Académique Documents
Professionnel Documents
Culture Documents
Department of Mechanical
Engineering
ACKNOWLEDGEMENT
I wish to acknowledge the encouragement received
from Mr. Naveen Kumar (HOD, Mechanical
engineering department, SPSU, Udaipur) & Mr.
Satish Ajmera (Training Incharge) for initiating my
interest in training.
Shubham Sen
(12ME001672)
PREFACE
Practical training is a way to implement theoretical
knowledge to practical use to become a successful
engineer. It is necessary to have a sound practical
knowledge because it is only way by which one can
acquire proficiency & skill to work successfully in
different industries.
Shubham Sen
(12ME001672)
TABLE OF CONTENTS
Title
Page
Acknowledgements.............................................................................................I
Training Certificate.............................................................................................II
Preface................................................................................................................III
1. Company Profile ...................................................................................01
1. Vedanta ...................................................................................................01
2. Hindustan Zinc Limited ..........................................................................01
3. Zinc Smelter Debari ................................................................................02
2. Zinc ................................................................................................................04
1. Introduction .............................................................................................04
2. Properties of Zinc ....................................................................................05
3. Zinc Smelting ..........................................................................................05
3. Zinc Smelter Debari .....................................................................................07
1. General Process Overview ......................................................................07
2. Raw Material Handling Section ..............................................................09
4
Page
1.
2.
3.
4.
5.
6.
7.
Title
Page
TABLE OF FIGURES
Fig.-1 Plants at Zinc Smelter Debari .......................................................07
Fig.-2 General Processes In Plant ............................................................08
Fig.-3 Raw Material Handling Flow Sheet ..............................................10
Fig.-4 Process Flow Sheet In Roaster Plant ............................................12
Fig.-5 Calcine Balance Over Roaster Plant .............................................19
Fig.-6 Process Diagram For Acid Plant ...................................................37
Fig.-7 Process Diagram for Neutral Leaching ..........................................45
Fig.-8 Process Diagram for Acid Leaching and Neutralization ................47
Fig.-9 Process Diagram for Residual Treatment Plant ............................48
Fig.-10 Purification Plant .........................................................................52
COMPANY PROFILE
Vedanta
Vedanta is an LSE-listed diversified FTSE 100 metals and mining company, and
Indias largest non-ferrous metals and mining company based on revenues. Its
business is principally located in India, one of the fastest growing large
economies in the world.
In addition, they have additional assets and operations in Zambia and Australia.
They are primarily engaged in copper, zinc, aluminium and iron businesses, and
are also developing a commercial power generation business.
Founder of this recognition is Mr. Anil Agarwal, who is chairman of this group,
a simple person without any special degree in management field but have a
great experience in this field and a sharp sight of the future conditions and
requirement.
Hindustan Zinc Limited
Hindustan Zinc Limited was incorporated from the erstwhile Metal Corporation
of India on 10 January 1966 as a Public Sector Undertaking.
In April 2002, Sterlite Opportunities and Ventures Limited (SOVL) made an
open offer for acquisition of shares of the company; consequent to the
disinvestment of Government of India's (GOI) stake of 26% including
management control to SOVL and acquired additional 20% of shares from
public, pursuant to the SEBI Regulations 1997. In August 2003, SOVL acquired
additional shares to the extent of 18.92% of the paid up capital from GOI in
exercise of "call option" clause in the share holder's agreement between GOI
and SOVL. With the above additional acquisition, SOVL's stake in the company
has gone up to 64.92%. Thus GOI's stake in the company now stands at 29.54%.
Hindustan Zinc Ltd. operates smelters using
Location
Technology
with
Certifications
22.65
126
Products Range
(a) High Grade Zinc (HG)
(b) Cadmium
(c) Sulphuric Acid
80,000MT
Acid
130,000MT
Cd
250MT
Zinc dust
360MT
Work force
876 Nos.
84 Nos.
58 Nos.
Labour
729 Nos.
(a) Skilled
154Nos.
(b) Semi-Skilled
555Nos.
(c) Unskilled
250Nos.
INTRODUCTION
10
Zinc is a metallic chemical element with the symbol Zn and atomic number 30. In
nonscientific context it is sometimes called spelter. Commercially pure zinc is known as
Special High Grade, often abbreviated SHG, and is 99.995% pure.
Zinc is found in the earths crust primarily as zinc sulfide (ZnS). Zinc (Zn) is a metallic
element of hexagonal close-packed (hcp) crystal structure and a density of 7.13 grams per
cubic centimeter. It has only moderate hardness and can be made ductile and easily worked at
temperatures slightly above the ambient. In solid form it is grayish white, owing to the
formation of an oxide film on its surface, but when freshly cast or cut it has a bright, silvery
appearance. Its most important use, as a protective coating for iron known as galvanizing,
derives from two of its outstanding characteristics: it is highly resistant to corrosion, and, in
contact with iron, it provides sacrificial protection by corroding in place of the iron.
Zinc ores typically may contain from 3 to 11 percent zinc, along with cadmium, copper, lead,
silver, and iron. Beneficiation, or the concentration of the zinc in the recovered ore, is
accomplished at or near the mine by crushing, grinding, and flotation process. Once
concentrated, the zinc ore is transferred to smelters for the production of zinc or zinc oxide.
The primary product of most zinc companies is slab zinc, which is produced in 5 grades:
special high grade, high grade, intermediate, brass special and prime western. The primary
smelters also produce sulfuric acid as a byproduct.
With its low melting point of 420 C (788 F), unalloyed zinc has poor engineering
properties, but in alloyed form the metal is used extensively. The addition of up to 45 percent
zinc to copper forms the series of brass alloys, while, with additions of aluminum, zinc forms
commercially significant pressure die-casting and gravity-casting alloys. Primary uses for
zinc include galvanizing of all forms of steel, as a constituent of brass, for electrical
conductors, vulcanization of rubber and in primers and paints. Most of these applications are
highly dependent upon zincs resistance to corrosion and its light weight characteristics. The
annual production volume has remained constant since the 1980s. India is a leading exporter
of zinc concentrates as well as the worlds largest importer of refined zinc.
