
----~
--.-----o
I
I
I
I
I
I
I
0
I,i
B
i
w--------o--o-I
I
UJ
J
I
I
I
I
I
I
I
I
I
I
I
I
I
s\
I
-I
t-s
g&-T.
*--0-0
:!
I
p----------------k-
I
I
I
I
-----------I
s
(*
2
2:
fy.2
!I
e-
I
I
I
I
I
I
I
t
I
i
P
I
I'
A-23
I
I
I
I
I
I
I
I
I
I
Table A-5.
Location
v2
V3
v4
v5
E washer vent
H tower vent
H washer hood
Bleach plant scrubber inlet'
l
A-24
Table A-6.
Summary
of
I
I
Average
(lb/W
v2
0.001
0.
0.000
-0
0.010
-0
-0
0.171
.0.012
0.001
0.007
0.083
0.000
-0
0.011
0.004
0.
-0
-0.
0.000
0.000
0.000
0.001
0.000
0.002
0.063
Constituent
Acetaldehyde'
Acetone'
Acetoneb
Acrolein'
ChlorineC
Chlorined
Chlorine Dioxided
Chloroformd
Chloroformb
Formaldehyde'
Hydrogen Chloride'
Methanol*
Methyl Ethyl Ketone' .
Methyl Ethyl Ketoneb
Methylene Chlorided
Methylene Chlorideb
Propionaldehyde'
Benzeneb
Carbon Tetrachlorideb
l,l-Dichloroethaneb
Chloromethaneb
Tolueneb.
Bromodichloromethanee
a-Pineneb
p-Cymeneb
a-Pinene'
Total Hydrocarbons
8
Vent Emissions at
A-25
Measurement Points
v5
v3
v4
I
I
I
0.002
0.002
NA
0.001 0.005
NA
NA
0.016
NA
0.002
0.045
NA
0.044
53.121
NA
0.071
5.187
NA
0.011
1.305
NA
0.301
2.863
NA
NA
0.059
NA
0.001
0.013
NA
0.011
1.131
NA
0.622
2.042
NA
0.002
0.030
NA
NA
0.000
NA
0.012
0.126
NA
NA
0.011
NA
0.000
0.014
NA
NA
0.001
NA
NA
0.003
NA
NA
0.001
NA
NA
0.010
NA
NA
0.001
NA
NA
0.007
NA
NA
0.001
NA
NA
0.001
NA
NA
0.000
NA
0.121
0.872
0.974
Site
Table A-7.
Location
Weak black liquor from Kamyr digester
Pulp out of Kamyr digester
Pulp out of Kmyr digester - extended cook
Pulp into brownstock washer No. 7
Weak black liquor from brownstock washer N
Soft pulp into C C D washer
*
Pulp into C & D washer
Pulp into E washer
Pulp into H washer
Pulp out of D washer
Pulp into screw press
Spent liquor from screen press
Bleach plant scrubber wastewater
Digester & blow tank off gas condensates
C stage filtrate
A-26
Pl
P2a
P2b
P3
P4
P5
P6
P7
P8
P9
PlO
Pll
WWl
WW4
Ww5
procedures
Site 3.
A.2.3
paper mill.
Occasionally
and
in Figure A-12.
Sampling points from Site 3 are located in the pulping,
chemical recovery,
and digestion.
One blow
tank.
vapor sphere.
the noncondensible
variations
are routed to a
in gaseous flow.
digester gases in the blow tanks *are then sent to the brownstock
washers.
Figure A-14 presents the brownstock washing configuration
Site 3'. Pulping
vacuum washer
A-27
is washed in a
Fresh
at
(a)
Ac.Wdah&
(.,
PI
Pa
3.2
1.1
P2b
P3
P4
P5
Pa
P7
P8
PO
PI0
PI1
0.03
27
3.4
4.7
0.043
0.352
0.557
0.732
0.87
0.27
<o.oos
4.5
0.032
0.11
0.018
0.032
0.015
kabm
C)
29
17
43
30
43
0.212
OR40
o.!a7
h.uddn
(4
co.01
co.01
CO.20
<O.Ol
<O.Ol
0.010
<O.Ol
co.01
P-h+
(d
krnpl dlfl
lwDM
(a)
ti4
0.063
1.3
<O.Ol
so.01
0.07
0.13
0.03
0.1
0.076
OR3
<O.Ol
0.00
0.08
7.3
0.05
0.05
2.5
ND
ND
ND
(a)
(a)
515
75.5
340
273
2.150
2.5
2.4
2.0
<O.OS
0.54
<OR4
<OR0
wmo.
72.153
13.750
ND
O.W!l
0.002
0.W
ND
ND
O.Wl
0.0035
0.012
No
0.313
ND
0.000
ND
ND
ND
ND
O.Wl
ND
ND
0.011
0.002
ND
ND
ND
ND
ND
ND
O.WSS
O.OCW
Ee-omnmdum
@I
ND
0.003
ND
0.003
ND
ND
(b)
ND
ND
0.15
ND
ND
O.WO
0.33
0.338
ND
0.010
0.008
ND
ND
ND
0.M
ND
ND
ND
0.204S
0.037
ND
0.003
0.002
0.002
R-1
SW--
b)
O.OW
ND
0.033
ND
ND
ND
Td-
0.13cs
0.025
ND
0.001
0.003
0.008
ND
ND
Mnjichlwlde
m-w*
(b)
(b)
@)
kamfb, @)
tkomodkhlcmmmdun.
1.3-Dkhkmbmzmm
olln+l
d2da
ND
ND
0.001
ND
ND
o.ons
ND
ND
ND
0.000
ND
ND
0.46
ND
ND
ND
OR35
0.521
ND
0.m
0.036
o.ow
(b)
(I.)
ND
ND
ND
0.001
ND
0.010
0.01m
ND
0.13
ND
ND
ND
18
0.w
0.W
ND
ND
ND
0.024
ND
ND
ND
0.000
eb)
1.s
@)
4.6
2.1s
O.COS
ND
0.000
b-Phm
04
1.4
0.00
0.002
ND
ND
ND
0.24
O.OWS
0.11
ND
ND
ND
ORWS
ND
No
ND
ND
2.45
s.s
ND
2.m
ND
ND
ND
0.004
ND
3.1
0.041
ND
ND
0.W
ND
em-
@)
3+Meaqphmd
(cl
P--h-W-d
Ph.nd
(cl
C)
2.1
l-Pln.n.
6)
Wlmm (c)
0.515
ND
*TN-d t-3
1.w
ND
l -amlnd
Udng whk
- Not uulpd
ND-No(&*s(d
ND
2.430
0.06
(?a)
<I
ND
0.620
ND
(b)
ND
ND
ND
(b)
ND
Chkmrmdun.
Trlchkmatmm
so.01
0.507
0.04
<O.Ol
O.W3
ND
0.18
<O.Ol
O.OW
ND
~%l--~~
94
co.01
o.oso
ND
0.28
1.0
0.34
1.4
lodorm-
Q.27
1.5
14
x0.01
ND
(b)
0.26
<O.aO
0.M
IO
n+hurn
0.01
so.01
61
l.l-Dkhkm.durm
-.
0.44
0.01
I.5
<I
Ch@)
DlbmmmnUum
<O.W4
ww6
Gil
--
0.1
2.2
Cattarnchkeide
0.01
wws
0.14
(a)
(a)
<o.oM
2.5
0.33
(a)
Mdlmd
<o.ow
w4
0.49
b-Plnm
M.dl*chw
~0.1s
WI
0.34
a-Plwm
Chkmkrm
.t sh. 2 (q/ml)
Measurement Points
(compond
Fmldahvdm
Condbnn~ -(ntlons
ND
134
13S
14
1.5w
57
1.5
4
Wood Preparation
r
2 Kamyr Digesters
6 Batch Digesters
c
I
f
9
3 Stage Vacuum
Pulp Washing
No. 4
3 Stage Vacuum
Washer
Pdp Washing
w
J
f+JlP
stotaga
1
b
Bleaching
.
/ Papmakfng
1:
Figure
I--
Unbleached
Papc#makfng
MarketPulp
A-29
-
0
8
psc
ii
Sri,3
.
-El+- f
A
&
. - _. . _. - . - . -
:-..A
:e...-
_,.I
a- *.
....<
__c
F
*
;. . .. .. .. . .
--c
4
,4--
*.
....<
;*...F
;
__c
I
;._...... .. .._..... .. ... . .. . ..a....
:
I
i
:
:
:
.* -.
....,
*...l
:
:
;
:
:
:
.- -.
.....
:
+-.:
;
I
.I
.... . .(. ... ... . . .. .. .c..
:
:
Ii.....&-)q
4fi
2 a
iii l
,-if
0
t-7
2
.c(
VI
e,
a
:
3
:
E
&
42
tl
%
V-4
P
za
0
44J
z
%
z
PC
B
P
c;
Pl
k
E
g
4kl
A-30
s +t
II*
a; 3
F d%
Ei
az
b 5
p
0
5
@$f
LL
:
1 i -: :1
;
r.*#
gBQ
b
b
s
z
fb
.: 8
l
51
sl
\
-..*
0
z *-we
b
dx+ d
*--
I! .:y>. I:>
g
*
. ..-
,....p
. . .. .. .. . .. .....i
..
<
c-
:
:
l
.<
iI:
,.._....
..:Pq .... .. . ... ... .. ..
....
..-a
.
r
:
3,
Ic:.
%
31
v:
.
I
b
I$
.m
1
cf
x
:
:
-I
e0
$ ..
& .....
.._,,,.%
._
e
W
._
Ii
...J,
c-
3
-jjj
V,
c-
%
2
i....i
A-31
*
I
-1 B
*pn@
..
water, evaporator
The
brownstock pulp is then used to make unbleached products.
Pulp and liquor from the batch digesters and Kamyr No. 1 is
at
stored, and sent through weak black liquor oxidation where some
sodium sulfide
(Na2S203)
to the evaporators
the plant, strong black liquor from the No. 1 and No. 2
evaporators
another oxidation
system.
A-32
Fresh
WdW
.:
Figure
A-15.
No. 4 Washer
at Site
Market Pulp
UnbleachedStock.
and/of Blench Ptant
c-7
J
.-I
v1
u
a
e
,B
fz
rag
Sd
6
4
B
8v
c
z
9
K8
wg9
p$J
s
4
z
6
(Y
F,
.
2
Jc
518
fa
e -3
8
s
2
4
e
a
a!
4. .. .
.I.
%
y -;I
---. iI.3s
a
3
z&
B
v. .,\
%
3,
g3jra! jj
ii
b
4
-4
Of
at-
A-34
Smelt produced
carbonate
Brownstock
Extraction
Chlorine dioxide.
From the
bleaching.
The
C12/C102 tower, all filtrate tanks, and all bleach wash stages
are vented to a caustic scrubber.
vented to the atmosphere.
.
A-35
chwhead from
vwsphere
uldEvqxmtor8
.
i
:
:. .
;
:
3&i
ler....m.*--.
jy]
~.~..-.~I~.~--.-.~.
rpgijq
-..b--------:
---ToUmKilns
VW
:
:
-..
m-
f3ec8te.r
Sullamic
Tuqentina to Slorcrge
.w
Lisuld
.
-----
vrpor
B.
Figure A-17.
,rJt
41ii i:;
[3
ir
hb,..0
,\.--l -81
I
I
I
3
,
,
7
.
cr)
$
-4
ro
.
,...
0
c
g
*
E
0
b a
\ 5
----1
1;
-.
i
.U
.
,
.
.
.
. .*
gr
Q IA-..
i ! ---
-j
;
t
i
1.m
i
+
I
:....._.,......................
a $I
!P
B.
i
,i
.. . .._.................
*....
1
3c
,.._ +
._.........
.c 0
gL
I
.
E
,C
a
i#
....I
&C ...
a
i
....._.....
*--c3
d
j
.
. . . . . . . . . . . . . . . . . . . ._......_.___._
t
. . . ..
?.
.
..
A-37
. . . . . . . . . . . . ...!
2
:
8.
E
PI
4z
3
t
04
PI
L
4
A
z
g
4h
Gas samples
were collected at two locations, the vent from washer no. 2 foam
tank and the vent into the bleach plant scrubber.
locations and associated
Gas sampling
identifiers are shown in Table A-9. The
Site 4.
and
paper
pulp
paper, photocopy
A-38
Table A-9.
Location
Gas sampling
locations
Vl
v2
SPl
SP2
SP3
SP9
SPlO
SP5
SP6
SP7
SP8
SPll
WWl
WW2A
WWZB
WW3
WW4
WW5
WW6
WW7
A-39
Table A-10.
Constituent
Acetaldehyde'
Acetone'
Acetoneb
Acrolein'
ChlorineC
Chlorined
Chlorine dioxided
Chloroformd
Chloroformb
Formaldehyde'
Hydrogen chloride'
Methanol'
Methyl ethyl ketone'
Methyl ethyl ketoneb
Methylene chlorided
Methylene chlorideb
Propionaldehyde'
Carbon tetrachlorideb
n-Hexaneb
Chloromethaneb
2-Butanoneb
Tolueneb
Bromodichloromethane'
Dibromochloromethanef
Dimethyl sulfide
Dimethyl disulfide
a-Pinene
b-Pinene
p-Cymene
p-Cymene
a-Pinene
b-Pinene
a-Terpinol
Total Hydrocarbons'
Measurement Points
v2
Vl
I
0.098
0.001
0.316
0.001
0.043
0.004
0.
0.005
NA
0.041
NA
1.112
6.648
NA
NA
0.235
0.
0.045
0.003
0.002
NA
'0.011
4.839
2.265
0.194
0.009
0.019
0.000
-0
0.042
-0
0.001
0.012
0.001
0.
0.002
-0
0.001
-0
0.049
0.019
0.000
-0
0.001
-0
0.004
0.
0.001
0.920
-0.249
0.
1.376
0.396
0.508
O.f35
0.058
0.009
0.256
0.001
6.471
0.000
0.970
0.000
0.110
-0
27.306
1.437
A-40
MeasurementPoints
1-d
F-W*
(4
A--*
(4
Acaom 8
Acmhbl (4
plopkru@.h* b)
SPI
2s
SPZ
6.1
SP3
2.813
BP6
23.aS7
BP6
15.227
SP7
1.023
spa
0.111
SP6
5.1
SPlO
6.6
SPll
a,
wwl
0.64
ww24
0.37
ww2b
0.02
ww3
0.87
ww4
0.66
wws
0.64
1.1
1.4
0.26
0.47
0.25
0.197
0.077
0.047
0.15
0.06
0.2
0.6
0.02
16
31
0.61
0.4
0.1
2.3
0
<0.03
26
P.7S7
2.033
0.66
0.39
26
1.6
1.2
<0.03
=ZO.O3
<0.03
co.03
!u
<0.03
2.2
<0.03
26
SO.03
0.02
<0.03
31
<ox)3
2.2
<0.01
0.05
0.04
SO.03
<o.a
1.6
SO.43
0.077
0.287
1.647
1.467
9.66
0.807
0.127
0.07
0.67
0.44
1.4
<0.03
0.24
3.5
2.2
0.21
0.1
0.12
0.n
0.10
0.06
<o&3
<0.03
1.6
0.01
23
7.6
1.11
0.1
0.14
1.133
ND
ND
1.2
1.S
ND
116
2.1
ND
1.04
ND
1.4
1.6
ND
?D
ND
ND
Mayi
lhyl
kdom
(a
1.4
ND
a-PhbJ
ND
b-Phm4
(4
Me6lylamchbdda
(a)
chat bJ
60
Mdund
b)
0.001
Blwvwhm
@J
Cubondlul~
@)
0.044
0.001
~loml @J
ND
cumn Cl
EM=--
(b)
Dlbmmmeum
0
@)
l.l.l-Tllchhmhun
2--
lw
~~
@)
lw
4-M.w-+pnMonm-
@)
0
SW=@)
1.1.2.~T.mdlkm9
huu
@I
Qlum
@I
1.1.a1lkhlaa(huw
b
P
@)
7.zu
<0.60
7.133
<o.m
6.6
<o.w
w4
177
63
ND
ND
ND
0.014
O.W6
0.021
ND
0.157
366
392
10
ND
ND
ND
ND
ND
0.001
ND
0.008
ND
ND
0.001
ND
ND
0.011
ND
0.017
0.061
ND
0.S
ND
0.0-M
0.047
0.002
YD
ND
ND
0.006
0.024
ND
0.044
ND
0.007
ND
0.01
0.001
ND
ND
0.046
0
ND
ND
O.W3
0.010
0.001
ND
ND
ND
ND
O.cQl
ND
lmmwm 6b)
Vlnyi#Un
@)
0.001
ND
ND
rnlPXb+-
0.001
ND
ND
0.34
ND
0.064
@)
O.lP
AcdmN tw
BmmodkMocwn1.34khkrokn2m
l.PDkhbmb.nx~n
l.+Dkhloro2-buWm
3.11
EWmM@)
2-t+m0
nkhlomn -6lu.b.
1.2.~nkhbmpmpuN
Dlrnhyl ulfb
@J
oknhyi
dINma
ND
0.a
0.002
ND
ND
0.001
ND
ND
ND
ND
ND
@)
O.W3
ND
ND
ND
0.002
0.003
ND
ND
ND
ND
ND
ND
o.m2
ND
ND
ND
0.003
ND
1.6
ND
ND
ND
24
ND
ND
1.0
0.22
ND
ND
ND
ND
@J
0.011
a-Plnn
(b)
b-P!Mm
0.017
@J
Phmol 0
b-f+fWm. 0
a-1.Qld
(c)
-oWlkwdu~~*rr~m(HRC/OC)
b-ObWudn#mti6240
c - cmdmd
ND
0.001
ND
0.001
0.4
0.137
PCP-
ND
ND
0
6s)
tb)
iv
@)
udng 6270
ND
0.043
ND
ND
2.663
ND
3.36
ND
ND
0.06
ND
ND
0.857
2.06
ND
ND
O.Wl
SO.03
0.121
0
0.001
n-N.@J
Chbmw*un
0.15
<l.O
1.64
7.7
as2
aa
CO.60
pz
3.6
C0.W
<on3
<o.w
ND
66
63
3.731
2,442
211
WM
WwrI
3.4
1.6
ND
ND
<o.w
ao.60
<O.SO
co.60
a3
165
in Figure A-19.
Sampling
points for Site 4 are located in the pulping,
at the mill.
and pulp/liquor
Black
liquor is washed from the pulp in brownstock washers and sent to
delignification
tower.
Evaporator
condensates from chemical recovery are used as wash water for the
second stage. A fraction of the filtrate from the first stage
A-42
I
I
I
I
I
I
I
woakw
-w-w----
5
m
WrHp
c)wrJerl
-G
E
l
vaw
t,
-.
Figure
A-19.
~General
Prtkeqw Diagram
A-43
for
Site
NCGS
10
lrlcinefal~
&
&
s
:
i
I
I
i.. ,.
HU
w&
,*- Toczhulk
. ._- :$
II
iziklI
,
I
I
codrho I
I
CMhloll -1
W&U-q
sctoatu
- -to
Wbll
SlwnsllfQpI
( Hnfw WOA-I LZde )
Pulp IO
Wuhino
7,
12%ZOd
-of
A-20.
fgg
Figure
TLIIpUM-
.
.
.:..v?JIt0
\1
* ,----; B 4_........
Y
--,-M--4
----
171
-w-w--
4....
.
.
.
c+
8*.....t*
I1 CI
l
aH
g
8
*...-
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
C
fh
i?
OZ
z;f
m
$i
-4
Ceudkor
oxkRzMlwhRruqllol
I
To Dikle
NC-Y-n
To
I
I
:1 ti
?z
5
I
1 sfia
weekm
-- usuwb
d*
To
I-
To hoi
., ._,...._,.,e
l---\
I
I
I
:
!
I
;
z--pi I
I
I
I
I
j pt-
i
I
lEaka
-y-A
I
I
I
I
;-?
I
I
I
I
b
-A0
-es--
I
. . . . . . ... .. . . .. . ..
vq@g
I3
.Figure A-22.
I
I
oxygen washer and filtrate from the presses are used as wash
water on the brownstock washer.
The softwood line is similar to the hardwood line.
differences
The only
brownstock
press.
as wash water on the second stage washer in the hardwood
line,
Clean evaporator
condensates
steam stripped and the stripper effluent is then used for pulp
Other pulp mill foul condensates are also stripped in
washing.
furnace.
lime in a slaker.
a causticizing
The.bleaching
(No. 1 line) or
(No. 2 line).
(chlorine/chlorine
chlorine dioxide).
T?
-0
t
_-e-e
I
I
ESP
U
:
I
t
I
I
3;
;fpp
:
8
-s-c
.
*
Nc(3trlo
-----cm
Figure A-23.
4
c
A
;.
---s----
----~--------------~-~
?I
8
tgj
Hi
I I I
I
I
I
I
I
I
I
I
I I
I I
I I
I I
41
8 wo
-1
I
I
I
I
I
I
I
I
I
I
.........~~~---.-~-~~~~~~
~a
I
I
,;F.
.................
1.
ma--
I.
-------------4
c-I----
;
UJ
II. t
:,-....T 2
3
; f7
4 --------------~----------~--
we---
A-49
I ;.
II I ;
IL-,,,,,,,,
4.
I :
.ii
0I-0
a
e.Ba
5
8
i
i
extraction
stage for the hardwood line does not use oxygen, the
the mill uses technologies that might represent MACT for the
industry.
were to characterize
and weak black liquor, kraft hardwood and softwood bleaching with
chlorine dioxide substitution, screens/deknotters,
and kraft
included quantification
substitution.
Ejf
1&i
e
!
I ,%1
a6ta
g va3
,Qe
f
i\\
&k
cl
i
I
b--
$2
e-e-
----
-,
,__,,(,,__.__.._._.
. . .._..............
..\
33I-
..
A.
83
f3
:
a..m
a
. . .._....._.._...._....
I;
II
;;--
......-
----w-e-,
I
I
I
I
I
T
7
s
..........
I
I
B
Q
9 n L---- 4 asl4i-h
:&.....-.........I -- -
..i
.A
cn
c,
4
VI
VI
?i
0
k
Site
5.
A-52
Table A-12.
Location
Hardwood Plant
Brownstock washer vent
Vent into bleach plant scrubber*
HVl
Hv4
Softwood Plant
SVl
sv4
sv5
SV8
A-53
A-54
Table A-14.
-
Location
HP1
HP2
HP3
HP4
HP5
HP6
HP8
HP9
Wastewater Processes
Blow tank condensate
Evaporator condensates to steam stripper
Evaporator condensates to 0, delignification washer
Acid sewer
Caustic sewer
Scrubber effluent
WWl
WW2
WW3
WW4
WW5
WW7
A-55
SPl
SP2
SP3
SP4
SP5
SP6
Measurement
1-d
(a,
Fwldah+
hbtiva C)
hc.lcm
(4
Acmhln
w
-W*
b)
M.ul*
dlyl
kabn(a)
llm
(e)
b-Phm w
ti*ykmfhchl#oloml
(a)
Mdwml
-
(a)
HP1
HP2
HP3
3.300
3.033
2.337
0.~
O.&SO
tips
HPa
45.111
Points
npa
HPa
1.284,
1.500
ww2
ww3
w4
ww8
ww7
0.7a7
I.533
1.W?
0.~
2.133
2.067
0.~
0.01
l.OOU
7.433
0.~
0.143
O.aW
0.~
0.311
0.170
0.256
2700
0.710
l.aw
9.417
4.327
4.732
3.156
0.057
0.037
0.003
0.010
1.464
l.ad
0.W
0.043
0.010
0.~
0.017
0.183
0.273
0.130
0.211
ad42
0.270
0.27a
ll.Mo
4.143
0.387
4.042
1.403
24aa
10.222
1.362
1.~
12.037
0.157
l.eca
ND
0.011
0.~
0.403
0.101
ND
0.117
ND
ND
No
ND
O.CQP
NO
0.280
0.180
0.02a
0.870
0.557
0.023
l.loQ
1.213
8.503
0.771
4ad37
l.z3a
2350
18.233
3.700
ND
No
No
ND
ND
ND
<I.0
4.733
1.I#)
ND
0.333
No
0.111
ND
ND
<I.0
1.767
ct.0
ct.0
qt.0
et.0
1.333
<I.0
w
MO
Nolmp*d
udng wllok uwlB adymmqiPLc/cic)
l.M4
738
818
aa
224
Ma
101
SPl
WI
0.130
No-Nc.ldebcbd
. - cbulmu
HP4
ia.
