Fastness information:

The fastness properties stated on the shade card were determined with 1/1 SD
dyeing on bleached cotton.
Exceptions are the black dyes which were tested at 2 %.
Fastness to light
Fastness to washing 40 C
Fastness to water
Fastness to perspiration

DIN EN ISO 105-B02

DIN EN ISO 105-C06/A1S
DIN EN ISO 105-E01
DIN EN ISO 105-E04

Ecological data information:

1)

Method of determination: DIN EN 1485.

2)

 he heavy metal is complexly bonded and therefore an integral part of the dye
T
molecule.

The TUBANTIN range does not contain any dyes which can be split into amines of
the MAC classes III A1 and A2.

02/09_en

The data contained in this shade card is given to the best of our knowledge and
belief.
It does not guarantee specific product properties.
All information is subject to change without notice.

Tubantin
B

Basics

Direct dyes for cellulosics.

www.yekrang.ir
info@yekrang.ir
Tel:+98(21)33958270-2
Fax:+98(21)33923561

BEZEMA AG | Kriessernstrasse 20 | CH-9462 Montlingen

Tel +41 71 763 88 11 | Fax +41 71 763 88 88 | www.bezema.com | bezema@bezema.com
CHT R. BEITLICH GMBH | Bismarckstrasse 102 | D-72072 Tbingen
Tel +49 7071 154-0 | Fax +49 7071 154-290 | www.cht.com | info@cht.com

Unique ideas. Unique solutions.

Tubantin
Dyes

30 45 minutes

120

Temperature [C]

140

Basics

Inexpensive standard range adequate for

normal requirements.

100

80
60

A B

40
20
0
0

20

40

60

80

100

120

140

160

180

200

220

240

Time [min]

Dye group

S.D.C

Solubility in g/l

90 C
60 C
25 C

24
8
4

50
40
35

80
60
50

32
32
32

20
20
15

100
80
50

40

80

60

60

80

95

1/1
1/25

4-5
3

5-6
4

5-6
4

6-7
4

6
5-6

4-5
3

CC
CO
WO

3-4
3-4
4-5

4
2
4-5

2
2-3
5

3-4
3
4-5

3-4
3
5

3-4
3
4-5

CC
CO
WO

4
3-4
4-5

4-5
3
4-5

3-4
3-4
5

4
3-4
5

4
3-4
5

4-5
3-4
5

CC
CO
WO

2-3
2-3
3

3
1
2

2-3
1
2

3-4
2-3
4

4
2
4

4
3
3-4

aftertreated

CC
CO
WO

4
4
4-5

4-5
4-5
5

4-5
4-5
4-5

4
4-5
5

4-5
4-5
5

4-5
4-5
5

alkaline

CC
CO
WO

4
4
4

4-5
4-5
4-5

4-5
4-5
4-5

5
4-5
5

4-5
4-5
5

4-5
5
5

acid

CC
CO
WO

4
4
4

4-5
4-5
4-5

4-5
4-5
4-5

4
4-5
5

4
5
5

4-5
5
5

AOX *)

free

free

free

free

free

free

Heavy metal content

Me
%

free
-

free
-

free
-

free
-

free
-

free
-

Best exhaustion ability

Light

Washing 40 C
aftertreated

Water

Perspiration
aftertreated

Yellow R conc.
0.5 % 2 %

Yellow GR
0.5 % 2 %

Scarlet BNL 200

0.5 % 2 %

Orange GGLN 200

0.5 % 2 %

Orange 7GL conc.

0.5 % 2 %

Yellow 4GL conc.

0.5 % 2 %

2.0
1.0 2.0

g/l CHT-DISPERSING AGENT ORM

g/l BIAVIN BPA

2.0

g/l Ammonium sulphate

1.0

g/l Acetic acid (pH 5.5-6.0)

5.0 25.0

g/l Glauber salt

x
Y

% BEMACRON
% TUBANTIN

3.0 5.0
2.0
0.3

g/l Soda (for black dyes)

% REWIN ACP
ml/l Acetic acid

Note:
The cooling phase of 130 90 C should be as regular as possible, as the affinity
of the Tubantin dyes decreases at above 100 C but increases again after cooling
to 90 C.
Cooling at a gradient of 1.5 C/min from 130 C to 90 C and then at 2 C/min
from 90 C to 60 C is recommended.