Density
7140Kg./m3
2.
Melting Point
693K
11
3.
10 J/ Kg
4.
5.
Linear expansivity
6.
Thermal conductivity
7.
Electric Sensitivity
8.
40/k
9.
Tensile Strength
10.
Elongation
50%
11.
Young modulus
110 Gpa
12.
Passions Ratio
385 J/Kg/K
31/K
111 W/m/k
150 Mpa
0.25
Zinc Smelting
Zinc smelting is the process of recovering and refining zinc metal out of zinc-containing feed
material such as zinc-containing concentrates or zinc oxides. This is the process of converting
zinc concentrates (ores that contain zinc) into pure zinc.
The most common zinc concentrate processed is zinc sulfide, which is obtained by
concentrating sphalerite using the froth flotation method. Secondary (recycled) zinc material,
such as zinc oxide, is also processed with the zinc sulfide. Approximately 30% of all zinc
produced is from recycled sources.
Globally, two main zinc-smelting processes are in use:
(a) Pyrometallurgical process run at high temperatures to produce liquid zinc.
(b) Hydrometallurgical or electrolytic process using aqueous solution in combination
with electrolysis to produce a solid zinc deposit.
The vast majority of zinc smelting plants in the western world use the electrolytic process,
also called the Roast-Leach-Electrowin (RLE) process, since it has various advantages over
the pyrometallurgical process (overall more energy-efficient, higher recovery rates, easier to
automate hence higher productivity, etc.).
In the most common hydrometallurgical process for zinc manufacturing, the ore is leached
with sulfuric acid to extract the Zinc. These processes can operate at atmospheric pressure or
as pressure leach circuits. Zinc is recovered from solution by electrowinning, a process
12
similar to electrolytic refining. The process most commonly used for low-grade deposits is
heap leaching. Imperial smelting is also used for zinc ores.
Zinc Smelter Debari
Zinc Smelter Debari have following main plants
13
Step 4: Purification: removing impurities that could affect the quality of the electrolysis
process (such as cadmium, copper, cobalt or nickel) from the leach solution;
14
15
Fi
g.-2 General Processes In Plant
Step 5: Electrolysis or electro-winning: zinc metal extraction from the purified solution by
means of electrolysis leaving a zinc metal deposit (zinc cathodes);
Step 6: Melting and casting: melting of the zinc cathodes typically using electrical induction
furnaces and casting the molten zinc into ingots.
16
Additional steps can be added to the process transforming the pure zinc (typically 99.995%
pure zinc known as Special High Grade (SHG)) into various types of alloys or other
marketable products.
Raw Material Handling Section(RMH)
Smelters use a mix of zinc-containing concentrates or secondary zinc material such as zinc
oxides as feed to their roasting plant. Debari smelter is characterized by a relatively high
input of secondary materials. Smelters located inland receive their feed by road, rail or canal
depending on site-specific logistical factors and the type of feedstock (eg, secondary zinc
oxides come in smaller volumes and are typically transported by road). Concentrate
deliveries typically happen in large batches (eg, 5,000 to 10,000 tonnes).
Hindustan Zinc Smelter Debari is strategically located close to the Zawar mines that serves as
a global concentrate hub and provides for an extensive multi-modal logistical infrastructure.
It is 14 kms away from Udaipur well connected by rail, road and air. Most zinc smelters use
several sources of concentrates. These different materials are blended to obtain an optimal
mix of feedstock for the roasting process.
The zinc concentrate is delivered by trucks and is discharged into two underground
bins. Several belt conveyors transport the concentrate from the underground bins to the
concentrate storage hall. A Pay loader feeds the materials into two hoppers. By means of
discharging and transport belt conveyors including an over-belt magnetic separator, a vibro
screen and a hammer mill, the materials are transported to the concentrate feed bin. Dross
material from the cathode melting and casting process will be added to the feed
material before the vibro screen. For moistening of the concentrate several spraying nozzles
are foreseen in the concentrate storage hall, as well as on the conveying belt before
the concentrate feed bin.
17
18
ROASTER PLANT
Roasting is a process of oxidizing zinc sulfide concentrates at high temperatures into an
impure zinc oxide, called "Zinc Calcine". This is a metallurgical process involving gas-solids
reactions at elevated temperatures. A common example is the process in which sulfide ores
are converted to oxides, prior to smelting. Roasting differs from calcination, which merely
involves decomposition at elevated temperatures. A typical sulfide roasting chemical reaction
takes the following form:
S
O2
SO2.
2 ZnS +
3O2
2 ZnO
SO2
O2
CuS
1.5O2
SO3
CuO + SO2
The gaseous product of sulfide roasting, sulfur dioxide (SO2) is often used to produce sulfuric
acid.
Approximately 90% of zinc in concentrates are oxidized to zinc oxide, but at the roasting
temperatures around 10% of the zinc reacts with the iron impurities of the zinc sulfide
concentrates to form zinc ferrite. A byproduct of roasting is sulfur dioxide, which is further
processed into sulfuric acid.
Reduction of zinc sulfide concentrates to metallic zinc is accomplished through either
electrolytic deposition from a sulfate solution or by distillation in retorts or furnaces. Both of
these methods begin with the elimination of most of the sulfur in the concentrate through a
roasting process,
19
20
The roaster has a cylindrical bed section, a conical intermediate section, a cylindrical
enlarged top section, and a grate area of 123 square meters. The enlarged cylindrical section
enables a complete roasting of even the finest calcine particles without the occurrence
of a secondary combustion phenomenon. For process optimisation 10 secondary air
nozzles are installed to be able to distribute additional roasting air above the bed. A slight
draught is maintained at the roaster gas outlet to ensure the safety of the roaster operation.
Depending on the raw material, the roaster operates with a capacity of 15 000 - 300 000 t/y
(zinc) and respectively 55 000 260 000 t/y (pyrite).
