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JEE (Main)-2014
ANSWERS, HINTS & SOLUTIONS

FULL TEST II
(Main)
ALL INDIA TEST SERIES
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FIITJEE
Q. No.
PHYSICS
A
CHEMISTRY
A
MATHEMATICS
B
2.
3.
4.
5.
6.
7.
8.
9.
A.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
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30.
1.
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website: www.fiitjee.com
AITS-FT-II-PCM(S)-JEE(Main)/14
Physics
1.
PART I
Avg. speed 3
(v r t)2 (v mr t)2
t
2
r
v 59
vr 2m / s
1 t
1
v v
3v
2
2 2
t
4
2.
v avg
3.
m
m
gT a
2
2
T cos 60 =
(i)
ma
cos 60
(ii)
Solving (i) and (ii) acceleration of ring =
2g
9
4.
Work done by all the forces on the block equal to change in kinetic energy.
6.
No effect of a and g on time period of spring pendulum.
7.
8.
1 1 8R
= R 2 2
3 1
1 3 9
1
1 1 3R
= R 2 2
2 1
4
1 2
3 1 27
2 1 32
1
x
dx
Work done by friction F ds mgcos
cos
0
= mg x = 20 J
mg
cos
dx ds
ds
dx
9.
There will be no change.
h = h
h
A
10.
Conservation of energy
3
mv 2 mg mg m 3 2
g
2
2
2
2
v 8g
60
dy
11.
Potential across capacitor is zero, hence energy stored is zero.
12.
vA vB = E. dx = 10 (1)
= 10 volt.
13.
Z=
14.
R 2 X 2 = 9 X2
R 3
but cos =
Z 5
X = 4 .
vA vB =
(b) (a)
0
0
Q
(b a)
0
W = Q(vA vB) =
15.
= 0 + 1 10 = 10 rad/sec2
v = r = 1 10 = 10 m/s
q(v r )
qv
B 0
| B |= 0 2
r 3
4r
7
10 0.1 10
B=
= 10-7 T
2
(1)
16.
P = AT4
4
PA A B TB
16 =
PB A A TA
Since mT = constant, A
B
B =
17.
A
14
5000
14
2 TB
1/4
TB = TA(8)
1 TA
TB
14
8
TA
For adiabatic process, TV1 = constant

1
m
T = constant
T
= constant
1
1
3 = 4/3
1
2
2
f=
6
1 4
3 1
P(x, y), A(3a, 0), B = (3a, 0)

1 2Q
1 Q
VPA =
, VPB =
40 PA
40 PB
According to equation
T1 1
18.
1 2Q
1 Q
=0
40 PA 4 0 PB
2
1
2
2
4PB = PA
PA PB
(x 5a)2 + y2 = (4a)2
19.
i = 5A
qm2
q2 1 2
Li qmax = 6 C
2C 2C 2
21.
f = ma2
a1
2f
=
I mR
f
a2
a2 = F/4m, f = F/4
22.
The process is equivalent to TV1/2 = C

Compare with TVx1 = C x = 3/2
R
R
R
R
3
1
C=
= R 2R R
1 1 X
2 3 1 3 2
2
2
23.
Intensity will be highest at the nearest point.
28.
tan =
u2
u2
100
10
R
Rg
g tan 10 3
3
Chemistry
14.
15.
PART II
hc
2.9 10 19 J
Total energy of 10 quanta = 10 2.9 10-19J

112 4.18 103
Energy stored for process
7.8 1019 J
23
6 10
7.8 1019
% efficiency
100
29 1019
= 26.9%
E
ra 2
Mb

rb 1
Ma
T
M
Vrms
Vrms a
Vrms b
16.
(As Vrms 3RT )

