Paper - 1: Chemistry, Mathematics & Physics 1:: 40 Test Booklet Code

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PAPER - 1
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: CHEMISTRY, MATHEMATICS & PHYSICS

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3. U 3 U
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5. U S A, B, C ,
U , 30 U
U 4 (U)
U
6. U U 5
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7. U U U
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8. U cU-1 cU-2 U U U U
U / U U

9. U mU U / U U
U , S, , U,
U U U U
U
10. U U S U U
cU U U U S cU U
(cU 39)
11. U U, U / U U
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A U
PART A CHEMISTRY
1.
2.
possible excited state of hydrogen ?
U S
?
(1)
26.8 eV
(1)
26.8 eV
(2)
23.4 eV
(2)
23.4 eV
(3)
16.8 eV
(3)
16.8 eV
(4)
113.6 eV
(4)
113.6 eV
Which of the following is the energy of a
In the following sequence of reactions :

KMnO 4
SOCl 2
Toluene A
B
H2 /Pd
BaSO 4
1.
2.

KMnO 4
SOCl 2
Toluene A
B
C,
H2 /Pd
BaSO 4
the product C is :
(1)
(2)
(3)
(4)
3.
C6H5CH3
(1)
C6H5CHO
(3)
C6H5CH2OH
(2)
C6H5COOH
Which
compound
(4)
would
give
3.
5 - keto - 2 - methyl hexanal upon
C6H5CH3
C6H5CH2OH
C6H5CHO
C6H5COOH
$ U U
5 - U - 2 - ?
ozonolysis ?
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
B/Page 2
SPACE FOR ROUGH WORK /
4.
5.
6.
The ionic radii (in ) of N32, O22 and F2
4.
N32, O22 F2
( )
are respectively :
(1)
1.36, 1.71 and 1.40
(1)
1.36, 1.71
1.40
(2)
1.71, 1.40 and 1.36
(2)
1.71, 1.40
1.36
(3)
1.71, 1.36 and 1.40
(3)
1.71, 1.36
1.40
(4)
1.36, 1.40 and 1.71
(4)
1.36, 1.40
1.71
The color of KMnO4 is due to :
5.
KMnO4
U U
(1)
d 2 d transition
(1)
d 2 d
(2)
L M charge transfer transition
(2)
L M
(3)
s 2 s* transition
(3)
s 2 s*
(4)
M L charge transfer transition
(4)
M L
Assertion : Nitrogen and Oxygen are the
6.
main components in the

atmosphere but these do not
SU
SU
U U U
U U U
U U
react to form oxides of nitrogen.

Reason :
The reaction between nitrogen
and oxygen requires high

temperature.
(1)
Both assertion and reason are
U U

(1)
U U
ScUU
(2)
(3)
(4)
U U
ScUU
correct, but the reason is not the

correct explanation for the assertion
(2)
The assertion is incorrect, but the

reason is correct
(3)
Both the assertion and reason are

incorrect
(4)
Both assertion and reason are

correct, and the reason is the correct
explanation for the assertion
B/Page 3
7.
Which of the following compounds is not
7.
an antacid ?
8.
(1)
Cimetidine
(1)
(2)
Phenelzine
(2)
(3)
Ranitidine
(3)
(4)
Aluminium hydroxide
(4)
In the context of the Hall - Heroult process
8.
for the extraction of Al, which of the
UU
UUU
UU
-UU c
?
following statements is false ?

(1)
Al 2 O 3 is mixed with CaF 2 which

lowers the melting point of the
(1)
mixture and brings conductivity

(2)
Al31 is reduced at the cathode to
(2)
form Al
9.
(3)
Na3AlF6 serves as the electrolyte
(3)
(4)
CO and CO2 are produced in this

process
(4)
Match the catalysts to the correct
9.
processes :
Catalyst
Process
CaF2 Al2O3
U
U
U U Al31 U Al
Na3AlF6 l U U
CO CO2
U
U
U
(A) TiCl3
(i)
U
(B) PdCl2
(ii) -^
UU
(C) CuCl2
(iii) S
(D) V 2O 5
(iv) U
(A)
TiCl3
(i)
Wacker process
(B)
PdCl2
(ii)
Ziegler - Natta
(C)
CuCl2
(iii)
Contact process
(D)
V 2O 5
(iv)
Deacons process
(1)
(A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)
(1)
(A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)
(2)
(A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)
(2)
(A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)
(3)
(A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)
(3)
(A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)
(4)
(A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)
(4)
(A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)
B/Page 4
polymerization
10.
10.
In the reaction
NaNO /HCl
0258 C
CuCN/KCN
D
NaNO /HCl
0258 C
D E 1 N 2
CuCN/KCN
D
D
E 1 N2
the product E is :
11.
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
of paints and lacquers ?
U
?
(1)
Glyptal
(1)
(2)
Polypropene
(2)
(3)
Poly vinyl chloride
(3)
UU
(4)
Bakelite
(4)
Which polymer is used in the manufacture
B/Page 5
11.
12.
13.
exist for square planar [Pt (Cl) (py) (NH3)
(NH2OH)]1 is (py 5 pyridine) :
[Pt (Cl) (py) (NH3) (NH2OH)]1

(py 5 pyridine)

(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
The number of geometric isomers that can
Higher order (>3) reactions are rare due
12.
13.
U (>3)
to :
(1)
increase in entropy and activation
(1)
U U
h
(2)
U UU U U
SU
energy as more molecules are

involved
(2)
shifting of equilibrium towards

reactants due to elastic collisions
(3)
loss of active species on collision
(3)
UU S$
(4)
low probability of simultaneous
(4)
UU

collision of all the reacting species
14.
Which among the following is the most
14.
reactive ?
(1)
Br2
(1)
Br2
(2)
I2
(2)
I2
(3)
ICl
(3)
ICl
(4)
Cl2
(4)
Cl2
B/Page 6
15.
Two Faraday of electricity is passed
15.
through a solution of CuSO4. The mass of
copper deposited at the cathode is :
CuSO4
, UU l
U U :
(Cu U 563.5 amu)
(at. mass of Cu563.5 amu)
16.
(1)
63.5 g
(1)
63.5 g
(2)
2g
(2)
2g
(3)
127 g
(3)
127 g
(4)
0g
(4)
0g
adsorbed (per gram of charcoal) is :
S 0.06N U 50 mL
3 g cU
U U U S
0.042 N U
(cU- U)

