Académique Documents
Professionnel Documents
Culture Documents
Section
Number of questions
A
B
20
8
Number of
questions to be
answered
20
8
Total
Total marks
20
43
63
Directions to students
Materials
Question and answer book of 12 pages, with a detachable data sheet.
Answer sheet for multiple-choice questions. You should have at least one pencil and an eraser.
An approved calculator may be used.
The Task
This paper consists of two sections, Section A and Section B.
Answer all questions from Section A. Section A is worth 20 marks.
Section A questions should be answered on the answer sheet provided for multiple-choice
questions.
Answer all questions from Section B. Section B is worth 43 marks.
Section B questions should be answered in the spaces provided in this book.
There are a total of 63 marks available.
Working space is provided throughout this book.
All written responses should be in English.
At the end of the task
Place the answer sheet for multiple-choice questions inside the front cover of this book and hand
them in.
SECTION A
Specific instructions for Section A
Section A consists of 20 multiple-choice questions. Section A is worth approximately 31 per cent of the
marks available. You should spend approximately 26 minutes on this section.
Choose the response that is correct or best answers the question, and indicate your choice on the multiplechoice answer sheet according to the instructions on that sheet.
A correct answer is worth 1 mark; an incorrect answer is worth no marks. No mark will be given if more than
one answer is completed for any questions. Marks will not be deducted for incorrect answers. You should
attempt every question.
Question 1
Which one of the following atoms represents an isotope of
A.
7
14
B.
14
8
C.
15
7
D.
15
8
14
7
N?
Question 2
As you move down the elements in Group 1 of the periodic table, the atomic size
A.
B.
C.
D.
Question 3
The molar mass of calcium phosphate, Ca3(PO4)2 is
A.
199
B.
279
C.
310
D.
430
Question 4
An element was found to consist of two isotopes. One of the isotopes has a relative isotopic mass
of 30 with a relative abundance of 76%. The second isotope has a relative isotopic mass of 33 with
a relative abundance of 24%. The relative atomic mass of the element is
A.
31.5
B.
1536
C.
30.72
D.
9.9
Question 5
Determine the amount, in mol, in 60 g of urea, NH2CONH2
A.
60
B.
C.
6.02 x 1023
D.
1.0 x 10-22
Question 6
The number of molecules in 1.5 mol of H2 gas is
A.
9.03 x 1023
B.
1.81 x 1024
C.
1.5
D.
3.0
Question 7
The element sodium has which of the following properties?
A.
B.
C.
D.
Question 8
Which of the following substances is the best conductor of electricity?
A.
B.
iron
C.
pure water
D.
ethene gas
Question 9
The bonding within metallic solids may be described as
A.
ionic; formed between positively charged ions and negatively charged ions
B.
C.
D.
CH2CHCl
II
C8H18
III
CH3F
IV
CH3OH
Question 10
The substance(s) that contain(s) molecules that are attracted to each other by hydrogen bonds
is (are):
A.
III
B.
III and IV
C.
D.
IV
Question 11
The substance that relies on dispersion forces alone for attraction between its molecules is:
A.
B.
II
C.
III
D.
IV
Question 12
A list that contains empirical formulas only is
A.
B.
C.
D.
Question 13
The empirical formula of ethane, C2H6, is
A.
CH
B.
CH3
C.
CH2
D.
CH4
Question 14
Which one of the following molecules is polar?
A.
CCl4
B.
CH2Cl2
C.
SiH4
D.
CO2
Question 15
Which of the above can form polymers?
A.
All of them.
B.
1 and 2 only
C.
3 and 4 only
D.
None of them.
Question 16
Which of the above are structural isomers?
A.
All of them.
B.
1 and 2 only
C.
3 and 4 only
D.
None of them.
Question 17
Which of the compounds are members of the alkene homologous series?
A.
All of them.
B.
1 and 2 only
C.
3 and 4 only
D.
None of them.
Question 18
All alkenes have
A.
B.
C.
D.
Question 19
1-butanol
B.
2-butanol
C.
3-butanol
D.
4-butanol
Question 20
The electronic configuration of
A.
1s22s22p4
B.
1s22s22p6
C.
1s22s22p63s22p4
D.
