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  • Chem 17 Mock Exam - Finals

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    Chem 17

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    151 vues6 pages

    Chem 17 Mock Exam - Finals

    Transféré par

    Sam Go
    Chem 17

    Droits d'auteur :

    © All Rights Reserved
    Téléchargez comme PDF ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    sur 6
    CHEM 17 THQR2 MOCK FINAL EXAMINATION General Instructions: Write the letter of the best answer in the answer sheet provided. Use CAPITAL LETTERS. You may use the questionnaire for scratch work. Which of the following 0.100M aqueous solution (V = 100mL) has the lowest pk A. NaNOs > C. NHal v B. KCH3CO0 « D, NaaPO, » | What is the pH of a buffer containing 0.25M benzoic acid (CslisCOOH) and 0.15M sodium benzoate (NaCsHsCOO) Ka = 6.5x10°5? A. 4.83 c. 397 B. 4.19 D. 3.40 ‘Atacertain T, Ke= 1.810" for the reaction: Nz + 3H2® 2NHs. Ifthe equilibrium concentrations of No and NH; are 0.015 M and 2,00 M respectively; the equilibrium concentration of He is: A. 050M C. 0.25M B. 0.20M D. 0.013M . Of these salt solutions, the most acidic is (Given: Ky NH3=1.8x10°S; Ks CHsCOOH=1.8x10°) A. 0.10 M KCH3COO & €. 0.10 M NHsCHsCOO » B, 0.10MNHsBr D. 0.10M KBr> |. In the reaction CoCls (aq) + 6NaCN(aq) ~* [Co(CN}e}**(aq) + 3Cl-(aq) + 6Na*(aq) which statement is correct? ‘A. The compound that acts as a Lewis base C. Cl isa conjugate acid in the reaction. is CL. Co? D. H20 is a conjugate acid in the reaction B. The compound that acts as a Lewis base is AGB. CNT | Consider the titration of a 20 mL. 0.100 M HCN solution using a standard 0.100 M NaOH. Given :Ke of ICN=4.9310-!9What is the pH of the solution after 1.00 mL of the titrant has been added? AL 4.45 C. 8.03 B. 6.75 D. 5.97 | Consider the proposed reaction mechanism for the destruction of the ozone, Osi, layer by the urban-pollutant NO2(q) (i) NO2G) + O3i—)> NOs) + O24) NO3 qq +NO2@q> N20s@ Which of the following is TRUE if the rate law was determined to be rate = k[NO2][0s]? ‘A. The first step is the slowest step and the rate determining step. « B. NOs both catalyzes the first and second steps; hence, there is no rate determining step. C. ‘The second step is the slowest and the rate determining step. D. NOsis an intermediate and it is decomposed back into NO2 and Os with the same rate as it reacts with NOzin the second step. For nos 8-10: Consider the experimental data for the kinetic analysis (at 300 K) of the reaction SO2Clajs)> SO2q) + Cla) Experimental Data Results of the analysis Time(min) | [SO2CI2] | T. Plot of Time vs y oa (sozci2] 1oo | 0.088 Slope p67 89 10: 200) 0.077 Intercept, 9.091410 300 0.067 RSQ or r? 0.962 Tl, Plot of Time vs. 17 400 0.059 [s02C12] 500 0.052 Slope 2.901 x 107 600 0.045 Intercept, 6.926 700 0.04 RSQor 2 0.961 il, Plot of Time vs. In 800 0.035 1s02C12) 900 0.031 Slope mpcex it 1000 0.027 Intercept” = 2.303 1100 | 0.023 RSQ or 12 0.999 and 8, Whatare the order and the half-life of the decomposition reaction of $02Chz, respectively? A. Zero, 736 min B. irst, 525 min C. Second, 345 min D, Pseudo, 500 min 9. Consider the volume of the reaction vessel to be 1.00 L. How many moles of Clz have been formed after 13 hours? A. 0.036 B. 0.047 C. 0.053 D. 0.064 10. Ifthe energy of activation for the reaction is 50.00 kJ, what is the approximate rate constant at 450.0 K, assuming E, is invariant between 300 ~ 600 K range? A. 5.146 x 107 B. 1.053 min ©. 23.10 Mtmin+ D. 797.7 MAmin+ For nos. 11-13: Refer to the following kinetic data for the reaction 2A + B> C Run [A]o, M [BJo, M Initial rate of formation of C t - _(M/s) 1 bs, 1.0x102 } 1.0x10% 2.0x10°5 i 20x10 | 1.0x107 4.0x10% il 1.0x102 0.5x10 1.0x105, } 11. The rate of the reaction fo Run lis: A. 2x105 M/s B. 0.5x105 M/s C. 4x105 M/s D. 1.0x10-5M/s / 12. The rate lawis: |“ A. r=kpBP 7 B r=K{A}{B] C. r=K{AP[B) D. r=K{Al[B] 13. The average rate constant (k) from Run I to II] is A.0.20 Mast B.6.7 Mts C.0.17 Mt st D.8.0 M4 st 14 Given the following half reactions and standard reduction potentials 2H* + 2e Ha(g) 2=0.000V Oa(g) + 4H? +4e © 2H,0(1) B= 1.229V > Determine the E%.ei for the reaction 2H2(g) + O2(g) = 2H20(I). A. -1.229V C. -2.458V \ B. +1.229V D. +2.458V } 15. The redox reaction involved in the electrochemical cell: SHE // CHaCOOH (0.1302 M) / He (1.00 atm)/Pt (Ka of CHsCOOH = 1.8x10°) is A. CH3COOH + H2> CH3C00- + 3H* C._2H* + HoH: + 2H* B_2HY+2e9 Ha D. CH3COO- + 3H*> CHsCOOH + Hz For no. 16: Given the following half reactions No3* + 3e No Cot + 2e Co Po + 2e © Po Rhe+3e 6 Rh 16. Which species will reduce thallium(III) to metallic thallium? TH* + 3e 2 TI E?