(1)
36 mg
(1)
36 mg
(2)
42 mg
(2)
42 mg
(3)
54 mg
(3)
54 mg
(4)
18 mg
(4)
18 mg
3 g of activated charcoal was added to
16.
50 mL of acetic acid solution (0.06N) in a

flask. After an hour it was filtered and
the strength of the filtrate was found to be
0.042 N.
17.
The amount of acetic acid
accomplished by :
UU
U
(1)
Sandmeyers reaction
(1)
UU
(2)
Finkelstein reaction
(2)
SU
(3)
Swarts reaction
(3)
SU
(4)
Free radical fluorination
(4)
The synthesis of alkyl fluorides is best
B/Page 7
17.
18.
The molecular formula of a commercial
18.
resin used for exchanging ions in water

softening is C8H7SO3Na (Mol. wt. 206).
What would be the maximum uptake of
Ca21 ions by the resin when expressed in
U$ C8H7SO3Na
( U = 206) U$ Ca21
(
U$) ?
mole per gram resin ?
19.
20.
(1)
1
206
(1)
1
206
(2)
2
309
(2)
2
309
(3)
1
412
(3)
1
412
(4)
1
103
(4)
1
103
soluble ?
(1)
Vitamin D
(1)
U D
(2)
Vitamin E
(2)
U E
(3)
Vitamin K
(3)
U K
(4)
Vitamin C
(4)
U C
Which of the vitamins given below is water
The intermolecular interaction that is
19.
20.
dependent on the inverse cube of distance
U-
U U U ,
between the molecules is :

(1)
ion - dipole interaction
(1)
- m
(2)
London force
(2)
(3)
hydrogen bond
(3)
(4)
ion - ion interaction
(4)
B/Page 8
21.
The following reaction is performed at
21.
298 K U
298 K.
2NO(g) 1 O 2 (g) 2NO 2 (g)
2NO(g) 1 O 2 (g) 2NO 2 (g)

298 K U NO(g)

86.6 kJ/mol 298 K U NO2(g)
? (Kp51.631012)
The standard free energy of formation of

NO(g) is 86.6 kJ/mol at 298 K. What is
the standard free energy of formation of
NO2(g) at 298 K? (Kp51.631012)
22.
23.
(1)
866001R(298) ln(1.6310 12)
(1)
866001R(298) ln(1.631012)
(2)
86600 2
(2)
86600 2
(3)
0.5[2386,6002R(298) ln(1.631012)]
(3)
0.5[2386,6002R(298) ln(1.631012)]
(4)
R(298) ln(1.6310 12)286600
(4)
R(298) ln(1.631012)286600
ln (1.6 3 1012 )
R (298)
ln (1.6 3 1012 )
R (298)
colored yellow ?
U
?
(1)
K3[Co(NO2)6]
(1)
K3[Co(NO2)6]
(2)
(NH4)3 [As (Mo3 O10)4]
(2)
(NH4)3 [As (Mo3 O10)4]
(3)
BaCrO 4
(3)
BaCrO 4
(4)
Zn2[Fe(CN)6]
(4)
Zn2[Fe(CN)6]
Which of the following compounds is not
In Carius method of estimation of
22.
23.
halogens, 250 mg of an organic compound

gave 141 mg of AgBr. The percentage of
bromine in the compound is :
U 250 mg
141 mg AgBr
:
(U Ag5108; Br580)
(at. mass Ag5108; Br580)

(1)
36
(1)
36
(2)
48
(2)
48
(3)
60
(3)
60
(4)
24
(4)
24
B/Page 9
24.
Sodium metal crystallizes in a body centred
24.
cubic lattice with a unit cell edge of 4.29.

The
radius
of
sodium
atom
is
U
SU U 4.29
U U
approximately :
25.
(1)
3.22
(1)
3.22
(2)
5.72
(2)
5.72
(3)
0.93
(3)
0.93
(4)
1.86
(4)
1.86
Which of the following compounds will
25.

?
(1) 3 - - 1 - U
(2) 2 - - 1 - U
(3) 1, 1 - U - 1 -
(4) 1 - - 2 - U
26.
208C U
exhibit geometrical isomerism ?
26.
(1)
3 - Phenyl - 1 - butene
(2)
(3)
1, 1 - Diphenyl - 1 - propane
(4)
The vapour pressure of acetone at 208C is

185 torr. When 1.2 g of a non-volatile
substance was dissolved in 100 g of acetone
at 208C, its vapour pressure was 183 torr.
The molar mass (g mol21) of the substance
U c 185 torr
208C U, 1.2 g c 100 g
U , c 183 torr
U (g mol21 )

is :
27.
(1)
64
(1)
64
(2)
128
(2)
128
(3)
488
(3)
488
(4)
32
(4)
32
From the following statements regarding
27.
H2O2, choose the incorrect statement :

(1)
It decomposes on exposure to light
(2)
It has to be stored in plastic or wax

lined glass bottles in dark
(3)
It has to be kept away from dust
(4)
It can act only as an oxidizing agent
B/Page 10
H2O2
,