The combustion air serves both as a carrier medium for the fluid bed and as a source of
oxygen for the predominant reaction, which convert the metal sulfide to metal oxide and
sulfur dioxide. The combustion air is provided by a high pressure air fan, which is controlled
between the lower and a upper limit for a stable fluidization of the bed. The reaction in the
roaster is strongly exothermic, and the gas leaves the roaster with a temperature of
approximately 800C to 975C and an SO 2 concentration of approximately 10 % by volume,
dry basis.
As combustion medium during the above described preheating diesel oil is used. The
maximum flow of diesel oil amounts to 3000 kg/h. The composition of offgas during furnace
heating is shown in below table:
The roasting process is fully automated, controlled and operated from a central control room.
Debari operates some of the worlds largest roasters, which are modelled after those used
throughout the industry.
The roasting step results in the production of calcine material (which is transported to the
subsequent leaching plant) and sulphur dioxide-rich waste gases. Waste heat boilers remove
the calcine contained in these gases as well as recovering the heat in the form of steam that is
used in the leaching plant and/or converted into electricity.
The hot dust-laden gas stream leaving the roaster is drawn into the waste heat boiler under
suction from the SO2 blower. In the boiler, the dust-laden gases are cooled down from the
roasting temperature to about 350C before entering the dust precipitation system. Finally, the
sulphur dioxide is converted into sulphuric acid in a contact process, generating an important
smelter by-product.
21
Debari is able to deliver the whole off-gas treatment and energy recovery system after the
roaster which includes following process steps:
Fluidized-Bed Roaster
In a fluidized-bed roaster, finely ground sulfide concentrates are suspended and oxidized in a
feedstock bed supported on an air column. As in the suspension roaster, the reaction rates for
desulfurization are more rapid than in the older multiple-hearth processes. Fluidized-bed
roasters operate under a pressure slightly lower than atmospheric and at temperatures
averaging 1000 C (1800 F). In the fluidized-bed process, no additional fuel is required after
ignition has been achieved. The major advantages of this roaster are greater throughput
capacities, greater sulfur removal capabilities, and lower maintenance.
arrangement.
The waste heat boiler is equipped with a membrane tubed settling (drop-out) chamber ahead
of the front convection bundles. In the settling chamber, part of the dust carried along with
the gas is separated. Since the waste heat boiler handles roasting gases having a very
22
high dust content, a mechanical rapping device has to be provided. Pneumatic cylinders
drive these rappers. Depending on the degree of fouling, the rappers can be actuated by a
cylinder controller from a switching cabinet.
The pneumatic cylinders are operated by compressed air, which can be taken from the plant
air system. The gas-flow velocity through the tube banks was designed to be very low to
avoid erosion. The tube banks can be easily removed for maintenance after the plant has been
taken out of operation. The rapping device is automatically actuated at certain time intervals.
The dust separating out in the boiler is collected in a chain conveyor and fed to the rotary
drum cooler. The combined system of cooling coils in the roaster, superheated tube bundles,
evaporator tube bundles, and membrane wall casing is designed for the maximum load
of the boiler. The boiler produces steam in a forced circulation system and is equipped with
two circulating pumps, one motor-driven and one turbine-driven. Each pump is capable of
handling the maximum rating of the boiler continuously. The stand-by steam-driven
circulating pump will start automatically when the electric power supply fails or when the
flow of circulating water falls below a preset quantity. The water-steam mixture, produced in
the forced circulation system, is separated in a steam drum by means of a demister. A pressure
relief system is included to exhaust steam directly to the atmosphere via a noise damper in the
event of curtailed steam usage in the leaching plant. The steam relief system is designed for
the full waste heat boiler production of 49 metric tons per hour. The level-control valve
installed in the incoming demineralized water line controls the feedwater tank level.
The demineralized water is deaerated in the deaerator on top of the feedwater tank.
Deaeration is accomplished by means of steam from the saturated steam line. The
feedwater tank pressure is maintained by the pressure control valve. The deaerated feedwater
is preheated and fed to the steam drum via the feedwater pumps, one motor-driven and one
steam-driven. The steam drum level is controlled using a three-element control system.
An additive preparation and dosing station for the boiler feedwater is included in the system.
Cooled gases leaving the waste heat boiler flow into the hot electrostatic precipitator (ESP)
for final dust removal.
23
Cyclone
The cooled and dust loaded gas enters the two parallel cyclones for pre-dedusting
with a temperature of approx. 350 C. The gas leaves the cyclones at the top whereas the
dust is collected in the lower part of the cyclones and removed via rotary valves. Final
dedusting of the hot gas is achieved in the hot ESP.
24
and a key-system is used to secure every door. By this way they are protected against
accidental contact to personnel.
Separate transformer-rectifier sets per each electrostatic field (= 3 fields = 3 units) are
installed. The discharge electrode systems is supplied with high voltage DC by modern
transformer rectifier sets. Each transformer rectifier set will have its own cubicle for control
and regulation. Such a transformer rectifier set (power pack) contains a high tension
transformer and semi conductor rectifier pack. Both are installed in a steel vessel immersed in
oil. The vessels of the power packs are located in the high voltage room below the hot gas
electrostatic precipitator. The optimum values of the high voltage are controlled by a special
low voltage control system.