M
Ta Mb 2
2 2 2

Tb Ma 1 1
1
k1 E1 1 1

k1 R T1 T2
... (i)
k 2 E2 1 1

k2
R T1 T2
Eqn. (ii) Eqn.(i)
E E1 1 1
k k
n 2 1 2
k 2 k1
R
T1 T2
(For equimolar formation of B and C, k 2 k1 )
n
... (ii)
k 8314 T2 300
n 1
k 2 8.314 300 T2
17.
8314 T2 300
n2
8.314 300 T2
T2 = 329.77 K.
2SO3 g
2SO2 g O2 g
at equilibrium 1 2x
x
2x
Only SO2 will oxidized.
Equivalent of SO2 = Equivalent of KMnO4
2x 2 = 0.2 5
2x = 0.5
2
0.5 0.25
2 2

0.125
Kc
2
0.5
2
18.
Tb i kb m
2.08 = 0.52 1 i
i=4
It means salt on dissociation gives 4 ions. Thus the salt that gives 4 ions is K3[Fe(CN)6].
19.
Cu2 e
Cu ;
Eo X1V
G1o FX1
... (i)
In3 2e
In1
Eo X2 V
Go2 2FX2
...(ii)
o
3
In e
In
E X3 V
G FX3
From Eqn. (i) + (iii) (ii)
In2 Cu2 In3 Cu
Go FEo
... (iii)
Go F X1 X3 2X2 FEo
20.
23.
Eo X1 X3 2X2
Due to Fajans rule.
Green ppt. is Cr(OH)3
25.
O
H3C
HVZ
Br2 /P
OH BrCH2
O
KCN
H3 O
||
C OH OH C CH2 COOH
Y
X Malonic acid
26.
28.
1o aromatic amine on diazotisation followed by coupling with -napthol gives azo dye test.
(A) Viscosity intermolecular attraction
intermolecualr H-bonding tendency
(B) No intramoecular H-bonding in the cis-isomer due to loss in planarity as a result of steric and
electronic repulsion.
stability symmetry.
29.
30.
(C) Even though o-nitrophenol shows intramolecular H-bonding but has greater R and I effect
than Cl.
(D) H3BO3 + 3 C2H5OH B(OC2H5)3 + 3H2O.
No cage lattice structure of H3BO3.
Because phenol is less acidic than H2CO3.
S is less electronegative and therefore more reactive towards SN2.
Mathematics
PART III
1.
Given equation can be written as |x 1|2 + |x 1| 6 = 0

t2 + t 6 = 0
t = 2 or 3 |x 1| = 2
x 1 = 2 or x = 3, 1
2.
|z1 z2|2 + |z2 z3|2 + |z3 z4|2 + |z4 z1|2

= 2(|z1|2 + |z2|2 + |z3|2 + |z4|2) + |z1 + z3|2 + |z2 + z4|2 8 + |z1 + z3|2 + |z2 + z4|2
3.
Tr
r 2r 2 r 2 2r 2
4r 2
1
1
1
1
1
1
= 2
4 r 2r 2 r 2 2r 2
4 r 12 1 r 12 1
1 1
1
1
Sn 1 2
4 2 n 1 n 12 1
4
r 4
r 2 2
1 1 1
1 1 38 37 26 1
1 1380
345
1
4 2 26 37 4
26 37
4 26 37 26 37
7
338
37S5
13
26
26
S5
4.
Number of terms = Number of nonnegative integral solution of the equation p + q + r + s = 50