(1) U
(2) SU U U

(3) U U
(4) U
U
28.
greater than its lattice enthalpy ?
U U

?
(1)
BeSO4
(1)
BeSO4
(2)
BaSO4
(2)
BaSO 4
(3)
SrSO 4
(3)
SrSO 4
(4)
CaSO 4
(4)
CaSO 4
Which one of the following alkaline earth
28.
metal sulphates has its hydration enthalpy
29.
300 K for the reaction 2A B 1 C is
U 2A B 1 C
$ 2494.2 J
2494.2 J. At a given time, the composition
The standard Gibbs energy change at
of the reaction mixture is [A] 5
29.
1
, [B]52
2
[B]52 U [C] 5
1
. The reaction proceeds in
2
the : [R58.314 J/K/mol, e52.718]
30.
300 K
1
2
[A] 5
and [C] 5
[R58.314 J/K/mol, e52.718]
(1)
reverse direction because Q > Kc
(1)
U Q > Kc
(2)
forward direction because Q < Kc
(2)
Q < Kc
(3)
reverse direction because Q < Kc
(3)
U Q < Kc
(4)
forward direction because Q > Kc
(4)
Q > Kc
Which one has the highest boiling point ?
30.
(1)
Ne
(1)
Ne
(2)
Kr
(2)
Kr
(3)
Xe
(3)
Xe
(4)
He
(4)
He
B/Page 11
1
,
2
PART B MATHEMATICS
31.
The sum of coefficients of integral powers
31.
32.
50
( )
1 50
3
2
(2)
1 50
3 21
2
(3)
1 50
2 11
2
(4)
1 50
3 11
2
1 50
3
2
(2)
1 50
3 21
2
(3)
1 50
2 11
2
(4)
1 50
3 11
2
Let f (x) be a polynomial of degree four
32.
x51
f ( x )
If lim 1 1
5 3 , then f (2) is equal
x 0
x2
f (x)
(1)
24
(1)
24
(2)
(2)
(3)
(3)
(4)
28
(4)
28
The mean of the data set comprising of 16
x52

U U
f ( x )
lim 1 1
53
x 0
x2
to :
33.
observations is 16. If one of the observation

valued 16 is deleted and three new
observations valued 3, 4 and 5 are added
to the data, then the mean of the resultant
(1)
16.0
(1)
16.0
(2)
15.8
(2)
15.8
(3)
14.0
(3)
14.0
(4)
16.8
(4)
16.8
, f (2) UU
16
16 , U U, 3
3, 4 5 ,
,
16
data, is :
B/Page 12
( )
(1)
having extreme values at x51 and x52.
33.
m U
is :
(1)
50
of x in the binomial expansion of
(1 2 2 x )
(1 2 2 x )
34.
The sum of first 9 terms of the series
34.
13 1 2 3
13 1 2 3 1 3 3
13
1
1
1 .... is :
1
113
11 31 5
13 1 2 3
13 1 2 3 1 3 3
13
1
1
1 ....
1
113
11 31 5
35.
(1)
96
(1)
96
(2)
142
(2)
142
(3)
192
(3)
192
(4)
71
(4)
71
Let O be the vertex and Q be any point on
35.
the parabola, x258y. If the point P divides

the line segment OQ internally in the ratio
1 : 3, then the locus of P is :
36.
U x258y O U
Q P, U U OQ
1 : 3 U U , P

(1)
y 2 5x
(1)
y 2 5x
(2)
y 2 52x
(2)
y 2 52x
(3)
x 2 52y
(3)
x 2 52y
(4)
x 2 5y
(4)
x 2 5y
Let a and b be the roots of equation
36.
x 2 26x2250. If a n 5a n 2b n , for n/1,

a 2 2a8
then the value of 10
is equal to :
2a9
a b m U x226x2250
n/1 , an5an2bn ,
a10 2 2a8
2a9
(1)
26
(1)
26
(2)
(2)
(3)
23
(3)
23
(4)
(4)
B/Page 13
37.
If 12 identical balls are to be placed in 3
37.
identical boxes, then the probability that

one of the boxes contains exactly 3 balls
12 , 3 U
, U 3

is :
38.
10
(1)
2
55
3
(2)
1
220
3
(3)
1
22
3
(4)
55 2 11

3 3
2
55
3
(2)
1
220
3
(3)
1
22
3
(4)
55 2 11

3 3
12
11
A complex number z is said to be
38.
unimodular if ?z?51. Suppose z1 and z2

z1 2 2 z2
are complex numbers such that
2 2 z1 z2
10
(1)
12
11
z
?z?51 z1 z2
z1 2 2 z2
2 2 z1 z2
is unimodular and z2 is not unimodular.

Then the point z1 lies on a :
, z1 S
(1)
straight line parallel to y-axis.
(1)
y-
(2)
circle of radius 2.
(2)
(3)
circle of radius
(4)
straight line parallel to x-axis.
B/Page 14
2.
z2
U U U
U
(3)
(4)
x-
U U U
39.
The integral
dx
x 2 ( x 4 1 1)3 4
equals :
39.
(1)
( x 411) 4 1 c
(2)
2( x 4 1 1) 4 1 c
(3)
x 41 1 4
2
1c
x4
(4)
x4 1 1 4
1c
x4
x ( x 1 1)
1
(2)
2( x 4 1 1) 4 1 c
(3)
x 41 1 4
2
1c
x4
(4)
x4 1 1 4
1c
x4
co-ordinates as integers, that lie in the
40.
interior of the triangle with vertices (0, 0),

(0, 41) and (41, 0), is :
, (0, 0), (0, 41) (41, 0) ,

U S
Z ,
(1)
861
(1)
861
(2)
820
(2)
820
(3)
780
(3)
780
(4)
901
(4)
901
The distance of the point (1, 0, 2) from the

of
intersection
of
the
41.
line
y 11
x 22
z 22
5
5
and the plane
3
4
12
x2y1z516, is :
(1)
(2)
3 21
(3)
13
(4)
2 14
B/Page 15
UU
The number of points, having both
point
( x 411) 4 1 c
41.
(1)
40.
dx
2
y 11
x 22
z 22
5
5
3
4
12
x2y1z516 U ,
U
(1)
(2)
3 21
(3)
13
(4)
2 14