17.333
ND
6.110
a.%
24.900
3.m
8Ps
2.311
0471
0.m
0.278
0.738
0.702
0.042
iads
ND
ND
0.043
No
ND
ND
O.#o
0.021
0.001
1411
zwo
0.434
0.351
35.444
zw2z?
1.022
1.433
12.333
ll.ooo
0.77s
om7
-
at.0
la3
s1.0
<I.0
07
0.333
703
sm.1
SP4
34da7
3l.Mo
<I.0
a8
SP3
ia.a73
et.0
277
SP2
703
w4
et.0
ct.0
1.872
Cl.0
215
Ma
176
o
0)
f------s-
A-57
LEGEND
ProcesslPu!pFlow
.-* .
b%m
----
I
1
,6
mua
8omNood~&chipe
EiEr
Megnewm-0ased
suaaecooking
bquof to olgaeiwr
stoun
I
--
5
9
Red
tlqua
Idi3
4 Accumuletolsyatuna
(?-@~4--@
WdU
-*
.*A
I+
-.
. .
..a
8wh
cl
1
t
i
Figure
A-27.
Wood
Preparation
and
Pulping
Process
at Site 5
A-59
:i .j-Liiii-j
..* ToAddPld
1 l-~~tia~to~,tim
AciiPblm
=!P. .. .
Aah
=-
El-
Fzkz
Z&isxJT&r~
J=sz
b SYlr
I
-we-.... ..... h w
Figure
4-28.
Chemical
Recovery
at Site
A-61
Table A-16.
Location
Green stack'
Roof vent2
No. 2 (E stage) combined seal tank vent
No. 2A (E stage) combined seal tank vent
No. 3 seal tank vent
Oxygen stage blow tank vent
Nuisance scrubber inlet
Vl
v2
v3
V3A
v4
v7
V8
' This vent includes the C-stage tower, washer, and seal tank (no
chlorine was added at the stage during the test), El-stage
washer, P/H-stage tower and washer, and D-stage tower.
* This vent includes the E2-stage washer and the D-stage washer.
A-62
Table A-17.
I
compound
Acetaldehyde'
Acetone'
Acetoneb
Acrolein'
ChlorineC
Chlorined
Chlorine dioxided
Chloroformd
Chloroformb
Pormaldehyde'
Hydrogen chloride'
Methanol'
Methyl ethyl ketone'
Methyl ethyl ketoneb
Methylene chlorided
Methylene chlorideb
Propionaldehyde'
Chloroformb
Chloromethaneb
2-Butanoneb
Methylene chlorideb
Acetoneb
a-Pineneb
p-Cymeneb
Hexac,hlorocyclopentadiene'
p-Cymene'
a-Pinene'
Total hydrocarbons
Sampling Locations
v2
Vl
I v7
I v4
I
0.004
0.009
NA
NA
0.585
0.240
NA
NA.
0.143
NA
NA
NA
0.057
0.002
NA
NA
22.25
-NA
NA
9.096
-NA
NA
1.887
-NA
NA
0.362
0.103
NA
NA
0.095
NA
NA
NA
0.006
0.002
-NA
NA
0.216
0.009
NA
NA
0.200
0.144
NA
NA
0.168
0.043
NA
NA
NA
NA
NA
0.085
-0.016
NA
NA
0.001
NA
NA
NA
0.005
0.003
NA
NA
0.082
0.048
0.074
0.001
0.124
-0.042
0.001
0.028
-0.911
0.438
A-63
0.072
3.389
V8
0.051
0.027
0.000
0.000
NA
NA
NA
NA
-0.000
NA
3.607
0.002
-NA
0.001
0.003
0.027
0.007
0.002
0.258
0.343
0.001
2.708
Table A-18.
compound
mdehyde'
Acetone'
Acetoneb
Acrolein'
Chlorine'
Chlorined
Chlorine dioxided
Chloroformd
Chloroformb
Formaldehyde8
Hydrogen chloride'
Methanol*
Methy:Lethyl ketone'
Methy:Lethyl ketoneb
Methy:Lenechlorided
Methylene chlorideb
Propionaldehydeb
Bromomethaneb
Chloromethaneb
Methy:Lenechlorideb
Acetoneb
1,2,3Trichloropropaneb
a-Pineneb
b-Pineneb
p-Cymeneb
Hydroquinone'
p-Cymenef
a-Pinene'
b-Pinene'
Total hydrocarbons"
Vl I v2
0.015
NA
0.039
NA
NA
0.001
0.176
NA
4.363
NA
3.867
NA
NA
0.396
0.030
NA
-NA
0.003
NA
NA
0.389
0.117
NA
0.031
NA
NA
-NA
-0.033
NA
0.003
NA
Measurement LOCatiOnS
1 v3 1 V3A 1 v4 1 v7
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.030
0.001
0.006
0.003
0.069
0.001
0.445
V8
0.018
0.014
0.001
0.000
NA
NA
NA
NA
-0.000
NA
2.175
0.001
0.000
NA
-0.001
0.006
0.046
0.250
A-64
0.007
0.160
0.005
1.309
0.031
0.014
0.132
0.003
0.531
0.037
0.001
3.298
TABLE
B-a.
EMISSION
CObfRXJNDs
compound
Names
301
l.o97,a2
Acetone
Methanol
____
---_-
_----
ethyl ketone
Hydrogen Sulfide
Dimethyl
disulfide
I0.24236
1
0
1.54827
0
0
0
0
0.065
0.01344
0
1
G
-a..
4
11.79168
_--13 .a".""
I
n
ii
0
O
I
henol
GZn
SL:
nkl nrrnr+lnr
a~;77~
ic;
. es
1
I
FACTORS
FOR
(g/Mg pulp)
302
1.09782
I 0.24236
I
0
I
11.54827
!
0
0
0
0
0.065
0.01344
0
INDIVIDUAL SOURCES
(CONTINUED)
303
EP Codes
304
15
15
3.5
0
15
0
0
0
0
0.065
0.2
0
1
*.4 F
1 .i
-.-
11.79168
-_. ---I ".-rv-w
c, 77finF1
I
n
ii
0
0
I 2.5
17.96728
-.--.I
n
0
0
0.15
0
0.15
A
v
I
n
"
n
B-65
306
10.77623
8.15671
0
u
0
lJ
0.065
0.2
0
0
u
0.00343
0.15355
0
1.5
v-v
2.6251
0
0.03803
0.22788
0.25477
;
0
0.15
0
305
10.77623
3.5
0
15
0
u
1
I 2.5
IS.27608
I
AND
n
"
n
2.6251
0
8.15671
0
0
"
n
0.00343
0.15355
0
0.03803
0.22788
0.33882
0
0
*
0.00209
0
n
II
0
1
'
II
;
0
-0.00209
0
I
"
II
TABLE
B-8.
EMISSION
COMPoumS
AND
A.3
REZEREXCES
1.
2.
3.
4.
5.
6.
7.
8.
9.
Trip Repogt.
20, 1991.
10.
Roy F. Weston.
Field Test Data Summary for Site 5.
Prepared for U.S. Environmental Protection Agency, Research
Triangle Park, NC. December 1992.
A-67
11.
A-68
APPENDIX
AIR
EMISSION
ESTIMATES
AND EMISSION
FACTORS
APPENDIX
AIR
EMISSION
ESTIMATES
AND EMISSION
FACTORS
INTRODUCTION
B.1
This
factors
appendix
from
estimated
presents
pulp
the methods
and paper
and presents
the resulting
of tables.
The developed
either
the
from
pulp
results
and paper
sampling
Appendix
B.2
mills
and
were based
program
on
at five
Data'from.
values.
at five mills
in a
are presented
in
DISCUSSION
emission
factors
emission
sources
results
of a test
involving
both
materials.
in the pulp
emission
factors
per
the
megagram
different
factors
Air
emission
industry
and liquid
were
for the
based
pulp
calculated
pulp
were
on the type
number
mills
of process
in units
of grams
produced
(g/Mg
used
These
of
to calculate
of emission
source.
of
on the
and paper
measurements
of air dried
factor
calculations
measurements
at a tested
Air
factor
emission
source
and the
procedures
Air
with
emissions
treatment
collection
Air
emission
tanks
tank
estimation
using
the direct
based
of the
on the direct
liquid
stream
the vent.
estimation
based
from
vent.
of the composition
associated
for a large
following:
measurement
*
and paper
procedures
depending
available
developed
at five different
Emission
of data
included
program
sampling
Several
were
vent
air emissions
types
factors
factors
literature
were
A.
Air
pulp)
air emission
and analysis
or on existing
program
air emission
processes
emission
a sampling
analysis
by which
manufacturing
series
the
from wastewater
on theoretical
and treatment
factor
losses
emissiofi equations.
from
and
model
systems.
estimates.for
a modification
collection
black
liquor
of the conventional
storage
storage
8.3
EMISSION
When
the vent
a specific
estimated
per
rate
emission
flow
therefore
per
grams
of emissions
factor
pulp
(grams
(megagrms
of the emission
per metric
can be
of the vent
rate
for
was measured
emission
of air dried
The units
day).
an
emission
rate
MEASUREMENTS
composition
or vent,
the mass
by the mass
tons
FROM VENT
and chemical
source
by dividing
day)
metric
FACTORS. ESTIMATED
factor
or
are
pulp
(g/Mg pulp) .
The
flow
rates
of pulp
used
factors
are based
on reported
typical
operating
conditions.
B-.4
EMISSION
When
FACTORS
direct
measurements
vent
to theoretically
units.
These
estimate
Since
depends
on temperature,
the
effect
rates
or on
MEASUREMENT
being
liquid
processed
equilibrium
a theoretical
of temperature
rate
can
from
the
on equilibrium
between
components
the
of emission
are,unavailable,
estimates
of the volatile
gas phase.
LIQUID
of the material
theoretical
and the
production
'.
FROM
measurements
be used
estimate
plant
ESTIMATED
representative
partitioning
in the calculations
the
liquid
partitioning
phase
factor
was developed
method
to
on the equilibrium
partitioning.
V'alues of the
property
partition
25 OC.
adjusted
data
base
Henry's
were
coefficient
This
value
used
in the process
for each
other
from
as an estimate
stream
of the partitioning
to represent
Coefficients
law constants
temperatures
compound.
B-2
EPA's
of.the
compound
value
of the
at a temperature
coefficient
using
may be
the Antoines
of
where,
%
T
Vapor
pressure
Temperature
A,BtC
Antoines
p25
Vapor
estimate
how
the
shows. the
Coefficients.
at 25 OC.
correlation
the Antoine's
vapor
equation
pressure
ratio
temperature
T to the vapor
This
of 25 OC.
The value
then
25
adjusted
is illustrated
of the Henry's
by the
of the Henry's
pressure
law
vapor
constant
pressure
at the
Law constant
from
ratio
the
to obtain
PT
equation
at
reference
(3).
=Hzs
(2)
(3)
+ 25
HT.( p 1
(1)
to
Dividing
in Equation
pressure
for
and Equation
of 25 OC.
of vapor
+C
Equation
can be used
at any temperature
the
coefficients
temperature..
coefficients
pr = EXp- B
C+T
with
for a temperature
2, yields
1 by equation
@Wig).
pressure
illustrates
(OC).
pressure
The values
the vapor
at temperature
temperature
data
base
is
an estimate
as follows:
(4)
25
where,
HT
Henry's
law constant
at temperature
H25
Henry's
law constant
at 25 OC.
B.5
METHOD
OF ESTIMATING
material
other
'is achieved
phase.
in the
in each
THE PARTITION
are mixed
FRACTION
in a tank,
of the tw'o.phases
If chemical
mixture
T.
equi&ibkium
leaving
B-3
IN MIXED'TANES
some
can partition
between
the tank,
of the
into
the partitioning
of
the volatile
partition
components
be used
plant/brownstock
as an example
chloroform
is emitted
that
for both
the process
for the
entering
spray.
the
washer
from
same
from
at the
concentration
pulp
or at the
can be estimated
phase
mol
mol
f=
from the
liquid
recycle
leaving
stream
that.the
inside
the washer
leaving
using
vapor
is
the washer,
the
ratio of the
to the component
phase
in conjunction
is illustrated
and
the
of the
liquid
in the exiting
liquid
This
in the
is
the washer
discharged
liquid
plant
of chloroform
that
By assuming
in.the
bleach
entering
assumed
stream
pulp.
vent
of the
and analysis
concentration
component
exiting
constant.
exiting
the
liquid
in the pulp
sampling
of chloroform
from
volatilized
pulp
It is also
the'washed
as the
emissions
in the
by
the concentration
of chloroform
is known
produced
the
can be described
shown
unknown
concentrations
washer
of two-phase
It is assumed
washer.
washer
coefficients.
The bleach
case,
into
with
the
Henry's
law
below:
vapor
liquid
(5)
d,
= H, 2
LP
where,
'f
The
the
HT
Henry's
Gas
Liquid
Atmospheric
Gas
The
overall
liquid
that
flow
rate,
fraction
T, atm-m3/mol.
m3/s.
pressure
density,
to
m3/s.
flow. rate,
exits
at temperature
gas phase
(assumed
to be one
atmosphere).
moles/m3.
of volatile
with
the
material
in the
gas is .estimated
B-4
entering
as follows:
process
!a1 n vent
QC ie
spray in
SP3
SP4,
SPl 0
vent
,n
recycle
SP24
Figure
B-l.
I
drain
Illustration
of Air Emissions
Plant/Brownstock
Washer.
B-5
from
a Bleach
F=f
(6)
l+f
where,
F
The fraction
reactor that
a numerical
AS
of chloroform
is vented
,
with
the
from
in the
f
emission
characteristics
using.the
per
vapor
factor
following
fraction
per
chloroform
of the
second
exits
in the vapor
entering
chloroform
by
(l+O.l)
orF=l/ll
can be estimated
and the
the
of chloroform
The fraction
is given
F =. O.l/
grams
second
remaining
The fraction
or
entering
eleven
per
second).
phase
/ (l+f)
that
one gram
and the
washer,
or f = 0.1.
F=
An air
the
assume
a washer,
(10 grams
water
exits
example,
enters
is f = l/10,
that
based
of volatiles
(7)
on the unit
lost
from
the unit
equation:
E=
CL F L
(8)
where,
E
Air
CL
Concentration
Fraction.of
the
that is emitted
Liquid
The
emission
flow
following
.calculating
an air
factor
(g/Mg pulp).
of the component
emission
stream
bleach
plant/brownstock
(g/m3).
liquid
phase
(m3/Mg pulp).
example
process
liquid
component
in the entering
as air emissions.
rate
liquid
in the
illustrates
rate.
samples
washer
were
the procedure
In the EPA
taken
identified
B-6
field
at the
for
test
entrance
in Table
A-15
program,
of a
as
Sampling
these
Point
SPl
samples
was
concentration
pulp/g
this
4.l
determined
of pulp
the
example,
in the stream
vent
concentration
to be the
same
of acetone
The concentration
to be '4.327 mg/L
The measured
slurry.
estimated
at Site
was
and the
determined
rate was
to be
90.5 m3/Mg
of acetone
in
pulp.
in the washer
as the concentration
in the
0.0163
In
is
inlet
pulp
slurry.,
The molar
volume
the
calculated
from
ideal
liquid
per
Mg of dry pulp
Pulp*
in the
Using
gas
law:
from
0.02887
is calculated
the washer
m3/mol.
is
The volume
as l/.0163,
of
or 61 m3/Mg
this
information,
the partition
fraction
may
be estimated
from Equation
(5) above
washer
vent
of acetone
as
follows:
f
= H, z
dG = 0.000169
1
0.02887
$$
= 0.0086,
(9)
where,
f
in the
Ratio of the exiting component
component
in the exiting liquid.
HT
Henry's
G/L
43
Gas
The
the
gas
Law
constant,
density,
overall
l/O.02887
fraction
is estimated
using
from
air
the
unit
using
emission
Equation
E=C,FL
factor
characteristics
atm-m3/mol.
liquid
entering
Equation
l+f
to the
flow
rate,
acetone
that
moles/m3.
of the
F=.f=
The
0.000169
gas phase
exits
with
(6) as follows:
0.0086
1'+ 0*0086
for acetone
and the
(10)
= 0.00857
fraction
lost
from
the unit
(8):
= 4.327 x0.00857
where,
B-7
x61.3
= 2.27 g/Mgpulp
(11)
Air
emission
factor,
2.27
CL
Concentration
=
.
liquid
B.6
COMPARISON
g/Mg
pulp.
of the component
flow
rate,
61.3 m3/Mg
OF ESTIMATED
in the
liquid,
4.327
g/m3.
pulp.
FROM LIQUID
AIR EMISSIONS
CONCENTRATIONS
Emission
samples
are generally
emission
data
estimates
which
B-l,
information
The table
samples
vent
from
streams
the
contains
test
in the bleach
SP3,
liquid
if accurate
where
data
are
liquid
and gas'flow
rates,
liquid
temperature,
and
Henry's
gases
law constants.
from
and
a material
liquid
balance
might
(Test Points
of the
SPl,
estimated
consistent
in the
FROM
and analysis
process
washer
with
sampling
valid
from
the
points.
emission
liQuid,
EMISSIONS
sampling
program.
obtained for:
AIR
on
of the process
air emissions
to produce
concentrations
OF
in
washer
for most
constituent
ESTIMATION
field.test
samples
are relatively
expected
based
plant/brownstock
and liquid
If data
vent
a bleach
sampling
information
estimates
plant/brownstock
would-be
no gas sampling
on measured
by the
of emissions
SVI,
on vent
sampling
where
4 of the EPA
As can be seen,
SP4).
based
estimates
B.7
Site
concentrations
estimates
Liquid
and
gas
liquid
air emission
plant,
vent
estimates
point
of
of calculating
based
is illustrated
from
softwood
means
estimates
in the
contains
obtained
in the
SP2,
This
measurement
in situations
gases.evaporate
estimates.
Table
accurate
concentraitons
the vent
factor
the most
emission
a.re available,
which
on direct
However,
factors.
constituent
based
streams,
be used
B-8
MATERIAL
BALANCES
are unavailable
there
are
to estimate
some
for both
situations
emission
Examples
rates.
would
include
TABLE
B-l.
where
this
situations
SAMPLES
approach
where
might
a large
yield
fraction
COLLECTED AT A BLEACH
WASHER1
Air
emission
factors
valid
results
of the volatile
PLANT/BROWNSTOCK
(g/Mg pulp)
compou.b~~
svla
8plb
8p2b
8p3b
8p4b,=
Acetone
3.04
2.27
2.51
1.67
7.82
1.22
1.46
1.178
93
146
147
125
34
PULP
WATER
WATER
PULP
IN
OUT
Methyl
ethyl
ketone
Methanol
45
IN
OUT
estimated
from process
A-15, using procedures
liquid measurements
described
in the
B-9
I
with
the
components
the
fraction
below
the
balance
B.8
of volatiles
detection
approach
MODEL
would
and treatment
an example
model
described
stream
the model
flow
collection
B.9
presented
OF AIR
TREATMENT
Emission
at pulp
Table
and Table
B-3
together
with
fraction
of volatiles
using
data.
revising
will
collection
described
for the
lists
the
above
and
The
system.
estimates
B-2 presents
and treatment
system
are
the
assumed
elements
within
system.
the model
wastewater
and anticipates
the emission
change.
EMISSIONS
and paper
concentrations
element
used
FROM
for wastewater
measured
the
valid
WASTEWATER
COLLECTION
AiJD
SYSTEMS
factors
summing
system
collection
here
at Or
a material
and treatment
and B-3.
and treatment
methods,
wastewater
the procedures
collection
is currently
ESTIMATION
systems
rates
wastewater
The Agency
factors
EPA used
B-2
is low or iS
to generate
for
factors
of the model
in Tables
where
PARAMETERS
wastewater
characteristics
air
test
not be expected
emissions
units,
to'the
of available
WASTEWATER'PLANT
In cases
to the air.
released
limits
In developing
waste
is released
of a stream
the
mass
estimated
the
plants
collection
were
of pollutants
flow
rate
emitted
following
F,
calculated
based
from
system
each
was
on
in the wastewater
of the streams.
from
emisqions
and treatment
streams
The total
estimated
collection
by
system
equation.
= c:
: ;
fq
t-1
fo,.,
where,
Ft
f ei
Fraction
unit i.
f,(H)
Fraction
of the initial constituent
that remains in the waste entering
of a constituent
B-10
,
emitted
to the
ai,r
air in
concentration
unit i.
TABLE
Waste
acid
wastewater
condensates
condensates
blow
blow tank
condensates
black
scrubber
FLOW
RATES
OF WASTE
STREAMS'
m3/Mg
bleach
plant
C or CD washer
bleach
plant
E washer
liquor
effluent
1
I
I
pulp
15
13
1.2
pulping
evaporator
evaporator
pulping
continuous
condensates
other
wastewater
turpentine
underflow
weak
PLANT
location
wastewater
digester
foul
MODEL
stream
caustic
clean
B-2.
gas condensates
0.16
pulping
pulping
storage
recycle
bleach
scrubber
bypass clarifier,
sent
directlv to aeration basin
11
0.06
.12
B-11
.
TABLE
B-4.
Name
Model
of unit
for calculations
Trench
trench
Drains
equilibrium
collection
Junction
box
Collection
Junction
main
box
Collection
main
Aerated
Non
aerated
impoundment,
manhole
cover
aerated
I
1 manhole
cover
impoundment
aerated
impoundment
aerated
Chemdat7
venting
Water7
impoundment,
non aerated
Chemdat7
Chemdat7
venting
impoundment,
clarifier,
Clarifier
headspace,
system models
Chemdat'l
impoundment,
B-12
air emissions
If
constituent
from
a waste
remain
in the waste
of the
fraction
unit
and
are the
stream
the
leaving
of loss
fraction
a unit
emitted
of a
of volatiles
is equal
in the waste
fraction
fq
source
the
stream,
of volatiles
one minus
only
collection
stream
that
to-the
product
entering
the
in the unit.
(13)
= f,l _ 1( 1 - fe,)
where,
the fraction of volatiles
in the waste
stream
wastewater
collection
or treatment
unit.
f oi
When
other
volatiles
than
the
air
adsorption,
these
calculation
of the
leaving
unit.
the
Once
the
wastewater
emission
are lost
from.a
such
emissions,
other
mechanisms
fraction
total
fraction
collection
and/or
must
for in the
treatment
be accountep
in the waste
emitted
system
In3
( MS PUlP
stream
from
Emission
The
(14)
Concentration
Ft
the
total
Several
wastewater
Reference
factor.
wastewater
flow
rate.
of volatiles.
fraction
emitted.
exampl'e calculations
collection
and treatment
4.
B-13
of emission
units
an
as follows:
where,
Ef
is calculated,
can be estimated
Jf9 PUJP 1
by mechanisms
and
of constituent
=Q
stream
as biodegradation
of volatiles
Ef
waste
leaving
factors
can.be
found
for
in
B.10
ESTIMATION
OF AIR
EMISSIONS
Weak
liquor
is generated
black
an estimated
normalILy collected
can
due to changes
large
this
approach
working
rate
there
to the
effect
stack
would
tend
from
working
between
the
tank,
storage
a further
all
.vapors would
.Table
B-4
containing.black
primarily
be vent
these
suggest,
thus,
emitted
of liquid
air
in the
larger
selection
'factors,
at a rate
equal
than
it is not
from the
effects
and due
which
contribution
whether
will
vent
be achieved
rates,
of the vent
to half
the
exchange.
the
it was assumed
for
During
in the tank,
than
a theoretical
constant
greater
for the
available
is more
moist
with
roof with
sources.
rate
liquid
especially
of these
were
It is also uncertain
alone.
the
a conical
of gas
at
is
and to-atmospheric
to develop
from
rate
by warm
the vent
be emitted
of liquid
the quantity
created
consideration
Considering
would
to the working
losses
e.quilibrium
in the tank
operations
wastewater
of air emissions
measurements
rates
exchange
will
to make
unit has
TANKS
are equipped
in the tank
necessary
emission
that
which
quantities
level
became
level
be equal
tanks
in the model
of liquid
Furthermore,
rate
liquid
it thus
to assume
would
storage
No emission
wastewater
realistic
vent
tank
vent.6
and
STORAGE
during
substantial
to estimating
the
use,
in the
central
source
in large
release
The
conditions.
