.s..

f'

.g

Page 1112

:::

Material Safety Data Sheet

acc. to ISO/DIS 11014

"

Reviewed on 03R0/2010

Version:3

Printing date 03/30/2010

'Pr oduct detalls

'Tr adE name: !9Fl 1??LQE

'A pplication of the substance / the preparation: Catalyst
'Ma nufacturer/Suppller:
ADVANCED REFINING TECHNOLOG IES

Grace Davison
W.R. GRACE & Co.{onn.
7500 Grace Bive
Columbia. MD 21044

USA

'ln formation

dePartment

Health ano safdty (9 Afrr to 5 PI/I-EST) 1-410-531-4000

MSDS.Davison@grace.com
'Em ergency informatlon:
Transportation EmergencY (24 hr)

Chemtrec 1 -800-424-9300

'

Other Emergencies (24 hr)

-'

1-410-531-4000

'Che mlcal charactorization: Preparation.

.Des criptlon: Mixture of the substances listed below with nonhazardous additions.

eESTo. EndEesCripti

on

-Ii442-8-lTaluminumoxide(non'fi brousforms)
778+3G7 | aluminum phosphate
' CAS No- & List of Dangerous Components

3;EXn, ffi Xi; R 36137-40

carc. cal 1; ffi l, 8i xi; R 49-43-53
F T, ffi Xi: R 4943-52
arc. Cat. 1;[ET,ffi Xi; R 4943'48t23
ffi Xn, ffi Xi; R 22-36
Carc, Cat.

'1313-27-5 molybdenum trioxide

't313-99-1 nickel oxide
14177-55-O nickel molybdenum oxide

12004-35-2 nickel aluminate

15't23-80-5 atuminum molybdenum oxide

'A ddltional

lnformation:

('l

U"/o

<5'/o

<5%
<1Yo
<1Yo

li

EPA has designated that non-fibro$s forms of alUmlnum oxide

are not a toxic chemical, under Section 313 of SARA .

Th;

.ln formation pertaining to particular dangers for man and environment:

May cause cancer bY inhalation.
lrritlating to eyes and respiratory
Limited-eviCdnce of a caicinogenic effect'
May cause sensitizalion by skin

sysiem.
contact.

,i

'Clqs sification system:

The classificatiori was made according to the laiest editions of international substances lists.

'

(Contd' on Paqe2)

Page 2112
=..;,

Material Safety Data Sheet

acc. to lSOIDlS 11014

Printing date 03/30/20'1 0

Version:

Trade name: ICR 122LSF

Reviewed on 03/3012010

(Conld. of page 'l)

'NF PA ratings (scale 0 - 4)

^A.

Health = 3

f(gt ['i?i,3n,=o
.HMl S-ratings (ecale 0 - 4)
*3
Heatth =
Fire = 0
Reactivity = 0

' Produd presents long-lerm adverse effects.

'Can adian Hazard Symbol

'W HMIS classification D'l8 - Toxic material causing immediate and serious toxic effects

'A dditional information:

The product conlains component(s) which is(are) classified as carcinogenic.
WARNING. Contains a substance known to the State of Califomia to cause cancer.

'Ge neral information:

lmmediately remove contaminated clothing if necessary to prevent direct skin conlact.

'A fter inhalation:

Supply fresh air and to be sure call for a doctor.
ln case of unconsciousness place patient stably in the recovery position for transportation.

'A fter skin contact

Remove contaminated clothing immediately.
lmmediately wash with water and soap ahd rinse thoroughly.
lf skin initation continues, consult a
l

dqctor.

'A fter eye contact:

Flush opened eye with large quantities of running water for at least 15 minutes. lf symptoms
persist, consult a doctor.

'A fter swallowing: Do not induce vomiting; immediately call for medical help.