(1, 0, 2)
42.
parallel to the plane, x13y16z51, is :
U 2x25y1z53, x1y14z55 cU
U , x13y16z51
U , U
(1)
x13y16z527
(1)
x13y16z527
(2)
x13y16z57
(2)
x13y16z57
(3)
2x16y112z5213
(3)
2x16y112z5213
(4)
2x16y112z513
(4)
2x16y112z513
The equation of the plane containing the
42.
line 2x25y1z53; x1y14z55, and
43.
The area (in sq. units) of the region

described by
43.
{(x, y) : y2[ 2x y / 4x 2 1} mU
( )
{(x, y) : y2 [ 2x and y / 4x 2 1} is :
44.
(1)
5
64
(1)
5
64
(2)
15
64
(2)
15
64
(3)
9
32
(3)
9
32
(4)
7
32
(4)
7
32
If m is the A.M. of two distinct real

numbers l and n (l, n > 1) and G1, G2 and
44.
G3 are three geometric means between l

and n, then G14 1 2G24 1 G 34 equals.
S l n
(l, n > 1) U (A.M.) m U l
n U (G.M.) G1, G2
G3 ,
(1)
4 lm2n
(1)
4 lm2n
(2)
4 lmn2
(2)
4 lmn2
(3)
4 l2m2n2
(3)
4 l2m2n2
(4)
4 l2mn
(4)
4 l2mn
B/Page 16
G1 1 2G2 1 G 3
UU
45.
Locus of the image of the point (2, 3) in
45.
the line (2x23y14)1k (x22y13)50,

straight line parallel to y-axis.
(2)
circle of radius
(3)
circle of radius
(4)
46.

(1) y- U U
2
(2)
3
(3)
(4) x- U U
2.
3.
straight line parallel to x-axis.
The area (in sq. units) of the quadrilateral
(2, 3)
(2x23y14)1k (x22y13)50, k e R
k e R, is a :
(1)
46.
y2
x2
1
51
9
5
U U
S U mU
( )
formed by the tangents at the end points

of the latera recta to the ellipse
y2
x2
1
5 1 , is :
9
5
(1)
(2)
(3)
(4)
47.
(1)
18
27
2
27
(2)
(3)
27
4
(4)
The number of integers greater than 6,000
47.
that can be formed, using the digits 3, 5, 6,
18
27
2
27
27
4
3, 5, 6, 7 8 , U,
6,000 Z
7 and 8, without repetition, is :
48.
(1)
192
(1)
192
(2)
120
(2)
120
(3)
72
(3)
72
(4)
216
(4)
216
having at least three elements is :
A B U
, A3B
,
,
(1)
256
(1)
256
(2)
275
(2)
275
(3)
510
(3)
510
(4)
219
(4)
219
Let A and B be two sets containing four
48.
and two elements respectively. Then the

number of subsets of the set A3B, each
B/Page 17
49.
49.
Let
2x
tan21 y 5 tan21 x 1 tan21
1 2 x2
where ? x ? <
(1)
(2)
(3)
(4)
50.
1
. Then a value of y is :
3
?x? <
(1)
1 2 3 x2
3 x 2 x3
(2)
1 1 3 x2
3 x 1 x3
(3)
1 1 3 x2
3 x 2 x3
(4)
1 2 3 x2
The integral
2 log
2x
tan21 y 5 tan21 x 1 tan21
1 2 x2
3 x 1 x3
51.
50.
log x 2
x 2 1 log (36 2 12 x 1 x 2 )
1
3
1 2 3 x2
3 x 2 x3
1 1 3 x2
3 x 1 x3
1 1 3 x2
3 x 2 x3
1 2 3 x2
2 log
log x 2
dx
x 2 1 log (36 2 12 x 1 x 2 )
is equal to :
UU
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
The negation of ~ s (~ r s ) is equivalent
51.
, y
3 x 1 x3
dx
~ s (~ r s )
to :
(1)
s (r ~ s)
(1)
s (r ~ s)
(2)
s (r ~ s)
(2)
s (r ~ s)
(3)
sr
(3)
sr
(4)
s~r
(4)
s~r
B/Page 18
52.
If the angles of elevation of the top of a
52.
tower from three collinear points A, B and

C, on a line leading to the foot of the
tower, are 308, 458 and 608 respectively,
U A, B C, U U
S U ,
U U
308, 458 608 , AB : BC
then the ratio, AB : BC, is :

(1)
54.
3: 2
(2)
1: 3
(2)
1: 3
(3)
2:3
(3)
2:3
(4)
53.
(1)
3: 2
(4)
3:1
lim
x0
( 1 2 cos 2 x )( 3 1 cos x )
x tan 4 x
is equal to :
53.
lim
x0
3:1
( 1 2 cos 2 x )( 3 1 cos x ) UU
x tan 4 x
(1)
(1)
(2)
(2)
(3)
1
2
(3)
1
2
(4)
(4)
Let a , b and c be three non-zero vectors
54.
such that no two of them are collinear and
( a 3 b )3 c 5
1
b c a . If u is the
3
angle between vectors b and c , then a

value of sin u is :
a , b c U
U
( a 3 b )3 c 5
2 2
3
(1)
2 2
3
(2)
2
3
(2)
2
3
(3)
22 3
3
(3)
22 3
3
(4)
2 2
3
(4)
2 2
3
u , sin u
(1)
B/Page 19
1
b c a
3
55.
1 2 2
If A 5 2 1 22 is a matrix satisfying
a 2 b
55.
(a, b) is equal to :
(1)
(22, 1)
(1)
(22, 1)
(2)
(2, 1)
(2)
(2, 1)
(3)
(22, 21)
(3)
(22, 21)
(4)
(2, 21)
(4)
(2, 21)
identity matrix, then the ordered pair
57.
U AAT59I, cU U ,
I, 333 ,
(a, b)
the equation AA T 59I, where I is 333
56.
1 2 2
A 5 2 1 22
a 2 b
If the function.
56.
k x 1 1 , 0 [ x [ 3
g( x ) 5
m x 1 2 , 3 < x [ 5
k x 1 1 , 0 [ x [ 3
g( x ) 5
m x 1 2 , 3 < x [ 5
is differentiable, then the value of k1m is :
, k1m
(1)
16
5
(1)
16
5
(2)
10
3
(2)
10
3
(3)
(3)
(4)
(4)
system of linear equations :
, U
U
2x 122x21x 35lx 1
2x 122x21x 35lx 1
2x 123x 212x 35lx 2
2x 123x 212x 35lx 2
2x112x2
2x112x2
The set of all values of l for which the
57.
5lx3
has a non-trivial solution,