LIQUOR
pulping
This
of 11 m3 per Mg dry p~lp.~
rate
vetits which
FROM BLACK
that
which
in
is
rate.
saturated
of the working
exchange.
lists
a set df emission
liquor.
determined
The emission
by the.volatility
compound.
B-14
factors
factor
of each
for storage
values
are
individual
tanks
Table
AIR
B-4.
EMISSION
FACTORS
FOR BLACK
Compound
LIQUOR
Fraction
emitted
emissions
acetone
0.001
2-butanone(MEK)
0.003
methanol
0.000
acrolein
0.002
acetaldehyde
0.002
alpha
0.055
beta
pinene
pinene
0.039
a-terpineol
0.010
chloroform
0.065
.methylene
chloride
0.061
formaldehyde
0.001
dimethyl
sulfide
0.100
dimethyl
disulfide
0.041
dichlorothiophene
0.017
dichloroacetonitrile
0.007
toluene
0.120
chloromethane
0.143
p cymene
0.254
proprionaldehyde
0.001
111 trichloroethane
0.261
B-15
STORAGE
TANKS
as air
B.ll
SELECTION
OF EMISSION
Emission
sources
factors
in the pulp
sotirces, emission
resulting
were
developed
and paper
factors
in multiple
for some
factors
by others
literature
sources.
Under
Agency
to select
the emission
represents
actual
protocol
was
emission
factor
established
value
protocol
takes
the
methods
test
test
consistency
used
of test
beach
can be used
factor
example,
acetone
at site
sample
4.
at site
factor
B-6.
factor
consistent
test
the
pulp
Because
value
was
the
vent
samples,
was
to retain
the
from
test
Site
almost
of the
and
available
with
results
from
results
an order
concluded
existing
tests
the
considerations
available
made
compared
B-l
an
For this
for two
and 1 vent
with
the
shown
that
in
the emission
is reasonably
Site
for Site
B-16
in Figure
samples
indicate
agreement
literature
data.
for selecting
were
3 but
concentration
that
adequacy
are available.
literature
the
performed,
taken,
literatureas
from
goal,
multiple
procedure
of magnitude
good
obtained
it was
the
in the
4 where
relatively
results
from the
data
this
and the
lists
were
the
of these
Examination
estimate
B-6
available
with
estimates
estimates
of the
The established
estimates
factor
These
best
measures
of a typical
emission
that
washer illustrated
multiple
lic$uid samples
Table
Table
been.
appropriate
of source
an emission,factor
when
goal
documentation,
plant/brownstock
emission
emission
source
have
the
in achieving
control
results.
as an example
value
available.
and test
one way
in existing
the most
for the
used,.quality
in selecting
The
factor
than
sources
circumstances,
to determine
factors
procedures
of the
To assist
to use
of emission
estimates
of the
emissions.
of these
in more
these
of
constituents.
for some
estimated
number
For many
calculated
previously
was
for a large
industry.
were
values
emission
Additionally,
FACTORS
lower
between
not with
of acetone
than
the
3 for both
the most
value
the
at site
3.
literature
liquid
appropriate
without
in
and
action
change.
TABLE
B-5.
CONSIDERATIONS
IN SELECTING-EMISSION
(LISTED IN ORDER OF' IMPORTANCE)
Quality of documentation
for on-site
sampling.
and quality
Vent
Type of test reported.
are preferred
to estimations
liquid measurements.
Source
characterization
Representativeness
Number
6
7
control
FACTORS.
procedures
measurements
of emissions
of vent emissions
from
and documentation.
of the source.
of compound.analyses
included
in the
field
test'.
B-17
TABLE
B-6.
EMISSION
FACTOR SELECTION
FOR ACETONE EMISSION
A SOFTWOOD BLEACH PLANT/BROWNSTOCK
WASHER.
Sample
Identification
Test
Sample
Twe
Site
Calculated
Emission
Factor
(g/M9 dry pulp)
SP3
Liquid
SVl
Vent
3.04
SPl
Liquid
2.27
SP2
Liquid
2.51
SP3
Liquid
1.67
SP4
Liquid
SPl
Emission
factor
Selected
emission
from
Liquid
literature
27
7.82
38
33
33
factor
B-18
FROM
Procedures
the
similar
emission
Table
factors
B-7
contains
model
typical
and paper
some
subset
The table
of pulp
each
the
source
estimating
the
emission
factor
estimated
Sources
factors
literature
sources,
which
estimate
emission
source
two
sources
was
with
were
emission
factorvalues
ratio
set
data
was
rate
the type
test
were
not
and data
found
for these
for
emission
measurements.
as a basis
data
also
as the basis
how the
of source
utilized
the-table
served
or describes
for emission
from
existing
to
Several
sources.
were
such
sequentially
handle
from
data
factor
to relate
sources
a product
stream.
factors
for
B-19
I
to
sources
in series
and
That
sources
when
Another
of wood.
These
the
ratio.
of the.
both'softwood
a hardwood/softwood
individual
for
Another
same.
for emission
processing
to establish
the
of factors
emission
for a
factor
characteristics
nearly
while
to estimate
available
of emissions
emission
as the emission
For example,
to establish
used
the
available
used
then
was
are
same
a series
from
of sources.
data
that
to be very
to establish
were only
approach
listed,
if the emissions
judged
was
hardwood
an
(e.g., pulping,
that
absence
the
data
approach
for which
involved
source
was to assume
no data
source
another
factor
approach
with
another
source,
were developed.
alternatives
One
process
field
factors
B-7.
(i.e., hardwood
factor
Data
A
contain
in Table
individual
to
for an emission
in the
sources.
industry.
described
of information
both
used
source,
of information
indluded
sources
be expected.to
of each
individual
identifies
was
sources
of
discussion.
and paper
would
of each
bleaching).
i.e.,
as the basis
or softwood),
unit
process
a description
number,
selection
following
individual
contains
used
in the
the
plants
of the
identifying
.
presented
characterize
pulp
were used.in
to this
the
relative
that
factors
were
used
to
TABLE
B-7.
EMISSION
SOURCES
Mili
Process
AND
DATA
SOURCES
Basis
Emission
Emission Point
Description
for
Factor
EP
Code
wood
WFJe
Bleaching
chlorine dioxide
generation
Not
used in Model
Plants
Bleaching
chlorine dioxide
generation
Not
used in Model.
Plants
Bleaching
C-stage
tower
vent
Extrapolateda
from
EP Code 71
Bleaching
C-stage
tower
vent
Extrapolated
from
EP Code 72
7'
Bleaching
C-stage
acid
sewer
'Ratioedb from EP
Code 8'
Bleaching
C-stage
acid
sewer
Assumed same as
EP Code 40
Bleaching
bleaching
effluent
10
Bleaching
bleaching
effluent
Not
13
Bleaching
bleach
plant
vents
14
Bleaching
bleach
plant
vents
Not
15
Bleaching
fugitives
16
Bleaching
fugitives
17
Bleaching
H-stage
(0.1~<0.5%)
vent
Assumed same as
EP Code 19
18
Bleaching
H-stage
(0.1~<0.5%)
vent'
Assumed same as
EP Code 20
19
Bleaching
H-stage
vent
(0.5-2%)
tower
Extrapolated
from
EP Code 151
20
Bleaching
H-stage
vent
(0.5-2%)
tower
Extrapolated
from
y Code 152
21
Bleaching
H-stage
(~0.5%)
B-20
,
vent
Not
used in Model
Plants
used in Model
Plants
used in Model
Plants
TABLE
B-7.
EMISSIONS
SOURCES
Mill
Process
AND
DATA
FACTORS
(CONTINUED)
Basis
Emission
Emission Point
Description
for
Factor
EP
Code
Wood
Type
22
Bleaching
H-stage
(~0.5%)
23
Bleaching
H-stage
(>2%) vent
24
Bleaching
H-stage
(>2%) vent
25
Bleaching
no H-stage
use,
vent
26
Bleaching
no H-stage
use,
vent
Bleaching
vent
H-stage
(O.l-<0.5%)
wastewater
H-stage
(0.1-X0.5%)
Not
used in Model
Plants
H-stage
effluent
(0.5-2%)
Not
used in Model
Plants
wastewater
30
31
Bleaching
H-stage
effluent
(0.5-2%)
Bleaching
H-stage
wastewater
(<O .5%)
Not
Bleaching
H-stage
(<O.5%)
I
32
wastewater
Ik
33
Bleaching
H-stage
(>2%)
wastewater
(>2%) wastewater
used in Model
Plants
I
Not used in Model
Plants
34
S'
Bleaching
H-stage
35
Bleaching
no H-stage
wastewater
use1
Bleaching
no H-stage
.wastewater
use,
Not
used in Model
Plants
38
'Bleaching
bleaching
effluent
w/slimacide
Not
used in Model
Plants
Bleaching
bleaching
effluent
w/slimacide
Not
used in Model
Plants
-
B-21
TABLE
B-7.
EMISSIONS
SOURCES
Mill
Process
AND DATA
FACTORS
Basis
Emission
Emission Point
Description
for
EP
Code
wood
Type
39
Bleaching
ClO, subst.
sewer
(0%) acid
Ratioed from EP
Code 40
40
Bleaching
ClO, subst.
sewer
(0%) acid
41
Bleaching
ClO, subst.
sewer
(0%) caustic
Ratioed from EP
Code 42
42
Bleaching
ClO,
(0%) caustic
subst.
sewer
Factor
43
Bleaching
ClO, subst.
effluent
(0%)
44
Bleaching
ClO, subst.
effluent
('0%)
45
Bleaching
ClO,
vent
subst.
(0%) tower
Extrapolated
from
EP Code 75
46
Bleaching
ClO,
vent
subst.
(0%) tower
Extrapolated
from
EP Code 76
47
Bleaching
ClO, subst.
sewer
(100%) acid
48
Bleaching
ClO, subst.
sewer
(100%) acid
49
Bleaching
50
Bleaching
Bleaching
ClO, subst.
effluent
51
(CONTINUED)
'H
(100%)
52
Bleaching
53
.H
Bleaching
ClO,
vent
54
55
subst.
.
(100%) tower
Extrapolated
from
EP Code 79
Bleaching
'ClO, subst.
vent
(100%) tower
Extrapolated
from
EP Code a0
Bleaching
ClO, subst.
sewer
'
B-22
(high)
.
acid
Ratioed from
Code 56
EP
TABLE
B-7.
EMISSIONS
SOURCES
AND
DATA
FACTORS
Emission Point
Description
Mill
Process
(CONTINUED)
Basis
Emission
for
EP
Code
Wo'od
Type
56
Bleaching
ClO, subst.
sewer
57
Bleaching
ClO, subst.
(high)
caustic sewer
58
Bleaching
ClO, subst.
(high)
caustic, sewer
Site
'59
Bleaching
ClO, subst.
effluent
(high)
Not
used in Model
Plants
60
Bleaching
ClO, subst.
effluent
(high)
Not
used in Model
Plants
61
Bleaching
ClO, subst.
vent
(high) tdwer'
Extrapolated
from
EP Code a3
62
Bleaching
ClO, subst.
vent
(high) tower
Extrapolated
from
EP Code a4
63
,Bleaching
ClO, subst.
sewer
(low) acid
Site 1 (HP2),
Site 4 (WW4)
64
Bleaching
ClO, subst.
sewer
(low) acid
65'
Bleaching
ClO, subst.
(low)
caustic sewer
Site 4 (WWS),
Site 1 (HP3)
66
Bleaching
ClO, subst.
(low)
caustic sewer
67
Bleaching
ClO, subst.
effluent
(low)
Not
used in Model
Plants
68
Bleaching
ClO, subst.
effluent
(low)
Not
used in Model
Plants
69
Bleaching
ClO, s&t.
vent
(low) tower
Extrapolated. from
EP Code a7
70
Bleaching
.(low) tower
Extrapolated
from
EP- Code 88
71
Bleaching.
'Clo, subst:
vent
C-qtage
(high)
washer
B-23
acid
vent
Site
Factor
3 (SP6, WW6)
Ratioed from EP
Code 58
3 (SP7, WS)
TABLE
B-7.
EMISSIONS
SOURCES
Mill
Process
AND
DATA
FACTORS
(CONTINUED)
Basis
Emission
Emission Point
Description
for
Factor
EP
Code
Wood
VP=
72
Bleaching
C-stage
washer
73
Bleaching
C-stage
seal
tank
vent
Extrapolated
from
EP Code 71
74
Bleaching
C-stage
seal
tank
vent
Extrapolated
from
EP Code 72
'75
Bleaching
ClO, subst.
vent
(0%) washer
76
Bleaching
ClO, subst.
vent
(0%) washer
77
Bleaching
ClO, subst.
tank vent
(0%) seal
Extrapolated
EPCode76
78
Bleaching
ClO, subst.
tank vent
(0%) seal
Extrapolated
from
EP Code -75
79
Bleaching
ClO, subst.
washer vent
(100%)
80
Bleaching
Cl02 subst.
washer vent
(100%)
81
Bleaching
C102 subst.
tank vent
(100%)
seal
Extrapolated
from
EP Code 79
82.
Bleaching
ClO, subst.
tank vent
(100%)
seal
Extrapolated
from
EP Code a0
a3
Bleaching
ClO, subst.
washer vent
(high)
Site
84
Bleaching
ClO, subst.
washer vent
(high)
Site 4 (SV4),
Site 1 (SPS,
SP6)
as
Bleaching
ClO, subst.
tank vent
(high)
seal
Extrapolated
EPCode83
86
Bleaching
ClO, sub&.
tank vent
(highj
seal
Extrapolated
from
EP Code a4
a7
Bleaching
ClO, subst.
vent
(low) washer
88
Bleaching
Cl02 sub&..
(low) washer
vent
B-24
vent
Site
(ma,
from
WW4)
from
1 (Hp2)
Site 1 (SP6),
Site 2 (P6),
Site 4 (SPS)
TABLE
B-7.
EMISSIONS
Mill
Process
SOURCES
AND
DATA
FACTORS
(CONTINUED)
Basis for
E'mission Factor
Emission Point
Description
EP
Code
Wood
Type
a9
Bleaching
ClO, subst.
tank vent
(low) seal
Extrapolated
from
EP Code 87
90
Bleaching
ClO, subst.
tank vent
(low) seal
Extrapolated
from
EP Code 88
91
Bleaching
El-stage
(0%) tower
vent
Extrapolated
from
EP Code 93
92
Bleaching
El-stage
(0%) tower
vent
Extrapolated
from
EP Code 94
93
Bleaching
El-stage
vent
(0%) washer
Ratioed from EP
Code 94
94
Bleaching
El-stage
vent
(0%) washer
.
9s
Bleaching
El-stage
vent
Extrapolated. from
EP Code 93
96
Bleaching
El-stage
vent
(0%) seal
Extrapolated
from
EP Code 94
Bleaching
El-stage
vent
(100%) tower
Extrapolated
from
EP Code 99
98
Bleaching
El-stage
vent
(100%) tower
Extrapolated
from
EP Code 100
99
Bleaching
El-stage
vent
(100%) washer
100
Bleaching
El-stage
vent
(100%) washer
101
Bleaching
El-stage
(100%) seal
tank vent.
Extrapolated
from
EP Code 99
102
Bleaching
El-stage
(100%) seal
tank vent
Extrapolated
froin
EP Code 100
103
Bleaching
El-stage
vent
(high) tower
Extrapolated
from
EP Code 105
104
Bleaching
El-stage
vent
(high) tower
Extrapolated.from
EP Code 106
10s
Bleaching
El-stage
vent
(high) washer
Site
97
B-25
tank
Ratioed from EP
Code 100
Site
5 (SPS)
4 (HP9, WWS)
TABLE
B-7.
EMISSIONS
SOURCES
AND DATA
FACTORS
(CONTINUED)
1
EP
Code
wood
Type
106
Mill
Process
Bleaching
Basis
Emission
Emission Point
Description
El-stage
vent
Site
(high) washer
for
Factor
4 (SVS,
-61,
-Site 1 (SP7)
Bleaching
El-stage
(high)
tank vent
seal
Extrapolated
from
EP Code 105
Bleaching
El-stage
(high)
tank vent
seal
Extrapolated
from
EP Code 106
Bleaching
El-stage
vent
(low) tower
Extrapolated
from
EP Code 111
Bleaching
El-stage
vent.
(low) tower
Extrapolated
from
EP Code 112
111
Bleaching
El-stage
vent
(low) washer
Site
1 (HP3)
112
Bleaching
El-stage
vent
(low) washer
Site
1 (SP7)
113
Bleaching
El-stage
vent
Extrapolated
from
EP Code 111
El-stage
vent
(low) seal
tank
Extrapolated
from
EP Code 112
Dl-stage
(0%) tower
vent
Extrapolated
from
EP Code 117
(0%) tower
vent
1 Bleaching
1 Dl-stage
Bleaching
(0%) washer
-G-p-
Dl-stage
vent
Ratioed from EP
Code ii8
Bleaching
Dl-stage
vent
(0%) washer
Extrapolated
from
EP Code 116
m/
Bleaching
Dl-stage
vent
'Extrapolated
from
EP Code 117
116
117
Site
(P6 DG)
120
,
Bleaching
Dl-stage
vent
Extrapolated
frdm
EP Code iis'
121
Bleaching
Dl-stage
vent
(100%) tower
Extrapolated
from
EP Code 123
122
Bleaching
Dl-stage
vent
(100%) tower
Extrapolated
from
EP Code 124
B-26
TABLE
B-7.
EMISSIONS
SOURCES
Mill
Process
AND
DATA
FACTORS
(CONTINUED)
Basis for
Emission,Factor
Emission Point
Description
EP
Code
Wood
TYPO
123
Bleaching
Dl-stage
vent
(100%) washer
124
Bleaching
Dl-stage
vent
(100%) washer
125
Bleaching
Dl-stage
(100%)
tank vent
seal
Extrapolated
from
EP Code 123
126
Bleaching
Dl-stage
(100%)
tank vent
seal
Extrapolated
from
EP Code 124
127
:K
Bleaching
Dl-stage
vent
(high) tower
Extrapolated
'from
EP Code 129
128
Bleaching
Dl-stage
vent
(high) tower
Extrapolated
from
EP Code 130
129
Bleaching
Dl-stage
vent
(high) washer
130
Bleaching
Dl-stage
vent
(high) washer
131
Bleaching
Dl-stage
(high)
tank vent
seal
Extrapolated
from
EP Code 129
132
Bleaching
Dl-stage
(high)
tank vent
seal
Extrapolated
from
EP Code 130
133
Bleaching
Dllstage
(low) tower
Extrapolated
from
EP Code 135
(low) tower
Extrapolated
from
EP Code' 136
vent
134
Bleaching
Dl-stage
vent
Ratioed from EP
Code 130
.
Site
Site
3 (SP8,
SPll)
1 (HVIA)
13s
Bleaching
Dl-stage
vent
(low) washer
136
Bleaching
Dl-stage.
(low) washer
(low) seal
Extrapolated
from
EP Code 135
vent
137
Bleaching
Dl-stage
vent
138
Bleaching
Bleaching
vent
139
tank
E2-stage
tower
vent
Extrapolated from
EP Code
B-27
137
141
TABLE
B-7.
EMISSIONS
SOURCES
Mill
Process
AND DATA
FACTORS
(CONTINUED)
Basis
Emission
for
Factor
EP
Code
Wood
Type
140
Bleaching
EZ-stage
tower
141
Bleaching
E2-stage
washer
vent
Ratioed from EP
Code 111
142
Bleaching
EZ-stage
washer
vent
Ratioed from EP
Code 112
143
Bleaching
E2-stage
seal
tank
vent
Extrapolated
from
EP Code 141
144
Bleaching
EZ-stage
seal
tank
vent
Extrapolated
from
EP Code 142
145
Bleaching
DZ-stage
tower
vent
Extrapolated
from
EP Code 147
146
Bleaching
DZ-stage
tower
vent
Extrapolated. from
EP Code 148
147
Bleaching
D2-stage
washer
vent
148
Bleaching
D2-stage
washer
vent
149
Bleaching
DZ-stage
seal tank
vent
Extrapolated
from
EP Code 147
150
Bleaching
DZ-stage
seal tank
vent
Extrapolated
from
EP Code 148
151
Bleaching
H-stage
. vent
(O.S-2%)
washer
Ratioed from EP
Code 152
ISi
Bleaching
H-stage
vent
(0.5-2%)
washer
Site 5 (P7.DG),
Site .2 (Pa)
153
Bleaching
H-stage
(0.502%)
tank vent.
seal
Extrapolated
from
EP Code
151
154
Bleaching
H-stage
seal
Extrapolated
from
EP. Code 152
Emission Point
Description
tank
(0.
Extrapolated
from
EP Code 142
vent
S-2%)
vent
155
Digesters
batch
156
Digesters
continuous
relief
B-28
gases
relief
Site
4 (WWl)
TABLE
EP
Code
'Wood
W?e
EMISSIONS
B-7.
SOURCES
Mill
Process
AND'DATA
FACTORS
(CONTINUED)
Basis
Emission
Emission Point
Description
for
Factor
157
NCG
System
batch turpentine
condenser
158
s;
NCG
System
cont. turpentine
condenser
Site
159
,
Tall Oil
Recovery
batch
Reference
160
Tall Oil
Recovery
continuous
vent
Reference
161
NCG
System
turpentine
condensates
162
NCG
System
turpentine
(IMP)
condensates
Assumed the
as EP Code
163
Digesters
batch
blow
condensates
Site
164
Digesters
batch
blow
condensates
1.65
Digesters
batch
blow
gases
166
Digesters
batch
blow
gases
167
Digesters
continuous
blow
gases
168
Digesters
continuous
blow
gases .I
169,
Digesters
continuous
blow'gases
ND
170
Digesters
continuous
b,low gases
ND
vent
3 (ww3)
Site 3 (WW3)',
Site 1 (WW3)
same
161
1 (WWl, Wl)
Site
2 (WW4,
SP1) ,
Site 3 (WW2A)
Extrapolated
from
EP Code 177
Site
I
site
3 (WW24,
SPl)
4 (HPl)
Ratioed from EP
Code 167
Ratioed from EP
Code 170
Site
1 (SP2,
SPl),
Site 3 (WW2B)
171
Digesters
continuous
condensates
blow
I
Assumed the
as EP Code
same
173
172
Digesters
continuous
blow
condensates
I
Assumed the
as.EP Code
same
174
173
Digesters
continuous
blow
condensates
ND
B-29
Site
4 (WWl)
TABLE
B-7.
EMISSIONS
SOVRCES
Mill
Process
AND DATA
FACTORS
Emission Point
Description
(CONTINUED)
Basis
Emission
for
EP
Code
Wood
WPe
174
Digesters
continuous
blow
condensates
ND
175
Knotters
hood
vent
Extrapolated
from
EP Code 177
176
Knotters
hood
vent
Extrapolated
from
EP Code 178
177
Washers
hood.vent
Site
178
Washers
hood
vent
iai
Washers
deckers/screens
Extrapolated
'from
EP Code 177
182
Washers
deckers/screens
Extrapolated
from
EP Code 178
183
Washers
foam
tank
tank
Site
Factor
3 (WW2b)
4 (HVl, HP3,
HP6, HP4),
Site 1 (HPl)
Site
Site
(P4)',
(SP2)
Extrapolated
from.
EP Code 178
184
Washers
foam
185
Evaporators
vent
186
Evaporators
vent
la7
Evaporators
condensates
Site 1 (WW2),
Site 4 (WW2)
188
Evaporators
condensates
Site 3 (WW4,
WW7)r
Site 5 (WW2, DG)
189
.K
Evaporators
surface cond.
condensates
190
Evaporators
surface cond.
condensates
191
Oxygen
Delig.
192
Oxygen
Delig.
Site
Site
.blow tank
blow
tank
B-30
Site
4 (WWZ)
(WWZ, DG)
4 (WW3)
Ratioed from EP
Code la9
Extrapolated
from
BP. Code 193
Site
1 (SVl, SP4)
TABLE
B-7.
EMISSIONS
SOURCES
Mill
Process
AND DATA
FACTORS
(CONTINUED)
Basis
Emission
Emission Point
Description
for
Factor
EP
Code
Wood
Type
193
Oxygen
Delig.
washer
tank
vent
194
Oxygen
Delig.
washer
tank
vent
197
Site 4 (HP2,
HP4),
Site 1 (HPl)
198
Site
Ratioed from EP
Code 194
Site
Site
1 (SP4, SP5)
3 (SP3,
SPlO),.