'Suit able extinguishlng agents: Use fire fighting measures that suit lhe environment.
'F orsafety reasons unsuitable extinguishing agents: Waterwith full jet
'Spe cial hazards caused by the material, its products of combustion or resulting gases:
Toxic metal oxide smoke
'Pr otective oquipment
Wear self-conlained respiatory protective device.
Wear proteclive equipmenl.

'A dditional lnformation

Collect contaminated fire fighting water separately. lt must nol enter the sewage system.
Dispose of fire debris and conlaminated lire fighting water in accordance with official regulations.
USA

(Conld. on pago 3)

Page 3/12

Materlal Safety Data Sheet

acc. to ISO/DIS 11014
Reviewed on 03/30/2010

Version: 3

Printing date 031302010

Trade name: ICR 122LSF'

(Conld. ot page 2)

'Perso n-related safety precautions:

Avoid formation of duit.
Wear respiratory protective device.
Wear proiective equiprnent. Keep un protected persons away'
Ensure adequate ventilation
'Me asures for environmental protection:
Do not allow to enter sewers/ surface or ground water.
Damp down dust with water spray'
Keep contaminated washing water and dispose of appropriately'
.Me asures for cleaning/collecting:
Vacuuming or wet sweeping may be used to avoid dust dispersal'
Ensure adequate ventilation'

'A dditional informatlon:

tn case of fire nickel oxide, classified as carcinogenic, can be evolved. Nickel compounds are
;"bl."i t,o environmental release regulations and reporting requirements in some jurisdictions.
Consult a pplicable regulations.

'Han dling:

'ln formation for safe handlingl

Prevent slatic electric sParks.
Open and handle receptacle with care.
Prevent formation of dust,
Ensure good ventilation/exhaustion at the workplace.,

'ln formation about protection against explosions and firesl

When transfening ttiis material into flammable solvenls, use proper grounding to avoid static
electric sparks.
,i
Keep respiratory protective device av4ilable.

'Sto rage:
'Req uirements to be met by storerooms and receptacles: No special requirements.
'ln formation about storage ln one common storago facility:
Do not store together wilh toxic or very toxic substances, which are combustible.
Store away from foodstuffs.

'F urther lnformation about storage

condltions:

Ac,cess rostricted to technical experts or their assistants only'

.A dditional informailon about deslgn of technical systems: No further data; see item 7.
GiGs that require monitoring at the workplace:

Page 4l'l?

Material Safety Data Sheet

acc. io ISO/DIS 110'14
Reviewed on 03i30/2010

Version:3

Printing date 03/30/2010

Trade name: ICR 122LSF

PEL 0 IS'E* mg/nr"

*total dust *trespirable fraction
REL 0 Short-term value: 1.5* mg/m3
*as resprable ftaction
TLV () 1* mg/m"
"as respirable fraction
:

13fu-2-smolybdenum

trioxide (9%)

mdffi-

PEL 0 TE
OSHA, lnsoluble Mo Compounds (Total Dust)
REL O 10 mgy'm"
NIOSH, lnsoluble Mo Compounds (Total Dust)
TLV O 10 ng/mr
ACGII-|TWA, lnsoluble Mo Compounds (Total Dust)

ffihate(sv")
-15
PrL 0

"S mg/m'

OSHA, 'Total Dust

*15 *5 mg/m3

REL

TLV

PEL

(.1

REL

as Ni
0.015 mg/rn3
as Ni

TLV

0.2t mg/m3

**Resplrable fraction as Al

*Total Dust '*Respirable fraction as Al

NIOSH,
10 rng/rn3
ACGIH TWA, as AlDust

as Ni;*as inhalable fraclion

were valid.durinq the creatlon were used as Dasls

'Person al protective

equipmenh

'Ge neral proteclive and hygienlc moasures:

Keep away from foodstuffs, beverages and feed.
lmrnedialely remove all soiled and contarhinated clothing.
Wash hands before breaks and at tho pnd of work' l
Store protective clothing separately' '
.Breat hing equipment:
i i
ln case oiUri6f 6xpo"ure use respimtory |ilter device. ln case of intensive or longer exposure us
respiratory proteciive device that is independent of circulating air. As appropriate for the employee
exfosure, use a NIOSH approved respirator and cartridge'
'Pr otection of

hands:

'

Protective gloves

Wear gloves for the protection against mechanical hazards'

Use gloves of stable material (e'g. Nitrile)
'Ma terlal of gloves
Butyl rubber, BR
Nitrile rubber, NBR
Recommended thickness of the material: > 0'35 mm

.Not sultable are gloves made of the ioltowing materials: Sirong fabric gloves

(Contd. on Page 5)
usA

?age 5112

Material Safety Data Sheet

acc. to ISO/DIS 11014
Reviewed on 03/30/2010

Version: 3

Printin g date 03/30/201 0

Trade name: ICR 122LSF

(Contd. of page 4)

'Ey e protectlon:
saretv slasses

'Bod y protection: Protective work clothing

'Gen eral lnformation

Form:

Beads

Colon

Greenish

Odon

Odorless

'Cha nge in condltlon

,l

..

Boiling polnUBoiling range: Undetermined.

'Fl ash

point

Not aPPlicable.

'Fl ammablllty (solid, gaseous): Product is not llarnmable

'A uto igniting:

Product is not self-igniting.

'Dan ger of exploslon:

Product does not present an explosion hazard.

'Vap or pressure:

Den sity at 20'C (68'F):

Bu lk density at 20"C (68'F):

'Solu bSlity in I Mlscibility with

Water:

PartlY soluble.

'p H-value at 20"C (68'F):

'Visc osity:
Dynamic at2O"C

hPa

0,92 g/cm"
520 kg/m"

3-4

(68'F): - mPas

'T herunal decomposltlon / conditions to be avoided:

No decomposition if used according to specifications.
'Ma terlals to be avoided:

'Dan gerous reactions Reacts with acids.

'Dan gerous products of decomposition: Toxic melal oxide smoke

Page 6112

Matsrlal Safety Data Sheet

acc. to tSO/DIS 11014
Version:

Printing date 03/30/2010

Reviewed on 03/30/2010

Trade name: ICR 122LSF.

(Contd. ofpage 5)

cute toxlclty:

'A.

lassification:

@non-Rbrousforms)
Oral

LDsO

> 5000 mg/kg (rat)

I UCL| D D;ta;er (i areOlzooo)

OECDTG4O1

@irioxide
Dermal

LDsO

'

2689 mg/kg (rat)

MSDS Merck (03lFeb/2005)
>2000 mg/kg (rat)
MSDS Merck (03/Febl2005)

lnhalative LCso (4 h) >5840 mg/m'(rat)

MSDS Merck (03/Feb/2005)
7784LD5O

-5000 ms/ks (rat)

Dermal

LDSO

RTECS
>4640 mg/kg (rabbit)
RTECS

31 3-99.
Oral

nickel oxic le

Oral

LDSO

>5000 mg/kg (rat)

IUCLID Dataset
OECD TG 401

(1

B/Feb/2000)

T2oo4-3EZ nickel atuminate

Oral

LD5O

>2000 rnglkg (rat)

OECD TG 423
GRACE

'Pr imary irritant effectl

,:i
i ti

'o n the skin:

May cause irritation with dryness and

---Il6o+-sst;itkel

lrrilation of skin IS

alurninate

f.3%

(in'viho)

EPISKIN
GRACE

'o n the eye:

lrritating effect.

'Sens itization:

ffi

Sensitization possible through skin contact

uenstilzailon EC3 2.3 % (mouse)

comparable substance
LLNA
on pag

Page 7112

Material Safety Data Sheet

acc. to ISO/DIS 11014

Trade name: ICR

Reviewed on 031302010

Version: 3

Printing date 03/30201 0

i22LSF,
(Contd. of page 6)

Other information (about experimental toxicology);

1 2004-35-2 nickel aluminate
AMES Test >5 mg/plate (Salmonella typhimurium)
negative with and without metabolic activation
OECD TG 471
GRACE

'A ddltlonal toxlcologlcal information:

lnitant
Carcinogenic if inhaled.