There is a high voltage switch on top of the T/R set for manual operation for disconnecting of
high voltage supply and earthing of the discharge electrode system
25
= 39.75
= 39750
= 10 %
= 0.111
=39749.8
t/hr
kg/hr
Dry feed
kg/hr
Concentrate composition
Component
%
Kg/hr
Zn
Fe
Lead
52
8.5
1.5
20669.94
3378.74
596.25
Copper
0.1
39.75
Suphur
30
11924.97
0.9
357.749
Cd
0.16
63.60
SiO2
795.00
Insolubles
397.50
26
1. Reactions of zinc:
Zn
ZnS
65.4
32
97.4
20669.94
10113.73
30783.68
1.5 O2
48
15170.60
ZnO
81.4
25726.81
ZnS
97.4
30783.68
kg/hr
+
SO2
64
20227.47
kg/hr
2. Reactions of lead:
Pb
207.2
596.25
PbS
239.2
688.33
S
32
92.08
PbS
239.2
688.33
1.5 O2
PbO
48
138.13
223.2
642.29
kg/hr
+
SO2
64
184.17
kg/hr
3. Reactions of copper:
Cu
63.5
39.75
CuS
95.50
59.78
S
32
20.03
CuS
95.5
59.78
1.5 O2
CuO
48
30.05
79.5
49.77
kg/hr
+
SO2
64
40.06
4. Reactions of iron:
Fe
Fe
+
+
S
S2
FeS
FeS2
75 %
25 %
27
=
=
2534.06 Kg
844.69 Kg
kg/hr
Fe
56
2534.06
S
32
FeS
88
3982.09
2 FeS
176
3982.09
3.5 O2
112
2534.06
Fe2O3
160
3620.08
Fe
56
S2
64
FeS2
120
965.35
1810.04
5.5 O2
176
1327.36
Fe2O3
160
1206.69
844.69
2 FeS2
240
1810.04
2 SO2
128
2896.06
4 SO2
256
1930.71
5. Reactions of cadmium:
Cd
112
63.60
S
32
18.17
CdS
144
81.77
CdS
144.00
81.77
O2
32
18.17
CdO
128
72.69
6. For Silica:
SiO2
795.00
SiO2
795.00
28
SO2
64
36.34
7. For Carbon:
C
12
O2
32
CO2
44
Feed
Oxides
rate
(kg/hr)
Wt of oxides
Oxygen
SO2
(kg/hr)
req.
(kg/hr)
(kg/hr)
ZnS
30783.6
ZnO
25726.80882
15170.5998
20227.4664
PbS
8
688.33
PbO
642.2906757
138.13
184.17
FeS
3982.09
Fe2O3
3620.08
2534.06
2896.06
FeS2
1810.04
Fe2O3
1206.69
1327.36
1930.71
CuS
59.78
CuO
49.77
30.05
40.06
SiO2
795.00
SiO2
795.00
29
C
CdS
357.75
81.77
Insolubles
Total
CO2
CdO
44.00
72.69
32
18.17
0
36.34
397.50
397.50
0.00
0.00
38955.9
32510.82
19250.36
25314.81
3
Oxygen Required for 38.956 tonnes of concentrate
19250.36 kg/hr
494.16 kg/hr
346.13 m3/hr
13758.49 m3/hr
65516.60 m3/hr
Excess air
25 %
16379.15 m3/hr
CO2
82.1846667 m3/hr
SO2
8865.72238 m3/hr
68137.26
m3/hr
m3/hr
81895.75
m3/hr
77085.17
75 %
24383.11
kg/hr
25 %
8127.70
kg/hr
=
45 %
40 %
=
15 %
=
=
Dust removing capacity of boiler
Dust removing capacity of Cyclone separator
Dust removig Capacity of HGP
Boiler
Cyclone separator
Intlet
outlet
Underflow
24.38 t/hr
13.41 t/hr
13.41 t/hr
3.66 t/hr
10.97 t/hr
9.75 t/hr
30
HGP
3.66
t/hr
0.01829 t/hr
3.64 t/hr
Heat Balance
Reactions involved :
Hf(KJ/mol)
Enthalpy
ZnS
-204.6
PbS
-98.12
CuS
-48.5
2 FeS
-201
2 FeS2
-355
CdS
-208.4
1.5 O2
0
ZnO
-348
1.5 O2
0
PbO
-218.08
1.5 O2
0
CuO
-155.2
3.5 O2
0
Fe2O3
-825.5
5.5 O2
0
Fe2O3
-825.5
O2
0
CdO
-235.6
O2
CO2
31
SO2
-296.84
KJ/mol
-440.24
SO2
-296.84
KJ/mol
-416.8
SO2
-296.84
KJ/mol
-403.54
2 SO2
-593.68
KJ/mol
-1218.18
4 SO2
-1187.36
KJ/mol
-1657.86
SO2
-296.84
KJ/mol
-324.04
-393.5
KJ/mol
- 4460.66 KJ/mol
Calcine flyover
M=
24383.11 kg/hr
Q=
21248538.45 kj/hr
21248.53845 MJ/hr
Cp = 1 kj/kg-k
Q
= 102968915.5 kj/hr
= 102968.9155 MJ/hr
SO2
M = 25314.81 kg/hr
Cp = 0.645 kj/kg-k
Calcine uderflow
Q = 19071167.99 kj/hr
M = 8127.70 kg/hr
= 19071.16799 MJ/hr
Cp = 0.75 kJ/kg-k
Q = 7082846.15 KJ/hr
= 7082.84615 MJ/hr
CO2
Radiation
M = 44.00Loss
Kg/hr
= 3%
Cp = 1.22
KJ/Kg-K
= 40699.3869
Q = 62698.24
KJ/hr MJ/hr
= 62.69824 MJ/hr
water evap.
Q=ml
= 8581320 Kj/hr
= 8581.32 MJ/hr
32
For
cooling
coils
Q
latent heat of vaporisation, L
m
M
=
=
=
=
m*L
2.42
Q/L
1739
9.04
= 17.4
MJ/Kg
Kg/hr
t/hr
=
=
=
=
=
=
97%
33
104.86
4398
4293.14
mh
Q/h
9.80766316
kJ/kg
kJ/kg
kJ/kg
at 25 C
at 920 C
t/hr
= 0.82
MJ/hr-m2-C
8
= 925
Calcine flyover
M
Q
Air
M
Cp
Q
=
=
=
=
=
=
=
13410.71
8434832.922
8434.832922
Kg/hr
Kj/hr
Mj/hr
68137.26
m3/hr
88158.32
1
74317462.16
74317.46216
kg/hr
kj/kg-k
kj/hr
MJ/hr
SO2
M
Cp
Q
= 25314.81
= 0.645
= 13764550.1
kg/hr
kj/kg-k
kj/hr
8
= 13764.5501
MJ/hr
Calcine uderflow
34
M = 10972.40 kg/hr
Cp = 0.75 kJ/kg-k
CO2
Q = 2398647.08 KJ/hr
M = 44.00 Kg/hr
= 2398.64708MJ/hr
Cp = 1.22 KJ/Kg-K
Q = 45252.24 KJ/hr
= 45.25224 MJ/hr
Water evap.