1 (SP2),
Site
4 (SP6)
199
Sulfite
Digesters
batch
relief
gases
Extrapolated
from
EP Code 206
200
Sulfite
Digesters
batch
relief
gases
Extrapolated
from
EP Code 207
201
Sulfite
Digesters
batch
blow
gases
Extrapolated
from
EP. Code 206
202
Sulfite
Digesters
batch
blow
gases
Extrapolated
from
EP Code 207
203
Sulfite
Evaporators
multi
effect
evap.
vent
204
Sulfite
Evaporators
multi
effect
evap.
vent
20s
S-
Sulfite
System
turpentine
NCG
condenser
206
.H
Sulfite
Washer'
hood
vent
207
Sulfite
Washer
hood
vent
210
Sulfite
Washer
decker
vent
Extrapolated
from
EP Code 206
211
Sulfite
Washer
decker
vent
Extrapolated
from
EP Code 207
212
Sulfite
Digesters
blow
condensates'
B-31
Site
(PI DG)
Ratioed from EP
Code 213
TABLE
B-7.
EMISSIONS
SOURCES
Mill
Process
AND DATA
FACTORS
(CONTINUED)
Emission Point
Description
Basis
Emission
condensates
Site
for
Factor
EP
Code
Wood
'W-P
213
Sulfite.
Digesters
blow
214
Sulfite
Washer
waste
liquor
215
Sulfite
Washer
waste
liquor
216
Sulfite
217
Sulfite
weak
218
Sulfite
Oxygen
Delig.
blow
tank
219
Sulfite
Oxygen
Delig.
blow
tank
220
Sulfite
Oxygen
Delig.
washer
tank
vent
221
Sulfite
Oxygen
Delig.
washer
tank
vent
228
Sulfite
Washer
foam
tank
vent
Extrapolated
from
EP Code 220
229
Sulfite
Washer
foam tank
vent
Extrapolated
from
EP Code 221
230
Sulfiti3
Washer
improved
Sulfite
improved
washer
vent
231
(Pl DG)
Ratioed from EP
Code 217
Site
black liquor
storage tank
5 (P2 DG)
Extrapolated
from
EP Code 220
Assumed the
as EP Code
washer
same
192
vent
5 (P4 DG)
Ratioed-
Code
Site
from
231
EP
3 (SP2)
Washer
232
Washers
improved
washer
vent
233
Washers
improved
washer
vent
234
S'
Bleaching
scrubber
effluent
B-32
Ratioed from EP
Code 233
Site
1 (SPl, SP3)
Site 3 (wWl)t
Site 1 (WW6)
TABLE
B-7.
EMISSIONS
SOURCES
Mill
Process
AND DATA
FACTORS
Emission Point
Description
(CONTINUED)
Basis
Emission
for
EP
Code
wood
WPe
235
Kraft
covered weak
liquor tank
black
Site 1 (SP2),
Site 4 (SP2),
Site 3 (SP3,
SPlO)
236
Kraft
covered weak
liquor tank
black
Site 1 (HPl),
Site 4 (HP2)
,237
Sulfite
covered weak
liquor tank
black
Site
301
Bleaching
EZ-stage
vent
(low) tower
Reference
302
Bleaching.
E2-stage
vent
(low) tower
Reference
303
Bleaching
E2-stage
vent
(low) washer
Reference
304
Bleaching
EZ-stage
vent
(low) washer
Reference
30s.
'H
Bleaching
E2-stage
vent
Reference
306
Bleaching
E2-stage
vent
Reference
307
Bleaching
EZ-stage
vent
(high) tower
Reference
308
Bleaching
EZ-stage
vent
(high) tower
Reference
309
Bleaching
EZ-stage
vent
(high) washer
Reference
310
Bleaching
EZlstage
(high) washer
Reference
311
'Bleaching
E2-stage
(high) seal
tank
vent
Reference
312
Bleaching
EZ-stage
(high)
tank vent,
Reference'
jl3
Bleaching
E2-stage
vent
Reference
Factor
(P2 DG)
vent
B-33
seal
(100%) tower
TABLE B-7.
Basis for
Emission Factor
EP
Code
wood
Type
Mill
Process
314
:3
Bleaching
EZ-stage
vent
(100%) tower
315
:K
Bleaching
E2-stage
vent
(100%) washer
316
Bleaching
E2-stage
vent
(100%) washer
'317
Bleaching
Reference 8
318
Bleaching
Reference ti
401
oxygen
Delig.
blow tank
Reference 9
402
Oxygen
Delig.
blow tank
Reference 9
403
Oxygen
Delig.
Reference 9
404
Oxygen
Delig.
Reference 9
405
Bleaching
EOP-stage
vent
(100%) tower
Reference 9
406
Bleaching
EOP-stage
vent
(100%) tower
Reference 9
407
,H
Bleaching
EOP-stage
tank vent
(100%) seal
Reference 9
408
Bleaching
EOP-stage
vent
(100%) washer
Reference 9
409
Bleaching
EOP-stage
vent
(100%) washer
Reference 9
410
Bleaching
EOP-stcge
tank vent
(100%) .seal
Reference 9
DG = Disolving grade;
Emission Point
Description
Reference 8
'Reference
Reference 8
H = Hardwood;.S = Softwood
estimate
units
for other
emissions
in the
developed
using
pr0grams.l'
factors
series
but
complete
can be found
determinations
those
factor
for that
estimated
points
other
data
vent
were
emission
based
point.
presented
here
will.be
set
of these
some
factors
Of
under,other
associated
direct
data
heavily
When
vent
were
was
EPA
ratios
and
emission
identified
for an emission
no vent measurement
described
being
factor
measurements.
of an emission
data
above
were
collected
were
used
found,
instead.
for emission
The list
manufacturing.
updated
with
in the determination
and paper
pulp
factors
than
are currently
with
for
available
latter
developed
shortcomings
data
associated
were
d0cument.l'
on the procedures
measurement
This
units.
measurement
weighted
data
of the development
separate
by methods
values
Additional
discussion
in
where
emission'models
the
when
point,
for'all
recognizes
The Agency
Consequently,
not
analytical
situations
in the futurewhen
of emission
warranted
by new
data.
B.12
EMISSI6N
This
group
FACTORS
section
presents
of individual
described
summary
for each
constituents
previously
document.12
emission
in this
Separate
source
of emission
a listing
ati pulp
document,
emission
listed
factors
and paper
mills
and as detailed
factors
in Table
B-35
B-7.
developed
using
for a
procedures
in a separate
are presented
in Table
B-8
TABLE B-8.
Compound
EMISSION
AND
COMPOUNDS
(g/Mg Pulp)
EP Codes
19
0.14272
0.03659
70
70
0.01317
Names
Acetone
SOURCES
20
1
6.30142
Methyl
ethyl
0.24772
ketone
I
SC hrr
mrrl ii
dr
e-*&d--
0
n
v. *a&b
n
Aa
I
n
"
I
I
I
I
I
I
7G
-4
n
"
I
I
I
I
I
I
25
-n
_0258
-.----
1.4
I
I
I
I
0
0
I o.loda
.-- -in
2,4,6-Trichlor--'---'
Chlorophenol
Bet; "1---IlAcrolein
IIAcetaldehvde
'
I
IO.6
I
n
u
n
I
I
I
"
n
0.02385
0
0.49
n n-73,
B-36
n3n77
0.02
II
TABLE
rnmantirld Names
B-8.
40
B-37
41
EP Codes
I
A2
AND
45
4Q
TABLE
B-8.
(g/Mg
COMPOUNDS
II
IIcOF-,,hA
LLL~V.."..
..-.
--Names
a+ h"O
EP
47
2.7
500
. .
._I,,~~~(..,:rr+?.aPnlorlaC
:nercaptan
-..----J:L
sulfide
methy. disulfidt
ainene
...,ric Acid
-__ini dioxide
-----,'I chloride
f-h
AQ
TV
xi
AQ
Codes
7~7
-.
7.9--
3.5
500
_ _
300
300
-~
1
,
I
I
,
017
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
3.3
0.07
0.24077
0.36852.
0
0
0
6
--
1 drhvrlr
PL wr-w.-------x -DpPWVnW-PP
LbY*".* YL
Total
Total
TRS
I
I 0.0022
I
i
1 7.6171
n ?I3
sLJ
0.72253
0
0
0
0
0
0
0
3.3
0.2
0.7
I .l.l
I
I
I
I
--n
0.2
n-7
-_.
1.1
0.16
3
016
0
0
nnnn7
l n.;-
, n1. l-lonnk5
o---
1
I 0.16
3
0.6
0
0
0
0
0
I
0
0.01344
50
105
0.50167
0.05725
HAP
UOC
A 7flfJflI
51,.,-*a, e-m.----
519.7209
0
CI
r;3Ql
I11
B-38
, O-00006
- -,-~- _ _ ,
__..~
s-e.---~~ -m.-c_520.2709
520.1791~314.0008~
-.-.-_ _- -___--1314.1286
- -----
54
I
I 0.07319
10.623-2-2
nt
U.-l
11
II
0.00103
0
0
0
0
0
0.02015
50
125
0.14333
1.93089
I
, O.OQ003
- _ -~---
z
Ip;,-.
53
0.89839
Acro1ei.n
Acr+aldchvde
50
'-------------ketone
I------~U~~~rnnrnbthyl
Sulfide
nha
I
I
AND
(CONTINUED)
.*bw.--.----
pulp)
714.3286
0.04416
0.11249
0
0.07436
0.06
o
62.91806
20.2505
0.00128
0
0.00002
0
0.06
;;
,,
53.87992
3.71864
TABLE
B-8.
-*3imethvl----- sulfide
L-- ~~ _I
Dimcthvl
disulfide
Rlpha pinene
d
L Hvdro Chloric
Acid
_
__.._
_-.-L
--
0
0
0
0
I
I
imz-- -
Chlorine
rChlori-a
,A.- riinvidc
w-v----chloride
Methyl
___---~~
Chloroform
0
n
-I
1
I
'.
I
I
l
----
=----.-
EP codes
I
ca
0
0
0
0
0
0
0
.n
0
0
I
I
3.3
0
0
0
0
0
I
I
3.3
0.59376
0
0.09609
-. .
1.1
Chlorc
Rrta
k
V. I
1.1
f-
o.n;;oos I
10.00003
L-3
I
I
PCP-EF
2,4,6-Trichloro~henol
I.96125
0
____,,
c-
2.2&4
1 Rrnz
-,
me
AND
0.6
10.00006
I
B-39
0.6.
I
10.00006
I
I
0
l-l
0
n
0.01344
0.02015
50
10s
---
lo.50167
1 1.16436
L
I
I
50
125
II
II
1I 0.14333
11
1 I.93089
!I
TABLE
Compound
B-8.
Names
t.rmtmno
I-
athnn
tettachlotide
-W.-J- ._---~~-
im-+hvl sulfide
7. disulfide
II; ;--- --*
.pha
pinene
II
A.,
ll,;;;-i~;;loric Acid
dioxide
EP Codes
63
64
2.2
460
I
1
1
200
AND
65
I
2
100
0
66
I
69
1 0.14272
30
28.73723
70
IO.03659
2.07739
0.3
-0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
210
0
210
0
105
.o
B-40
TABLE
B-8.
B-41
AND
B-8.
TABLE
EMISSION
COMPOUNDS
EP
n~~nd Name3
Camp,--.- -.Acetone
Methanol
tetrachloride
ethvl--x- .
ketone
,- - ---Sulfide
'IHydrogen -___~~
mrrrant
an
.
..--w-c ----
77
78
I
0.35921 (1.40091
311.2622122.50088
0
Carbon
~Methvl
0.54378
I--- -
0
0
I
I
I
I
l------l
10.00266
I
11.30507
I- ~~~
I
I
I
1
0
0
II
II
F$nene
:o C%oric
Codes
ai
79
80
1
110
0.03
0.71842
82
IO.02155
~~~
0.29
I
I
1
82.5 0323
6.75026
0.3
0.00257
0.00266
I
I
I
I
0 .Ol
3.80647
0.00544
0
0
I
I
0
0.2
!thvl sulfide
J -. ___ ---- --
AND
0
0
0
n
0
n
0.3
0.15355
0.23033
5.324
n
5.32471
2.66236
50
105
50
125
1.268
2.66236
1.26779
0.04133
0.39861
0.04558
, ~.~
l&37(369
-.---__
0.7
0.2
I 0.06381
1 0.05505
I
n
1 0.01823
1
0.124
I
I
0
Acid
SM..-
I
IO.85725
--_-I
n
I
11.93089
~.~~
~~.
I
n
Dioxin
Furan
0
n
0
0
0
0
0
0
>etant
0.00139
oI3
Dphenol
0
0
0.00417
0
9
0
0
0
II;;.
;T,;
II Chlc--k-fil
-, -, -
r&y**SAAL
c-hlntnnhrnnl
-^-.,..----r..-.--
IIBet:i Pinene
Ta Terpinol
0
0
II
n
0
0
0
0
0
4.82303
Acetaldehyde
Propionaldehyde
13:7A I
-.-SW.
1.3
---
0.06616
n
". n6;r;ir;
"""-1
IO.01923
0.4
-_
0.06
DACETON-EF
Toluene
Htxane
Chloroxnethane
p-Cymene
n
0.02273
p-Dichlorobenztne
Formaldehyde
0.5
1 n-non7
-.---0
0.06
1.8
0:s
a
.0.3
0
0.3
7767ei
3.9
B-42
0
0
0.30917
0.00128
IIAcet A-b.-r-1
II
0
0
Acre-3lmin
-_-..
0.01237
0
0
I
1
I 0.81734
i
0.1303
I
tl
3.16947
Phenol
l,l,l-Trichlorc
2,4,5-Trichlorc
E-DC-D,PP
11
0
0
I
11
11
II
0
0
0.00128
0
I
I 0.0002
_...~
ll
0.001.92 0.00192
0
0
I
I
I o-08181
- ,--- --
lo.02273
11
I
I 0.06678
~~
1 O-01223
0
I
I
10.01223
II
It
2.69
TABLE
III--Comoound
-
B-8.
Names
1
83
Hydrogen
Mat h.rl
0.71842
--qg
0.03
a4
9
0.02155
0.3
0.01
_ ._-
3.80647
1:s
0.5
0.08181
0.02273
0.5
a.
n.7
-.s
.o
l-l.3
v-v
0.06678
0
0.01223
---~---
0
0
0
n
3.9
2.69835
0
n
0
n
0
n
0
0
6.75026
0.00266
0.00544
2 .4
Sulfide
1
Chloromcthane
p-Cymene
n-n i ph 1 nrnhrnvmnr
82.50323
0.00257
110
0.29
km+ nnr
AND
f-l
B-43
a.01223
-_-----
8
I
1
*
I
0
n
--II
TABLE
B-8.
2.66236
.0.04193
0.04558
3.58
0.34738
0.27736
7.93
B-44
AND
TABLE B-8.
IICInmanrlnd Names
95
96
97
EP c;oaes
98
99
6.22096
IEl
15.25021
--.---_- 15.25021
--.---_- 15.40121
-.-----
AND
5.40121
0
85
78
78
n
l-t
w
6.50274
63
0
I
3671 14.5867'
100
85.
67
~~~x14,:
I ;;,&
piGI.L&...
In
5095~ ID.67763
-.--e--.-- -- 13.95654 12.89633 13.95654 12.89633
A.
c;~Lh.~.l.VS
FF--
PeIIL
Phenol
Dioxin
Furan
l,l,l-Trichloroctant
2,4,5-Ttichlorophtnol
PCP-EF
Chlorophenol
k$%aldehyde
DACETON-EF
.Idd#
I,
I ,&;A
i A 58
.XII
.---.-
-----IA
'
= A
-4..
V.7
;
0
0
0.00417
0
0
0
0
0
0.00417
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0014
0
1.23667
0
I
0.66156
0
0.16025
0
0
0
0
0.0014
0
1.23667
0
0.66156
0
0.16025
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.18548
0.18548
2.1
0.18171
0.09747
0
6
0
0
0.18171
0.09747
0
6
0
0
2.1
1.2
0
6
0
0
B-45
II
0
0
0
0
0
0
0
0
0
2.1
2.1
1.2
0
6
0
0
II
TABLE
Compound
Carbon
B-8.
Names
tetr
achloride
Chlorine
d&ox~a
Methyl chloride
Chloroform
IIAcrolein
1
101
104
61.06531 6.22096
6.22096
58.50229 5.40121
5.40121
0
0
0
-. _____,_ ____ A c Ch97,
134.25819134.2581916.~u~/4
IW-JVLI~
I
n
I
I A
c.-.-,e.~
u.Joaar
-A,...-
U.3UJJl
0.25408
(1.29851
-
103
61.06531
58.50229
0
032
It
--
102
I A
CnCl,
--d,*
I A
4nfi7*
r.-rvv.l
85
78
0
-63
,.
3.95654
n
2.89633
11.29851
lo.18548
Io.iassa
I.
Ifi
,A
.a.-.
a5
0.18599
n
-a..-*
106
78
0
-63
r
(
I
105
I
I
2.1
2.1
II
Propionaldehyde
-TV-_
II
2.89633
,b,f-
II
c
A
.-a
3.x54
II
..--
Other
Total .SiAP
,,5~~a ,~~
I
B-46
168~0565
168.0565
247.6565
166.9963
166.9963
246.5963
TABLE
rr
Compound
E-8.
I
Names
lAcctone1
------..~.
rethvl
ketone
mareant an
. ..-..
W-r
---!thvl sulfide
Hydro
C.hlotic Acid
108
109
58.50229
61.06531
58.50229
61.06531
2.19563
0.48472
in
40777
" .-I
n
Chlorophc---Bets Pinrne
.o
In
0
4R-477
- _----n
3
3
17.58
111
lli
2.19563
0.48472
0
30.
7
0
30
7
n
(3.09655
0
30
n
30
l-l
i34.25819~34.25819~3.09655
0
0
I
0
I
0
I
0
0
I
I
!
0
0
0
0
0
0
0
0
0.13
0
0
0.02687
I
aL.7e-f -Ia
11
EP Codes
110
107
AND
0
0
0
0
e
.q
.,.J
I
1
I
0.4
7
n17
v-a.4
'
1
0
0
.n
U.A.1
10.02687
I
3
I
I
I
I
I
0.4
3
4
II-
TABLE
B-8.
EMISSION
COMPOUNDS
B-48
(CONTINUED)
SOURCES
AND
TABLE
B-8.
I
Compou&
-_& ^_^
Names
119
n
71Rd7
In
71r
B-49
121
EP Codes
I 122
AND
123
124
II
II
TABLE
B-8.
AND
EP Codes
129
.004
B-50
130
I
1.0.004
TABLE
B-8.
EP Codes
134
131
132
133
0.00287
0.0075
0.00287
0.0075
0.07319
0.20774
B-51
0.07319
0.20774
AND
135
1
3-
136
1
3
TABLE
B-8.
AND
EP Codes
Compound
137
i38
139
140
0.71842
0.71842
1.09782
1.09782
2.25009
0.24236
0.24236
15.27608
Name's
12.25009
--_------
btafonn
iii447
I
IO.91528
I
13.96728
I
I
I
0
0
I
I
0
0
I
,
I
0
-
IIiP,,,an
II-l.l.l-Trichloroetane
---.IIF
2.4.5-TtichlaraDhcno1
--
I
I
I
I
I
I
I
0
0
3.
0
0
13.96728
aI
I
I
I
I
I
0.15
0
0
0.15
0
0
0
0
0
0
0.00942
0.15
0
0
I
I
0
0
0.00942
1 0.01
IS.27608
n
I
0
B-52
10.34388(11.65268
10.83584112.14464
II
II
0.15
0
0
0
0.01
Alph
Acro
15.88277115.78358
15.80072~15.70153
11
II
Chlorophenol
Pinene
0
0
ropntnor
Beta
I
1
142
29.34228)30.65108
44.06728145.37608
II
TABLE
B-8.
AND
EP Codes
10
10
10
40
40
1.07501~
1.5
0.03379 IO.04616
40
1.07501
0.04616
Furan
l,l,l-Trichloroetane
2,4,5-Trichlotophenol
PCP-EE
2,4,6-.Trichlorophenol
Chlorophenol
Beta Pinene
Alpha Terpinol
Acrolein
Acetaldehyde
Bfnaldehyde
DACETON-EF
Tolueae
0
0.00209
0
0
0
0
0.0007
0
0.61834
0
0.33078
0
0.08012
Hexane
Chloromethane
(TRS
0
0.00209
0
0
0
0
0.0007
0
0.61834
0
0.33078
0
0:08012
.o
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
I
11
II
0
0.00417
0
. 0.0173
0
0
10
40
1.5
0.03379
0
0.00417
0
0.0173
0
0
0.00461
0
0
0
0
1.12778
11.12778
.0.05306
0.00461 1 0.06
0
I
0
0
0
0
0
0
0
1.11541
1.63116
11.11541 11.63116
O-04069
0.13516
0
.
B-53
0.06
0
0
0
0
1.61879
11.61879
0.12279
TABLE
B-0.
B-54
AND
TABLE
B-8.
I---
EMISSION
COMFO~S
FOR
(g/Mg
pulp)
I~.IVIDUAL SOURCES
(CONTINUED)
Compound
Carbon
IF
--~~~~-tetrachloride
Methvl ethvl ketone
Hydrogen
Sulfide
Acid
0.064
3.2
0.064
7 7
0.12
7 7
0.12
3.2
0
0.8
27
Y1
0
0.8
69
0
0.2
69
I
I
(
1
0
0.2
69I
245
823
3
CA?
AJ9L
0
i-l'
0
0
160
0
n
95.7
0
95.7
245
823
1542
245
823
1542
1
w.16
1.16
0
0
0
0
0
0
0
0
0
0
1
I
0
I
icetophenol
1imethvltrisulfide
Carbon disulfide
Total HC
Other
Total HAP
Total VOC
TRS
I
I
159
I 3.3
I
2.2
I ^^_
--I I,.34
-
.--
I
I
I
I
3.3
7~7
-.--"(4
.--
II
II
II
----c-------
-.*I
158
0
0
C-v-i-klaraahenal
I*.-*
157
y*br**r
Hvdro Chloric
arine
156
225
823
1542
a 1rrkm rr;nanr
11
155
I
1
I
Methyl mercaptan
Dimethyl
sulfide
Dimethyl
disulfide
cu.p.A.a
AND
FT
-- Codes
-----
Names
Acetone
I-
FACTORS
0.03
0.03
0.0
0
0
0
0
0
0
4.2
4.2
4.2
4'.2
2594.264 2614.264
2617
1 2679
B-55
I
I
I
I
II
'0.
II
0.008
.o
0
0
1490
4.0395
4 io395
4105.32
2679
.0.008
0
0
0
1490
4.0395
4.0395
4105.32
2679
0
0
0
0
0
0
0
5.83
101.53
0
0
0
0
0
.
0
0
5.83
101.53
TABLE
B-8.
AND
TABLE
B-8.
B-57
AND
TABLE
B-0.
B-58
AND
.
TABLE
B-8.
B-59
AND
TABLE
B-0.
AND
TABLE
B-8.
EMIk3ION FACTORS
COMPOUNDS
FOR INDIVIDUAL
SOURCES
(q/Mq pulp) (CONTINUED)
.04
oric Acid
I
I
rll--.w:
".-.I
0
0
0
0
0
0
0
0
I
(
I
,
I
0.85
550
0
8.5
0
0
0
0
0
0.006
I
I
550
0
3.9
0
0
0
0
i
II
-_-.---- ---_---- I
n
I
n
I
11.78799
1rl-b...Ar
0
0
0
0
0.007
0.008
98
1
0
0
I
0
0
AND
In
11.78799
Il.78799
nai1i7
nna7
I
I
0.3
nfJlA
".\
I
0
22.4803
22.4803
5372.93
252.246
0
22.4803
22.4803
5377.684
257
B-61
0
22.4803
22.4803
5222.691
128.007
87
71.114
71.114
248.659
128.015
2640
20.987
20.987
3223.387
550
348
1.75
1.75
906.457
550
II
TABLE
B-8.
AND
TABLE
B-8.
AND
EP Code3
Compound
Acetone
Methanol
rather!
Hvdraaen
tetrachloride
216
2
300
0
Sulfide
0.4
0
Names
I
I
ph
1 hroftane
rmhenol
I
Ifi-Trichlorophenol
G,phenol
Zinene
E
Terpinol
I
I
218
4.81615
4.72202
0
0
0
0
0
0
0
0
0
4
0
1
Y
0
0
0
0
0
n
i
0
0
0
^ --ma.
