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Indian Minerals
Yearbook 2013
(Part- II : Metals & Alloys)
nd
52 Edition
GOVERNMENT OF INDIA
MINISTRY OF MINES
INDIAN BUREAU OF MINES
Indira Bhavan, Civil Lines,
NAGPUR 440 001
PHONE/FAX NO. (0712) 2565471
PBX : (0712) 2562649, 2560544, 2560648
E-MAIL : cme@ibm.gov.in
Website: www.ibm.gov.in
May, 2015
14-1
EXTRACTION
Selenium and tellurium metals were being
recovered as allied products at Ghatsila Copper
Smelter of HCL in Jharkhand, where the annual
installed capacity to produce selenium was
14,600 kg. HCL has not reported production of
selenium since 2006-07 and that of tellurium since
2004-05. Hindalco Industries Ltd reported
73,870 kg production of selenium from imported
copper concentrates at its Dahej Smelter in Gujarat
during 2010-11and thereafter no production data
is available.
USES
Selenium
In glass manufacturing, selenium powder in
traces is used as a decolourant for removing the
green tint caused by iron impurities in container
glass and other soda-lime silica glasses.
Approximately, 1 kg selenium is used for about
150 tonnes of glass production. It is also used in
architectural plate glass to reduce solar heat
transmission. High-purity selenium compounds
were used principally as photoreceptors on the
drums of older plain paper copiers which
are gradually being replaced by newer models
that do not use selenium in the reproduction
process. Dietary supplement for livestock is the
largest agricultural usage of selenium. Also,
selenium is known to be added to fertilizer to
enrich selenium-poor soils.
14-2
Tellurium
WORLD REVIEW
Selenium
The world reserves of selenium at 120,000 tonnes
only cover the estimated contents of economic
copper deposits. Selenium was obtained as a byproduct with copper. Substantial resources also
exist in association with other metals, coal deposits
and in uneconomic copper deposits (Table - 1).
In 2012, the production of selenium metal
in respect of 13 countries for which data is available
was estimated at 2,241 tonnes. The chief producers
were Japan, Germany, Belgium, Russia, Canada,
Kazakhstan, Mexico, Finland and Poland (Table - 2).
Global seleniumm and tellurium output cannot be
determined easily because not all companies or
countries report production and because trade in scrap
and semi-refined products may be included with refined
metal trade data.
Table 1 : World Reserves of Selenium
(By Principal Countries)
(In tonnes of metal content)
SUBSTITUTES
High-purity silicon has replaced selenium in highvoltage rectifiers and is the major substitute for selenium
in low and medium-voltage rectifiers and photovoltaic
cells. Other inorganic semiconductor materials, such
as, silicon, cadmium, tellurium, gallium and arsenic as
well as organic photoconductors are the substitutes
for selenium in photoelectric applications. Cerium Oxide
is substitutes of selenium as either a colorant or
decolorant in glass. Amorphous silicon and organic
photoreceptors are substitutes of selenium in plain
paper photocopiers. Sulphur dioxide can be used as a
replacement for selenium dioxide in the production of
electrolytic manganese metal.
Several materials can replace tellurium in most
of its uses, but usually with loss in production
efficiency or product characteristics. Bismuth,
calcium, lead, phosphorus, selenium and sulphur can
be used in place of tellurium in many free-machining
steels. Several of the chemical process reactions
catalysed by tellurium can be carried out with other
catalysts or by means of non-catalytic processes.
The chief substitutes for tellurium were selenium and
sulphur in rubber compound applications and
selenium, germanium and organic compounds in
electronic applications.
Country
Reserves
120000
6000
25000
26000
13000
3000
20000
10000
21000
2010
2011
2012
World: Total
Belgium (e)
Canada
China (e)
Finland
Germany (e)
Japan
Kazakhstan (e)
Mexico
Poland
Peru
Philippines (e)
Russia (e)
Sweden
2076
200
97
65
73
250
754
130
62
79
59
65
170
7 2 (e)
2209
200
35
65
86
250
809
130
95
85
54
65
265
7 0 (e)
2241
200
144
65
93
250
820
130
95
90
42
70
172
7 0 (e)
14-3
Tellurium
The world reserves of tellurium were
24,000 tonnes contained in copper resources.
Concentration of tellurium could also be found
in lead and gold deposits. The quantities
of tellurium in deposits of coal, copper and
other metals that are of sub-economic grade
are several times the amount of tellurium
contained in identified economic copper deposits
(Table-3).