Q = ml
Radiation Loss
=3%
= 8581320 Kj/hr
=0 Mj
= 8581.32 MJ/hr
Heat leaving Boiler
Q entering Boiler
Total Q leaving from top
Heat leaving from boiler bottm
Q1 retaining inside boiler
=
=
=
=
1513349.34
105143.418
2398.64708
1405807.27
MJ/hr
MJ/hr
MJ/hr
MJ/hr
= 68137.26 m3/hr
M = 88158.32 kg/hr
t = 50 C
Cp = 1 kj/kg-k
Q = 28475136.75 kj/hr
Calcine flyover
M = 3657.47 kg/hr
= 28475.13675 MJ/hr
Q = 881414.1164 kj/hr
= 881.4141164 MJ/hr
SO2
M = 25314.81 kg/hr
Calcine uderflow
Cp = 0.645 kj/kg-k
M = 9753.25 kg/hr
Q = 5273961.696 kj/hr
Cp = 0.75 kJ/kg-k
= 5273.961696 MJ/hr
Q = 2350437.64 KJ/hr
= 2350.43764 MJ/hr
35
water evap.
Q = ml
CO2
M = 44.00 Kg/hr
= 8581320 Kj/hr
Heat Entering
at cyclone
inlet =105143.418MJ/hr
Cp = 1.22
KJ/Kg-K
= 8581.32 MJ/hr
Heat leaving
from Cyclone
top =MJ/hr
Q = 17338.64
KJ/hr
Radiation Loss
Heat leaving
cyclone bottm
= at
17.33864
MJ/hr =2350.43764MJ/hr3%
Heat Entering HGP
=102792.98MJ/hr
0 MJ/hr
Air
68137.26
= 88158.32
Cp
= 1
Calcine flyover
M = 18.29kg/hr
SO2
Q
= 3861.303327kj/hr
M = 25314.81 kg/hr
= 3.861303327MJ/hr
Cp = 0.645 kj/kg-k
m3/hr
kg/hr
kj/kg-k
Q = 4620839.505 kj/hr
24948804.02 kj/hr
= 4620.839505 MJ/hr
= 24948.80402 MJ/hr
Calcine uderflow
M
=
3639.18 kg/hr
Cp
0.75 kJ/kg-k
768399.362 KJ/hr
Water evap.
Q = ml
768.399362 MJ/hr
CO2
M
44.00 Kg/hr
Cp
1.22 KJ/Kg-K
15191.44 KJ/hr
15.19144 MJ/hr
8581320 Kj/hr
8581.32 MJ/hr
Radiation Loss =
3%
= 0 MJ/hr
36
102792.98
768.399362 MJ/hr
102024.581
MJ/hr
MJ/hr
Quench Tower
In the quench tower, the hot gas is cooled by the evaporation of water. The heat of the
incoming gas (Temperature: > 300C) is used for the evaporation of water that is sprayed into
the Quench Tower. The sensitive heat of the gas is converted into water vapor (latent heat).
This type of cooling can be considered as an adiabatic process. Adiabatic means, the
process step is operated without energy exchange with the environment. But besides this
quenching, also a part of the dust and condensable impurities in the gas will be scrubbed in
the quench tower. At the outlet of the tower, the gas contains water vapor. If the temperature
is lowered, water vapor will condense. The Quench Tower is designed as counter current flow
type quencher. The gas inlet is at the bottom part of the casing. The gas outlet is at the top of
the quench tower. The liquid is sprayed into the quench tower in counter-current flow to the
gas. A part of the spray does evaporate, but the biggest portion will be collected in the lower
37
part of the tower which does serve as pump tank. A side stream of the spray circuits is guided
through a settling tank for removal of suspended solids.
Excess liquid from the washing and cooling system is discharged from the quench tower
circuit via strippers.
38
the aerosols and particles are electrically charged due to high tension and migrate to the
collection tubes.
Particles and aerosols separated from the gas will be removed continuously together with the
condensate at the bottom of the ESPs, respectively from the connected gas ducts. The liquids
will be directed to a tank, which does also serve for wet ESP flushing.
Normally wet ESPs do have a good self-cleaning. This self cleaning can be improved in the
second stage wet ESPs by the installation of a continuous spraying system But from time to
time, depending on the operating conditions, each precipitator must be flushed. This is done
with liquid, that is withdrawn from a tank and that is pumped to the flushing nozzles installed
in the top part of the wet ESPs.
All parts of the wet electrostatic precipitators in contact with the gas stream will be made of
the following acid resistant materials: Homogeneously lead lined steel PVC, PP, FRP or FRP
with PVC-lining
The materials are selected in accordance with the operating conditions and mechanical loads
to which the equipment is subjected.
Mercury Removal
For the production of sulphuric acid with a low mercury-content, so-called Norzinc Mercury
Removal Process (Calomel Process) is in foreseen. This process allows a cost efficient
removal of metallic mercury vapours from SO 2-gases upstream of sulphuric acid plants. The
ingress of mercury into the sulphuric acid is prevented and a safe and reliable production of a
sulphuric acid with low mercury contents is achieved.
39
ACID PLANT
Plant Description
The sulphuric acid plant mainly consists of 2 plant sections:
40
The irrigated acid is distributed uniformly over the packing by the irrigation system. At the
gas outlet of each tower gas filters are installed, for the drying tower a wire-mesh filter, for
the intermediate and final absorber candle type filters made of a casing plugged with
special glass wool. Most part of the acid mist and all acid droplets will be removed from the
gas by the filters.
The gas flow through the towers is countercurrent to the acid flow, i.e. the gas flows from the
bottom to the top of the tower. From the bottom of the tower(s) the acid flows to the pump
sump and is pumped from there by the acid pumps (via the acid coolers) back to the irrigation
system.