~U.l3wJ4
)1.02599
B-63
219
1
50
0
0.2
0
7.90645
0
0
4
0
4
4
0
217
2
300
0
0.4
0
I
Aceta.Ldehvde
0
0
0
0
0
I
I
"
0
0
0
0
0
0
0
0.7
0
A
220
221
73
76
0
73
76
0
82
82
I
I
I
0
0
0
0
0
0
0
0
0
0
0
0
0
0
I
.
e
L.D
0
0
0
0
I
,
c
A.P
II
II
TABLE
B-8.
EMISSION
CO~OUNDS
FACTORS
(g/Mg
FOR INDIVIDUAL
SOURCES
pulp) (CONTINUED)
EP codes
Compound
Names
B-64
AND
TABLE
B-8.
EMISSION
COMPOUNDS
AND
EP Codes
Compocnd
Names
Acetone
Mat hanol
__--_~~
It?%%-tetrachloride
Methyl. ethvl
Hydrocc
Methyl. me
ketone
301
302
303
304
1.09782
0.24236
1.09782
15
3.5
15
3.5
0~
I11.54827
0
0.24236
i
omm
il.54827
15
15
305
306
10.77623 10.77623
2.6251
I 2.6251
,i 0
18.15t
_-__
0
II
I=-
Formaldehvde
Acetcphenol
D~ethyltri~mlfidm
E"otal
Carbon
G.
disulfide
HC
0.00192
I
0
0.00192
I
0
( '0.025 I 0.025
0.0173
0.0173
0
I
0
0
0
0
.I
0
0
0
n
0
0
0
0
0
0
0
0.77484
0.77484
2
2
0.32951
0.32951
10.33044
11.63924
29.14228 30.45108
12.31309 12.39714
--_---_--_----dlr;kfi;all:,
Te;flC;Q
29.34228130.6~~
*e.x"""x
w-.-v--10.34388 11.65268 L-------,----~-WV,
.--- --_--.-_ ------~~ II
10.83584 12.14464 44.06728145.37~~~~2~-1~7~~~2~-28121
I
n
n
0
0
0
0
B-65
11
TABLE
E-8.
AND
EP Codes
Compound
Names
Acetone
Methanol
307
308
309
310
3.11048
3.11048
42.5
42.5
2.70061
2.70061
79
39
311
312
0
0
0
0
1.97827
IFChloroform
1 Benz
Phenol
Dioxin
Furan
l,l,l-Trichloroetane
2,4,5-Trichlorophenol
Beta
II
1.97827
0
0
0
0
0
0
1.44816
0
0
0
0
0
0
0
0
0
0
P.Lnene
;
11.44816
0
0
0
0
-0
.o
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.64925
B-66
0
0
0
0
0
0.64925
0.66016
0.66016
0.39694
-0-39694
TABLE
B-8.
EP
B-67
Codes
AND
TABLE
B-8.
EMISSION FACTORS
FOR INDIVIDUAL
SOURCES
(g/Mg pulp) (CONTINUED)
COMPOUNDS
Methyl
Chloroform
1 Benz
I
1
.Dhrnnl
..w..w-
___-------.~
Dioxin
Furan
l-l-l-Trichloroetane
2,4,5-Trichlorophenol
PCP-EF
2,4,6-Trichlorophenol
Chlorophenol
Beta Pinene
.O
I
I
0
0
0
0
0
0
0
0
0
0
0
0
0
0.16254
0
0
0
0
0
0
0
0.7
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
0
0
0
2
B-68
.I
1.
I
AND
.I
0
0
0
0
0
0
0
0
0
0.18548
0
0
0
0
0
0
0
0
0
0.18548
II
II
TABLE
B-8.
II
compound
AND
Names
Acetone
Methanol
Carbon tetrachloride
34.38898
0
64.4519
0
1 Benz.
Phenol
Dioxin
Furan
l,l,l-Trichloroetane
2,4,5-Trichlorophenol
0
0
0
0
0
0
0
U
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1.29851
1.32032
0.79388
2.1
2.1
1.2
0
0
2.1
0
0.1923
n
0'
UPV-F.r
a
-- me
3 A
1111
C-v~ri
rhl
v L**u..*C
nt-nnhenol
Ch]----r------nrnahrnnl
Bet:a Pinene
3ha Terainal
Al&---=----Acrolein
Acetaldchvdc
--------a
--nionaldehyde
Prc,
DACETON-EF
Toluene
"ava,nr
I
Total HAP
Total VOC
0
64.61748
0
59.15395
0
34.37835,
0
0
.o
0
0
0
0
0
0
0
0
0
0
2.1
1.2
i-29851
1.32032
0.79388
n
0
0
0
1
0.1923
I
0
0
10.00835
B-69
B-12
REFERENCES
1.
2.
Radian Corporation.
Calculation Sheet, Job No. 239-026-60,
Model Wastewater Flow Rates, Pulp and Paper NESHAP.
Prepared for the U.S. Environmental Protection Agency,
Research Triangle Park, NC, December 29, 1992.
3.
Radian COrpOratiOn.
Calculation Sheet, Job No. 239-026-60,
Model Wastewater Collection and Treatment Plant for the Pulp
Prepared for the
and Paper Industry, Pulp and Paper NESHAP.
U.S. Environmental Protection Agency. Research Triangle
Park, NC. December 28, 1992.
4.
5.
Ref. 2.
6.
7.
8.
9.
10.
B-70
11.
12.
Ref. 11.
B-71
APPENDIX C
MODEL PROCESS UNITS
c.1
C.2
C.3
APPENDIX C.l
PULPING MODEL PROCESS UNITS
This appendix presents emission points, emission factors,
and vent and wastewater stream characteristics for each of the
18 pulping model process units (MPU's) presented in
Chapter 4.0. The model process units are defined based on
.pulp type, wood type, digester type, washer type, and whether
oxygen delignification is used (see following summary table).
The following figures (Pl-P18) represent the emission points
associated with each model process. Tables following each
figure identify the emission points within the model and the
associated emission factors and process vent and wastewater
stream characteristics of each emission point in the model
process unit. These characteristics include:
l
Flow rate factor; and
l
Hazardous air pollutant concentration.
The assumptions and derivation of the emission factors
are presented in Appendix B.
The following example presents how a model process unit
would be assigned (or lqmapped")to a pulp mill. Assuming a
Kraft pulping mill with a batch line pulping hardwood
(1,000 tons per day) and a continuous line pulping softwood
(1,000 tons per day), two pulping model process units would be
assigned to represent the two pulping lines. The batch,
hardwood line utilizes a rotary vacuum drum brownstock washer
and no oxygen delignification. Using the summary table as a
guide, the batch process would be assigned model process
unit P-l. The continuous line utilizes a diffusion washer and
C-l
1 Year
c-2
Year
SUMMARY
TABLE
OF PULPING
MODEL
PROCESS
UNITS
Wood
typa
Chemical
Pulping type
Digestion
type
recovery
Washer type
Oxygen
delignification
(Yee or No)
P-l
Kraft
Batch
Hard
Kraft
Rotary drum
No
P-2
Kraft
Batch
Soft
Kraft
Rotary drum
No
P-3
Kraft
Continuous
Hard
Kraft
Improved washing
No
P-4
Kraft
Continuoue
Hard
Kraft
Rotary drum
No
P-5
Kraft
Continuous
Soft
Kraft
Improved washing
No
P-6
Kraft
Continuous
Soft
Kraft
Rotary drum
No
P-7
Sulfite
NAa
Soft
Sulfite
Rotary drum
No
P-8
Sulfite
NA
Hard
Sulfite
Rotary drum
No
P-9
Semichem/kraft
NA
Soft
Kraft
Rotary drum
No
P-10
Semichem/kraft
NA
Soft
Sulfite
Rotary drum
No
P-11
Kraft
Continuous
Hard
Kraft
Improved washing
Ye8
P-12
Kraft
Continuoue
Soft
Kraft
Improved washing
Yee
P-13
Kraft
Batch
Hard
Kraft
Improved washing
Ye8
P-14
Kraft
Batch
Soft
Kraft
Improved washing
Ye8
P-15
Sulfite
Batch
Hard
Sulfite
Rotary drum
Ye8
P-16
Sulfite
Batch
Soft
Sulfite
Rotary drum
Ye8
P-17
Kraft
Batch
Hard
Kraft
Improved washing
No
P-18
Kraft
Batch
Soft
Kraft
Improved washing
No
'Model
proceer3
unit
WA = Not applicable.
jlh.lO8c
c-tbl
C-16-93
WOOD
CHIPS
BATCH
DIGESTER
BLOW
TANK
:
I
I
I
I
1
-----
COOKJNG
LKNOR
\I
163
KNOTTEA
WASHERS
,I
J
;
I
I
I
,O
A
; 184
I
I
t
I
WEAK BLACK
McdelPl
I
1 IW-CODE
1 EP-CODE
SCURCE
Lf
I
I
!
LI
1 PaOC,lrPe
WLP
I
1
I
1
PULP
KRAfl
WlP
KilAfl
PULP
KRAfT
____---
Dipmsters.
relief 9mrcs
DiResters,
blow cadensmtms
DiResterr,
blw
Knotters,
9ascs
hod
vent
Umrhcrm,
hood vent
WSHERS,
DECKERS/SCREEYS
urnshers, for
tmnk
Evmpormtors,
vent
Evapwmtors,
conrknsmtes
Evmfxwmtors,
surfmce cd.
PULP
KRAfl
Pulp
KRAfT
PULP
KRAfT
PULP
KRAfT
PULP
KRAfl
PULP
KRAf 1
PULP
I
1
KltAfl
wdel
i MPU~CODE
i EP-CODE
- Edssim
frtor
1 5.9OE-1
J l.ZDE-3
Dlgestwm,
blw
Knotters, hood vent
1 l.IZE-3
1 5.D6f-3
1 b.ZlE-3
1 Z.D7E-2
1
1
1 2.3OE-2
1 l.DOE-1
YASHERS. DECKERSISCREEYS
I 5.12E-4
1 Z.ZJE-3
taM
J 3.84E-2
J l&E-l
vent
I Z.DDE-4
1 Z.DLX-2
1 l.DDE-2
1 3.ooE+o
relief Rascs
DIgesters,
bla
for
cordensmtcs
gmses
candensmtcs
IANK
T
Dl9atrrs.
Dlguters,
relief Rmses
blow cmdmsmtes
DlRmstcrr,
blw
Knotters,
l&SllERS,
Umshmrs,
hoed
I Z.IOE-3
1 &15E-1
1 s.DOE-4
1 l.DoE-l
1 PCP-Ef
1
I
I ACROlElYEf
1
I
,
I
I
I
J s.soE-4
YUCE-IIP
1
I
I
/
I
1I
Z.LIE-4
1 SfLO-fAC
I
,
I
J 1.4cwo
1 1.3Mto
1.42E-3
T
f
I
I
SWP~CDN
VMP~cm
8.&x*2
VEYl
J l.aoE-1
VEIN
J z.m-3
SlREAJt
J 4.9DE+o
SlREAM
I 4.2W*O
I 2.74E-3
I
1
1
VENT
T
I
II
I
----r-l
9.96E+2
C.laol
1.03E*z
2.03E*o
I
-I.
2.99E+C
l.DDE-3
Ii
Y
II
I
I
1.46E*3
II
S.SSE+Z
I
1
1
1I WL-Ef
I l.llE-4
J 3.26E-3
1i MCL-Ef
iI CLZ-Ef
I
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1 CHCL5-Ef
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1I LJEYZJf
I1 PMYLJf
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I1
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fU.NCL=f
1 1-24sRf.
1
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1
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1 TOLUEWE+f
I
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1 QIElHAMEf
I
f
4.24E-3
1 ICDOJf
I
I
5.5%.4
2:3lE-3
1 lCDf_Ef
1
I
1 A~ElOPWff
1
I
1 CARloIS-Ef
I
1
1 WxrJK-Ef
1
I
1 Wtmf
4
I toI~f
I
I t@S-gf
i L.ZDE-3.
i Z.SpE+D
i 2.62WO
-I
1
1 5.9lE-1
1 8.5%.1
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1 LW-l
LSDE-2
J 1.01-l
I 4.37Eto
I 4.02E*o
5.loL-2
I 9.6OE-2
1 &lU-l
'1 l.W+O
1.24E-5
1.7OE-2
1 1.74E-1
5.431-6
1 J&L-3
1 9.06E-3
3.24E-5
I 2.02E-l
1 S.IlL-1
1 Z.zQE-1
I Z.lOE-2
1 5.39EM
1 3.%E*O
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1 7.N.1
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TANK
I
1
I
1 HAL~SIAIUS
5.9&*2
4.13E+3
I
I
SKIRADE
1 VflD-fAC
I
I
1 2.57E-3
!i.uE*l
J 2.Dw3
J 6.oaE:S
vmt
condensates
surface cd.
VEYI
1
1I fcu_Ef
Rmscs
VEYI
STREAM
SwrV
hood rat
DECKERS/SCREEYS
Evqaormtorr.
Evmpermtorm,
PI
J l.ZOE-3
Diprsterm,
fQyCE
1
I
I
1 PCOR-Ef
I Evmprmtors, condensmtes
I Evmpormtors. surfmce cod.
I YEAK ILACK LIINKU 'SWRACE
HARD
,
1I IyKJf
Evmporatorm.
1
I
I
I1 WET-Ef
T
/;
II
I
II
1 EPJC@E
I ENCLOSURE
1
I
I
11 ItEOtl~Ef
umsherr.
I WU~CtllE
1 WDD-1VP
1
1
11 ACEIJf
SOJRCE
W/12/93
Chmrmctcrirticm
KRAfl
cwwknsmtea
IANK
PULP-fvP
. strm~
,I
1 I.4600
!;O157
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II
c
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DIGESTER
I
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TANK
I
I
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w-
0159
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TALL OIL
EOILER
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_------_____-___
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__----------a
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z
r
4
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:
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5zoz 34
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;c;n;n;v;c; 0
__-__--------
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i-T-------------
w---w-__-----
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s;
g;
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2
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=
4
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I iri-----
________
f ; ;, j rzzii;iii;igig
3
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z
,:
s
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s
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2 ~zz~~:zi2r~z~~
YIllYYIYIIYYY
2
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f
ki
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ff;igivgi&i;
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-----___----ruNNNNNNNNN--lm
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turpmtin
turpentine
.I-
comknscr
tmtch rent
;I-I .
conbnsatcs
164 I Dinritcrr,
blw
cmdensAtcs
166 I Digestcrr,
blw
gases
I
1
::
I
1
z!.ooE-6
J.U.5
l.ooE-6
4.3x-4
l.W-3
3.54t-5
I
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IM
for
1 MNhers.
tank
106 I Evaporators,
vent
100 I L*poraws,
cmdmyt~s
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surface cud
1W
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feccor fiery
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1 ICOf-Ef
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z.zOE-4
Z.OOE-4
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1
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M/12/93
TI
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cmdmr*tcs
IAY
Emission
I
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178
176 1 KnottArs.
Moshws.
hood
hood vent
vent
102 1 NASHEIS,
.--
PRceAl~Ef
1 ACfiOLCIYEf
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2.**0
1 3.83EL3
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I 5.05.E.I ! 9.74E-1
7.11E-2
I 1.04E-I
I 3.93E-4
5.79E.l
3.OOE- I
I 1.00E- 1 I 3.47E.l
3.2OE- 5
I 4.751-3
1.09E.l
I
I l.M-3
1.71E-1
.I
I 3.91E-2
I r.zlf-2
I
..--.I-A--
1 3.42E-1
Z.VE-I
1 3.97E+0
4.02L*o
.I 2.6lE+0
1 3.42E*O
Z.llE+b
1 Z.UE-2
1 l&E*0
z.w-1
I 3.07E*O
3.54E*O
1 S.CZE-1
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I l.I(Y-1
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1 &WE-Z
i
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1
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A
; 169
RECOVERY
:
I
? 232
:
I
:
I
:.
_ _ _ _ _ _ _.
_ _
WOOD CHIPS
I
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COOKING
LlQlJOR
_--
j71
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; WI-Cf8lE
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_ _ . -...-.
---.-.---_
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turp"tln
162 I WC.Syrta.
i ~PROC~1IPE
condenser
t
1
PULP
vent
PULP
bath
turpentine
--_
.~.._r--------
PULP
condensates
1 p:: I1
I pm
lR4 1 OiRmterA.
blow cmdmrAtcr
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166 I DiRRrtRrr.
blow R.scr
PULP
176
182 1 UUNERS,
DECKERSISCREENS
113 1 UArhwA.
for
:::
186 I EvAporRtors,
"em
PULP
1M
comknsetcs
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surface cad.
PULP
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1 ::: I
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1 Knottws.
1 EvrporAtora,
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PULP
1~4
PULP
SIORAGE
condmrarrs
PULP
IANK
hood vent
7.
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162
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cm
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for tnlr
186 1 ErqmAtors.
vmt
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a,
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1 WU
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1 SWRCE-UP
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1 SfLO-FAC
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KRAfl
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card. condmratcs
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1
APPENDIX C.2
BLEACHING MODEL PROCESS UNITS
This appendix presents emission points, emission factors,
and vent and wastewater stream characteristics for each of the
.
12 bleaching model process units (MPU's) presented in
Chapter 4.0. The MPUIs are defined based on wood.type,
bleaching sequence, and percent chlorine dioxide substitution
level (see following summary table). The following figures
(Bl-B12) represent the emission points associated with each model process. Tables following each figure identify the
emission points within the model and the associated emission
factors and process vent and wastewater stream characteristics
of each emission point in the MPU. These characteristics
include:
l
Flow rate factor; and
a
Hazardous air pollutant concentration.
The assumptions and derivation of the emission factors
are presented in Appendix B.
The following example presents how a model process unit
would be assigned (or "mapped@@)to the bleaching process at a
pulp mill. Assume the same mill in Appendix C.l has two
bleaching lines, one dedicated to bleaching hardwood
(1000 tons per day), the other bleaching softwood (1000 tons
per day). The hardwood line uses a CdEHD process with 30%
chlorine-dioxide substitution. Because hypochlorite use has
been determined to result in increased chloroform generation,
the existence of a hypochlorite stage was designated a higher
criterion in model assignment than chlorine dioxide
c-50
Day
Year
c-51
= 12,700 kg chloroform
Year
Bleaching sequence
(% Cl02 substitution)a
Wood type
B-l
B-2
B-3
B-4
B-5
B-6
B-7
B-8
B-9
B-10
B-11
B-12
CEHD (0%)
CEHD (0%)
CEDED (0%)
CEDED (0%)
CdEDED (10w)~
CdEDED (10~)~
CdEDED (high)c
CdEDED (high)c
CdEDED (100%)
CdEDED (100%)
O-Ed
O-Ed
Hard
Soft
Hard
Soft
Hard
Soft
Hard
Soft
Hard
Soft
Hard
Soft
Key :
Cd
= Chlorine
D
= Chlorine dioxide
E
= Extraction
0
= Oxygen/Ozone
A low substitution range is 10 to 50 percent substitution.
Less than 10 percent is considered to have the same
emissions as 0 percent substitution.
A high substitution range is 50 to 90 percent substitution.
Greater than 90 percent is considered to have the same
emissions as 100 percent substitution.
An oxygen delignification precedes this sequence and is part
of the associated pulping model for the process.
c-52
I
$Ja
In*~~~~~~-~~
---------OaP
0
I
big.
'II Q
c:
.-0
02
I
I
I
4------*----I
3
.c
E
00G
5
8 ,--I
---.
I/
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b
0 I/
g /I
a /I
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r
8
32
m
.
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in
@..------------.
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y :I
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:
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C-53
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b----l----l "
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1
I1
91
It!
7
!9
Cl
1
II ml
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81
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t:
"pi
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t:
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Bl
91
95
93
117
11s
151
153
1
1 EP-CODE
1
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1
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---
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1
::
71
73
91
PROC-IVPL
.- --__._
_.-_._
glcxhmg,
Blcgching,
C-stage
wld
vcnl
Seder
tltler be??
I BIgAching.
I Blmching.
I BIgAching.
Cl02 s&t.
glcwhing.
El-stage
Blegching.
El-stage
1lggFhinp.
El-skggc
Blerching.
Dl~stbge
llmchmg.
Dl~sCb9e'tOXl
glcuhing,
Dl~stgg*
Ilmching.
Y-stage tO.S-2X1
ugshcr
Y-stegg (0.5-2X1
rogl tmk
73
71
119
I
I
r!II
..
I BIgAching,
L
(0%) cAusttc
9LEACll
IlARD
gLEACH
l4ARD
BLEAC)!
WAR0
BLEACII
IIAPD
masher vent
glEACll
IlARD
glEACH
IlARD
IJLEACII
MAR0
IOX1 wgshcr
gLfACY
HARD
IILEACY
HAAD
llEACY
Ml0
gLfACY
IlARD
rwher
Vent
vent
SCUbCE
Bleaching.
Cl02 tit.
Ilmching.
(OX1 tcww
glggching,
Y-stew
Blgwhing.
Cl02 s-t.
glgwhing.
C-stage usher
glgxhing,
C-sfgge
gleuhing.
El-stage
(0.5-211
rent
towr
vent
(OX1 cwstIc
swcr
vent
vent
93
gleuhing.
El-stew
tOI1 wshgr
glguhing,
El-stage
vmt
vmt
115
Ileeching.
Dl-stage
(OX) t-r
117
Blmching,
Dl-stwe
(OX1 wsher
Blwching,
Dl.ruge
glggching,
tl-stage IO.S-2X1
mmshcr
glwching,
Y-stggg
le1
(0.5.2X1
vmt
vent
wnf
rant
tank vent
@lEACW
BLEACII
ILEACY
i ACEI-Ef
i IYOU-Ef
-.
---7..------I
1 MO~IVP
I EYCLOSlJRE 1 SMKCE~IIP
1 _.__
._ 1 -.--.-.+-.--
C-stqe
vent
Stream Characteristics
Hodel 81
,.
_.__
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C.stwc
9s
153
151
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(0.5-2X) toyr
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(OX) cutic
sewer
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t:
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tsar
vat
117 1 DImchIn&
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(of' wehw
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::
110 I Wachlna,
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151 I Blaachin#,
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5.OOE-3
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l.OOE-3
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6.626-b
IAOE-4
4.42E-5
l&E-4
5.oQE-4
z.OoE-3
I
I
3.09E-4
1.32E-3
z.rQE-4
l.wc-3
z.IoE-4
1
1
1
1
1.m-A
6.62E-b
&OlC-6
rht
1
"UN
wnt
1OUlEttf~Ef
vmt
vent
PROPAL-Ef
CMEIYANEEF
1 KC+-Ef
:COf-EF
1 ACEIOPWEF
1 CMODI\
i
I
I
I
I
I
I
:f 1 YEXAUE~Ef
1 lOlW'E~
IOWOCEf
i ISS-Ef
/
I
I
I
I
I
1 1.2oE-1
1:9aE-1
1 &WE-Z
5.55E-2
I. l.llE-1
Z.OlE-1
I b.UE-1
4.39E-1
1 3.23E-1
3.2oc-1
1 2.37E-2
2.176-z
1 &17E-2
I.IlE-2
1 2.506-Z
4&E-2
1 3.11-z
l.?&-2
1 5.m-2
3.77E.2
1 1.59E-2
l.uc-2
1 1.53E-1
1.542-l
1 r.rn-2
7.5X-2
I
I
/
1
I
I
0
116
162
116
A
t'
t
I
,
1
I
,-----4-q--
-dI
E
STAGE
rOWEi
C
STAGE
OWER
I
I
0
I !
i
Q6
I
I
--.\AClD
.
-.
al0
-00
06
L
1
I
I
I
I
I
i
;
I
1
:
I
0
164
t
)
I
I
I
I CAUSTIC 42
I
I
n- 0
WASTEWATER
COLLECTION
& TREATMENT
D
STAGE
I-OWER
I
I
I
I
I
I
I
I
I
I
I
I
I
I
i
I
I
0
120
SEAL
1 TANK
n&l
-r---
I--
; WU~CODE
+------j
I
I
!
a2
82
i EP-COOE
_.~ __
4
8 t
B2
20
::
::
tf
96
Qb
82
116
::
120
111
I
I
152
SOHICE
___-.-._
154
-_
C-stage
tower "cm
acid sc~cr
Ileaching,
C.stagc
Bleachiw.