.Eco toxicaI effectsr

'A cquatic toxiclty:

-l34+t8--a|uminu m oxi de (no n-fi bro us forms)

NOEC

(S

h) >100 mg/l (Salmo trutta)

IUCLI D Datasel (1 8/Febl2000)

OECD TG 203
rlybdenum
trioxide
1313-27-5 m<

--LciiT6II- @

MSDS Merck (03/Feb/2005)

77

8+30-7 aluminum PhosPhate

LC50 (s6 h)

>250 mQ/l (Oryzias latipes)

NITE 2003

{313-99-t nickel oxide

LC50 (e6 h)

26.5 mg/l (Oncorhynchus mYkiss)

comparable substance

' Water flea toxicity

13M-28-1 aluminum oxide (non-fibrpus forms)
NOEC (s6 h) >100 mg/l (Daphnia magna)
IUCLID Dataset (1 B/Febl2000)
OECD TG 202
1i13 -27 -5 molybdenum trioxide
EC50 (4E h) 150 mg/l (Daphnia magna)
MSDS Merck (03/Feb/2005)

1313-99-1 nickel oxide

rrcso-l4alcomParable

substance

mo4:35-2 riIEel atuminate

024fmgll

EC50 (4E h)

(Ceriodaphnia dub ia)

comparable Subslance
water solubli$ is lower than EC50.
' Algae toxicity

1344-28-l altrminum oxlde (non-fibrous forms)

-Ndder2D

tuct-to Dalaset (18/Feb/2000)

lorco

TG 201

Page 8/12

Material Safety Data Sheet

acc, to lSOlDlS 1'1014
Printing date 03/301201 0

Trade name: ICR

Reviewed on 03i3012010

Version: 3

l22LSF,

{313-99-1 nickel oxide

EC50 (72 h) 0.06 mg/l (Selenastrum capricornutum)
comparable substance

20M-35-2 nickel aluminate

rcso (72 h) 0.1 1 1 mgll (Pseudokirchnerlella subcapitata)

OECDTG 201
comparable Substance
water solublity is lower than 1C50.

'A dditional ecologlcal lnformatlon:

.Ge neral notes: Do not allow product to reach ground water, water course or sewage system'

'Pr

oduct:

'Rec ommendation:
\Mntever cannol be saved for rec,overy or recycling should be managed in an appropriate and
approved waste disposal facility.'Processing, use or contamination of this product m.ay ch.ange the
waste managemeni options. State and local disposal regulations may differ from federal disposal
regubtions. bispose of container and unused contenls in accordance wiih federal, state and local
requirernents.

-DOT r egulations:
-Haza rd class:
-L and transport ADR/RID (cross-border):

.A DR/RID class:
'Ma ritlme bansport IMDG:

'lM DG Class:

ir transport ICAO-TI and IATA'DGh:

'lCA O/IATA Class: 'T ransporUAdditional information:

Not dangerous according to the above specifications'
GRACE iecommendalion for air transport: Cargo aircraft onty.

.SA RA
ingredients

Pago 9/12

Material Safety Data Sheet

acc. to ISO/DIS 11014

Trade name: ICR

Reviewed on 03/30/2010

Version: 3

Printing date 0313012010

{22LSF.
'

(Contd, of Paga 8)

Delayed (Chronic) Health Hazard.