Acid transfer lines between the drying tower, the intermediate absorber and the final absorber
and injection lines for dilution water at the intermediate absorber and final absorber
enable to control the necessary acid concentration for each of the towers. The acid cooler for
the drying tower, intermediate and final absorption as well as for the product acid system are
plate-type acid coolers.
Converter system
The converter system consists of a stainless steel 4layer converter. The arrangement of the catalyst beds
is 3 + 1, i.e. the intermediate absorption is after the 3rd
layer. The converter itself is an insulated, vertical
and cylindrical vessel divided in four sections: called
layers or trays. The catalyst required for the conversion
of SO2 to SO3 is arranged on these layers.
41
removal of moisture from the gases heat is liberated which increases the temperature of the
circulating acid.
Cooling of circulating acid is done by passing the acid through PHE(Plate heat exchanger),
where filter water is used as coolant. The concentration of circulating acid is maintained by
crossing through FAT & IAT vessel acid. This is done automatically based on sensing of
concentration of circulating acid by concentration analyzer.
SO2 Blower
Blower to circulate the sulphur dioxide bearing gases in converter through heat exchangers
and mixer
The SO2 gas blower is arranged downstream the drying tower and transports the gas from the
roaster section via the gas cleaning plant through the sulphuric acid plant. The blower will be
provided with an electric motor.
Converter Group
After being discharged from the SO2 blower the gas will be then routed to the shell side of
heat exchanger IV. In this heat exchanger, the main part of the SO 2 gas will be preheated to a
temperature of about 255C. A small part of the cold SO 2 gas will be withdrawn from the
lower part of the heat-exchanger IV and routed to the tube side of heat exchanger II where it
will be preheated to a temperature of about 255C while cooling the gas between layer II and
III. Both gas streams will be collected at the entrance of heat exchanger I. Before entering the
first bed of the converter the gas will pass first through the shell side of that heat
exchanger.
The gas exits this heat exchanger at a temperature of approx. 400C and enters the
first catalyst bed. Bypass lines will be located around heat exchangers IV and I to the
inlet of the first bed.
These bypass-streams will be utilized for adjusting the gas inlet temperature to the first
and third bed of the converter. The gas leaving the first pass will be cooled in the tube side of
42
the heat exchanger I to approx. 425C and enters the second bed. After passing through the
second bed the gas will be routed through the tube side of heat exchanger
II thus
cooling the SO3 gas to approx. 433C by preheating the SO 2-gas coming from the
drying tower. The gas will be fed to the third pass of the converter. After the third layer the
temperature of the gas is approx. 443 C.
The gas will be cooled will be cooled in the heat exchangers III A/B to temperature of
165 C and leaving to the intermediate absorption. After the SO 3 has been absorbed in the
intermediate absorber, the gas is returned to the converter via the shell side of heat exchanger
III A and III B where it will be preheated to a temperature of approx. 400C before entering
the fourth catalyst bed The gas leaving the fourth bed at a temperature of approx. 410C,
passes through the tube side of heat exchanger IV where it will preheat the cold SO 2 gas
before entering the first bed. After being cooled to 271 C, the gas enters the economizer.
The gas leaving the economizer at approx. 180C will then passed to the final absorber
where the remaining SO3 will be absorbed.
Preheater
The preheating is needed to preheat the converter system (e.g. catalyst and heat
exchangers) from cold conditions to operating conditions and low SO 2 strength,
whereas during normal operation of the plant the heat released within the process
allows autothermal operation of the plant. In addition lower or varying SO 2concentrations can be compensated. The separate preheater preheats air or, in start-up phases,
SO2-gas to the required temperatures.
43
absorber will be pumped through plate type acid coolers by the vertical intermediate absorber
pump back to the absorber distribution system.
A bypass located around the cooler ensures a constant temperature of approx. 70C to the
absorber. The concentration of the circulating acid, measured downstream of the cooler, will
be maintained by the addition of 96 % acid from the SO2 drying tower and by addition of
dilution water. The level in the absorber will be controlled by transferring 98.5 % acid to the
final absorption system
44
Water Balance
The water balance of contact sulphuric acid plants in general may simply be defined by the
specific amount of process water required for achieving the desired product acid strength
from the amount of SO2 converted to SO3.
In the case of cold gas acid plants (like roasting plants) the process water requirements are
usually balanced nearly completely by the water vapor content of the SO 2-feed gases
entering the drying tower except for a small margin necessary for the automatic acid strength
control.
Thus at a given SO3 gas concentration and SO2 conversion rate as well as at a fixed product
acid strength, the only variable that can and has to be controlled or limited is the water vapor
content of the feed gases entering the drying in order not to exceed the water balance of the
whole system.This is done in the wet gas purification system by cooling the SO 2 gases down
to the dew point temperature corresponding to the maximum allowable water vapor content.
When evaluating the required dew point temperature, it is important not only to
consider the designed suction pressure of the gas purification system but also the
45
external barometric pressure which depends largely on the elevation of the plant above sea
level.
Absorption of SO3
Sulphur trioxide formed by the catalytic oxidation of sulphur dioxide is absorbed in
sulphuric acid of at least 98 % concentration, in which it reacts with existing or added water
to form more sulphuric acid. The process gas leaving the converter system is cooled, first
in a gas-gas heat exchanger to a temperature of about 180C before entering the
absorber. The gas entering the absorber is therefore not completely cold and it passes heat to
the absorber acid as it passes through the absorber; by the time it reaches the outlet it is
virtually at the same temperature as the incoming absorber acid.
A substantial amount of heat is also generated in the absorber acid from the absorption of
sulphur trioxide and the formation of sulphuric acid, and the acid temperature rises in
consequence by a margin which depends on the acid circulation rate. The acid
concentration is maintained constant by adding process water to the acid leaving the absorber
and the acid crossflow from the dryer at a rate controlled by a concentration measuring
device. The circulated acid is cooled by indirect cooling.