If-stage 10.5-2X)
nlcuhinp,
Cl02 r&sr.
Bleaching,
C-slap9 masher
touer "cm
(0%) caustic
SCYW
"cm
EP$XIE
l2
20
I2
42
72
::
14
2
2
u
92
94
12
116
'lb
w
12
I
I
@2
u
,I
I
I
fil
1
($I
Vb
120
152
154
BLEACtl
SOFI
ILEACH
SO11
ULEACH
So11
9lEACH
SOfl
BLEACH
Sofl
SIrcam Chwacrrrisrics
-T--._.SLUKE~IVP
..I-.
--
I
i
VEYl
SIREM
VEYl
SIREN
Ilcuhin9,
C-rte9c
9LEACfl
Sofl
VEYl
El-stage
OLEACII
Snfl
VEYl
Bleaching,
El-slap"
(0%) rasher
OLEACH
SOfl
VEYl
Ileeching.
El-rtqpc
9LEACll
Sofl
VEYl
BLEACII
Soil
VElfl
9LEACll
Sofl
VEYl
9LEACfl
Sofl
WY1
OLEACY
Sofl
VEYl
ILEACH
L/
Sofl
I
1
vent
Ilrnch:ng,
Dl-stage
Ileaching.
Ol~sla9c
(OX) uashcr
Bleaching.
Dl-sta9c
Blewhing,
Y-stA9e
Ileachinp,
ll~stmgc (0.5-2X)
"NM
wrhrr
"WM.
seal tmk
"mt
WINCE
Cleachina,
I Ilmching.
Blwching,
I Blmching,
Bleaching.
I Blwching.
#lmchirq.
I Umching,
8leachln&
I Blaaching,
Ilwching,
I Ilmchin#.
Blwchiw.
filmchino,
LI
i
I
I
I
I
I
ACEl_Ef
C-s19tw
touw
C-star
lid
n-e-
(0.5.2X)
Cl02 m&t.
sewer
r.wIE-2
t-r
"mt
(OX) cvrtic
C-stage usher
C-stage
l.bAE.5
vent
sewer
"mt
seaI tub
b.?OE-2
5.0&-L
"mt
3.59E-4
El-a*
(OX) towc
El-sage
(OX) washer
El-stm9a
"mt
Z.ZQ-3
"mt
Dl-ste99
(OX) t-r
Dl-sla9e
Dl-sta9e
l.oOE-3
l.OOE-2
"mt
Z.lbE-2
I.lZE-5
l.ooE.3
"mt
W-9~99
(0.5-2X)
wsfw
Y-9taw
(0.5-2X)
7.I8E.b
l.W-4
"cat
I
L
1.2x-4
-1---TVflO-fAC
___
2.4rJE-2
Z.COE-2
VElfl
1 VlUP~COfl
.____
_
t
1 '.33E*l
1 l.O4E*l
1
! 5.19E+2
1
1 9.97Lll
'.4OE-2
1 l.OlE+Z
z.cOE-2
1 1.5&Z
3.62E-1
1 2.53E+l
l.COE-2
1 Z.ibE+Z
2.4OE-2
I 2.1bE+2
l.bZE-1
1 2.2bEtl
1.4oE-2
1 1.65E+2
l&E*1
1 b.ou*1
'.4oE-2
I
i
1 7.bOE*Z
1
. Emissld\
I
WOU-EF
1 ClEl-Ef
1
2.OffE.3
1 ftEK_EF
1
I
1 1:03E-4
1 PKII-ET
4
I
1
I.OOE-2
1 Z.IOE-2
4.voE-4
1 l.loc-3
SWAP-CON
Mi12/93
1~.---~ --.( HAL-SlAlUS
i
v-
-----!-l.lbE+l
I
I
'.53E+l
!
I
"
I
v
r
v
I
v
v
/
I
I
I
I
I
I
I
/
I
A
factor Suwry
l.OOE-1
1 z.aoE-2
l.OOE-2
1 l.ooE-3
2.25E.Z
1 5.4LE-4
4.eE-4
1 l.loE-3
7.OOE-3
1 l.OOE.2
5.25E-3
z.OaE-4
I l.lOE-4
l.onE-3
1 l.oLx-3
2.25E-3
1 l.b3E-3
9.1OE~Z
I 2.5oE-4
t..8#-2
1
1
1 1.3bE-4
I
1
I
l.bY-2
1 SfLO-fAC
..---t
1
!
IiI
i
I
I
I
I
LI
----__
1 9.obE+o
lto&l 02
i
I
I
I
/
I
I
I
L
T:f
i
I
I
I
I
LI
l.bZE-1
VW
Ileaching.
---__
/
UWD~lVP
.-.
1 PfWJC~lVPE
_ , -_.. _..--,
DIeaching,
I
I
1
I
I
ri
92
i
I
42
72
I&?
I--_ ---
) EYCLOSURE
.I.---_._.
1
I
I
I
I
I
I
LI
fLMft-Ef 1 ACL-Ef
,on-r
1:zoE.2
3.om-3
9.oix-3
4.ooE-4
2.77E-4
3.&E-6
1 2.696-5
5.ol&-5
1 I.ofx-4
3.a.5
1 3.07E-4
P.ZlE-4
l.ZoE-2
&3oE-3
l.wE-3
1 '.5bE-3
6.92E-4
1 l.ZOE-3
I
I
I
-7
CLZ-If
Z.lOE-1
1 IYCL-If
,
1
I l.IllE-4
1 3.CmE.l
l.OoE-2
Z.lOE-1
1 2.OOE.2
1 l.OOE-3
I I.oOE-4
5.32EE-3 1 4.5bE-5
I
I
I
I
l.ooE-3
1 3.58E-3
l.oaE-3
1 I.oM-3
7.blE-5
1 4.5bE-4
l.oOE-2
I 4.3OE-3
l.OOE-2
I b.olx-3
2.54E-4
I I.LTE-4
l.o(w-2
I 7.OoE-3
I 2.54E-4
-I.
I 6.38E.C
1
l
I
I
I
I
I
I
LI
CflCLl~EF
-l.OOE-2
5.OP-3
I.OOE-2
Z.lOE-3
l.o(y-2
6.42E-4
l.obE-2
l&E-2
b.mE-4
Z.OSE-2
2.05E-2
l.lZE-3
b.OOE-2
2.57E.l
I
I
I
t
I
/
II
L-BENZ-Ef
1
I PYEYL-Ef
I
I
1 ftCHCL3Ef 1 lCP245Ef
I
1
---+----i---
I I.
I l.ooE-4
I
1 l.OoE-4
I
I
1 l.lpc-6
1 l.wE-4
1 4.
'*E:::
I
I
I
I
I
I
; l.oOE-4
I
/
I
mdela2
-
-I-
iwu_coPc
I
-:
1 f
I
! :2
I ::
j !
B
I ::
I w
I :
!
I
i
I
PCP-EF
4
Blmching,
c-stage
t-r
vent
Blmching,
C-St-
acid suuc
20
Slmdbing.
I-stop
#0.5-2X!
42
Blmchin&
cl02 l6mt.
Ilushiqt,
c-t*
w&w
l.ToF-3
toner vent
(OX) caustic
74
Bl*achllt@. C-etIl*rhln&
94
llawhlnq.
El-tmw
(0%) umh*r
96
Blwhlrp,
El-*ta~
.(0X) *ml
II6
alwc.hin#,
D1-8tbge
(OX) t-r
119
9lmchln#,
Dl-etaga
WXl,wsh~r
129
Blowhl~,
ml-ate
sd
I
1 IOl~UE-EF
1
I
I 6.ooE-4
! 2.m.5
1
j
1.6&-2
'I.aoE-4
1
!
2.102-3
l.ZoE-3
z.ooE-6
2.wE-3
l.ow-3
06112193
Factor kvry
I
I PROWL-Ef
1
I
1 I.l2E*6
8
1 CMFIWIEEF
1
1
SAOE-4
1
1 ICW~EF
I
I
I
I
1 ICBF-EF
1
8
I
6CEltWiYEF
CASWIS~EF
tnd
vent
FOX) toWr
l.UE-S
6&E-S
1.92E-S
vwlt
1.77E-4
&WE-s
s.o(y-3
vmt
2.oof-3
l.ooE-3.
s.w-3
tnlr mt
1.24E-3
6&E-4
1.6oc-4
vult
4.42E-S
1.62E~C
wnt
s.ooc-4
rent
3.ovE-4
:-2::
152
2.7OE-4
l:tJOE*3
Z.Mc-4
Is4
1.67E-4
1
1
6.629-4
1
1
&OlE-6
I WIUE-EF
I
I
1 101ltAPEF 1 IOIUYEF
I
1
I
I
1 2.24E-1
1 1.34E-2
I
I
i
2.27E-S
vent
92
El-rta#e
sewer
_ Emisaim
I
1 ACIOLEIYEF
1
I
1 1.77E-6
INS-EF
I
1
____(.
I l.lR-1
I l.W.1
! 8.7SE-2
! l.WE-1
1 1.3&E-1
1 2.02E-1
1 2.53~.1
I 4.3SE-2
1 2.96E-2
1 2&E-2
I
i
I
1 2.63E-2
6.436-2
1 2.41-2
9.09E-2
I
I
1 2.521-2
3.6SE-2
1 4.66E-2
2.21-2
I.
1 5.74E-2
1 4.24E-2
I l&E-2
I 1.6lE-2
1 l.S3E-1
I l.uc-1
1 7.47E-2
1
1 I.SIE-2
I
,--a
40
t
--
---w--
@-----i/
yc
0
I-
--------
f
1,
------A---*-
&$I
i
I
+---
52
2Oy
fr
c1
0
w
~--------L.-.
q--a-
-------I
3
4
u,s
(0
I
I
I
----
------------
1,2P6Ec
i
0: ,I.
g /// %~a
5 ,I /
I
WEi
In
*
~-~~~~-~~
:.A
___-__
ocq
=
0
I
/
//
I
I
.O
I
I
I
F
E
8
2
I
I
~-----.-
0
L;
8
;E=
.E
iii
E
II
f
d
t1
s
u
:
:
:
:
:
:
I
I
I
I
I
I
1 gj /
0s*----.r---,.-.-..,.
c-59
ltcdcl 03
r ---I WU-CODE
t
E3
E3
::
@I
E3
I
I
I
I
I
E3
---
-.-_-.
EP-CODE
SOLMCE
-._---__-Bleuhing,
C-stage
Bleaching,
Cl02 s&t.
j B!crcblc$), C.stsse
t"wr
NLEACI!
vent
BLEACN
BLEACH
I Blcachirq,
C-stage
91
93
Ileaching,
El-stapc
Bleaching.
El-stage
(OX) ubshcr
El.stmgc
01.stwc
(OX) tam
(0%) usher
Ol-stage
I
I
I
1
I
I
I
E3
119
Dl~rtaBc~tOX)
I39
Bleaching,
EJ
BleachimX,
EZ-rt*Br
I43
145
149
rent
vent
seal tu*
I
f
usher
EZ-stage
vent
02.staBc
t-c
DZ-stwe
washer
Ileachlng,
02.staw
seal tmk
HARD
I
i
6lEACW
IIARO
Stream Characteristics
1 --- -. ---.
1 EYClOSUBE ; StXKtCE-ItP
., ------+.--.--
I
I
SIREM
OlfACll
BLEACH
OLEACY
I
I
.L
UIACII
vent
3.62E-1
WAIID
VEYI
l.LOE-2
MAit
vflll
Z.LOE-2
VEYI
3.62E-1
VENI
l.LM-2
VENI
2.4OE-2
VENI
3.62E-I
VENI
l.4Iy-2
VENI
Z.LOE-2
I
nAn0
I
1_
ttodelB3
1 WU~UIDE
I EP-CODE
I XWACE
1 ACEI-EF
1 MON-EF
---t---d-
1
I
I
I
I
I
I
I
i
-L
CIEI-EF
VENI
3.62~~1
vEwi
1.4oE-2
VENI
2.4OE-2
VENI
3.62f-i
VENI
1.4OE-2
1
1
_ Emission
I
1 ttEKJF
--j-AZ
t:
41
39
1 Blmchlng,
lleachlnp.
Cl02 u&t.
C-stage
KMI (OX)
S-C cwstic
63
45
1 8lmchlrq.
C-stm9c
'3
::
7S
I Bleachinn,
fi;
91
77
I Ileaching.
6lmching.
II
E3
93
1 II.achin&
El-rtwe
tOI) wsher
gl
lJ
9S
1 Xlmchirq.
El-stage
115 I BlomchimX,
Dl.@taBe
(OX) t-r
117 I Ilmchin&
Ol-stage
(OX) wshcr
II9 I Blwchinp.
Dl-stapr
139 I Xlwchirq.
E2-stmw
I
I
.I
I
I
I
a3
63
'3
u
83
I
I
::
I
I
scycr
I6.7OE-2
1
I.OOE-2
1 I.o(y-2
l.o(y-1
tower "ent
1 l.43E-4
1 Z.WE-2
C-staw
wshw
1 I.OSE-3
1 4.!5E-I
El-staw
C-sta@e
seal
(OX) tank
tawr vent
vent
1 3.S9E-4
2.2OE-3
1 4.BSE-4
3.llE-1
1 3.OOE-2
1 7.OOE-3
1 2.16E-2
I 5.25E-3
1 7.32E,5
I 2.ME.4
1 t.ooE-3
1 3.ow-3
1 I.lBE-4
I 2.25E-3
t-r
1 l.lOE-3
I 2.42E-4
1 l.IOE.2
I 3.SOE.3
1 l.O&-2
I 2.6x-3
16.9OE-7
vmt
"mt
vent
rmt
vent
vmt
141 I @leaching,
tZ.stm~a
rashm
143
EZ-rtapc
seal
14s I Bleaching,
DZ-stage
tower vent
1 2.9OE-7
D2-stag0
rasher
1 4.OOE-6
1 l.ooE-5
02.staw
1 2.67E-6
I
I 7.11-6
1
I Llmchinp,
03
147
'3
I49 1 nlmchin&
I
1 Elmchins,
rmt
tank vent
vent
1 9&o
VEYI
IlARD
I.
-y-i-G!
OttAd
1 SFLO-FAC
Z.COE-2
BLEACH
vmt
VFLO-FAC
VCNI
N&m
llEACY
vmt
-----
SlKEAlt
I
I
BLEACW
8lEACY
EZ.stagc
WCO-IIP
-I
BLEACN
Ilmchinp,
Bleaching.
BLEACN
vent
tcucr vmt
Ilcachin&
1 Xlcuhwq.
147
vent
Bleaching,
Bleaching,
141
sewr
Xl.achmt+,
I?
II7
yefit
masher
::
63
X3
BLEACH
C-stage
'3
BLEACN
Bleaching.
95
sewer
(OX) caust!c
7s
I15
::
.._..~ .~,
lad
39
41
4s
1
1 PRUC~IIPE
I.--.--
1 2:oaE.z
3.ooE-4
1 Z.CEiE-4
3.1%.4
1 2.4I-3
1 5.44E-4
1 3.loE-3
1 3.OM.2
1 1.63E-2
1 l.loE-4
1 3.oM-3
1 1.63E~-3
1 1.55E-3
1 l.SoE-2
1 &ME-3
1 Z.loE-7
1 Z.OOE-6
1 l.WE-6
I
Tutor
OBJl2193
71
I
/
YWAP-COY
-I-___... .- r
SNAP-COY 1 HAL-SIAIUS )
----..-I..-. ..{
2.52E+2
Y
v
v
v
v
v
---I
Z.%f+Z
l.Mw2
2.07Ell
1.6lEr2
b.l4E*l
l.lSE*l
1.27E+2
6.6Wtl
4.s7E+o
4.%x*0
1 3&E-6
2.69E-5
1 5.ooE-s
4.wE-4
1 3.46E-s
3.07E-4
1 9.2lE-4
1 l.2oE-2
1 8.3oE.3
1 1.92E-6
l.UE-S
1 2.soE-s
Z.oaL-4
1 l.TIE-5
l.S4E-4
"
l.ClE+Z
1 2.77E-4
1 i.lSE-S
2.4301
1 6.O&-1
I
I
I
I
I
LI
1 P.wL-3
1 4.61E-6
1.52Etl
l.C6E+3
/
I
Sury
rII-yGz
II
II
I
i
L
1.16E*1
3.2llE+S
KCL-EF
i
I
I
I
I
I
I
I
I/
CL2-EF
2.w-1
2.li*-I
s.k-3
3.oaE-3
J.ooE-3
7.6lE-5
l.ooE-2
l.ooE.2
t
I
!
I
I
I
2.54E-4
I
I
l.ooE-2
l.ooE-2
Z.S4E-4
/
L
1 L~DENZ~EF
1 PYNL-EF
1 ttCYCl3EF 1 ICP245EF
ItECL-EF
CnCl3-EF
3.ooE.3
EiTy-
3.oof-3
l.LZE-3
3.3oE-4
5.27E-3
4&x-4
5.27E-3
4.l#-s
3.99E-4
3.saE-3
7.93E-3
s.ooE-3
7.93E-3
4.56E-4
l.loE-4
4.3I.3
l.SI.2
6.OOE.3
l.SBE-2
s.i?E-4
9.wE.4
t.mE-3
3.97E-3
2.5W.3
3.97E-3
2.2M.4
2.55E.4
l.OBE-3
4.62E.l
l.SoE-3
C&?E-S
l.37E-4
2.96E-6
I-
--+q-Gq
I
I
I
I
1
I
I
I
1 l.JE.6
1 3.ooE.c
1 3.ooE.4
1 L.l7E-6
1.
I
I
I
t
I
!
1
1 1.5oE-4
1 l.5lx.4
1 2.09E.6
I
/
ttakl 63
,
1 EP-UXtE
1 XOJRCE
I1
INPUJWE
I
I:
;
::
II
::
I 93
I 81
I
I @I
I
39
'3
I :.
I 9iawhinl).
1 PCP-EF
Cost-
I
1
41
I Blmchi~.
Cl02 Wt.
45
1 Biaachlrl,
C-rte
7S
i iieacbi~,'c-stw
I
I
I
I
I
1
7-7 1 Iimchin#,
C-sta.0
91
93
1 9iowhlt16,
Ble.chiw,
1
El-rtw
El-Wa6m
9S
I 9ltachiq.
El.ataw
acid m-r
1 l.RE-3
tad
(OX) washer
t-c
vmt
(OX)
rent
(OX) seal tmk
117 1 DImchin&
Ol.stw
01.sty
(OX) wshw
Dl-rta#a
139 1 9lmchlw.
EZ-ata9a
t&r
I41 1 U.achl~,
f2-rtw
maher
143 1 9idlrl,
EZ-ata9a
maI
02-tw
t-r
147 I Il+chin#,
02-te
wrhw
rd
vmt
1
I
wnt
I19 1 Ilmrhlw,
14s I Blmchlm.
1
2.OOE-3
I
I
vent
(OX) towr
115 1 Blmchlqj.
ACALNEIYEF
mt
wa,t
tat& mt
vent
mt
trill mt
I
I
l.fJoE-3
6.X%*4
r.aaE-3
4.62EzL-3
l.TIE-4
2.ooC-3
1.24E-3
4.42E.5
vant
vent
I
I
I
I
I
I
I
I
I
I
s.OOE-4
3.m-4
I.NE-5
l.oQ-3
6.11-4
1.14.7
2.OOE~6
l-W-6
- Emissim
PAWAL-EF
J
I
I
I
I
I
I
I
I
I
IAOE-2
1.2%-3
6.621-S
8.12E-S
l.ooc-3
6.62E-4
IME-4
2.OOE-3
1.32E-3
4.06E-1
s.O9E-4
3.3lE-4
4.99E-7
6.04-6
3.9zE-4
I
I
I
I
I
I
I
I
Ii
OWl2193
Factor Swry
1OlUEME~EF
CttElWtEEF
s.o(y-3
S.WE-3
1 FCDPJF
1
I
1 ~~F~EF~~CE~OPHN~F
I
1
1
I CM6OlS~EF
1
I HEXAbE~EF
1
10lHAPEF
l.ZoE-I
2.OOE-6
l.PzE-5
2.27E-s
1.64-4
i
I
i
I
l.37E-1
Z.LAE-I
6.4lE-1
3.23E.l
6.17E-2
l.laE-2
2.3v-2
IOlWCEF
1
.
,,,
I 2.01E.l
! 3-W-2
4.33E-I
I 3-w-1
I 2.17E-2
2.S&-2
!
1
1
I
I
I 4&E-2
I 3.77E-2
l.wE-2
1
1
z.soE-3
l.OY-2
I.%-3
2.93E.2
4.4lf-2
&DIE-S
1.25E-2
I 2.32f.2
S.3lE-S
l.llE.2
l.lY-2
4.m-4
I l.ISE-4
I 6.43E-s
I
I
1.Sa.z
I l.oy-2
I
1
IAlE-
l.nE-2
s.zn.2
1
1 FXS-EF
1
1
1
I
I
I
I
I
i
*m-.-m
I
: -a-be.--.-.1
1
I
I
1
1
I
I
WE
us
g
L
.LJ
CD
Z
0
4-w-e
I !
e-w-
-----m-----
m
.-__
1
=
0 *---------/-j:
I
I
.
GE1 t /
f- I
II 1
*-a-..-.-.8
-0
d
I
-iI 0
I
I
@- ~~.~~~-.~~~~
/.
-___
{ Gg[
ewe
-0
I
I
I/
I
I
I
0s
I
I
+ j $:
I
I
*---E
0
Y1
*-r-------E
mm--0
$2
0
-0v)+
i
I
E8k
/I,@&
sabE
/ISOa
1
I
I i/
/ I!
/
I I
--
E
4
81f1
s
C-62
:I
:
I
*
I
I
Ncdcl 84
, --.---
Straa
,..---
( WXO_IIP
, __
( ENCLOSURE
, -.-- .
1 SOWEE-IVP
.
____.__
. . ..~.
WCE
-
?8
giwchmg.
C-stag*
glcuhing.
Cl02 w&at.
u&d
SCYIC
Jlewhing.
C-stage
giigching.
C.stage wshcr
9irachuvg.
C.stage
(OX) caubt!c
t-c
WYCC
I
.. -1 PROC-IIPE
, ._
BLEACW
Sofl
SIREAN
BLEACH
sofl
SlREAM
VEN!
B?EACbl
vent
ULEACH
vmt
BLEACfl
92
gicachlng,
El.stagc
(UX) twtr
94
Dicuhing.
El-stage
(OX) usher
96
Bimching,
El-siege
OLEACti
::
Ileaching,
DI-ruagc
(OX) t-r
OLEACII
116
'4
118
glcuhing.
Dl-stage
glEACll
120
Bleaching.
Dl-slage
BLEACH
140
gicuhing,
EZ-slage
towr
142
Iimching.
EZ~rlggc
wshcr
144
glruhmg.
EZ.stagc
BLEACY
146
gigaching.
02.rragc
tww
BLEACY
146
Wemching,
DZ-stage
wshw
110
Ilwching.
DZ.@tagc
sd
tt
I
I
DIEACII
vent
fItEACH
vent
vent
vent
OLEACII
vent
BLEACY
rmt
vent
vent
MEACY
tank rmr
-..
ILEACN
._A
i
f
I
f
I
I
L/
SW1
SOfl
SOf1
SOFI
SOf1
Sofl
SO11
SOf1
._ _..-.-
1 W-CWE
1 EC-CODE
1
1
I ii
1
f
;
I
I
J
II
wl
I
j
tt
u
u
t:
;
I :
I :
IU
40
42
46
I
I
Iimching,
I glmching,
Ilmching,
I Ileaching,
7a gioaching.
92
I gimching.
94 Bimching,
96 I Bimching,
116
Oimchlng,
118 I gieuhing,
76
120
140
142
I
I
SWRCE
344
146
146
,150
dIgaching,
I Binaching,
gimching.
I gigaching.
llgaching.
I DImchin&
I
L
giggchiw.
C.slage
acid s-r
Cl02 rtic.