(1)
is a singleton.
(2)
contains two elements.
(3)
contains more than two elements.
(4)
is an empty set.
B/Page 20
5lx3
U ,
(1)
(2)
(3)
(4) U
U
58.
The
normal
x212xy23y250,
(1)
to
the
curve,
58.
at (1, 1) :
meets the curve again in the second
x 212xy23y 2 50

(1, 1)
(1)
U m Z
(2)
U Z
(3)
U Z
(4)
quadrant.
(2)
meets the curve again in the third

quadrant.
(3)
meets the curve again in the fourth

quadrant.
(4)
59.
does not meet the curve again.
The number of common tangents to the

circles
x 2 1y 2 24x26y21250
x21y216x118y12650,
60.
59.
x21y216x118y12650
and
is :
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
Let y(x) be the solution of the differential
60.
cU S
x21y224x26y21250
equation
dy
1 y 5 2 x log x , ( x / 1).
dx
Then y(e) is equal to :
(1)
(1)
(2)
(2)
(3)
2e
(3)
2e
(4)
(4)
( x log x )
B/Page 21
dy
1 y 5 2 x log x , ( x / 1)
dx
y(x) , y(e) UU
( x log x )
PART C PHYSICS
61.
hydrogen - like atom/ion :
U, U U /
S S
U
(1)
(1)
, S

(2)
, S
U U
(3)

, S
(4)
h S

As an electron makes a transition from an
61.
excited state to the ground state of a
kinetic energy, potential energy and

total energy decrease
(2)
kinetic energy decreases, potential

energy increases but total energy
remains same
(3)
kinetic energy and total energy

decrease but potential energy
increases
(4)
its kinetic energy increases but

potential energy and total energy
decrease
62.
The period of oscillation of a simple

pendulum is T 5 2p
62.
L
. Measured value
g
of L is 20.0 cm known to 1 mm accuracy

and time for 100 oscillations of the
pendulum is found to be 90 s using a wrist
U ,
L
20.0 cm
the determination of g is :
(1)
3%
(1)
3%
(2)
1%
(2)
1%
(3)
5%
(3)
5%
(4)
2%
(4)
2%
L
g
100
90 s , 1s ,
g U
1 mm
watch of 1s resolution. The accuracy in
B/Page 22
T 5 2p
63.
A long cylindrical shell carries positive
63.
surface charge s in the upper half and

negative surface charge 2s in the lower
half. The electric field lines around the
cylinder will look like figure given in :
(figures are schematic and not drawn to scale)
64.
U U
cU s cU
2s (UU) U
U l -U,
U ?
( U S U U S
U )
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
signal is/are :
()
2 MHz U U U
, U ()

(1)
2005 kHz, and 1995 kHz
(1)
2005 kHz,
(2)
2005 kHz, 2000 kHz and 1995 kHz
(2)
2005 kHz, 2000 kHz
(3)
2000 kHz and 1995 kHz
(3)
2000 kHz
(4)
2 MHz only
(4)
2 MHz
A signal of 5 kHz frequency is amplitude
64.
modulated on a carrier wave of frequency

2 MHz. The frequencies of the resultant
B/Page 23
5 kHz
1995 kHz
1995 kHz
1995 kHz
65.
Consider a spherical shell of radius R at
65.
temperature T. The black body radiation

inside it can be considered as an ideal gas
of photons with internal energy per unit
volume
u5
U
; T4
V
and
() R U
T U c U U

U ,
pressure
1 U
p 5 . If the shell now undergoes
3 V
p5
1 U

3 V
u5
U
; T4
V
Lc
U , T R
an adiabatic expansion the relation

between T and R is :
66.
(1)
T ; e23R
(2)
T;
(3)
T;
(4)
T ; e2R
1
R
1
R
An inductor (L50.03H) and a resistor
66.
(R50.15 kV) are connected in series to a

battery of 15V EMF in a circuit shown
below. The key K1 has been kept closed
for a long time. Then at t50, K1 is opened
and key K 2 is closed simultaneously.

At t51ms, the current in the circuit will
be : (e5@150)
(1)
T ; e23R
(2)
T;
(3)
T;
(4)
T ; e2R
1
R
1
R3
U , U (L50.03H)
U (R50.15 kV) 15V l
(..) UU
K1 U
t50 U, K1 U
, K2 t51ms
U, U l U (e5@150)
(1)
67 mA
(1)
67 mA
(2)
6.7 mA
(2)
6.7 mA
(3)
0.67 mA
(3)
0.67 mA
(4)
100 mA
(4)
100 mA
B/Page 24
67.
A pendulum made of a uniform wire of
67.
cross sectional area A has time period T.

When an additional mass M is added to
its bob, the time period changes to TM. If
the Youngs modulus of the material of the
1
is equal to :
Y
(g5gravitational acceleration)
wire is Y then
68.
(g5L
2
Mg
2
1
(1)
TM
(2)
T
1 2 M
T
(3)
T
1 2
TM
(4)
TM
U SU
A
T U M
U
U TM U
Mg
Mg
2
A
21
Mg
1
Y
U)
2
Mg
2
1
(1)
TM
(2)
T
1 2 M
T
(3)
T
1 2
TM
(4)
TM
Mg
Mg
2
A
21
Mg
the diode is :
U ..U. ( UU)
0.1 U U, U
UU 1 m U U, l

(1)
2.45 V/m
(1)
2.45 V/m
(2)
5.48 V/m
(2)
5.48 V/m
(3)
7.75 V/m
(3)
7.75 V/m
(4)
1.73 V/m
(4)
1.73 V/m
A red LED emits light at 0.1 watt uniformly
68.
around it. The amplitude of the electric

field of the light at a distance of 1 m from
B/Page 25
69.
Two coaxial solenoids of different radii
69.
carry current I in the same direction. Let
F1
be the magnetic force on the inner
F2
solenoid due to the outer one and
U , I U
U , U U
U, U U U
F1
be
U U U, U U
the magnetic force on the outer solenoid
F2
due to the inner one. Then :