For further information and technical advice please contact our technical
department.
Our technical advice imparted verbally, in writing or test reports is given to our
best knowledge. It is, however, non-binding. This also applies in connection with
any rights of third parties and does not free you from examining the suitability of
the supplied product for your intended processes and purposes. The application,
use and processing of the products is outside our control and is therefore solely
your responsibility.

Pink 2B
0.5 % 2 %

Bordeaux 2BL conc.

0.5 % 2 %

Red 6BLL conc.

0.5 % 2 %

Red 8BL conc.

0.5 % 2 %

Red F3B conc.

0.5 % 2 %

Scarlet 4B conc.
0.5 % 2 %
B

15
15
15

40
35
30

30
25
15

20
10
10

16
16
16

100
100
100

60-95

95

60

90

60

80

3
1-2

5
2-3

5
3-4

5-6
4

6-7
5

5
4

4
1
4-5

3
3
4-5

1-2
2
4

2-3
3
5

3
3
4-5

3
3
5

4-5
2
4-5

4
3-4
4-5

2-3
2
4-5

4
4
5

4-5
3-4
5

4
3-4
5

4
1
3

4
2
4

2-3
1-2
3

2
4-5
3-4

3-4
2
4-5

3
2
4

4-5
4
4-5

4
4
5

4
3
3-4

4-5
4-5
5

4
4-5
4-5

4
4
5

4
4
4-5

4
4-5
5

3-4
3
3-4

4
4
3

3-4
4-5
5

3
3
5

4
4
4-5

4
4-5
5

3-4
3
3-4

4
4
3

3-4
4-5
5

5
4
5

free

free

free

free

free

free

free
-

free
-

free
-

free
-

Cu
4.4

free
-

2)

Dark Blue R
0.5 % 2 %

Blue BRR h.c.

0.5 % 2 %

Blue 2RL 200

0.5 % 2 %

Blue GLL 300

0.5 % 2 %

Blue FF2GL 200

0.5 % 2 %

Violet BL 200
0.5 % 2 %
B

15
10
8

40
35
30

15
12
10

15
15
10

20
15
10

25
20
15

80

60-80

90

80

90

95

6
4

6-7
4

5
3

5-6
3-4

5
3-4

3-4
-

3
2-3
3-4

2-3
3
5

3-4
2-3
4-5

2-3
2
4-5

2-3
2-3
4-5

3
1-2
4

4
4
4-5

4
4
5

4
3-4
5

4
3
5

4
3-4
4-5

4
2
4-5

3
2-3
3

3-4
2
4-5

4
2-3
3-4

2-3
1-2
3

3-4
2
3

4
2-3
3-4

4-5
4-5
4-5

4
4-5
5

4
4-5
5

4-5
4-5
5

4
4-5
5

4-5
4
4-5

4-5
4-5
4-5

4
4-5
5

4-5
4-5
5

4-5
5
5

4
4-5
5

4-5
4
4-5

4-5
4-5
4-5

4
4-5
5

4-5
4-5
5

4-5
5
5

3-4
5
5

4-5
4
4-5

free

3.2

free

free

free

free

Cu
4.1

free
-

free
-

Cu
4.4

free
-

free
-

2)

2)

Brown 8RL
0.5 % 2 %

Brown GGL
0.5 % 2 %

Green BL h.c.
0.5 % 2 %

Green 5GL conc.

0.5 % 2 %

Turquoise FBL conc.

0.5 % 2 %

Turquoise GL 200
0.5 % 2 %
A

50
40
40

32
26
20

20
10
10

30
10
10

36
36
36

10
5
5

95

95

95

95

95

90

6-7
4

6-7
4

6
4

5
3

5-6
3-4

6
4-5

1
3
3-4

2
3-4
3-4

3-4
3
5

4
3-4
4-5

4
2-3
4-5

4
3
4-5

4
4
4-5

4
4-5
4-5

4-5
4
5

4-5
4
5

4-5
4
4-5

4
3-4
4-5

1-2
1
2

2
1
2

4
3-4
3-4

4-5
3
4

4-5
2
4-5

4
1
4

4
4
4-5

4-5
4-5
4-5

4-5
4-5
5

4-5
5
5

4-5
5
4-5

4-5
4
4-5

4
3-4
3-4

4-5
4
4

4
5
5

4-5
5
5

4-5
4-5
4-5

2
3
4-5

3-4
3-4
3-4

4
4
4

4
4-5
5

4-5
5
5

4
4
4-5

2
4
4-5

free

0.1

0.2

free

free

free

Cu
3.5

Cu
4.4

free
-

free
-

Cu
1.3

Cu2)
5.2

2)