C-stage
(OX) curstic
tam
C-sfgge masher
C-stage
s-r
vent
vent
El-stwe
El-vcage
El-staw
Ol-tqw
(OX) 1-r
Vmt
Dl-stage
(OX) rusher
Ol*slage
(OX) swi
EZ.ntagm
fowc
EZ-stage
wshw
EZ-slagc
seai lti
DZ-acage
t-r
PZ-ataw
usher
o2-gtm
wal
vent
tank Vent
vmt
Vent
rmt
vent
rent
tank vml
L
I
I
I
I
I
I
t
I,
I
L
06112193
--
_. _--.-_.-1 SflO-fAC
-.-
1.16Ee1
I
!.3!E*3
VEYI
I --.~7.4oF.2
a
1 3.62E-1
P.IZE*l
VEYf
1 1.4OE2
s.ooE+z
VEYI
1 2.4OE.2
l.%E*Z
VEYI
1 3.62E-1
Z.S)E*l
VEYl
1 l.LOE-2
2.5&*2
WY1
1 Z.LOE-2
2.16E*z
2.26Et1
VENl
1 3.62E-1
YEN1
1 l.COE-2
1.65142
sofl
I
I
I
VENI
1 2.4oiE-2
6.91E+l
VENI
1 3.62E-1
l.ZlE+l
I
I
VENI
1 1.4OE-2
1.2602
YEN1
1 2.4oE.2
t+.WE+1
IN1
1 3.62E.l
4.57Et0
VENI
1 1.4OE-2
4.59E*o
--
SOfl
SOfl
sofl
swl
I4
ACEI-Ef
flEON~Ef
I CIEI-EF
I.OOE-2
------t--1
s.ooE-2
6.7OE-2
l.ooE-1
3&E-5
Z.WE-3
5.occ-4
3.OOE-2
l.COE-3
Z.ZSE-2
1 Z.&E-6
Z.ZOE-3
4.ISE-4
3.002-Z
7.ooE-3
2.16E.2
5.2SE.3
7.32E-5
2.06E-4
l.oOE-3
3.ooE-3
I.laEL-4
Z.ZSE-3
l.loE-3
2.42E-4
l.wE-2
3.%x-3
l.ME-2
2.63~.3
Z.p(Y-7
6.9OE-7
4.91X-6
l.o(y-5
z.a7E-6
7.%-6
1
I
. Emission
-I
1
I
I
t
I
I
I
I
Li
l@K-Ef
HAL~SIAIUS
I.
1.53E+l
!
/
I
1.
I
v
I
1
1
I
v
I
factor Smcy
1 PCDI-Ef
FORN-EF
-1-
-1 NCLJf
CLZ-Ef
1 NECL-Ef
--L
1.zQ-2
1
l.O3E-4 1
l.OoE-3 1
9.09E-3
3.07E-5
Z.loE-1
c.wE-4
2.1OE.l
z:oOE-2
1 3.OaE~3
1.31E-3
1
I
3.64f-6
2.69E-5
3.oM:l
1
1.63E-2 1
3.loE-4 1
3.0&-3
1
5.099-l
4.wE*4
I.ow*I
3.46E-I
3.07E-4
7.61E-I
P.ZlE-4
1.29E-2
l.OOE-2
1.63E-3
I.3&-3
2.5U-4
l.SSE-3
1.92E-6
I 1.34~.5
1.5&-2
Z.SlK-5
Z.ooE-4
&ME-3
1.73E-5
1.54E-4
2.lOE-7
4.61E-6
l.ooE-2
2&X-6
1
1
I
6.&N-5
l.ow-2
4.15E-5
2.54E-4
3.91X-2
5.32t.3
l.ow-2
-.- __
CllCL3-EF
--S.OY.3
l.loE-3
II
I
I
I
I
1
1 I
j I
.------L- .-I _.--.I!
I
i
I
l.ooE-6
-- __._
SYAP-CON
1.. . .._.
sot1
-r-
vHAP-cON
--_--
Sofl
N&i
r-
1 VflO-fAC
Charactcrlscics
--T----
I :
,._
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3.56E.4
5.wE.4
4.%E-5
3.56E.3
s.lw-3
4.%-4
4.3of-3
I Z.ME-3
b.ZlE-3
I b.ZlE-3
3.39E-4
I l.ME-2
1.06E.2
I 6.7EE.4
2.05E.2
5.47E-4
I Z.OSE-2
1.32E-3
1.79E-3
S.ZBE-3
6.OOE-3
z.s(Y-3
2.26E-4
l.O8E-3
l.SllE-3
1.37E-4
I
I
I
I
S.ZM-3
3.3%.4
3.36E-5
3.3&-5
2.96E-6
7-.-JI
I.
I
I
L-BENZ-EF
--
----T----
/
I
I
LI
1
I
I
I l.OlJE-4
1
1
1
1
l.o(y-4
J.ooE-4
3.mE-4
4.17E-6
I
,
1
1
,
1 1.9x-4
1 1.5OE.4
1 ZAWE-6
I
I
i
No&i
r
(*PV-CODE
I
;
u"
I ::
I
I fi
I ::
T
I
46 i
I
1 EPJCDf
I
I
I
I
I
sa*CE
40
Mewhim,
42
Blowhi~,Ci02rrlrt.
76
C-rtw
acid sewer
(OX) caustic sewer
iieuhi~.
t-at-
tour
Blwhin&
c-at-
Nashw
vent
vult
c-rto@a
l*i tuavent
I Ilmcth#,
92 Iiwhi~,
94 I ~bchln..
w I Ilmchiq,
El-at-
WX,
El-rtaw
(OX) ulw
tww
vent
vent
El-mtw
Bimchity.
Dl-*taoi
(OX) tamr
Dl-stage
(OX) wshw
~lwchl~.
Dl-at-
(OX) uAi
L2-t-
1-r
I Uwchlw,
I Ilodtl~,
Ilmchlrq,
I Bl*achl~,
8lnchl~.
I ~l*actlI~,
I wmc.hl~,
L
EZ*atb#e mmimr
EZ-rtw
02.atDZ-rt*
DZ-mtaw
went
vmt
mt
tmd
vent
vmt
, PCP-EF
1
, ACRO4EiNEF
1
1 1.7SE-3
2.OOE-3
l.ooE-3
i-776-6
z.Mc-s
1.24E-5
1.77f-4
Z.OOE-3
1.24L-3
4.4H-5
s.KJE-4
3.m-4
Lax-5
l.olx.3
6.18E-4
1-m-7
::z::;
mt
leoi Cd wnt
tarrvent
n&w
valt
amI tr* YIIt
I
I
I4
. Emission
1
j
I
I
PIOPAL-EF
1.&x-2
l.ZOE-3
_ ._.
9.1tE-6
l.of&-4
&II-S
l.ooE-3
6&Z-4
l&E-L
Z.OOE-3
1.32E-3
4.0&-5
s.ooE-4
3.31E-4
I
I
L
4.pQc-7
6.ooE-6
3.97@-6
hctor
IOlUENE-EF
Tj
I
I
I
I
I
I
I
L
2.OOE-6
WlZI93
Wry
I
1 CttEWANE~f
1
1 ICDD~Ef
1
I
1 ICOf-Et
L
1 ACEIWltNEF
I
I
, CAAUllS~Ef
I
I
, NE&ANEWEf
1
I
1 TOlNAPEf
1
I
, 1.1%.1
rorvoccr/
, 1.386-l
2:02E-1
1 2.5OE-1
9&E-3
.I 3.97E.2
1
1
2.43E-2
I2.%-2
1
1
c.(bL-2
O.Wf-2
1
1
,
b.Zlt-2
1.21E-2
l.LlL-2
1
1
I,
1
1
1
4.07E-5
1
1
I
1
L.ooE-4
SAKE-4
I
i
6.ooE-4
S.oQ-4
s.ooL-3
I
1
s.wf-3
1.6w-4
2.54-3
F
I.
i i.iOE-1i
.I
2.5aE-3
&OlE-5
I
I
I
i
1 2.63E-2
1 2.521-2
, 3.65E-2
, 5.74E-2
1 1.62E-2
1 2.9SE-2
I 6.43E-2
I
I
I
I
I
I
1 l.l7E-2
, 3.07E-2
, 1.266-2
1 1.166-2
,I
I 1.1x-2
1 4.5%.4
1
I 2.21-2
I
I
4.nE-2
I 2.33E-2
I 1.236-l
I 6.41-5
I
69
111
t
:I
I1
I
:
:
I
II
I
:
t
:.
1
I
1
1
I
I
------r-
-I
oi
Eli
mAGE
i
I
0
137
E2
STAGE
0
305
mWER
I
TOWER
I
I
--N
w-
0
65
63
--.
ACID --.
-_
--
.
\x\
CAusrlc
\
\
.\
-5.
\
-.
\
-N
.
-.
.
-.
-\
...
WASTEWATER
COLLECTION
&
TREATMENT
0
149
Ott/l2193
ltodelR5
,--
._ .r .._.. -_
63
I
'---t----R5
1
ill
65
7
t
I
SCURCE
--._.-.
1 ItPU-CaJE 1 EP-COOL
C.rtage
Olrwhing.
Rlwching,
C.stapc
l5
'5
::
::
113
us
1
135
145I Rbchiq,
69
87
i Rlwching.
Weaching.
;:
111
::
I fis
I
IS
133
I 85. 1
I
::
137
i PRUC-IIPE i UOU).IIP
; ',;;cw -.,....HARD
Rlcachtng,
acad )c"cr
C-stage washer
C-stage
vent
El-stage
(IOU) towr
8leuhing.
El-stage
tlou) uachcr
f Bleaching.
El.stagc
(1~)
Weaching,
Dl.stagc
(low) touw
1Bleaching.
Dl-stag*
(IOU) wshw
vent
vent
seal tmk.vcnt
vmt
vent
HARD
RlEACW
HARD
RlEACtt
ItAft
RLEACW
ItAR
PLEACII
klAftD
RLEACW
HARD
RLEACH
ttAf!D
OLEACH
HARD
RLEACH
YARD
BLEACH
HAtto
RLEACII
HARD
ILEACY
tlAR0
RLEACY
HARD
RLEACY
HARD
BLEACH
WAR0
1 RLEACH
-I-
IIARO
Y-t
Ileaching,
02.stage
wrhcr
02.stage
llraching,
EZ-stage
t-r
Ilenchinp,
EZ-stag8
washer
/;Ileaching.
L
t-r
I Bleaching.
305
IlLEACH
Ol.rtr~
149
301
02.wgc
147
303
WYCT
touer vent
I Bleaching.
Bleaching,
- Strer Charrctcristics
-..-...--._.
-I------~-~ENCLOSURE
SOLIRCE~IIP 1 VflO-fAC
._
._ ----.+--.
_--
vmt
vent
vent
I. _.--_. I,I
II
I
i
/
I
I
1
f
I
I
I
II
IL.
L
ltodel OS
r
I
1 ItPU~CdOE 1 EP-CQ)E
BS
B5
I
(
c)I
1
::
63
I
I
BI
I
1
69
a7
69
IS
1
65
1w
'5
113
::
135
15
145
:'5
85
I
I
t:
:I
111
85
13s
85
1
137
147
149
301
I
1
105
303
StXMCE
T
II
1 ACEl-Ef
.--+----t--
Rleuhing,
C-stage
Rl8whing,
Cl02 s&t.
8leachiw.
C-stage
Rlcwhing.
Bleuhtng.
Ileaching,
El-stage
(IOU) t-r
I Rl~aching.
wbd
s-r
1 WOH-Ef
I Z.ZOE-3
I 4.6OE-1
I Z.OOf-3
I l;o(w-1
tower vent
I 1.43Ec-4
I Z.ITE-2
C-rtqe
ushw
1 1.95E.J
1 4.1SE-1
C-stage
1 1.4OE-3
I I.llE-1
I 2.2oE.3
I 4.65E-4
(IOU) caustic
scwr
vmt
wnt
El.rtaga
(IOU) usher
I J.OM-2
I 7.WE.3
Ol*achlng.
Rl.stw
(lwl
1 2.1Y.2
I 5.2x-3
Dl'rtega
tlw)
tower vent
1 7.32E-5
I Z.OOE-4
Rleuhing,
Dl-stage
(IOU) uashcr
I Ileuhing,
1 l.oOE-3
I 3.ooE-3
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1 7.1&E-4
I Z.ZSE-3
Bleaching,
02.stage
tower vat
1 2.9OE-7
1 6.9OE-7
Rlruhing,
DZ-stag*
washer vmt
1 4.ooE-6
1 l.OOE-5
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02.stage
I 2.87E-6
1 7.54-6
#leaching,
EZ-staga
t-r
I l.lOE-3
I 2.42E-4
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wshcr
EZ-Rtaw
I Bleaching,
I Rlcwhing,
.IBleaching.
L
vmt
vent
vent
vent
1 1.50E.2
I 3.5OE-3
1 1.00~~2
1
1 2.63~~3
t
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l&E+1
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9.06E*o
l.LSE*l
1.46E+3
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1 3.62E-1
2.52E+2
VW1
1 1.4OE-2
3.2903
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1 2.4OE-2
l.ClE+Z
VEYf
1 3.62E-1
2.43Etl
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1 l.LOE-2
2.54E*2
VEYI
1 Z.COE-2
1.wE*z
VEYI
1 3.62L-1
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1 1.4OE-2
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VEYI
1 Z.LOE-2
6.6M+l
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1 3.61-l
4.57Eto
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1 1.4Q-2
4.59E+o
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1 2.406-Z
6.14E~+l
VEYI
1 3.621-l
1.15Ell
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1 1.4OE-2
I
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1 2.4BE-4
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1 2.4OE.3
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I 1.3tE-3
I I.l(Y-3
1 i-z::
I ,:a-4
1 3.oOE-3
I 1.63E-3
I Z.loE-7
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1 fQlt_Ef
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1 CLZ-Ef
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1 3.64E-6
I 2.696-S
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I LOIE-4
1 ?.61E-5
1 3.46E.1
1 9.211-4
1 l.ZoE-2
1 8.xX-l
1 4.61E.6
I 6.W.1
1 4.lSE-5
I 1.92E-6
1 Z.SOE-5
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I
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1 5.32E-3
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,----f-----t---64 1 Olcaching,
1
i
66
I
!
70 ! glcaching;
ii
I
1
I
08
1 glcaching,
90
1 Bleaching.
C'stagc
112 I Olerching.
El-stage
(Lou) uasher
I Ileaching.
El.stagc
tlw)
134 I Bleaching,
Ol.stmpc
(IOU) t-r
136 1 glrhchtng,
Dl-stage
(Lou) wshcr
136 I Ileaching.
Dl
146 I glcwhing.
DZ stage towr
148
I gleachiw,
DZ-stage
mshcr
150
I glewhing,
DZ-stapc
sggl la&
302
I Bleaching.
EZ-stage
truer vent
3D4
I Bleaching.
EZ-stgw
wshcr
306
I DIgaching,
1
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114
/
1
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tower vent
I 06
(IOU) csusttc
Cl02 stbst.
C-stegc
LtLEACW
acid scwcr
El-stage
t6"
:
C-stage
110 I Ilcaching,
ii
1 glcgching,
i PROC-IIPE
I
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vent
I
!
vent
; EYCLOSUAE
SCURCE~IVP
1
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I
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Safl
SOf1
SOfl
SOTI
II ltPU~COOE
1
I EC-CODE
1
1 &CL
I
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2
s
II
I
1
ml
66
WI
86
I
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66
I Weaching,
Cl02 IL&I.
70
1 glmching.
C-stage
tmm
I Blemching,
C-stag*
wshcr
90
I glmwhing,
C-stage
110 I glmching,
06
I ,=
1
it
I glmching.
I
/
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(1080 cwst~c
saw
VEYI
3.62E-1
VEYl
1.4oZ-2
SOfl
VEYI
2.4Of-2
SOfl
VEYI
3.62E-1
SOfl
VEYI
1.4OE-2
SOf1
VEttl
Z.COE-2
OLfACtl
SOTI
VEYI
3.62E-1
gLEACY
SOfl
VEYI
1.4DE-2
ILEACW
Mfl
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2.4OE.2
sof I
SOFI1
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SOff
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SOFl
VEYl
3.621-l
SoF'
I
L
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----.-
ILEACII
OlEACtl
ILEACH
ILEACV
BLEACN
ILEACY
I
L
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WEACY
I
1 ACEl-Ef
I
1 )(EOU-Cf
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1 l.DDE-3
I z.DDE-1
. Emirsim
1 Ml-El
I l.DDE-3
I l.tME-2
1 Z:OOE-3
1 3.66E-5
1 2.w-3
1 l.OY.4
rmt
1 s.DoE.4
1 3.ME-2
1 l.OoE-3
1 3.59E.4
1 2.25E-2
1 5.44E-4
1 2.2U.3
1 C.bSE-4
1 3.lcs-3
El-stage
(I&)
t-r
112 I glaching.
El-staw
(la)
uashcr vent
1 3.WE-2
1 I.OOE-3
1 3.OOE-2
114 1 glcmching.
El-stage
1 Z.lbEc-2
I 5.2SE-3
1 1.63E.2
134
I glguhing.
Dl-stag*
1 7.32E.5
I Z.DCtE-4
1 3.11-C
136
I DIgaching,
01.stage
(Iwl
1 l.o(y-3
I 3.wE-3
1 3.ooE~3
146
138
I Ileaching.
Ilwching,
DZ-gtagc
Dl-rtrgg
(low1
loycr rwl
vent tank vent
1 2.9OE-7
7.1&E-4
1 6.9oE-7
Z.TSE-3
1 1.63E-3
wgshw
vent
1 Z.lOE-7
I
141
I Ileaching,
DZ-rtagg
wrhrr
150
1 Bleaching,
02.&Cage
seal twk
302
I Dlewhiw.
EZ-gcgge
tow
vent
vmt
vmt
304
1 gIgaching,
EZ-rtage
w&w
306
1 Blguhing.
1
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ggrl tad
vent
vent
Factor
1 4.ooE-6
1 l.OOE-5
1 z.o(y-6
1 2.87E-6
I 7.5OE-6
1 l.D9E-6
1 l.lDE-3
I 2.42E.4
1 l.SSE-3
1 1.5oE.z
I 3.%x-3
1 l.SoE-2
1 l.tME-2
I
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1
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I
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;
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1 2.77E-4
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1 3.4&-5
1 P.ZlE-4
1 l.ZoE-2
1 L.3OE-3
1 4.61E-6
1 6.OOE.5
1 4.1SE-5
1 1.92E-6
1 2.54-5
1.73E-3
4.&x+0
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1.56E+2
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2.56E+2
1.7902
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1.61E+2
6.%X*1
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6.91E+l
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1 3:4OE.3
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rent
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. Stream ChAractaristics
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1 l.ooE-2
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1 l.OOE-2
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1 2.54E-4
1
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1
I
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--
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I 4.32E-3
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6.76E.4
/ 1.43E.2
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I P.lSE-4
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-:
1 PblEYlJf
1 MCMCl3fF
1 ICP245Ef
1
1
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1
;
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2.01X-6
1
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t
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I
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1 px-6
1
1
1
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64
1
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I
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CP-CrnE
1 l.RE-3
66
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CIOZ s&w.
70
I Blwchin9,
C-ltw
tour
80
1 Bl*wkin9,
C-it*
u*l*r
1 Bl*6cLin&
C-Ha@@
::
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vent
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El-Ar~9e
tlou) raw
112 I @louhi-,
El-At-
tlor) rusher
vent
114 I Bl.wbIn&
Ll*ata#e
Dl.nty
136 1 Ilawblw,
Ol-statp
(IOU) umber
Ol-rtaw
tlou) Cal
I ii
146 1 6lawhlw.
02-stw
t&w
1U
02.rtw
wabrr
I :
lS0 I nlwchiIl@,
oZ-~ta#e
real t&l
302 1 Il.acbln&
LZ-atarp
ttmw
304 1 Il*uhtn&
cz-ata@e
lwbw
SW
r2-tr
rul
I ii
i
vent
134 1 Ilewhin9,
I Blerhin9,
1 Il.achirq,
1 ll~acLIn#,
1
1Y
s-r
vent
I y
_3-
:
06
1 PCP-Ef
I
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vent
vent
tr*
v-t
I
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mt
MC
Kmb
vent
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ACROLEIYEF
5
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1
I
I
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1 PROPAL-Ef
I
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3.ol&-4
l.otx-4
a.oOE-4
1.77E-6
&.lZL-6
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1.005-L
1.24E-5
6.62E-5
1.77E-4
1.12E-5
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l.Z4E-3
6.62X-4
4.4X.5
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Z.OOE-3
3.09E-4
1.32E-3
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4.9OE-7
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6.ooC-6
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3.97E-6
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4&E-5
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I.mf-4
6.lI-4
1
1
3.3lC-4
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IOLUEltE~EF
I
I
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I
I
I
I
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I
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3.ooC-6
l.OOC-6
6.OW-4
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1.92E-5
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5.005-J
l.MK-4
I
/
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2.27E-5
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L
I
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2.5OE.3
06112/93
Suury
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1 4.2M-2
I 3.7&~-2
1 2.92E-2
2.4Y.2
1 2.63E-2
2.43E-2
1 6.4X-2
9.0&-2
1 2.52E-2
4.U.2
1 3.02E-2
l.W-2
1 5.12E-2
3.62E.2
I
I
1 1.5Y-2
l.Slt-2
1 l.llE-2
4.07E-5
1 l.l6E-2
1.23Es4
1 L.IZE-4
6.4X-5
1 l.l7E-2
l.ZlE-2
4.54E-2
1 3.07E-2
1.26E-2
1
2.33E-2
1
1
I
I
I
I
I
1
1
IOtWCEF
-6
1 Z.lZE-1
I
1 IRS-Ef
7-
I
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1 2.4M-1
I
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1
t------#---1 l---'--r-------"-n
n
:
1
1
1
I
:
,
1
a
I
TOWER
c/D
STAGE
w-
(-)-I
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,n
0
65
TANK
w
yz
-\-\
Nz
ACID
-.
-\
55
.
\
57
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.
WASTEWATER
COLLECTION
(L
TREATMENT
wodci 81
-T
II 'W-CODE
SOMCE
1 W-CODE
J
t------t-
Oicaching,
I Iicaching,
glcwhing.
thigh) cw.stIc
twrr
i Blc~hing,
Bleaching.
C-staw
masher
I Bigaching.
gigAching.
El-stage
(high)
El-stage
(high) rA+hcr
vent
vent
t-r
Dl.stagc
thigh)
I Bigrching.
Ol-stage
thigh) washer
glcuhing,
/ Iied~inp,
L
t-r
DZ-stage
toycr vent
02.stage
wshcr
DZ-stage
scai
EZ-stag8
tower vent
OLEACII
I
I
BLEAClt
vent
vent
~LEACW
BLEACil
BLEACii
UEACII
tank wnt
~LEACli
ILEACY
vmt
sea' tmk
ElLEACil
vent
vent
EZ-gtagr uashcr
glEACW
BLEACH
EZ-stwc
vent
t gi*achwq.
glcuhing,
BLEACH
BLEACH
vent
El-stage
i Ileaching,
gicuhln&
vent
I Ileaching.
gIgAching.
Iieuhmg,
s~uer
i PROC-IvPE
t ILEACH I
91 EACH
C-stage
vent
-
BLEACN
I ILEACil I
L -I
llAilD
'IA90
YAim
"AAD
IiAflO
HAAD
ilARD
WARD
HARD
'IA110
YARD
ilARD
tiAil0
IlAID
"MO
'IAlD
YAW
I SCUCE
1
-----1
c-y---+
55
1 BigachIng,
57
I IleAching.
Cl02 stit.
I
":I
Nl
1 EP-CODE
1
::
'I
I7
I
I
I
I
f
1
(htgh) CNSIIC
61
I giewhing,
C-staw
I3
1 Ilkhing,
C-stmge uerher
15
1 Biguhlns.
C-stew
103 1 Ileaching,
El-at+
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t-r
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1 3.%-l
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I
5.OOE-1
I
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thigh) wshor
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1 2.9OE-7
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vmt
3.m-1
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1 L.ZZE-3
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87
97
127
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129 I
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bl-*tog*
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307
309
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311
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1
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1
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I
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7
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toucr wnt
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Di-r1.o.
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glcuhin&
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106
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thigh) uarhw
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IlachinI,
I Ilcwhing.
glrrching.
1Ilguhing.
Ileaching,
I Ilmching.
Ileaching.