'TS CA (Toxic Substances Control Act):
Hydropiocessing catalysts are considered for TSCA purposes to be mixtures of the oxides related
to the manufacturing Process.
The following comp6dition details are for information only and may include incidential substances
not subject to listing.
134+28-1 Aumin um oxidelnon-fibrous form s)
131}27-5 moFbdenum trioxide
15123-80-5 SiliijEilm moiy6denrrm oxide
14177-55-O nickal motFdbnum oxido

7784-N-7 iiumin[m pn=osplrate

'1313-99-1

nickel oxide

l2ul4-3b-z nickel aluminate

'#r

fficausecancer:
ffi3-e9--iln'rc[eioxid-E

ffi

ffi

toiicitY for females:

reproductive toxlcity for males:

mental toxicitY:

'Carcin ogenic categories

' epn tenvironmental Protection Agency)
s

for Research on cancer)

1313-99-1

niifel oiide

lasNi

l2w4-35-2 nickel aluminate I

Toxicology Program)
'NTF {National
'1313-99-1

120M-35-2 nickel

nickeloxide

aluminate

2A as Ni

.Tlvfrh-reshold timit vatue established by AGGIH)

A4

@-fibrousforms)
-T313-TTI
.

A1

iiEkel oiide

lvt-EK@ennanTaximum Workplace Goncentration)

tlumlnurn oxiAtfton-fibrous forms)
mot6denum trioxide

-Ts48-T

-Ti13-21FT nickel oxide

2
3B
1

-tu-fiEATI

and Health)
-N65E-:eel-Nationat lnstitute for occupational Safety
131&99-1

rlckAloxiaie

,OSHA4a (Occ
131&99-1

nEGiotiAt-

Admin

catalysts are considered for DSL purposes to be mixtures of the oxides related io
the manufacturing Process.
in" ioii"*ins coriliosition details are for information bnly.

Htdr"dds;ing

(Contd. on page l0)

USA

',
:

l
:

Page 10112

Material Safety Data Sheet

acc. to ISO/DIS 110'14
Printing date 03/3012010

Reviewed on 03/30/2010

Version: 3

Trade namer ICR 122LSF,

(Contd. of page 9)

13/.4-28-1 aluminum oxide (non-fibrous forms)

1 31 3-27-5 molybdenum trioxide
14',177-55-O nickel molybdenum oxide
77E4-30-7 alumrnum pnospnate
1313-99-1
12Q04-3U2 nickel aluminate
Hydroprocessing catalysts are considered for NDSL purposes to be mixtures of the oxides related
to the manufacturing process.
The following composition details are for information only.
1 5123-80-5 latuminum molybdenum oxide

'European EINECS
All substances are listed

' Philippines lnventory of Chemlcals and Chemical Substances PICCS

@
1

313-27 -5 | rnolybdenum trioxide

U-30-7 | aluminum phosphate

1313-99-1 | nickel oxide

7 7

' lnventory of the Existing Chemical Substances manufactured or lmpofted in

lnventory listing could not be confirmed for one or more ingredients.
forms)
oxide (non1344-28-1
1313-27-5 molybdenum trioilde
77M-30-7 aluminum phosphate
1

313-99-1 nickel oxide

s
lnventory listing could not be confirmed for one ore more substances.
134+28-1 aluminum oxide (nonjibrous forms)
1313-27-5 nolybdenum lrioxlde
141 I I-55-U nickel molybdenum oxicle
7784-30-7

phosphate

1313-99-1 nickel oxlde

t2m4-35-2 nickel aluminale

. Existing and New chemlcal Substance List ENGS
1344-28-1

rlumlnum oxrde (non-tlbrous lorms)

1313-27-5 molybdenum trioxide

15123-80-5 aluminum molybdenum oxlcle
14177-55-O nickel molybdenum oxide
7784-30-7 aluminum phosphate
131 3-99-1 nickel oxide
aluminate
1ZUU4-J5-:l
' Korean Existing Ghemical lnventory KECI
1344-28-1 a{uminum oxide (non{ibrous forms)
1313-27-5 molybdenum tnoxrde
15123-80-5 rluminum molybdenum oxido
14177-55-0 nickel molybdenum oxide
7784-30-7 aiuminurn phosphate
1313-99-1 nickel oxide

