Académique Documents
Professionnel Documents
Culture Documents
Syllabus
Topic 1: Biodiesel Basics/Fuel Properties
Topic 2: Overview of Biodiesel Production Using Waste Oil
Topic 3: Feedstock Sources for Making Fuel
Topic 4: Operation of the BioPro 190 Equipment
Topic 5: Waste Disposal and Byproducts
Topic 6: Biodiesel Fuel Quality Assurance
Topic 7: Greenhouse Gas Reduction Calculations
Topic 8: Program Cost Estimates
Question and Answer
Visit to EcoPark and demo of equipment at RIT
Topic1:BiodieselBasics
WhatisBiodiesel?
Abiodegradable,combustiblefuelmadefrom
vegetableoilsand/oranimalfats
Usuallydonebybasecatalyzedtrans
esterification offats/oils(i.e.makeabigmulti
chainmolecule into3smallermolecules)
Canbeusedinanycompressionignitionengine
thatwillacceptregulardieselfuel
EnginedoesNOT needtobemodifiedtousebiodiesel
blended withregulardiesel
BiodieselBasics
Fats/oils are reacted with alcohol (methanol), using
a strong alkaline catalyst (sodium hydroxide NaOH
or potassium hydroxide KOH)
Example:
100 pounds + 10 pounds 10 pounds + 100 pounds
Triglyceride
Alcohol
Glycerin
Mono-Alkyl Methyl Esters
(Vegetable Oil) (Methanol)
(Biodiesel)
Reaction2:esterification tobiodiesel
Methanol
Reaction1:freefattyacidconversion
SulfuricAcid
KOH
biodiesel
Methanol
Varietyofused
cookingoils
glycerin
BiodieselBasics
Commercialbiodieselissoldasablendwithregular
ultralowsulfurdiesel(ULSD)
Example:B10
10%biodiesel
90%petroleumdiesel
PurebiodieselisknownasB100(100%)orneatbiodiesel
NormallyB100isnotusedinvehicleenginesdueto
enginewarrantyconcerns
Operationwithbiodieselblendsmayresultinvery
slightlylowermpg duetolowerenergycontent
MostvehiclesarenowwarranteduptoB20 (20%
biodiesel)
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EngineEmissions:
lowercarbonmonoxide(CO)
lowerparticulate(PM)
lowerunburnedhydrocarbons(HC)
increaseorreduceNOx emissions*
*enginedesigndependent
CloudpointforB100
fromvariousoils:
Soy biodiesel 32 F
Tallow (animal fat)
biodiesel 50-55 F
Canola biodiesel
27F
Palm (coconut)
biodiesel 55-60 F
Diesel fuel ~ -4 to 13 F
TwoASTMqualityB100batcheshadcloudpointsof6and8C(43and46F)
Biodieselblendswillgelsooner
thandieselblendsatlow
temperatures
Outdoor,abovegroundstoragetanksare
potentiallyvulnerabletolow
temperatureproblems
Splashblendingofbiodiesel with
petroleumdiesel willnotworkwellat
temperaturesbelowthebiodieselgel
point(typically1632 F), butthiscanbe
handledbyblendinginkeroseneas
donewithULSD
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RITStudyofBiodieselUse
RIThasanabovegroundtank
tofuel2studyvehiclesonthe
campus
3yearstudy
Monitoredvehicle
performanceandemissions
Variousblends
B20usedforallwinterdriving
Results:
Noadverseeffectswereseen
eitherinthevehiclesorinthe
storagetankfromthelow
wintertemperatures.
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restaurants,
foodcourts,
snackbars,
cafeterias,
lunchtrucks.
Somemunicipalitieshave
collectionsitesfor
residentialcookingoils
Makesurecookingoildrop
offisnotconfusedwith
usedmotoroildropoff
Somesourcesmayalready
havecontractedwith
commercialcompaniesto
Foodproductionfacilities
disposeoftheoil
mayalsohavewasteoilin
bulkstorage.
theypay~$1pergallonfor
wasteoil.
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Important:
Line up your oil
supplier(s) early and
confirm their participation
if using cafeteria or
restaurant fryer oil
The higher the quality of
the oil, the easier it is to
produce high quality fuel
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FreshOil:
allofonetype
nofreefattyacids
nowater
highestcost
RestaurantFryer
Oil:
typicallyalloneoiltype
maycontainwaterand
foodparticles
containsanimalfats
highfreefattyacids
lowercost
competewithrendering
companiesforsupply(They
payrestaurantsfortheir
wasteoil.)