O2
SO3
46
SO3
H2O
H2SO4
H2SO4 +
SO3
H2S2O7
H2S2O7
H2O
2 H2SO4
The dilution to acid production strength of 98.5 % H2SO4 and the condensation heat for
the water content of the gases entering the drying tower system. Sulphuric acid thus
produced is stored in acid storage tanks of capacity 6500 MT each. Finally gases are
discharged through chimney to atmosphere
O2 /SO2 Ratio
For the conversion of SO2 to SO3 the proportion of O2 volume to SO2 volume in the feed gas
to the converter, called O2/SO2 ratio, is an important factor for the conversion rate.The design
of the contact plant is based on a gas composition which is calculated on the basis of analyses
of the roaster gases be processed. However, in practice other gas compositions may occur and
their different water content may lead to substantial fluctuations in the gas composition.
Considering the SO2 concentration determined for the design of the double catalysis plant,
this may often mean an essential shifting of the expected O 2/SO2 ratio towards lower values.
On the other hand, the O2/SO2 ratio of the gases has a decisive influence on the final
conversion efficiency achievable in the contact plant.
LEACHING PLANT
Leaching is a widely used extractive metallurgy technique which converts metals into soluble
salts in aqueous media. Compared to pyrometallurgical operations, leaching is easier to
47
perform and much less harmful, because no gaseous pollution occurs. The only drawback of
leaching is its lower efficiency caused by the low temperatures of the operation, which
dramatically affect chemical reaction rates.
leach the zinc oxide from the calcine and oxidize the ferrous iron to the ferric state. In
addition to being an important zinc leaching step, the neutral leaching step is also an
important purification step. Impurities like Fe, As, Sb, and Ge are precipitated in the last
tanks of neutral leaching.
Neutral leaching consists of following main process equipment:
Calcine conveying
Calcine from roaster plant is taken through bucket elevator. There are two bucket elevator.
This calcine is transferred to calcine hopper. When calcine hopper is full, calcine is diverted
to storage silos through reddler conveyors to any of the seven silos depending on the level of
calcine present in each of them.
Neutral leaching
The ready for calcine(RC) and remaining leaching pachukas (Reactor) are all covered and
equipped with agitators and stacks. Pachukas are equipped with injectors for oxygen gas.
48
Execpt RC and the eight leaching pachukas are arranged in a cascade and are interconnected
with an overflow launder, so that the solution fed to the first tank flows by gravity to all the
tanks and to the classifier without pumps. Also , the launder system enables the bypass of any
single pachuka.
Fig.-7 Process Diagram for Neutral Leaching
Calcine from calcine hopper is fed through a screw conveyor and reddler conveyor. Ready for
calcine solution is prepared continuously in RC tank and in case of breakdown of RC tank
first pachuka is used for ready for calcine.
The main acid bearing solutions ,which is used to leach the calcine added into the neutral
leach step is the spent elecrolyte from cell house whith approx. 180 g/l free H 2SO4 along with
ball mill slurry and occasionally conversion overflow acid overflow also can be added. In
addition MnO2 (To control the ferrous content) KMnO4 are to be added in RC tank. The
dosing of MnO2 is carried out by a magnetic vibrator.
The solution mixture from the RC tank, with a free acidity of about 100-120 g/l H 2SO4
pumped to the pachuka. The acidity is lowered in the leaching tank series by calcine addition
in two steps.
H2SO4
ZnSO4 +
H2O
CuO
H2SO4
CuSO4 +
H2O
CdO
H2SO4
PbO
H2SO4
CdSO4 +
PbSO4 +
H2O
H2O
In addition to the reactions above , MnO2 reacts in the first leaching pachukas
2 FeSO4 + 2 H2SO4 + MnO2 Fe2 (SO4)3 +MnSO4 + 2 H2O
Where as in the last leaching pachukas oxygen is reacting and iron hydroxide is precipitated
2 FeSO4 + 2 H2SO4 + O2
+ ZnO
2 Fe(OH)3
49
3 ZnSO4
4 Fe(OH)3
+ Sb/As/Al/Ge-complex
Fe-OH-Sb-As-Ge-Complex
Acid Leaching
The main task of the acid leaching step is to dissolve the remaining zinc oxide, which was not
dissolved during Neutral leaching and to reach a zinc oxide leaching efficiency of more than
97%.
The main chemical reactions in weak acid leaching are:
ZnO
H2SO4
ZnSO4
H2O
MeO +
H2SO4
MeSO4
Neutralization:
Neutralization is used to remove the impurities Sb, As , Al and Ge by neutralizing the over
flow from acid leaching thickner and jarosite precipitation thickners with calcine before
sending it to neutral leaching.
50
The five conversion reactors are arranged in a cascade and are interconnected with an
overflow launder. The solution flows by gravity from the first conversion reactor down the
cascade through all reactors into the thickner of ccd system without the need of pumping.
Each reactor is covered and equipped with an agitator, a vent stack and steam heating
elements.
The weak acid leaching underflow is pumped through a flow indicator and controller into the
launder before the first conversion process in order to compensate for the sulphate losses.
MnO slurry from ZE plant is pumped in to inlet and is added to oxidize ferrous ion.the
temperature of all reactors is kept at 95-100. Ammonium sulphate or sodium sulphate diluted
with condensate water is added at outlet for formation of jarosite.
Magnesium Removal
The magnesium removal is required to maintain minimum magnesium in process solutions.
For the separation of Zn from the Mg, lime milk is used.
The magnesium plant consists of following main equipment
The lime milk solution is prepared in the lime milk tank. The Ca(OH) 2 is fed from lime bin
into the precipitation tank and the COF is fed using pump.Alternatively the feed can be
filtrate from the jarosite filtration step. The lime milk is circulated to the precipitation tanks
using pump.The neutralization process is continuous and dimensioned for about four hours
retention time.The precipitation tanks are run at pH 6.8-7.5. Zinc is precipated together with
which is not a desired situation.In pH 8 Zn is almost totally precipated and Mg has started to
precipitate. The zinc concentration will be below 10 mg/l after neutralization. Samples will be
taken and analyzed once/shift and correction in lime feed made if too much zinc is going
through.
