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10
11
12
13
14
Al
Si
15
16 17
18
Neutral H2O
H
Li
Be
Na Mg
Transition metals
Ca
Sc
Ti
Rb
Sr
Zr Nb Mo Tc
Cs
Ba
La
Hf
Ta
Cl
Se
Br
G Mn Fe Co Ni Cu Zn Ga Ge As
Ru Rh
W Re Os
Ir
Pd
Ag Cd
In
Sn
Sb
Te
Pt
Au Hg
Tl
Pb
Bi
Po
At
Basic oxide
Mostly amphoteric
oxides (depends on
oxidation state)
Amphoteric oxide
No oxides
(but
XeO3
has been
prepared)
Acidic oxide
N Neutral oxides also occur
Figure 7.5
The periodic table shows that metallic oxides are mostly basic and that non-metallic
oxides are mostly acidic. The elements with amphoteric oxides lie between these
two groupings.
%
%
%
%
Le Chateliers principle!
of transition metal oxides
define
Le Chateliers
principle!
Chromium oxides
Manganese
oxides
If a system at equilibrium
is disturbed, it will adjust to minimise the disturbance.%
MnO basic
MnO amphoteric
Equilibrium occurs when
the rate of the forward reaction equals the rate of the reverse
CrO acidic
Mn O strongly acidic
reaction. Thus a system is dynamic. %
CrO basic
Cr2O3 amphoteric
mphoteric
ric to acidic
eric
eric to basic
eric to basic
ric to basic
Group
(V) oxides pressure of a particular species (force the reaction in
concentration or gas
partial
direction
to remove the
species)%
CO
neutral;
NO added
neutral
CO acidic
N O neutral
total
pressure
or volume
on a reaction involving gases (force reaction in direction with
SiO
weakly
acidic
NO acidic
N
O
strongly
acidic
GeO
basic
to
amphoteric
less moles of gas or with liquid
or solid)%
GeO amphoteric to slightly acidic
P O acidic
P O acidic in direction to absorb (endothermic) or release
SnO
amphoteric
temperature
(force reaction
SnO amphoteric
As O amphoteric
(exothermic) heat to counter
temperature change)%
As O amphoteric to acidic
PbO basic to amphoteric
Group (IV) oxides
PbO2 amphoteric
10
Sb2O3 amphoteric
Sb2O5 amphoteric to acidic
Bi2O3 basic
Bi2O5 amphoteric to acidic
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catalysts do not alter the position of a system already in equilibrium, however they can
reduce the time to reach equilibrium%
Be careful about what the question asks for - is it specific effect on the yield of a
species or the overall effect on the reaction direction?!
an equilibrium shift to the left or right in any of the equations above leads to a change
in the concentration of the reactants and products in that reaction. This influences the
concentrations in the other three reactions causing the equilibrium in those reactions
to also shift to the left or right respectively.%
addition of acid (increased concentration of HO) shifts equilibrium to the left in
equations 3 and 4 above to remove added HO ions, and therefore results in a
decrease in dissolved carbon dioxide%
addition of base (reacts with and reduces the concentration of HO) shifts equilibrium
to the right in equations 3 and 4 above to form more HO ions to counter change,
and therefore leads to an increase in the concentration of dissolved carbon dioxide.%
addition of a soluble carbonate (increased concentration of CO) shifts equilibrium in
equation 4 above to the left and therefore results in a decrease in dissolved carbon
dioxide.%
additions of cations which form insoluble carbonates such as Ca or Mg will remove
CO from equation 4 and thus force 1, 2, 3 to move to the right.%
The overall dissolution reaction is exothermic. Hence decreasing temperature will
force CO to dissolve (which releases heat countering the change) and increasing
temperature will force the reaction the other direction (to absorb the added heat).%
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1. The mass of an unopened can of soft drink, of an empty 500mL beaker and of a
100mL beaker filled with salt, was measured using an electronic balance.%
2. The can was opened and the drink poured into the 500mL beaker and allowed to
drip out.%
3. Salt was transferred from the 100mL beaker with a plastic spoon into the 500mL
beaker, and then the drink was stirred with a stirring rod, alternately until no more
bubbles were released.%
4. The mass of the 500mL beaker with flat soft drink and salt, of the 100mL beaker with
less salt was measured using an electronic balance%
5. The can was allowed to dry and then its mass was measured using an electronic
balance%
6. The mass of the soft drink with and without the dissolved CO was calculated and
then the volume of CO released was calculated%
By measuring the mass of the carbonated soft drink in its unopened can, instead of
opening the can and pouring it into a beaker on an electronic balance, the validity
(and accuracy and reliability) of the experiment is improved since such an opening
would immediately cause CO to escape by the change in total pressure of the
system, and hence the calculated amount of CO would not be the total amount of
CO which was evolved from the mixture, i.e. the method would not properly suit the
aim of the experiment.%
By using salt and a stirring rod to ensure all CO evolved from mixture, accuracy,
reliability and validity are all increased.%
Accuracy because if not all the CO was evolved, then the final volume of evolved
CO gas calculated would be biased to be less than the true amount of CO initially
dissolved in the soft drink.%
Reliability because without this procedure which ensures all the gas is evolved,
replication of the results would be difficult, on repetition of the experiment there
would be a randomness in the results due to sometimes more CO being evolved
than other times.%
Validity since if not all the CO is evolved, then the final calculated volume of CO
would not the volume of CO which was initially dissolved in the can and thus the
experimental method would not test the aim of the experiment.%
By ensuring that the empty soft drink can is completely dry before remeasuring its
mass, accuracy is increased since any amount of liquid left in the can would bias the
calculated mass of soft drink with dissolved carbon dioxide to be less than it was, and
hence the calculated amount of released carbon dioxide to be less than it was.%
If the mass of each spoon of salt added was measured separately and the total
amount salt added were calculated by adding them together, the error in the
individual measurements would be compounded by the addition. By measuring the
total amount of salt added in one go, the precision of measurements is increased.%
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Natural Sources
Volcanoes%
Geothermal hot springs
Industrial Sources
NO
Lightening
sulfur impurities:
S (in compound) + O(g) SO(g)%
Smelting of sulfide ores:
metal sulfide + O metal OR metal sulfide + SO
ie. 2ZnS(s) + 3O(g) 2ZnO(s) + 2SO(g)
In all cases: O(g) + N(g) 2NO(g) due to the high temperatures present
NO Produced by oxidation of NO in atmosphere: 2NO(g) + O(g) 2NO(g); hence it has all the
same natural and industrial sources of NO.
NO Bacteria in soil in the process of
nitrification and denitrification
production of nylon%
burning of fossil fuel in internal combustion engines
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Description
Respiratory irritation SO and NO are respiratory irritants, particularly bad for asthmatics
and people with emphysema.
destruction of
buildings and
sculptures (acid
rain)
photochemical
smog
see above
Human
production of ozone
at ground level by
photochemical
smog (see Module
9.4.4)
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Description
global warming
Evaluation: there is significant cause for concern over the release of SO, NO, NO and
NO due to great human (respiratory problems, limestone buildings) and environmental
(global warming, ozone hole, haze, destruction of plants, acidification of lakes) impacts.