1s22s22p23s2
16
8
CHEMISTRY
Unit One: Unit Examination
DATA SHEET
Directions to students
The names and formulae of some common and positive and negative ions
Positive Ions (Cations)
+1
+2
+
+3
Lithium
Li
Magnesium
Mg
Aluminium
Al3+
Sodium
Na+
Calcium
Ca2+
Chromium
Cr3+
2+
Iron(III)
Fe3+
Potassium
Barium
Ba
2+
Silver
Ag+
Zinc
Zn2+
Copper(I)
Cu+
Copper(II)
Cu2+
Ammonium
NH4+
Mercury(II)
Hg2+
Iron(II)
Fe2+
Nickel(II)
Ni2+
Tin(II)
Sn2+
Lead(II)
Pb2+
-2
Hydroxide
OH
Hydrogen
carbonate
-3
2-
Oxide
Nitride
HCO3-
Sulfide
S2-
Phosphate
Nitrate
NO3-
Sulfate
SO42-
Fluoride
F-
Carbonate
CO32-
Chloride
Cl-
Chromate
CrO42-
Bromide
Br-
Dichromate
Cr2O72-
Iodide
I-
acetate
CH3COO-
Electronegativity values
N3PO43-
m
M
n=
N
NA
(RIM
No of C
atoms
1
Alkanes (CnH2n + 2)
Alkenes (CnH2n))
methane
CH4
Ethane
C2H6
Ethene
C2H4
Propane
C3H8
Propene
C3H6
Butane
C4H10
Butane
C4H8
Pentane
C5H12
Pentene
C5H10
Hexane
C6H14
Hexene
C6H12
Heptane
C7H16
Heptene
C7H14
Octane
C8H18
Octene
C8H16
Nonane
C9H20
Nonene
C9H18
10
Decane
C10H22
Decene
C10H20
Question 1
The element silver, Ag, occurs as two isotopes.
One isotope as a relative isotope of 106.9 and a relative abundance of 51.8%.
The other isotope has a relative isotopic mass of 109.0 and a relative abundance of 48.2%.
Calculate the relative atomic mass of silver.
RAM (Ag)
Question 2
The diagram below represents a section of the periodic table.
Li
Be
Na
Mg
Al
Si
Cl
From the list of elements, give the symbol for the element in this section that represents:
(a)
(b)
(c)
(d)
a period 3 element that would be expected combine with oxygen to form a metallic oxide.
Any of Na, Mg or Al
(e)
an element that would reaction combine form a non-metallic oxide that a linear shaped
molecule.
C
(f)
Question 3
Ethanol, C2H5OH, is being used a biofuel. When combusted (burnt) in air, (O2) it produces carbon
dioxide and water vapour.
The balance chemical equation for this reaction is:
C2H5OH(g) + 3O2(g) 2CO2(g) + 3H2O(g)
92 g of ethanol is burnt in excess air. (NOTE: This was a typo on the exam.)
(a)
(b)
(c)
= m/M
= 92/46
= 2 mol
(d)
= [(2 x 12) + (5 x 1) + 16 + 1]
= 46 g mol-1
= n(C) x NA
= 2n(C2H5OH) x 6.0 x 1023
= 2 x 2 x 6.0 x 1023
= 2.4 x 1024
1 + 1 + 2 + 2 = 8 marks
Question 4
Determine the percentage composition by mass of silver, Ag, in silver nitrate, AgNO3.
% (Ag) = 107.9/169.9 x 100
= 63.51%
Question 5
A liquid was found to contain 37.6% carbon by mass, 12.5% hydrogen by mass and 50% oxygen
by mass. Determine the empirical formula of the liquid.
n(C) : n(H) : n(O)
37.6/12 : 12.5/1: 50/16
3.133 : 12.5 : 3.125
1:4:1
So, empirical formula is CH4O
(4 marks)
Question 6
For each of the following substances, draw the structure the respective molecules in the boxes
and state in each case whether the molecule is (significantly) polar or non-polar.
(a)
H2O
Shape will be bent (or V-shaped). The molecule is polar.
(b)
CF4
(c)
CH3Cl
(d)
CH3CH2OH
The shape is based on a tetrahedral arrangement around the
carbon atoms.
The molecule is polar.
(2 + 2 + 2 + 2 = 8 marks)
Question 7
(a)
Draw two possible structural formulas for compounds with the molecular formula C3H6Cl2.
There are four possible isomers:
(b)
1, 1 dichloropropane
1, 2 dichloropropane
2, 2 dichloropropane
1, 3 - dichloropropane
Name: butane
(ii)
The boiling points for three hydrocarbon compounds are shown in the table below.
Compound
Methane
CH4
Octane
C8H18
Dodecane C12H26
(i)
Boiling
temperature
(oC)
- 162
126
216
What is the main type of bonding interaction between the molecules of each of
these three hydrocarbons?
Dispersion forces
(ii)
State the reason for the difference in the boiling points of these three hydrocarbons.
The strength of the dispersion forces increase with increasing molecular size,
hence more energy is needed to separate (boil) the larger molecules than the
smaller molecules.
(2 + 1 + 1 + 1 + 1 = 6 marks)
Question 8
The molecular formula C4H10O has several possible structural isomers.
(a)
(b)
(i)
In the two boxes below, write the semi-structural formula for two straight chain
hydrocarbon compounds with the molecular formula C4H10O.
Name:
(ii)
Name:
Give a specific name for each of the molecules you have indicated in (i).
There are four isomers with this molecular formula. They are:
(c)
Butan-1-ol
Butan-2-ol
Methyl propan-1-ol
Methyl propan-2-ol
END OF EXAMINATION