Académique Documents
Professionnel Documents
Culture Documents
Contents
Introduction to Ticona
Fortron PPS
Chemistry
Properties
Applications
Fortron PPS Composites
Background
Processing Options
Properties
Applications
Summary
Service temperature
Engineering Polymers
High-Performance
Polymers (HPP)
(TI1 > 150C)
Engineering
Polymers (ETP)
(TI1 90 150C)
Basic
Polymers
LCP
Vectra /Zenite
PPS
Fortron
PCT
Thermx
PET
Impet
PBT
Celanex
PBT Alloy
Vandar
TPC-ET
Riteflex
POM
Hostaform/Celcon
UHMW-PE
GUR
Amorphous
LFRT
Celstran, Factor
Compel
CFR-TP
Celstran Tapes,
Rods and Profiles
Partially crystalline
Fortron PPS
Summary Structure and Properties
Semicrystalline
Tg 85C, TM 285C
Density 1.35 g/cm
Dimensional Stability
Fuels, oils, solvents
Water-glycol
Easy to Process
Injection molding
Polyphenylenesulfide (PPS)
Extrusion
Fortron PPS
elevated temperatures
Resists: acids/bases pH 2 to 12
Resists: strong bleaches
Resists: auto fluids coolants,
transmission & brake
Resists: gas & alternate fuels
(methanol, ethanol)
Resists: hydrolysis
Fortron 0214C1
Matrix Material for Composites
Linear, unmodified PPS polymer
High molecular weight / high viscosity: 140 pas
For extrusion and injection molding applications
Specified for aircraft applications
In use at Airbus and Boeing
VIAM qualification
Federal state unitary enterprise All Russian Scientific Research
Institute of Aviation Materials
Tested in regards to flammability, smoke density and smoke
toxicity:
ABD0031
FAR/JAR 25.853
New: DIN 5510 and ISO 5659
Tox-Test (ABD0031):
ABD / FAR passed
Value
NF: 0 F: 0
150
NF: 0 F: 10
1000
NF: 0 F: 0
100
NF: 0 F: 10
100
NF: 0 F: 0
100
NF: 0 F: 0
150
Material
Part Thickness
Unaged Sample
Rating
Aged Sample
Rating
3.0mm (0.12)
V-0*
V-0*
1/32
V-0
V-2
1/64
V-2
V-2
3.0mm (0.12)
V-0*
V-0*
1.5mm (0.059)
V-0*
V-0*
1/32
No V-Rating
V-2
1/64
No V-Rating
No V-Rating
Unfilled PEEK
Control
10
11
0.16
0.14
0.12
(%)
0.10
0.08
0.06
0.04
0.02
0
PPS
PEI
PEEK
12
Industrial
EE & Sensors
Fibers
Composites
Automotive
13
Fortron PPS
Automotive: Under the Hood
Throttle Body 1140L4
14
Fortron PPS
Automotive: Fuel Applications
Fortron PPS was selected for:
Fuel Injection Rail
15
Fortron 1140L4
Water Pump Impellers
The challenge:
Improve pump efficiency
Decrease water pump cost
Improve fuel efficiency (Lower HP
requirements)
The innovation:
Exotic blade shapes improve
pump efficiency by 10-20% vs.
sheet metal
Fortron PPS has required
chemical / hydrolysis resistance
to OAT coolants
Excellent fatigue properties
withstand pressure cycles
Excellent erosion resistance
16
Chemical
Metering Pump
Instant Hot
Water Heater
Medical Forceps
Washing Machine
Light Fixture
17
Fortron PPS
Extrusion: Film, Fiber, Netting, etc.