=-0.34V A. Rh C. No B. Po D. Co 17. Using the following half reactions, and E° at 25°C PbSO4(s) + 2e- + Pb(s) + S042 (aq) ED=-0.356V Phia(s) + 2e © Pb(s) + 2'(aq) EP = -0.365V Calculate the equilibrium constant for the reaction PbSO¢(s) + 2F-(aq) © Pble(s) + SO4?(aq) A. 100 C. 4.02 B. 201 D. 050 18, Knowing the activity series of metals, which of the following reactions will occur? AL Maggy + Ca?*—> Cage) + Mg? * CC. Cugg + 2H* Hag + Cue B. Hag + Mg?*—> Mg + 2H* « D. Mgia + Cue» Cur + Mg? 19. Based on the Determination of Keq of [Fe(SCN)]**, which of the following is FALS! ‘A, [Fe(SCN)#*Jeq= interpolate in the calibration _—_C,_[Fe(SCN)**Jeq= slope in the calibration curve curve B. [Fe3*Jeq = [Fe®Jin- [Fe(SCN) ®Jeq D._[SCNJeq = [SCNJin~ [Fe(SCN) 2Jeq 20. What anion produces a very light-brown, irritating gas when reacted with 6M H2SO. in the test for volatile products? A. St C. C200 B. NOx D. $203? 21. Only ___ gives a white precipitate when reacted with acidified CaCl? AL C2042 C. POs B, COs? D. SOs? 22. In the Determination of Ca(OH)2Ks, what will happen to the Ksp of Ca(OH)2 if Ca(NOa)z was added to thesolution? A. Kop will decrease C. Kep will not change D. Kep will change sign 23. Which of the following statements is INCORRECT? A ion of Ca(NOs)2 to a Ca(OH)2 solution increases its solubility ¥? B. ion of KCI to a Ca(OH)2 solution increases its solubility v7 C. titration of Ca(OH): solution has a colorless endpoint ~ D. titration of Ca(OH)z solution enables the determination of [OH] v 24, The chemical formula of the compound diiodobis(ethylenediamine)platinum(IV) bromide is A. [PtBrla(en)2] B. [Ptlo(en)2]Br C. [Ptlo(en)2]Bre D. [Ptlo(en)2)Brs 25. The correct name for the compound [Fe(CO).]s{Co(OH)2Bra} is = A. Hexacarbonylferrate(II) tetrabromodihydroxocobaltate (11) B. Hexacarbonylferrate(II) dihydroxotetrabromocobaltate (111) C. Hexacarbonyliron(III) tetrabromodihydroxocobaltate(II} D. Hexacarbonyliron(II) tetrabromodihydroxocobaltate( III) 26. A coffee cup calorimeter was standardized and was calculated to have a heat capacity of 0.1116 KJ/°C. Using the same calorimeter, 10.0mL of 0.5M NazCO3 was reacted with 5.0 mL of 0.75 M CaCl. The temperature changed from 27.5°C to 26.99C. What is the enthalpy change of the precipitation reaction? (Given: AH, water=-55.8 kJ/mol; specific heat of CaCOs = 0.8181 J/g°C; MM of CaCO3 = 100.09 g/mol.) A. -1.07 kJ/mol €. 17.92 kj/mol B. 6249 k]/mol D. -0.0625 kJ/mol 27. Under what condition would reaction between permanganate and thiosulfate be autocatalyzed by its product? ; A. Acidic C. Basic B. Neutral D. Both A and B 28. Determine the standard heat of formation for ethylene using the given data: Enthalpy of combustion: -129.4 kJ/mol ethylene Enthalpy of formation for CO2(g): -393.5 k}/mol Enthalpy of formation for H20(I): -285.8 kJ/mol A,-2448 kJ/mol C.-521 kJ/mol B.-1224 kJ/mol D. None of the above 29, Consider the system: Co?*+ 2Cl©> CoCl?-. Which of the following statement/s is INCORRECT? A. Addition of HClfavors the forward reaction. B. The reaction is endothermic. C. Heating the solution causes the solution to turn blue, D. None of the above 30. Calculate the standard Gibbs free energy for the complex formation of FeSCN?* given that the KFat 298.15 Kis 3.1x 1018 A.-23.) C56) B.-77k] D.-101 Kj 31. Which of the following statement/s is/are TRUE? 1. Absorbance is proportional to the solute in solution. Il. The slope of the calibration curve, Absorbance vs Concentration, always yields the molar absorptivity. Ill The longer the path length the greater the absorbance measured. A.Tonly C. land Ul only ~ B.Land Il only D. Land Ill only 32. The formation of a white solid upon addition of ethanol to a saturated NaCl solution can be best explained by: A. ethanol reacts with Na* forming a white solid B. ethanol decreases the freezing point of the solution C.ethanol decreases the dielectric constant of water D. ethanol decreases the polarity of water 33. In which of the following solutions will Ca(OH)axs) be most soluble? A. Distilled H20 B. 2.0 M NaOH Cc. 10M MgClz D. 2.0MKCI arsion” > 6 34. Which of the following sets of cations will all give a black precipitate with (NHq)2S? , A. Ba?*, Cu, Agt C. Zn, Co?*, Fe3+ B. Ni?*, Co?*, Cu2+ D. Al3+, Cr3+, Ba2+ 35. Which of the following is true in Ksp determination experiment? A. Q

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