2)

2)

Black VSF 600

2%

Black AB 400
2%

Black G conc.
2%

Grey CGLL conc.

0.5 % 2 %

Grey 4GL
0.5 % 2 %

Brown BL
0.5 % 2 %
B

40
30
20

25
20
15

40
30
20

40
30
15

25
16
12

32
25
15

95

95

95

80

95

95

6
4

6
4

7
4

5
-

4-5
-

4-5
-

3-4
2-3
4-5

3-4
3-4
4

2-3
3-4
4-5

3-4
3
4

3-4
2-3
4-5

3
3
5

4
4
4-5

4-5
4-5
4-5

4-5
4
5

4-5
4
4-5

4-5
4-5
4-5

4-5
3-4
5

4
3-4
4-5

4-5
3
4

3-4
2
3-4

4
3-4
3-4

4-5
3
4-5

4-5
3
4-5

4-5
4-5
5

4-5
5
5

4-5
5
5

4-5
4
4

4-5
4-5
5

4-5
4-5
5

4-5
4-5
4-5

4-5
4-5
4-5

4
4-5
5

4-5
4
3-4

4-5
4-5
4-5

4-5
4-5
5

4-5
4-5
4-5

4-5
4-5
4-5

4
5
5

4-5
4
3-4

4-5
4-5
4-5

4-5
4-5
5

1.2

free

free

free

free

free

Cu
2.0

Cu
3.3

Cu
3.8

free
-

free
-

free
-

2)

2)

2)

15
10
10

35
20
20

25
20
12

25
15
10

95

95

95

95

4-5
-

4-5
-

4-5
-

4-5
-

3
3
5

3
2
4-5

3-4
3
4

3
2-3
4-5

4-5
3-4
5

4
3
4-5

4-5
3-4
4-5

4-5
3-4
4-5

4-5
3
4-5

3
1
3

4-5
3
4-5

4-5
3
4-5

4-5
4-5
5

4-5
4
4-5

4-5
4-5
5

4-5
4-5
4-5

4-5
4-5
5

4-5
4
4-5

4-5
4-5
5

4-5
4-5
4-5

4-5
4-5
5

4-5
4
4-5

4-5
4-5
5

4-5
4-5
4-5

free

free

free

free

free
-

free
-

free
-

free
-

Black FR 900
2%

Black RD
2%
B

Black RA
2%

Black VSF 1200

2%
B

1. General Information
The TUBANTIN shade card shows our direct dyes for dyeing celllulosic fibres and
blends with synthetic fibres.
2. S.D.C. Classification
Class A Dyes with good levelling and migration properties. Dyes of class A
require additional electrolytes for full exhaustion. Initial unlevelness
is equalised during the dyeing process.
Class B Dyes with low migration properties; equalisation can, however,
be controlled by the addition of electrolytes.
Class C Dyes with very low levelling properties. Level dyeing can only
be achieved by controlling the temperatures and the addition of
electrolytes.
3. Dissolving the dyes
Work the dye into a paste with a small quantity of cold soft water then add the
required quantity of hot soft water and boil. The quantity of water to be used
depends on the solubility of the individual dyes. This information is given in the
shade card.
4. Dyeing instructions
4.1 Recommendations, standard process
The exhaustion of TUBANTIN dyes can be controlled with levelling agents, temperature control and salt addition. With cellulose regenerated fibres it is better to start at
temperatures of above 80 C to prevent excessive swelling of the fibres. On equipment for dyeing packages in the creel in particular, an initial temperature close to
the boiling temperature should be selected. The wet fastness of materials dyed with
TUBANTIN dyes can be significantly improved by a cationic aftertreatment with
REWIN products such as REWIN ACP or REWIN FSN.
For TUBANTIN turquoise dyes, we recommend adding 0.5 1.0 g/l sodium
carbonate and using Glauber salt instead of common salt. As a general rule,
the TUBANTIN black dyes should be used with a soda addition of 2 g/l
(exception: TUBANTIN Black RD).