I Ilmching,
Ileaching,
I Ileaching,
I
L
Ileaching,
vent
vent
tower vent
BLEACn
NLEACY
HARD
OLEACW
llAR0
ILEACY
NARD
OlEACn
HARD
BLEACH
HARD
RLEACli
YARD
El-stage
BLEACH
nARD
Dl-stage
9lEACII
llAID
Dl-stage
t1OOX) wshcr
Dl-stage
4100X)
DZ-stag*
ILEACY
WAR0
ILEACY
IlARD
toycr vmt
ILEACn
HARD
DZ-stage
washer
ILEACY
MAID
02.stag8
seeI tmk
OLEACll
lkAI0
EZ-stage
tower vent
ILEACI
IlAID
ILEACW
nAm
1
1
ILEACY
1
1
MAID
-
rent
EZ-stage masher
EZ.stage
--
vent
vent
vent
---T
1
1 EP-CODE
k---r;
01
:p'
'9
11
I9
41
001
I9
IO
I
I9
19
19
IQ
I
I
I
lQ
I
1:
I
1
WEE
47
IleachtnI.
49
Ilaching.
Cl02 u&t.
53
Iloaching.
C-stoIe
t-r
79
Ilachiw,
C-stage
wshw
real tmk
C-styc
uid
s.ww
1100X) caustic
swcr
vmt
rwu
I1
glwching,
C-staw
97
Ileaching.
El-rtatw
(100X) t-r
QQ
IO1
Ilwching,
El-staga
(100X) uanhcr
Iluchirw.
El-rtw.
rent
1 ACEl-El
I
I
1 2.71X-3
1 ltEOI_Ef
E
I 3.50~.3
I 3.00~.I
1 ?.32E-5
1 7.62E-3
I l.ooE-3
1 l.loE-1
1 7.11.4
1 I.2SE-2
vent
1 6.22E-3
1 5.4OE.l
rmt
1 I.SiX-2
1 7.8M.2
I 6.11E-2
I S.ISC-2
I21
Ileaching,
Ol-ataw
1 Z.QOE-7
1 6.QOf-7
123
@leaching.
Dl*ata@e
(IMX)
1 4.OOE-6
1 l.m-5
1 2.67E-6
1 I.SOE-6
1 2.906-7
1 6.QOE-7
1 4.OOE.6
1 l.OOE-5
1 2.67E.6
1 7.SOE-6
I l.llE-3
I Z.IOE-3
1 C.ZSE-2
I 3.%-Z
1 3.OSE-2
1
1 2.93E.Z
1
masher
rent
125
Ilwching,
Dl*staga
145
Ileaching.
DZ-stw
t-r
147
Ileaching.
DZ-staw
usher
149
IlgwhinI,
02-stage
eed
313
Ileaching,
EZ-stag8
t-r
315
Ilwchimg.
EZ-stw
wslwr
'317
Ilomching.
EZ-stew
ant
w'Mt
tad
vent
vent
vCnt
vmt
.___.
d------
1 SWICE-IIP
SfLO-fAC
--
9.06Et0
I
I
I
f
I
VEYI
1 Z.COE-2
3.73Et2
VEYl
1 3.62E-1
6.97E+l
YENI
1 l.CoL-2
Q.lP+Z
VEYI
1 2.4W-2
1.62E+2
Vttll
1 3.62E-1
6.6lEll
VEYI
1 1.4OE-2
l.OY43
VEWI
1 Z.COE-2
6.60Etl
VEWI
1 3.62E-1
4.smo
VEYI
1 l.LOE-2
4.59Eeo
VEYI
1 2.4OE.2
6.6OE+l
VEttl
1 I&E-1
4.57E+o
QEYI
1 l.4tX-2
4.59E*o
VEYI
1 2.4OE-2
I.loE*l
VEYI
1 3.62E-1
3.3aE41
#II
1 1.4OE-2
s.nE*z
L- Emission
i
I
I
I
I
I
I
I
Ii
1 (rKJf
T
-t
I
I
I
I
I
I
I
II
factor S&a. vy
I
tIEI_Ef
1.04Erl
SIREAM
L/
) VfLO-TIC
t-----I
ltodel IQ
,
1 tW_CODE
08l12l93
- Stream Charbctcristtcs
69
._._._
...- -1EYCLOSUAE
I KKO-IlP
I._._._ ___.I.- ---.
1
nAnD
----I.
1 PROC-IIPE
, ..--_--
PCDI-Ef
t
--y--GI
1 fOItt_Ef
lbfl_Ef
1 CLZ-Ef
i
1 hce:3
2.W.4
1 7.2X-C
l.WE-4
1 2.QW.4
1.34E-5
I S.ooE*Z
Z.VOE-4
1 7.OOE-3
l.OOE*L
1 3.pot.l
Z.tUX-4
1 S.OOE-2
Z.WE-6
1 l.(llE-3
1.22E.5
1 2.7(y-3
l.SCE-4
1 1.27E-3
1 6.%-3
1 4.07E-4
1 6.3OE-2
1 5.3moE-3
1 3.43E-2
1 3.67E-3
1 Z.lOE-7
1 4.6lE-6
1 2.OOE-6
1 6.OM.I
1 l.OQE-6
1 Z.lOE-7
1 Z.OOE-6
t
I
I
II
G/l-Ef
I
1
I L-IEYZ-If
1
1
1
1 PVEYL-Ef
1
1 lKIcyCL3Ef
1
l.W-3
b.ME-3
5.02E-4
1 2.4lE-4
1
I.Qbc-4
1 I.WE-4
1
1
1
I
I
I
1 3.ooE-4
7.m.4
1 8.37E-4
I'
6.3&eS
1 5.51E-5
1
1
1
1 Z.HE-4
4.621-S
1
1 4.62~~5
1
1
I
I
t
l.OIE.3
5.83E-4
I.%-3
1 4.lSE-5
1 2:54E-4
1.37E-4
1 2.96E-6
1 4.6lE-6
1 l.ooE-2
l.OIE-3
1 4.62E-S
1 6.oQt-5
1 l.wE~2
1 4.lIE-5
1 Z.SZE-4
1.5M-3
l.J7E-4
1 4.62E-5
I Z.ME-6
I
I
1 4.17E-6
I
I
I
L
lV245Ef
1
iGJ
I
I
I
t
I
I
!
I
I
I
I
I
I
I
I
1 2.65E-3
1 l.Ix-3
1
1 l.pdE-3
J.W-3
1
1 l.oac-4
6.4OE-3
4.59E-3
/ ;.-;
1 Z.OlE-4
1 1.71E-2
I
I
2.29E-3
2.92E-4
l.ZoE-3
1 1.96E-3
1 1.9&-3
1.27E-4
1
1
1
1
I
I
I
L
--.----------B--v-
=I
::
z
3
6
c
::
3
5
--.--__--a---e---w
--.---------------
::
s
i
--.--------------_
:
2
s
_---------------__
I
y
Y
E
B
------------------
::
d
----------w---e---
::
i
ii
5
II)
b
E
.-s
.-2
I!!
$
ni
iii
---e-------------w
z
3
L
--mm----a---a-----
=,
z
8
L
ti
;;
$
l
yy?s?.e
gi
i%aw~~~Es~k
0: , ; ; d
fd
r;
ci ;
-_---------------_
?yy*yyfFt??nne
wmnna~~~~~~eii
. . . . . . . .
.%-*,nn-lu--N-c&Ld;;
_----------------_
n
s
%
------------------
..e....
$&EP.Er.!!!r.QZ~
---I
::
si
rr14191331~1Slf~~
.........
e-M
rr~zzz~117375z1z~
-----------------
$2::
p.&gbfzcS3LDSS
C-CLCCrmLlm
I
5
eeeeeaaeeteeaaenn
$
---,---e----m-----
c-79
a-----
~-----------
;!I
I
I
(3
W
I
*--f-.
I
I
I+;;----- Wf5
*
*-------,sg
II
0!!
L
.5
53
,4
0
/
/
g
1
I
/I
I
-r-
.___-I
I
Id
8
Q
,y
ge----Y / /
0
,----a--33
-r cot
--
/
/
/I
;
*-..e
3
0
Y,I
Be--ik
n mc
E
8.
04
1.
5
lil :: II
1
:
I
I
I
:
C-80
I
I
Itodel BlO
'10
I 10
wo
BlO
I 10
lctd sewer
Weaching,
C.stage
rlcachinp,
Cl02 a&t.
Bleuhing.
C.rtbgc
twcr
Bleaching.
C-stage
usher
C.stage
El-stage
(100X) twcr
Ilmching.
El-stage
Umchlng.
El-stbgr
146
Bleaching,
DZ.staoc
tower vmt
148
Bleaching,
DZ-stage
usher
(100X) wsher
vent
150
Ileaching,
DZ-stage
seeI tmk
Ilcuhing.
EZ.stagc
twer
316
Blwching.
EZ-sta9e
washer
311
Bleaching,
_____-
EZ-stage
seal tmk
'
vent
vent'
vent
01 EACH
BLEACII
BLEACII
BLEACH
vent
314
vent
IleachIng.
Dl-stage
8lcuhing.
Ileaching.
Ileeching.
I @loI
OLEACII
vent
Oleaching,
BLEACH
OLEACH
vent
124
PPOC-1VPE
BLEACH
126
I
1
OlEACtl
BlEACtl
f~lEACll
I
I
BLEACH
BLEACN
ILEACH
ILEACY
llEACll
vent
.____
I ILEACII
I --
iI KIW-IIP
1I
SW1
Sofl
I 10
cl
&
e
i
1
1 ACEl-Ef
48
r
1 SWRCE
I
I
I Ilwchirq.
C-stage
50
I Ileaching,
-----t---acid sewer
sewer
SIREM
SIREAH
VEYI
1 Z.COE-2
VEYI
I 3.62E-1
VEYI
1 1.4OE-2
VEYI
1 Z.COE-2
I
I
!
I
I
I
SOfl
VW1
1 3.62E-1
SOfl
YEN1
1 1.4OE-2
SDf1
VENI
1 Z.LOE-2
tiff
VENl
1 3&E-1
SOfl
VENI
1 l.:W-2
SOff
SMI
SOfI
SOfl
Sofl
SOfl
SDfl
i
.A.-
SDfl
I
L
sofl
ItEM-Ef
--
1 2.7OE-3
5.DDE-1
I 3.5OE-3
3.w.1
110
54
I @leachin&
C-step
tower vent
1 2.206-b
6.23E-4
llO
80
I Bleaching,
C-rtatp
masher vent
1 3.ooE.s
P.OOE.3
/
L
I'2.lbE.l
6.RE-3
1 6.22E.3
5.4OE-3
ClEl-Ef
i
I
I
VENI
1 2.4t1. ?
VEWI
I 3.62E-1
VENI
1 1.4llE-2
VENl
1 2.4DE-2
MN1
1 3&E-1
VENl
1 1.4DE-2
1
. Erirsta,
I
1 *EC-Ef
_.-_-_
-r
SftO-fAC
.VWAP-COY
--.-.i.
l.O4E*l
i
:
I
I
I
I
I
I
Ii
9.obttO
---yzk$
1 fDRft_Ef
v
---yQz
1 I.DDE-4
1 b.wE-3
3.DDE-4
1 l.O3E-6
I 3.oOE-4
3.w.4
1 l.DDE-5
I I.ODE-4
2.&E-6
1 S.LLE-6
1 1.22E.S
1 4.07E-4
110
12
I Ilwchiqt,
C-staw
PI
1 Blcuhinp,
El-stage
(IDOX) tour
100
1 Blwchiq,
El-stage
(100X) usher
1 8.5DE-2
7.ME-2
1 6.3QE-2
1 5.3wQ-3
102
I Bleaching.
El-stage
S.bSE-2
1 3.43E-2
1 3.67E-3
I b.llE-2
122 I Weuhinp,
bl-stage
(1MX)
1 Z.p(Y-7
b.voE-7
1 Z.lDE-7
1 4.blE-6
124 1 Bleaching,
DIestage
(100X) usher
1 ~.ooE~b
l.ooE-5
1 z.ooE-6
1 b.ooE-5
126 I Blcuhino,
Dl.stwp
1 2.a7E.b
I.IoE-6
146 I Blanching.
DZ-stqta
tower vent
1 2.VDE.7
b.wE-7
14b I #Iaching,
DZ-stage
usher
1 4.ooE-6
1.OOE.s
:I
:::
:::
810
NO
I ml0 I
I @IQ I
vent
rent
toner vent
vmt
vent
rent
I
I
I
I
I
b.%-3
1 l.O9E-6
1 4.lSE-5
1 Z.loE-7
1 4.blE-6
1 z.om-6
b.DDE-I
150 1 Bleaching,
DZ-stage
1 Z.b7E-b
7.5clE*b
1 l.D9E-b
1 4.lIE-5
314
I Blwching.
EZ-stage
towr
1 I.llE-3
2-m.3
1 3.2SE-3
1 2.03E-4
316
1 Blouhl~,
EZ-tetje wshcr
1 4.2%.2
3.%-Z
1 3.15E-2
1 Z.b5E-3
316
I Blwchiw.
1
EZ-stage
1 3.05E-2
1
z.v3EE-2
1 1.71E-2
1
1
1
1 lab-3
I
vent
vent
I
I
L
jY
I
1
6.57Ell
b.NWl
4.59E+o
1.2oE+2
2.4bE+l
EL5801
1.sbE*2
l.OJE+I
4.57E*o
b.%Wl
I
I
I
4.57E.O
4.wE+o
SWAP-CON
r---.1
1 HAL~SIAIUS )
7.7901
3.28Eel
I S.l3E+2 /
I
1.
factor S-TV
I
1 PCDI-If
110
I 0
1
I
1 EP-CODE
08~12193
Charactcristlcs
SOfl
It061 110
I
1 NPU~CCOE
StreY
._
1
I
I
I
/
I
I
I
LI
NCL-Ef
I CLZ-Ef
ii
Z.OZE-5
1 I.ODE-2
3.DDE-4
1 I.OOE-2
2.3DE-4
1 1.27E-3
I
I l.DOE-2
1 l.ODE-2
b.DW-3
1 b.OIE-4
3.uy-3
1 3.69E.4
1 1.4Y-4
I l.VY-3
1 P.oQE-4
1 l.PJE-3
1 l.QE-5
I 1.24E-4
I C.WE-3
b.LOE-3
1 WllCL3Ef
1 KP245Ef
--y----E
2.9OE-3
1 2.9OE-3
I 5.8X-4
I l.DaE-3
I 3.3&t-s
I l.SOE-3
I 3.3&E-5
1.8bE.4
1 Z.SLE-4
1 1.37E-4
I z.w-6
1 l.DDE-2
1 l.wE-3
I 3.3&E-5
1 l.DDE-2
1 1.5a-3
I 3.3aE-5
1 2.54E-4
1 1.3R-4
1 2.vbE.b
2.2W-3
1 1.4SE-3
3.2OE-3 1 1.45E.3
2.92E.4
i
I
I
I
I
!I
L-bEtlZ_Ef 1 PNENL-Ef
1 9.3DE.S
1
I
I
I
I
I
1
1 Wtf-caDE
I
1 EP-CODE
4
I
40
1 SOWCE
1
1
I Ilouhing.
i
1
810
IO
1 Blowkin&
cID2 s&at.
54
1 6lmchin#,
80
1 #Iaching,
C-Atw
tamher vent
a2
1 Blmchill#,
Castle
9U
1 Bleaching,
::oO
010
a10
810
"O
BlB
BlO
BlO
t::
n10
scuw
BlO
#IO
I
I
100 I Blmching,
I
I
I
I
1
I
!
1 ACRDlElNEf
1 1.7SE-3
El-At-
(1MX)
El-stw
(100X) vrhcr
twer
PIDf'Al-Ef
vent
124 1 Ilwchina,
Dl-At-
(100X) lwrhrr
126 1 Ileaching,
Dl-stage
146 1 Ilwhirp,
DZ.stage
tower vmt
DZ-At*
wmhor
150 1 Ilmchlry.
02-H-
Awl
314
1 W.achl~,
LZ-st~
t-r
3lb
I Ilqachlfu,
EZ-tAsm uAh*r
318
1 Iluchln&
I
El-A1a.e
vent
ralt
z.OOE-8
Z.oQL-7
I b5E-4
P.75E-5
2.14-3
l.ZOf-3
t.302.3
7.94E-4
l.MfQ-7
4.9m-7
Z.OOE-6
b.QM-6
1.241-b
3.VlE.b
l.uIc.7
4.x%-7
z.DtlE-6
b.OM-6
l.ZCE-6
3.97E-6
9.27E-5
4.m.S
l.DsE-3
b.DDE-4
b.4R-4
3.97E-4
I
I
I
vent
rant
b.OIX-4
1.21-b
3.oOE-7
vmt
rmt
tmh
vent
l.ba.4
1.2&-6
El-stage
l.loE-3
1.21-b
vCnt
Dl.stqtp
Z.oot-4
102 1 Bloachlng,
10
I
I
122 I Blushing,
I Ilwching,
1 PEP-Ef
IOLI%YE-Ef
---,--a
I
I
1 CffElNANEEf 1 IWf-Ef
I
1 ICDf-Ef
,
1 ACEKWUlEf
I
1 GWS-Ef-i
NEXANE-Ef
I
1
1 IOltlAPEf 1 IOIWCEf
IRS-Ef
3.OOE*8
1
-I----+---+b.o(y-L
1
2.5M-6
1 3.14E-1
1 3.14E.l
1 5.39E.2
I 3.72E-3
I 6.2t.f.2
1 l.ZlE-2
1 I.LlE-3
I 6.94E-3
5.W.4
b&If-5
I.OOE-4
1.92f-6
2.27E-5
b.OOE-3
I 2.63E6-2
I Z.WE-2
b&X-3
I l.b7E-1
I 2.47E-1
1.92E-4
I l.OlE-1
1 l.blE-1
1 l.llE-2
1 4.07E-S
1 l.lbE-2
I 1.21-4
1 4.52E-4
1 b.4Y-5
1 l.llE-2
1 4.OiE-5
1 l.lbE.2
I 1.23E-4
I 4.12E-4
I b.41E-5
I
.L
1 S.ZDE-1
b.DOE-5
1 5.2oE-1
J.ODf*3
3.oQ-3
e.b2e-5
1
1
!
i
I l.llE-2
I 1.44E.2
1 I.35E-2
1 l.ZY-1
1 S.OCE-2
1
1 LObE-2
I
I
1
C-stage wid
ml0
BIO
__-.
Obf12/93
factor Slury
------------
1
/
I
I
0
g
f
.
.._...__.
--__..-___..
(0.
0
I_...
_...
$ MS
-rx
z
4
as
___......._._..
__.._........_._.__
03 4..._...__.*._
EOP TOWER VENT
g
*
.-.......---.
-.
..__._
0
0
3
.q..
.
.
.
.
.
.
.
_
.
..-.-.....__.
3
0
-sm.-.
O2 DELIGNIFICATION
BLOW TANK
c-83
llcdd 811
. strem
08112193
Characteristics
--~~
j%U~CODE
1
I W-CODE
I fUJRCE
1
-1
I
I
1 PRDC-IYPE
1 UXD-IYP
1 ENCLOSURE
I
1 SWtCE-IYP
I
1 VFLOJAC
1 SFLO-FAC
I
I
1 VW-CON
1 SHAP,CCRl I
I
1 HAL-SlATUS
1
I
I
1
I
1
Rll
ill
403
401
1 DKYCEY
OwlDEN DELIG. UASHER
OLW YANK
IAUK VEYI
1 .RLEACH
BLEACH
HARD
VEYY
VE
1 2.6W2
1 l.DZE*Z
1.92E+2
1
I
Y
N
I
1
CO5
4D7
1 EC+-SlACE
i iOF-SIAGE
1
/
RLEACK
RLEACH
1
/
MRD
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VENI
YEN;
1 ;.z-;
.
i 1.35-2
1
1
1 l&E*2
; :.OJE*3
1
;
N
N
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I
409
1 EW-SAGE
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1
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t
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model
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Bll
111
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L
:::
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SWRCE
401
CO3
405
401
409
T
/
II
l-
1 7.9lE-3
4-m-3
1 &2oL-2
5.97E-2
1 6.22E-3
I 1.26E-2
1 7&E-3
1 S.LLE-2
1 6.46E-2
1
t
I
1 HEOR-El
I
CYEl-EF
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OXYGEN DELIG.
BLON 1ANK
DKYGEN DELIG.
UASKER
TANK VENl
(1DDX) MASHER
VENY
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1
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I
L
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1
1 DRVGEN DELIC.
403
1 OXYGEN
405
1 EOP-SIADE
RI1
407
1 EM-SIAGE
111
409
1 EDP-SIACE
(100%) WSHER
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1
Ill
FORN-EF
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Factor Suury
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1 7.3OE-2
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RLW
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DELIC. UASVER
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1
I
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i cm-2
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1 l.OlE-1
1 l.aE-1
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1 lRS_EF
1
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m
s:ta-1
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* e-.-....---.-.--..--.-..
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06/12193
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112
112
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404
406
406
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1 EOP-SIACE
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/
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1 5.00E-2
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1 IOLuENE-Et
1 CMIHANEEF
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1 CARRDIS-EF
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1 2.63E-2
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APPENDIX C.3
DEFiNITlON OF TERMS
Unitsa
Description/Compound
Abbreviation
ACET-EF
Acetone
kg/Mg pulp
MECH-EF
Methanof
kg/Mg pulp
CTET-EF
Carbon tetrachlorfde
Wh
pulp
MEK-EF
kg/M
pulp
HPS-EF
Hydrogen sulfide
w4
Pulp
MMER-EF
Methyl
DIMES-EF
Dimethyl sulfide
WW
DIMDS-EF
Dimethyf disulftie
@/Mg pulp
ALPINE-EF
Alpha-plnene
kg/W
pulp
HCL,EF
Hydrogen chloride
kg/W
pufp
Cu.-EF
Chlorine
kc04
pulp
CLC2-EF
Chlorine dioxide
kg/N
pulp
MECL-EF
Methyiene chloride
WMg
pulp
CHCL3-EF
Chloroform
kg/Mg puip
Benzene
kg/W
pulp
PHENOL-EF
Phenol
WMg
pulp
TCDD-EF
2,3,7,8-Tetrachloro-p-dioxin
kg/Mg pulp
TCDF-EF
2,3,7,8-Tetrachloro-p-furan
kg/h
pulp
MCHCL3-EF
kg/W
pulp
TCP245 EF
2,4,5Trichlorophend
kg/W
pulp
TCP246-EF
2,4&TrIchlorophend
WMg
pulp
L-BENZ-EF
kg/Mg pulp
mercaptan
c-87
puip
C-88
DEFUWON
OF TERMS (Continued)
Abbreviation
Description/Compound
Unitsa
VFLO.W-FAC
Vent flowrate
scmm/Mg
PWVday
SFLO-FAC
.e/min/Mg
PWdw
fwmv
SHAP-CON
w/L
HWD
Hardwood
Unitless
Unitless
SW0
softwood
Unitless
Chlorine
Unitfess
cd
Unidess
Extraction
Unitless
Hypochlorlte
Unittess
Chlorine dioxide
Unitless
ENCLOSURE
Unitfess
VHAP CON
--
HAL STATUS
u-
aKey:
WMg
scmm/Mg pulp = Standard cubic meters per minute vent flow per megagram of pulp produced.
I/min
c-89
REFERENCES
1.
c-90
NO.
EPA-453/R-93-050a
TITLE
AN0
complettig)
2.
3. AEC!PlENTS
SUBTITLE
5. REPORT
ACCESSION
NO.
DATE
October 1993
COOE
AUTHOR(S)
REPORT
PERFORMING
8. PERFORMING
ORGANIZATION
NAME
AN0
AOORESS
10. PROGRAM
AGENCY
NAME
AN0
ELEMENT
11. CONTRACT/GRANT
No.
NO.
NO.
68-Dl-0117
ADDRESS
ORGANIZATION
AND PERIOD
COVERED
Interium Find*
14. SPONSORING
AGENCY
CODE
EPA/200/04
NOTES
.
1.ABSTRACT
National
KEY WORDS
AN0
DESCRIPTORS
ANALYSIS
b.lDENTlFlERS/OPEN
Air Pollution
Volatile Organic Compounds
Hazardous Air Pollutants
Pulp and Paper Mills
Pulp Mills
Paper Mills
.DISTRIBUTION
DOCUMENT
ENOED
TERMS
STATEMENT
lg. SECURITY
20. SECURITY
Unlimited
Form
ZZZU--1
CLASS
CM
Unclassified
(Rev. 4-n)
PLICVIOUS
13 b
(TM
Reppow)
Unclassified
rzrA
c. COSATI Field/Group
CDITION
IS OBSOLETE
(Thk polr/
385
22. PRICE