(1)
F1 is radially inwards and F2 is
(1)
radially outwards
(2)
(3)
(4)
70.
F2
F1 is radially inwards and F2 50
(2)
F1 is radially outwards and F2 50
F1
(3)
F1 5 F25 0
(4)
Consider an ideal gas confined in an
70.
isolated closed chamber. As the gas

undergoes an adiabatic expansion, the
average time of collision between
q
molecules increases as V , where V is the

volume of the gas. The value of q is :
Cp
g 5
Cv
F1
F1
U U U () U
U U U
F2 50
U U U
F2 50
( ),
() (U)
Lc U U, UU
() Vq U ,
V q :
Cp
g 5
Cv
3g 2 5
6
(1)
3g 2 5
6
(2)
g 11
2
(2)
g11
2
(3)
g 21
2
(3)
g21
2
(4)
3g 1 5
6
(4)
3g 1 5
6
F1 5 F25 0
(1)
B/Page 26
U U U
71.
An LCR circuit is equivalent to a damped
71.
pendulum. In an LCR circuit the capacitor

is charged to Q0 and then connected to
the L and R as shown below :
LCR (..U) U
LCR U U
Q0 , U U U
U L R
If a student plots graphs of the square of
l L , , L1 L2
(L 1 >L 2 ) , t U U
with time(t) for two different values L1 and
schematic and not drawn to scale)
2
QMax

?
(U S U S U
)
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
2
maximum charge ( QMax
) on the capacitor
L2 (L1>L2) of L then which of the following
represents this graph correctly ? (plots are
B/Page 27
72.
From a solid sphere of mass M and radius

R
R, a spherical portion of radius
is
2
removed, as shown in the figure. Taking
72.
formed is :
(G5 gravitational constant)
(1)
2 GM
R
(1)
2 GM
R
(2)
2 2GM
3R
(2)
2 2GM
3R
(3)
2 2GM
R
(3)
2 2GM
R
(4)
2 GM
2R
(4)
2 GM
2R
speed 20 ms21. It is blowing its whistle at
73.
the frequency of 1000 Hz. The percentage

change in the frequency heard by a person
standing near the track as the train passes
him is (speed of sound5320 ms21) close
to :
U (U) UU U 20 ms21
U U U
1000 Hz
320 ms21 , UU U
U U U, mU
U U

(1)
12%
(1)
12%
(2)
18%
(2)
18%
(3)
24%
(3)
24%
(4)
6%
(4)
6%
B/Page 28
potential at the centre of the cavity thus
A train is moving on a straight track with
, U
2
U U r5:() U
L V (V50)
, U UU (U) U,
L
(G5 L SU )
gravitational potential V50 at r5:, the
73.
74.
74.
U (U) A U B
U 20 N 100 N ,
F mU U U U
, A B 0.1
B U U 0.15 , U mU
B U
Given in the figure are two blocks A and B

of weight 20 N and 100 N, respectively.
These are being pressed against a wall by
a force F as shown. If the coefficient of
friction between the blocks is 0.1 and
between block B and the wall is 0.15, the
frictional force applied by the wall on block
B is :
75.
(1)
80 N
(1)
80 N
(2)
120 N
(2)
120 N
(3)
150 N
(3)
150 N
(4)
100 N
(4)
100 N
Distance of the centre of mass of a solid
75.
uniform cone from its vertex is z0. If the

radius of its base is R and its height is h
then z0 is equal to :
U
U z0 U
R h z0
UU ?
(1)
3h
4
(1)
3h
4
(2)
5h
8
(2)
5h
8
(3)
3h 2
8R
(3)
3h 2
8R
(4)
h2
4R
(4)
h2
4R
B/Page 29
76.
figures below :
5 cm U
() l U, I 5 12 A, U
U U U
(S) U
(a)
(a)
(b)
(b)
(c)
(c)
(d)
(d)
If there is a uniform magnetic field of
equilibrium and (ii) unstable equilibrium ?
0.3 T
, z l ,
, () (i) S
(ii) S , ?
(1)
(a) and (c), respectively
(1)
(2)
(b) and (d), respectively
(2)
(b) (d)
(3)
(b) and (c), respectively
(3)
(b) (c)
(4)
(a) and (b), respectively
(4)
(a) (b)
A rectangular loop of sides 10 cm and
76.
5 cm carrying a current I of 12 A is placed

in different orientations as shown in the
0.3 T in the positive z direction, in which

orientations the loop would be in (i) stable
B/Page 30
10 cm
(a) (c)
77.
77.
resistor is :
(1)
0A
(1)
0 () A
(2)
0.13 A, from Q to P
(2)
0.13 A, Q
(3)
0.13 A, from P to Q
(3)
0.13 A, P
(4)
1.3 A, from P to Q
(4)
1.3 A, P
Q U
In the circuit shown, the current in the 1V
78.
1V U
R has potential V0 (measured with respect
U
cU V0 (: )
equipotential surfaces with potentials
A uniformly charged solid sphere of radius
78.
to :) on its surface. For this sphere the
V
3V0 5V0 3V0
and 0 have radius R1,
,
,
4
2
4
4
R2, R3 and R4 respectively. Then
3V0 5V0 3V0

,
,
2
4
4
V0
4
c U ,
R1, R2, R3 R4 ,
(1)
R1 0 and (R22R1) > (R42R3)
(1)
R1 0
(R22R1) > (R42R3)
(2)
R150 and R2 < (R42R3)
(2)
R150
R2 < (R42R3)
(3)
2R < R4
(3)
2R < R4
(4)
R150 and R2 > (R42R3)
(4)
R150
B/Page 31
R2 > (R42R3)
79.
and are not to scale)
U , C 1mF 3mF
U , 2mF U U Q2
U C M Q2
? (
S U U S U )
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
In the given circuit, charge Q2 on the 2mF

capacitor changes as C is varied from 1mF
79.
to 3mF. Q2 as a function of C is given

properly by : (figures are drawn schematically
80.
A particle of mass m moving in the
80.
x direction with speed 2v is hit by another

particle of mass 2m moving in the
y direction with speed v. If the collision is
perfectly inelastic, the percentage loss in
x-
2v m
, y- v 2m
, UU UU (UU)
S , UU U
()
the energy during the collision is close to :