= 50 + 4 1C50 = 53C50 = 53C3
5.
If a function is symmetric about two mutually perpendicular lines, it must be symmetric about their
point of intersection.
6.
x5
1 x
y5
dy
dy
a x2 y 2
dx
dx
1 y
y5
ay 2
1 y6
dy
x5
ax 2
dx
1 x6
1 y6 x 2 a 1 x6 x3
dy
dx
1 x6 y2 a 1 y 6 y 3
Also,
1 x 6 1 y 6
6
1 x 1 y
..... (1)
a x 3 y 3 or x3 y 3 a
1 y6 1 x6
a 1 y 6 y3 a 1 x 6 x 3
Hence, from equation (1),
1 y6 x2
dy
2
dx
1 x6 y
7.
For a triangle formed by joining any three conormal points, orthocentre consides with the fourth
point.
8.
HM of SP and SQ =
2 3 6
4 = semi latus rectum.
36
9.
If a circle cuts two circles orthogonally, radical axis of the two circles pass through the centre of
the first circle
Here radical axis of given circles is 6x 4y + 4 = 0 or 3x 2y + 2 = 0
3
1
Hence 3 2 + 2 = 0
4
2
2
10.
sin =
r1 r2
r1 r2
r1
r r
= 2 sin 1 2
r1 r2
1
11.
r2
O1
O2
Let r a i b j a2 + b2 = 1
Also,
(1)

r ( i j)
cos 45 = a + b = 1
| r || i j |

5
r (3 i 4 j )
3a 4b =
cos 60 =
2
| r || 3 i 4 j |
(2)
(3)
There exists no real values of a and b satisfying (1), (2) and (3)
Hence no such unit vector exists
12.
(1 + x)n = 3
8 80 240
n(n 1)x 2
3 4 .... = 1 + nx +
+....
3 3
2
3
On comparison, n = 3 and x =
13.
From
the
given
conditions,
2
3
yx
ba
1,
zy
c b
1,
zx
ca
x + a y + b z + c The determinant is a symmetric one. The determinant will be equal to zero if

x+a+y+b+z+c=0
but a + b + c = 0 (given)
x+y+z=0
y
y
x, , z are in A.P.
2
2
x + z = 2
14.
For x =1, y = a + b + c
Tangent at (1, a + b + c) is
1
y a b c ax b x 1 c
2
2
Comparing with y = 2x, c = a, b = 2(1 a)
15.
x (2, 3) 1 < x2 4x + 3 < 0, so f(x) is increasing in (1, 0)
f(sin x) is increasing on
(4n 1) ,2n
2
nI
16.
17.
Let point P on the straight line x + y = 4 be (m, 4 m), this will be nearest to the parabola if at
this point to the straight line becomes normal to the parabola.
Let it is normal at x 10 = t2, y = 2t
Perpendicular to x + y = 4 at (m, 4 m) is y (4 m) = (x m) ..(1)
2
3
Normal at parabola at (t + 10, 2t) is y + t(x 10) = 12t + t
..(2)
17
9
17
(1) and (2) are same t = 1, m =
so required point is ,
2
2
2
a . a c sin 3.1 3 = a . a
2
a a c 3b 3 b
3 = 3.2 sin sin =
ex
18.
cos x
x
e 1
1
3
cos2 =
2
4
2cos2x 2xsec2 x 2
(x) = ln 1 x
cos x
c sin
sin x
sinx
ex
sin2x tanx2
1
sin x
+
1 x
cos x2
ex
cos x + ln 1 x
ex 1 sinx2
2xsin x
sin2x
tan x 2
cos x
sin x
2xcosx 2
= B + 2Cx + .
1 2 0 1 0 0
1 0 0
Put x = 0, B = 0 1 0 1 0 1 0 1 0 = 0
1 0 0
1 0
0 1 0
19.
Let g(x) be the inverse of f, then f(g(x)) = x

3g (x)(g(x)2) = x
(g(x))2 2g(x) log3 x = 0
2 4 4log3 x
g(x) =
1 1 log3 x
2
Since g : [1, ] [2, ]
So g(x) = 1 1 log3 x
20.
Since
21.
Let f = (5 2 7)19
x f = an integer [x] + {x} f = an integer
{x} f = an integer, but 1 < {x} f < 1 {x} = f
So, x{x} = x.f = 119 = 1
Since 4x x 2 3 0 0 < cos 1 4x x 2 3