51
Ca(OH)2
+ 2 H2O
MgSO4 +
Ca(OH)2
+ 2 H2O
H2SO4
Ca(OH)2
2 H2O
+ CaSO4 .2H2O
The slurry from reactor is fed to drum under vaccum. The MgSO 4 is filtered out and cake is
retained over the cloth which is re pulped with COF and charged in reactors through
pumpfrom where it is pumped to ETP.
The underflow slurry of door is pumped with pump to HBF over head tank. For proper
vaccum control each horizontal belt filter will be equipped with its own water ring type
vaccum pump system.
The jarosite cake is separated on polypropylene filter cloth repulped with ETP water and
pumped to ETP via HBF slurry tank. Speed of the belt input slurry flow to HBF and wash
water quantity is controlled by the concerned C/H in the HBF control room. Vacculm pipes
are connected beneath the mother belt and filter water is used for the vaccum sealing purpose.
Mother liquor (collected in the feed zone and drying zone)
Purification
The neutral solution contains several impurities like copper, cadmium, cobalt and nickel.
Becide these major impurities also small amounts of arsenic and antimony can be analyzed in
the solution. Before the solution can be sent to the electrowinning these impurities habe to be
removed in the purification plant. The main reagent in the purification plant is the Zinc dust.
The basic reaction is that of cementation of those metals, whose positions in the
electromotive series for sulphates are below that of Zinc.
The purification of the neutral solution will be carried out in three steps.
52
Cadmium plant
Following are the main stages in the production of purified cadmium sulphate solution:
Gypsum Removal
The gypsum removal system will be necessary to remove gypsum from hot neutral solution
before it is taken to the cell house in order to reduce gypsum precipitation in electrolytic
cells, piping, launders and cooling towers. The neutral solution that is saturated with gypsum
53
will be cooled in three atmospheric cooling towers from 86C to 34C. This causes
crystallization of gypsum from the solution still remains saturated with gypsum. The gypsum
will be then removed in a thickener. Spent acid will be fed for pH adjustment and flocculent
(1 g/l aqueous solution) into the thickener. The thickener overflow will be taken to the
purified solution storage tanks. The underflow will be pumped to the jarosite step.
Prior to be directed to the cooling towers the pH of the solution will be adjusted to 4.9 to
prevent formation of basic zinc sulphates. The pH adjustment is made in the filtrate collecting
tank of the polishing purification step by adding a controlled amount of spent electrolyte.
The solution is fed to the top of the tank through nozzles. The falling solution meets the air
produced by the fan and solution will cool down when water is evaporated. The cooled
solution is collected on the bottom of the tower and leaves the tower trough an overflow box,
which is provided with temperature control and level detection. The overflow from the
thickener flows by gravity via the launder to the selected purified solution storage tank. In
this whole process, a part of gypsum, about 157 kg/h is removed from the solution.
Electrolysis Plant
Zinc is extracted from the purified zinc sulfate solution by electrowinning, which is a
specialized form of electrolysis. The process works by passing an electric current through the
54
solution in a series of cells. This causes the zinc to deposits on the cathodes (aluminium
sheets) and oxygen to form at the anodes. Sulfuric acid is also formed in the process and
reused in the leaching process. Every 24 to 48 hours, each cell is shut down, the zinc-coated
cathodes are removed and rinsed, and the zinc is mechanically stripped from the aluminum
plates.
Electrolytic zinc smelters contain as many as several hundred cells. A portion of the electrical
energy is converted into heat, which increases the temperature of the electrolyte. Electrolytic
cells operate at temperature ranges from 30 to 35C (86 to 95F) and at atmospheric pressure.
A portion of the electrolyte is continuously circulated through the cooling towers both to cool
and concentrate the electrolyte through evaporation of water. The cooled and concentrated
electrolyte is then recycled to the cells. This process accounts for approximately 1/3 of all the
energy usage when smelting zinc
The electrolysis phase uses large amounts of electrical energy and is responsible for the high
proportion of the energy-cost in the overall smelting process (typically about one third of
total plant cash costs). Hence, cell house productivity (and electrical current and energy
efficiency in particular) is a crucial driver in overall plant efficiency. Debari runs some of the
industrys largest and most efficient cell houses.
55
Cathode melting will be carried out in two identical electric induction furnaces. The furnaces
will have a guaranteed average melting rate of 22 tonnes per hour of zinc cathodes
(maximum ~ 24 tonnes per hour). The melting rate is infinitely variable between 0% and
100% of the maximum melting rate and is controlled by the automatic control system to
match the rate that molten metal is removed (pumped) from the furnace.
Each furnace is equipped with a still well equipped with one or more molten metal pumps.
The pump delivers molten zinc to a launder system feeding the casting machine. Each
furnace feeds a single casting line. In addition, provision is made to pump molten zinc from
one of the furnaces to the zinc dust production plant.
In addition to cathode bundles, the furnace chutes are designed to receive metallic zinc from
the dross separation plant and metallic zinc skims from the casting machines. This material
is fed to any chute (normally one dedicated chute) from forklift transported to hoppers that
have been raised to the charging floor by the freight elevator (lift). The required amount of
nh4cl to enhance the melting of this material is manually added to each hopper prior to
dumping in the charge chute.
When cathode zinc is melted, a layer of dross comprised mainly of zinc oxide entrained
molten zinc droplets is produced. This dross must be removed from the furnace once in every
24 hours by manually skimming the dross from the surface of the bath in a process called
drossing. This process consists of opening one of the doors on the side of the furnace,
manually spreading a few kg of NH4Cl onto the dross layer, manually agitating the dross
layer with a steel rake and finally using the rake to drag the dross through the open door
of the furnace into a forklift tote bin. During the drossing process, the furnace is operated
under conditions of increased ventilation to contain the fumes and dust that are generated by
the agitation and dross removal processes. The totes of furnace dross are transported by lift
truck to the dross cooling area, to await treatment in the dross separation plant.
56
REFERENCES
International Editions.
http://www.hzlindia.com/index.aspx
[Viewed on 10-06-2015]
http://www.vedantaresources.com/default.aspx Offical Website of Vedanta Resources
[Viewed on 10-06-2015]
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