Aircraft Composite
Stock Shapes
CPI Filter
18
Fortron PPS
for Thermoplastic Composites
May 2012
2013 Celanese PPS-014 AM 10/13
Melt processible
Can be reformed
Near infinite shelf life
No refrigeration needed
Common generalized attributes:
Good in fatigue
Insensitive to moisture
Tough
Higher temperature
Damage tolerant
Excellent FST
20
Improved Processing
Damage tolerant
Insensitive to moisture
High-temperature performance
Very low flammability, smoke, toxicity
Low residual stress in molded parts
Excellent chemical resistance
Green processing
Recyclable
No VOCs in processing
21
Processing
Material
System Cost in %
80
60
40
20
0
Conventional
Thermoplastic
Even the High Cost Thermoplastic Polymers Offer Improved Cost Savings
vs. Epoxy Based Composites
2013 Celanese PPS-014 AM 10/13
22
Raw
Materials
Fibers
E Glass
S2 Glass
Carbon/
Graphite
Aramid/Kevlar
Polymer
Boron/Ceramic
Resins
PEEK
PPS
PEI
Nylons
PP
Etc
Intermediate
Products
Film
Fabric
Prepreg
Dry Powder
Fabrication
Processes
End Users
Pultrusion
Sheets
Lamination
Rods
Molding
Oven
Pipes/Tubes
Beams
Slurry
Match
Shapes
Hot Melt
Bladder
Structures
Liquid
Comingle
Fiber Placement
Filawinding
AFP
Tows
Fabric
23
Plastic
Pellets
Film
Producer
Producer of
Composites
ThermoFormingProcess
Assembling
Aircraft
24
Fortron PPS
Pellets
Starting Product:
Film Production
PPS Pellets
Temperature stability
High level of hardness and
impact strength
Excellent resistance
to chemicals
Broad temperature range
Inherent flame resistance
25
Starting Product:
Basic Matrix of
PPS / Carbon Fiber Fabric
Laminate Production
Station 2 Ten Cate Advanced
Composites BV, Nijverdal, Netherlands. The
carbon fiber fabric and PPS film are bonded
together in a press, under high pressure
and high temperature, into high-strength,
dimensionally stable and resistant
composites in the desired layer thickness.
2013 Celanese PPS-014 AM 10/13
26
Station 3: Thermoforming
Positive Form
Composite
Plate
Starting Product:
Negative Form
Composite plates
in the required size
Shaping
Station 3 Fokker Special
Products, Hoogeveen, Netherlands.
The composite plates are preheated and subsequently shaped
into the desired form under
pressure and high temperature.
27
Station 4: Assembly
Starting Product:
Front wing portion
(Weight of the parts is
20 percent less than
aluminum)
Assembly
Station 4 Airbus
The completed construction
element is mounted at the
intended location.
28
29
Fortron PPS
Success in the Aviation Industry
Safe, efficient, environmentally friendly
Modern design
Licensed for aircraft construction
New applications from Fortron PPS
30
31
Part Complexity
In-Situ
Filament Winding,
Tape Placement
Continuous
Molding
Pultrusion
Diaphragm
Forming
Prepreg Molding
Compression Molding,
Autoclave
Sheet Forming:
Stamping,
Roll Forming
Relative Cost
Source: Composite Market Reports
32
33
Automated Dynamics
Fiber Placement
Lingol Thermoforming
34
35
36
Thermoplastics
37
Thermoplastics
Cool, removal
immediately
Additional Savings:
No Need for Prepreg Freezers
Reduced Facility HVAC Costs
Energy Required Per Part Can Be Less Than a Factor of 10 for TP vs. TS
with Match Metal Molding of Simple Parts
2013 Celanese PPS-014 AM 10/13
38
Thermoplastics
No Cure By-Products
No Halogenation Necessary for Most
High
Performance Thermoplastics
39
Tg, C
High Load
Continuous use
Temperature, C
Approx.