,i

1-23
1-479

l-5/9
1-24
1-517

KE-o1012

KE-25462
KE-12806
KE-25448
KE-o101

KE-25858
on page

Page 11112

Material Safety Data Sheet

acc. to ISO/DIS 11014
Version:

Printing date 03R0/201 0

Reviewed on 03/30/2010

Trade name: ICR 122LSF.

informations:

Produc

The producl has been classified and marked in accordance with EU Directives / Ordinance on
Hazardous Materials,
'Haza rd

symbols:

'l

T Toxic

'Haza rddetermining components of labelling:

molybdenum trioxide
nickel oxide
nickel aluminate
nickel molybdenurn oxide

'Ris k phrases:
May cause cancer bY inhalation.
lnil,ating to eyes and respiralory system.
Limited evidence of a carcinogenic effect.
May cause sensitization by skin contact.

'Saf ety phrases:

Avoid-exposure - oblain special instructions before use'
Do not breathe dust.
Avoid contact with skin.
:j
Wear suitable protective clothing and gloves. ' ;
ln case of accident or if you feel unwell, seek medical advice immediately.
This material and its container must be disposed of as hazardous waste.

'Nat ional regulatlons:

'ln formation about llmitatlon of

use:

Emptoyment restriclions concerning young persons musl be observed.

emptoyment restrictions Concerning pregnant and lactating women must be observed.

is based on our present knowledge. However, this shall not constitule a guarantee
for any specific product fealures and shall not establish a legally valid contractual relationship.

itris information

'Rel evant R-phraset

22 Harmtul if swallowed.
36 lnitaling to eYes.
36t37 lritating to eyes and respiratory system.
40 Limited evidence of a carcinogenic effect'
43 May cause sensitization by skin contact.
48/23 Toiic: danger of serious d-amage to health by prolonged exposuie through inhalation
49 May cause cancer bY inhalation.
52 Harmful lo aquatic organisms,
5a May cause long-terrnidverse effects in the aquatic envjrortment.
.Dep
artrnent issuing MSDS: GRACE Davison safety & Health Department

'Co ntact:
SALES OFFICES

U$A:
GRACE Davison
7500 Grace DR
Columbia, MD 21M4
Tel: +1 410-531 4000

(Contd on page 12)

USA

i
''l

Page 12112

Material Safety Data Sheet

acc. to ISO/DIS 11014
Version: 3

Printing dale 03/30/201 0

Reviewed on 03/30/2010

Trade name: ICR 122LSF.

{Contd. ofpage 11)

Europe:
Grace GmbH & Co. K,G.
tn der Hollerhecke 1
Postfach 1445
D7545 Worms, Germany
Tel: +49 6241 4O3O

Asia Pacific:
W. R. Grace Pte. Ltd.
501 Orchard Road
07-02 Wheelock Place
Singapore 238880
+65 6737 5488
Fax: +65 6737 5826

fsl;

19th Floor K.Wah Center

1010 Huai Hai Zhong Road
Shanghai,200031 China
Td: +86 2^15467 4678
Fax: +86 21 5405 1500
SALES OFFICES
USA:
GRACE Davison
750O Grace DR
Columbia, MD 21044

Tel.: +1-410-531-4000
Europe:
Grace GmbH & Co. K.G.

ln der Hollerhecke 1
Postfach 1445
D.67545 Worms, GermanY
Tel.: +49 (6241) 4030
Asia Pacific:
W. R, Grace Pte. Ltd.
501 Orchard Road

07{2

tA/treelock

Place

Singapore 238880
1*1.' +(65) 6737 54Bg
Fax.: +(65) 6737 5826
19th Floor K.Wah

ioio Huii

Centor

Hai Zhong Road

Shanghai,200031 China
Tg1.; +86 21 5467 4678

Fax.: +86 21 il05 1500

'' Data compared to the previous version altered.