(1)
50%
(1)
50%
(2)
56%
(2)
56%
(3)
62%
(3)
62%
(4)
44%
(4)
44%
B/Page 32
81.
Monochromatic light is incident on a glass
81.
prism of angle A. If the refractive index of

the material of the prism is m, a ray,
incident at an angle u, on the face AB
would get transmitted through the face AC
A U
,
m , AB
U, u U,
AC U
of the prism provided :
82.
(1)
1
u < sin21 m sin A 2 sin21
(1)
1
u < sin21 m sin A 2 sin21
(2)
1
u > cos21 m sin A 1 sin21
(2)
1
u > cos21 m sin A 1 sin21
(3)
1
u < cos21 m sin A 1 sin21
(3)
1
u < cos21 m sin A 1 sin21
(4)
1
u > sin21 m sin A 2 sin21
m
(4)
1
u > sin21 m sin A 2 sin21
m
From a solid sphere of mass M and radius
82.
R a cube of maximum possible volume is

cut. Moment of inertia of cube about an
axis passing through its center and
perpendicular to one of its faces is :
U M
R
() U
, , -,
U $U
U ?
(1)
MR 2
16 2p
(1)
MR 2
16 2p
(2)
4MR 2
9 3p
(2)
4MR 2
9 3p
(3)
4MR 2
3 3p
(3)
4MR 2
3 3p
(4)
MR 2
32 2p
(4)
MR 2
32 2p
B/Page 33
83.
Match List - I (Fundamental Experiment)
83.
with List - II (its conclusion) and select

the correct option from the choices given
- I ( ) - II ( U)
() U

below the list :

List - I
84.
- I
List - II
(A)
Franck-Hertz
Experiment.
(i)
Particle nature
of light
(A)
(B)
Photo-electric
experiment.
(ii)
Discrete energy
levels of atom
(B)
(ii)
(C)
Davison - Germer
Wave nature of
(iii)
Experiment.
electron
(C)
U U
(iii)
(iv)
Structure of
atom
(i)
(iv)
- II

SU
U U
U U
(1)
(A) - (ii)
(B) - (iv)
(C) - (iii)
(1)
(A) - (ii)
(B) - (iv)
(C) - (iii)
(2)
(A) - (ii)
(B) - (i)
(C) - (iii)
(2)
(A) - (ii)
(B) - (i)
(C) - (iii)
(3)
(A) -(iv)
(B) - (iii)
(C) - (ii)
(3)
(A) -(iv)
(B) - (iii)
(C)- (ii)
(4)
(A) - (i)
(B) - (iv)
(C) - (iii)
(4)
(A) - (i)
(B) - (iv)
(C) - (iii)
When 5V potential difference is applied
84.
across a wire of length 0.1 m, the drift

speed of electrons is 2.531024 ms21. If
the electron density in the wire is
831028 m23, the resistivity of the material
0.1 m
U U 5V UU
U U U
2.531024 ms21 U U
831028 m23 ,
U ,
is close to :
(1)
1.631027 Vm
(1)
1.631027 Vm
(2)
1.631026 Vm
(2)
1.631026 Vm
(3)
1.631025 Vm
(3)
1.631025 Vm
(4)
1.631028 Vm
(4)
1.631028 Vm
B/Page 34
85.
(graphs are schematic and not drawn to scale)
U , S d
U S d
S
() ?
( S U U S
U )
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
For a simple pendulum, a graph is plotted
85.
between its kinetic energy (KE) and

potential
energy
(PE)
against
its
displacement d. Which one of the

following represents these correctly ?
B/Page 35
86.
Two stones are thrown up simultaneously
86.
from the edge of a cliff 240 m high with

initial speed of 10 m/s and 40 m/s
respectively. Which of the following graph
best represents the time variation of
relative position of the second stone with
240 m U U ,
U U U ,
U 10 m/s 40 m/s , ,
() U
U U S U
(U) ?
respect to the first ?

(Assume stones do not rebound after
hitting the ground and neglect air
resistance, take g510 m/s2)
( , U UU
U U U U
, g510 m/s2)
scale)
( S U U S
U )
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
(The figures are schematic and not drawn to
B/Page 36
87.
contact with reservoirs in two ways :
U U (S) SU c U
1 J/8C c (c UU)
UU U ,
(i)
(i)
M 2 c
U UU c
c ,
(ii)
M 8 c
U UU c
c ,
A solid body of constant heat capacity
87.
1 J/8C is being heated by keeping it in
Sequentially keeping in contact with

2 reservoirs such that each reservoir
supplies same amount of heat.
(ii)
Sequentially keeping in contact with

8 reservoirs such that each reservoir
supplies same amount of heat.
S U U 1008C
2008C , S U
U U ,
In both the cases body is brought from

initial temperature 1008C to final
temperature 2008C. Entropy change of the
body in the two cases respectively is :
88.
(1)
ln2, ln2
(1)
ln2, ln2
(2)
ln2, 2ln2
(2)
ln2, 2ln2
(3)
2ln2, 8ln2
(3)
2ln2, 8ln2
(4)
ln2, 4ln2
(4)
ln2, 4ln2
resolve at 500 nm wavelength is :
0.25 cm, U
ScU U 25 cm ,
500 nm U , S
U
U ?
(1)
30 mm
(1)
30 mm
(2)
100 mm
(2)
100 mm
(3)
300 mm
(3)
300 mm
(4)
1 mm
(4)
1 mm
Assuming human pupil to have a radius
88.
of 0.25 cm and a comfortable viewing

distance of 25 cm, the minimum separation
between two objects that human eye can
B/Page 37
89.
89.
U I U U
L lU U
mU U
u S , U S
U U
l g L U , I