Resin Cost,
$/lb
Approx. Carbon
Reinforced
prepreg Cost, $/lb
Fortron PPS
90
85
5.00
30.00
PEI
217
115
10.00
45.00
PEEK
143
138
60.00
90.00
40
AS-4
Resin Type
PPS
Fiber Weight %
663
Resin Weight %
343
Fiber Volume %
593
Resin Volume %
413
150 g/m2
227 g/m2
Density
Thickness/Ply
Tape Width
12 (30.5 cm)
Test Data
297 (2,045)
7.2 (50)
18.5 (127)
1.3 (8.8)
162 (1,117)
17.2 (118)
243 (1,672)
16.3 (112)
11.1 (77)
41
E-Glass
683
533
260 g/m2
0.072 lb/in3 (2.0 g/cm3)
0.0076 (0.19 mm)
Resin Type
Resin Weight %
Resin Volume %
Total Areal Weight
PPS
323
473
382 g/m2
Tape Width
12 (305 mm)
Fiber Orientation
0
45
90
0
45
90
0/ 45/ 90
0/ 45/ 90
0
0
0/ 45/ 90
0/ 45/ 90
0
0
0
0
0
Test Data
162 (1,118)
19.5 (135)
6.7 (46)
6.3 (44)
2.1 (14.5)
2.0 (13.8)
30 (207)
2.7 (18.6)
161 (1,111)
6.0 (41)
44 (304)
3.4(23.5)
8.9 (61)
0.8 (5.5)
174 (1,201)
6.2 (43)
9.1 (63)
42
Mass of fabric
8.26
oz/yd2
280
g/m2
14.33
oz/yd2
486
g/m2
50
50
43
43
Moisture pick up
0.1
0.1
0.0122
In
0.31
mm
Specific gravity
96.7
lb/ft3
1.55
g/cm3
Tg (DSC) (amorphous)
194
90
Tg (DSC) (crystalline)
248
120
TM
536
280
Ply thickness
43
7781/PPS
49.3
ksi
340
MPa
48.3
ksi
333
MPa
3.1
Msi
22
GPa
2.9
Msi
20
GPa
61.6
ksi
425
MPa
42.8
ksi
295
MPa
3.7
Msi
26
GPa
3.5
Msi
24
GPa
74.2
ksi
511
MPa
56.6
ksi
390
MPa
3.3
Msi
23
GPa
2.9
Msi
20
GPa
11.6
ksi
80
MPa
538.5
ksi
3714
MPa
23.0
ksi
158
MPa
26.5
ksi
183
MPa
24.8
ksi
171
MPa
46.1
ksi
318
MPa
74.8
ksi
516
MPa
* TenCate
CETEX Data
44
140
23C
120
80C
100
80
60
40
20
0
Tensile
Strength
Compressive
Strength
Flexural
Strength
In Plane
Shear
Open Hole
Tensile
CETEX Data
45
-55C
23C
80C
6
5
4
3
2
1
0
Tensile Modulus, msi
Compressive Modulus,
msi
CETEX Data
46
Working Together
in the Aviation Industry
Airworthiness Authorities
Flown on a KLM aircraft for 3.5 years
48
49
Multi-technology concept
Panels and spars
Thermoset Prepreg lay-up
TP ribs and angles
Aluminum and titanium brackets
50
A340-600
A380-800
51
Edge Ribs
Main Ribs
Edge Rib
Leading Edge
Ribs, Angles & Panels
52
L = 700 1400 mm
W = 200 400 mm
Thickness 2.8 mm
Double-Curvature Shape
Material:
53
8 assemblies / wing
Wing length: 26 meters
16 segments, 52-meter length
400 kg total weight
54
280 g
150 g
55
56
57
Summary
composites needs
58
Contact Information
Disclaimer
This publication was printed on 1 October 2013 based on
Celaneses present state of knowledge, and Celanese
undertakes no obligation to update it. Because conditions of
product use are outside Celaneses control, Celanese makes
no warranties, express or implied, and assumes no liability in
connection with any use of this information. Nothing herein is
intended as a license to operate under or a recommendation
to infringe any patents.
Copyright 2013 Celanese or its affiliates.
All rights reserved.
Americas
8040 Dixie Highway, Florence, KY 41042 USA
Product Information Service
t: +1-800-833-4882 t: +1-859-372-3244
Customer Service
t: +1-800-526-4960 t: +1-859-372-3214
e: info-engineeredmaterials-am@celanese.com
Europe
Am Unisys-Park 1, 65843 Sulzbach, Germany
Product Information Service
t: +(00)-800-86427-531 t: +49-(0)-69-45009-1011
e: info-engineeredmaterials-eu@celanese.com
Asia
4560 Jinke Road, Zhang Jiang Hi Tech Park
Shanghai 201203 PRC
Customer Service
t: +86 21 3861 9266 f: +86 21 3861 9599
e: info-engineeredmaterials-asia@celanese.com
59
Thank you.
For more information:
1-800-833-4882
info-engineeredmaterials-am@celanese.com
celanese.com/engineered-materials