ResidentialCookingOil:
mixedoils
containsfoodparticles
containswater
containsanimalfats
lowinfreefattyacids
highlyvariablevolumeand
quality
onlycostiscollectingit
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Production ofBiodieselUsingWasteCookingOil
Residential Cooking Oil
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OilCollectionConsiderations
Visuallysort
incomingoil
Screeningoilto
removelarge
particles
Settlingtankto
removeoilandoil
wateremulsion
24hourdrying
cycletodriveoff
remainingoilwater
emulsion
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DaphneUtilities,Alabama
Cookingoilcollection
program
Decreasedtheamountof
oilsgoingtothePOTW
Collectedinconsumer
friendlyareas
Oilusedtomakebiodiesel
Startedin2006
Collect300500
gallons/month(population
22,000)
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DaphneUtilities,Alabama
http://daphneutilities.com/daphne/recycle_bio.htm
Startedtheirwholeprogram
for~$3,000
Recyclingprogram
Homemadebiodiesel
equipment
B20blendedandusedin
theirfleetofvehicles
$10,000annualfuelcost
savings
Reductionofgreasesinthe
municipalwastewater
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BioPro 190
Water
wash
drums
OilWater
SettlingTank
IncomingOil
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Containers, beakers,
buckets of various sizes
for chemical pouring,
waste glycerin, and waste
oil emulsion
Safety Equipment
Face shield,
gloves,
apron
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Filterwasteoil
(meshstrainer)
Settleoutwater
Cleanoilpumped
toBioPro 190
Dryoilwithheat
andstir
Addsulfuricacid
tomachine
Startprocessing
Addmethanolto
machine
AddNaOH orKOH
tomachine
Reaction1and
Reaction2
Allowglycerinto
settle
Drainglycerin
Testforreaction
completion
Pumpout
finishedfuel
Finaldryingcycle
Washcycle:
methanoland
solubles removed
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Settling Tank: To allow oil and oil emulsion to settle out (~24 hours)
for removal before going to the processing tank
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RobustProcessConsiderations
Useadditionalalkalito
drivethereactionto
completion
Approx10%additionalKOH
eliminatesresidualoilor
glycerides attheendofthe
biodieselreaction
Testforcompletionwith
273test
RerunbatchIfreactionnot
completeusing190gramsof
KOHand2galofmethanol
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RobustProcessConsiderations
Usewaterwashto
removereaction
byproducts
Salts
ResidualGlycerin
ResidualMethanol
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GlycerinDisposal
Crudeglycerinisnotahighvaluecommodity.
At2perlb.,15gallonsofglycerin=$3(excludingshipping)
Crudeglycerinfromthebiodieselconversionprocess
hasthreepossibleuses:
Compostaccelerator
Methaneboosterinanaerobicdigesters
Soapproduction
Lowenddisposal
sendtothelocalwastewatertreatmentfacility(with
permission)
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DaphneUtilities,Alabama
Theglycerin
byproductwasused
tomakesoap
Littlesoapsaretheir
mainmarketingtool
inschools
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ScreeningTests
Rawwasteoil
Freefattyacids,> 5%willhave
problems(dependsonoilsource)
Watercontent, KarlFischertest
Finishedbiodiesel
273testtoscreenforcompletionof
thebiodieselreaction
3ml.ofbiodiesel
27ml.ofmethanol
Ifthebiodieselfailsthe273test,it
willnotpasstheASTMtest
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Equipment
Accessories
Supplies
Oil
Feedstock
Costs
Utilities
Transport
Testing
Glycerin
Disposal
Labor
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$4 per gallon
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35
Paybackperiodreductionthroughhigherbiodieselproductionvolumes
36
Summary
Biodiesel
Theequipment
Safeandeffectivediesel
Iscommerciallyavailable
replacementwithsome
Canproduceroad
operationaladvantages
qualitybiodiesel
overpetrodiesel
Canbemadefromwaste Thedecision
cookingoil
makeorbuy
calculations
Reducestheamountof
greenhousegas
emissions
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References/Sources
The Biodiesel Handbook (2nd Edition) by Gerhard Knothe, J. Krahl, J.
Van Gerpen. Urbana IL: AOCS press, 2010.
National Biodiesel Board:
www.nbb.org
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Questions?
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