Two long current carrying thin wires, both

with current I, are held by insulating
threads of length L and are in equilibrium
as shown in the figure, with threads
making an angle u with the vertical. If
wires have mass l per unit length then the
value of I is :
(g5gravitational acceleration)
(1)
2sinu
(2)
(3)
(4)
90.
plgL
m0 cosu
(1)
2sinu
pgL
tan u
m0
(2)
plgL
tan u
m0
(3)
sinu
plgL
m0 cosu
On a hot summer night, the refractive
(4)
90.
index of air is smallest near the ground and

increases with height from the ground.
When a light beam is directed horizontally,
the Huygens principle leads us to conclude
that as it travels, the light beam :
(1)
goes horizontally without any

deflection
(2)
bends downwards
(3)
bends upwards
(4)
becomes narrower
-o0o-
B/Page 38
plgL
m0 cosu
pgL
tan u
m0
plgL
tan u
m0
sinu
plgL
m0 cosu
c U , - U,
U -
, -U-
U , h
U ,
-U
(1) ,
U
(2) U
(3) U U
(4) ()
-o0o-
B/Page 39
Read the following instructions carefully :

U U S U U (D -1) U U
U / U U
U D-2 U U / U
/ U U
3. U S/U U U S U
R
4. U

5. U U
- () U
U U ,
U
6. U S U U
US ( U S U
S UU), U U S
U
7. U U U U
, U S
U U mU
, U D U U U
S D U (D 39)
8. U, U / U U
U U
U S
9. U U U
10. U U
S U
11. U U U S
U U SU U U U
U U U S U SU
U U
U
U S S U

12. U/S U , U
U U
13. U U U .../U
U mU
.../U
U
14. S U S U

15. U mU U / U
U U , S,
, U, U
U U U
U
1. The candidates should fill in the required particulars 1.

on the Test Booklet and Answer Sheet (Side1) with
Blue/Black Ball Point Pen.
2. For writing/marking particulars on Side2 of the 2.
Answer Sheet, use Blue/Black Ball Point Pen only.
3. The candidates should not write their Roll Numbers

anywhere else (except in the specified space) on the
Test Booklet/Answer Sheet.
4. Out of the four options given for each question, only
one option is the correct answer.
5. For each incorrect response, onefourth () of the total
marks allotted to the question would be deducted from
the total score. No deduction from the total score,
however, will be made if no response is indicated for
an item in the Answer Sheet.
6. Handle the Test Booklet and Answer Sheet with care,
as under no circumstances (except for discrepancy in

Test Booklet Code and Answer Sheet Code), another set
will be provided.
7. The candidates are not allowed to do any rough work

or writing work on the Answer Sheet. All calculations/
writing work are to be done in the space provided for
this purpose in the Test Booklet itself, marked Space
for Rough Work. This space is given at the bottom of
each page and in one page (i.e. Page 39) at the end of
the booklet.
8. On completion of the test, the candidates must hand
over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to
take away this Test Booklet with them.
9. Each candidate must show on demand his/her Admit
Card to the Invigilator.
10. No candidate, without special permission of the
Superintendent or Invigilator, should leave his/her
seat.
11. The candidates should not leave the Examination Hall
without handing over their Answer Sheet to the
Invigilator on duty and sign the Attendance Sheet
again. Cases where a candidate has not signed the
Attendance Sheet second time will be deemed not to
have handed over the Answer Sheet and dealt with as
an unfair means case. The candidates are also required
to put their left hand THUMB impression in the space
provided in the Attendance Sheet.
12. Use of Electronic/Manual Calculator and any
Electronic device like mobile phone, pager etc. is
prohibited.
13. The candidates are governed by all Rules and
Regulations of the JAB/Board with regard to their
conduct in the Examination Hall. All cases of unfair
means will be dealt with as per Rules and Regulations
of the JAB/Board.
14. No part of the Test Booklet and Answer Sheet shall be
detached under any circumstances.
15. Candidates are not allowed to carry any textual
material, printed or written, bits of papers, pager,
mobile phone, electronic device or any other material
except the Admit Card inside the examination
room/hall.
B/Page 40

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This booklet contains 40 printed pages.

: CHEMISTRY, MATHEMATICS & PHYSICS

1. Immediately fill in the particulars on this page of the Test

Examination Centre Number :

Name of Examination Centre (in Capital letters) :

Test Booklet Code

Name of the Candidate (in Capital letters ) :

possible excited state of hydrogen ?

Which of the following is the energy of a

In the following sequence of reactions :

5 - keto - 2 - methyl hexanal upon

SPACE FOR ROUGH WORK /

The ionic radii (in ) of N32, O22 and F2

1.36, 1.71 and 1.40

1.71, 1.40 and 1.36

1.71, 1.36 and 1.40

1.36, 1.40 and 1.71

The color of KMnO4 is due to :

L M charge transfer transition

M L charge transfer transition

Assertion : Nitrogen and Oxygen are the

main components in the

react to form oxides of nitrogen.

The reaction between nitrogen

and oxygen requires high

Both assertion and reason are

correct, but the reason is not the

The assertion is incorrect, but the

Both the assertion and reason are

Both assertion and reason are

SPACE FOR ROUGH WORK /

Which of the following compounds is not

In the context of the Hall - Heroult process

for the extraction of Al, which of the

following statements is false ?

Al 2 O 3 is mixed with CaF 2 which

mixture and brings conductivity

Al31 is reduced at the cathode to

Na3AlF6 serves as the electrolyte

CO and CO2 are produced in this

Match the catalysts to the correct

(A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)

(A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)

(A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)

(A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)

(A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)

(A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)

(A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)

(A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)

SPACE FOR ROUGH WORK /

of paints and lacquers ?

Poly vinyl chloride

Which polymer is used in the manufacture

SPACE FOR ROUGH WORK /

exist for square planar [Pt (Cl) (py) (NH3)

(NH2OH)]1 is (py 5 pyridine) :

[Pt (Cl) (py) (NH3) (NH2OH)]1

The number of geometric isomers that can

Higher order (>3) reactions are rare due

increase in entropy and activation

energy as more molecules are

shifting of equilibrium towards

loss of active species on collision