2
0 < L.H.S < The given equation has no solution
x 2 3x 2 0 0 tan1 x 2 3x 2 <
10
23.
1
1
2
3
= 2e
... = 2eS
x
3 ! 5 ! 7 !
S=
r
1
(2
r
1)!
2
r 1
(2 r 1) 1 1
(2 r 1)!
2
r 1
1 1
1
1
1
...
2 2 ! 3 ! 4 ! 5 !
1 1
1
e =
2
2 e
(2
r 1
r)!
(2 r 1)!
1
2 e
= 2eS =
=1
x
2 e
1
So,
(y) logy x dy = 0
24.
Let any point on second line be (, 2, 3)

6
6
cos =
sin =
42
42
1
1
OAB =
(OA).OB sin =
3 . 14
2
2
=2
So, B is (2, 4, 6)
A (1, 1, 1)
6
42
B(, 2, 3)
abc
3
Now line joining the orthocentre and the circumcentre is divided by centroid in 2 : 1 ratio
internally, so orthocentre will be a b c .
25.
Centroid of triangle will be
26.
If we draw the graph of tan x and cot x, we

observes that range of f (x) is [1, 0) [1, )
1
So f (x) =
does not have any root.
3
27.
S Sn
1
300
1
1
3n 1 3 1 1 1 1
1
1
300
2
3n 00
1
1
3
3
1
1
2
1
1
n
n
3n > 450
300 3
450
3
3
1
Least value of n = 6
11
28.
f(x) =
4
|t x|
x
|t x|
dt e
dt =
4
x t
dt e t x dt = e x t
x
0
etx
4
x
ex e 4 x 2
f(x) = ex e4x = 0 x = 4 x x = 2
f(0) = f(4) = e4 1, f(2) = 2(e2 1), so maximum value of f(x) is e4 1.
29.
Given inequation can be rewritten as 3sec

3
y2
2y 2
1
3 9
1
1
y 3 9 1
sec 2 x
1
1 1
y 3 9 3
1
So, we should have sec2 x = 1, y =
3
x = 0, , 2, 3
Now, 3sec
30.
and
arc(AC) = 3, arc(AB) = 4, arc(BC) = 5

Let radius of the circle be r
r = 3 = 3 /r, = 4/r, = 5/r
Now, 3 + 4 + 5 = 2r r = 6/
r 6
ABC = OAC + OAB + OBC

=
1 2 3
4
5
r sin sin sin
2 r
r
r
1 36
2
5
. 2 sin sin sin
2 2
3
6
18
3 1 9 3 1 3
1
2
2
2

2

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JEE (Main)-2014

ANSWERS, HINTS & SOLUTIONS

ALL INDIA TEST SERIES

Solving (i) and (ii) acceleration of ring =

No effect of a and g on time period of spring pendulum.

There will be no change.

Potential across capacitor is zero, hence energy stored is zero.

For adiabatic process, TV1 = constant

P(x, y), A(3a, 0), B = (3a, 0)

The process is equivalent to TV1/2 = C

Intensity will be highest at the nearest point.

Total energy of 10 quanta = 10 2.9 10-19J

(As Vrms 3RT )

Given equation can be written as |x 1|2 + |x 1| 6 = 0

|z1 z2|2 + |z2 z3|2 + |z3 z4|2 + |z4 z1|2

Number of terms = Number of nonnegative integral solution of the equation p + q + r + s = 50

x + a y + b z + c The determinant is a symmetric one. The determinant will be equal to zero if

Comparing with y = 2x, c = a, b = 2(1 a)

x (2, 3) 1 < x2 4x + 3 < 0, so f(x) is increasing in (1, 0)

3 = 3.2 sin sin =

Let g(x) be the inverse of f, then f(g(x)) = x

Since 4x x 2 3 0 0 < cos 1 4x x 2 3

Let any point on second line be (, 2, 3)

Centroid of triangle will be

If we draw the graph of tan x and cot x, we

Given inequation can be rewritten as 3sec

arc(AC) = 3, arc(AB) = 4, arc(BC) = 5

ABC = OAC + OAB + OBC

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