Table 3 : World Reserves of Tellurium
(By Principal Countries)
(In tonnes of metal content)
Country
World : Total (Rounded off)
Canada
Reserves*
800
3600
USA
3500
Other countries
16000
World: Total
Canada
Japan (e)
USA
2010
2011
2012
105
8
47
50
103
6
47
50(e)
104
11
43
50(e)
China
In 2012, China was the leading consumer of
selenium accounting for about 40 to 50% of world
consumption. Despite being a significant producer of
selenium, China depends on imports for most of its
selenium needs and imported 1,610 tonnes of selenium
products in 2012, a 3% increase compared with 2011
imports. About 75% of China's selenium consumption
was used in the production of manganese.
Country
24000
Peru
(In tonnes)
Russia
Ural Mining and Metallurgical Co. (UMMC)
(Verkhnyaya Pyshma) announced plants to expand
production at its Uralelektromed plant from 30 to 40
t/yr by mid-2013. The expansion was estimated to
cost $3.02 million (105 million rubles).
Sweden
The Boliden Group's Kankberg gold and
tellurium mine commenced operation in March 2012.
The underground mine had mineral reserves of
3.58 million tonnes, with a gold grade of 3.8 grams
per tonne (g/t) and a tellurium grade of 177 g/t. The
mine is expected to produce 1.15 t/yr of gold and
41 t/yr of tellurium through 2020.
14-4
FOREIGN TRADE
Exports of selenium increased slightly to
192 tonnes in 2012-13 from 184 tonnes in the previous
year. Exports were mainly to China, Hong Kong, UAE,
UK and USA. In 2012-13. Exports of tellurium also
increased substantially to 31 tonnes from 13 tonnes
during the previous year (Tables-5 & 6).
2012-13
Country
Qty
(t)
Value
(L'000)
Qty
(t)
Value
(L ' 0 0 0 )
All Countries
184
11 8 7 6 9 2
192
879234
China
89
592935
93
496184
Hong Kong
15
92737
20
124205
UK
24
178178
16
99445
USA
9511
35887
Latvia
30081
++
19975
Germany
Singapore
4558
15370
Iran
++
1882
14715
UAE
41422
15
12883
Unspecified
49481
12593
38
216984
27
17896
Other countries
2012-13
Country
Qty
(t)
Value
(L'000)
Qty
(t)
Value
(L ' 0 0 0 )
All Countries
13
836
31
3478
UAE
20
2749
Malaysia
473
10
617
Indonesia
338
87
Tanzania Rep.
++
24
Other countries
25
++
14-5
2012-13
Qty
(t)
Value
(L'000)
Qty
(t)
Value
(L ' 0 0 0 )
All Countries
194
11 7 4 1 7 4
234
1424362
Japan
59
384307
66
412963
Korea, Rep. of
28
173664
58
338481
Germany
11
63406
32
221690
Belgium
32
219597
28
168136
UK
11
70829
13
92075
China
20
140295
10
64588
21843
10
6728
16932
Saudi Arabia
15964
France
10257
23
115348
15
61433
Canada
USA
Other countries
Qty
(t)
2012-13
Value
(L'000)
Qty
(t)
Value
(L ' 0 0 0 )
All Countries
30262
25349
UK
++
3682
10446
15924
++
3930
Korea, Rep. of
++
++
2451
Canada
++
1715
++
2216
Japan
++
3612
++
2196
USA
++
1368
++
1686
Philippines
++
2719
++
783
France
++
654
Switzerland
++
459
Hong Kong
++
263
++
1233
++
265
China
Other countries
14-6
FUTURE OUTLOOK
The supply of selenium and tellurium is
directly affected by the production of the principal
product from which it is derived-copper-and to a
lesser extent, by the production of gold, lead,
nickel, or zinc produced from sulfide ores.
Increased recovery rates at copper refineries could
increase selenium and tellurium supply, and longer
term investments in gold-telluride deposits and
other sources of tellurium could boost the global
rate of growth for tellurium production above the
rate of growth in copper concentrate production.
Although increased environmental regulation and
prices have encouraged the recycling of electronic
scrap, recovery of selenium and tellurium has been
declining during the past several years due to the
reduction in available scrapped selenium and
tellurium-based copier drums. However, many
14-7