120

Temperature [C]

30 60 minutes

100

80
60
40

A B

20
0
0

20

40

60

80

100

120

140

160

180

200

Time [min]

0.3 1.0

g/l SARABID SBF-N or SARABID PF

1.0 2.0

g/l BIAVIN BPA

0 2.0
B

5.0 20.0

0.3
3.0

g/l

Soda

% TUBANTIN dye

< 0.5

0.5 2.0

> 2.0

g/l Glauber salt or common salt

05

5 10

15 25

ml/l Acetic acid

% REWIN ACP/FSN

Technical information:
TUBANTIN

Suitability for Suitability for

pad-steam
pad-batch

Dischargeability
neutr.
alk.
4

Yellow 4GL conc.

4-5

3-4

Orange 7GL conc.

Orange GGLN 200

Scarlet BNL 200

Yellow GR
Yellow R conc.

3-4

Red F3B conc.

3-4

3-4

Red 8BL conc.

2-3

2-3

Red 6BLL conc.

Bordeaux 2BL conc.

Pink 2B

Violet BL 200

Blue FF2GL 200

4-5

4-5

Scarlet 4B conc.

Blue GLL 300

Blue 2RL 200

Blue BRR h.c.

4-5

4-5

Dark Blue R

Turquoise GL 200

3-4

Green 5GL conc.

Green BL h.c.

Brown GGL

3-4

Brown 8RL

Brown BL

2-3

Grey 4GL

Grey CGLL conc.

Black G conc.

Turquoise FBL conc.

Black AB 400

3-4

Black VSF 600

4-5

4-5

Black VSF 1200

4-5

4-5

Black RD

4-5

Black RA

4-5

4-5

Black FR 900
very suitable
Dischargability

suitable in some cases (for pale shades)

5
4
3
2
1

Bleaching/dyeing,
one-bath

Pure whites
Slightly dulled white
Suitable for colour discharge printing
Not suitable for discharge printing
Not dischargeable

not suitable

4.2 Recommendations for the one-bath HT dyeing process with TUBANTIN

and BEMACRON dyes
Selected TUBANTIN dyes permit HT dyeing in one bath with BEMACRON dyes.
The following dyes are suitable for one-bath, HT dyeing:
TUBANTIN Yellow GR
TUBANTIN Orange 7GL conc.
TUBANTIN Orange GGLN 200 %
TUBANTIN Scarlet BNL 200 %
TUBANTIN Scarlet 4B conc.
TUBANTIN Red F3B
TUBANTIN Bordeaux 2 BL conc.
TUBANTIN Violet BL
TUBANTIN Blue FF2GL 200 %
TUBANTIN Blue GLL 300 %
TUBANTIN Blue 2RL 200 %
TUBANTIN Blue BRR h.c.
TUBANTIN Dark Blue R
TUBANTIN Turquoise GL 200 %
TUBANTIN Turquoise FBL 200 %
TUBANTIN Green 5GL
TUBANTIN Green BL h.c.
TUBANTIN Brown GGL
TUBANTIN Brown 8RL
TUBANTIN Brown BL
TUBANTIN Grey 4GL
TUBANTIN Grey CGLL conc.
TUBANTIN Black RD
TUBANTIN Black G conc.*
TUBANTIN Black VSF 600*
TUBANTIN Black VSF 1200*
TUBANTIN Black RA*
TUBANTIN Black FR 900*
TUBANTIN black dyes
The black dyes marked with an * are stable to a temperature up to 130 C during
HT dyeing but must be overdyed at 90 C with 3.0 5.0 g/l soda for 20 minutes
after cooling to obtain the best possible colour yield.
TUBANTIN dyes which are suitable in some cases:
Due to their loss of colour of up to 40 % under HT conditions, the following dyes
are only suitable to a certain extent:
TUBANTIN Pink 2B
TUBANTIN Red 6BLL conc.