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make their way through the external circuit (doing useful work
such as turning a motor) and return to the cathode side of the
fuel cell.
Meanwhile, on the cathode side of the fuel cell, oxygen gas
(O2) is being forced through the catalyst, where it forms two
oxygen atoms. Each of these atoms has a strong negative
charge. This negative charge attracts the two H+ ions through
the membrane, where they combine with an oxygen atom and
two of the electrons from the external circuit to form a water
molecule (H2O).
This reaction in a single fuel cell produces only about 0.7 volts.
To get this voltage up to a reasonable level, many separate fuel
cells must be combined to form a fuel-cell stack. Bipolar plates
are used to connect one fuel cell to another and are subjected
to both oxidizing and reducing conditions and potentials.
Production process of hydrogen
1. Kvrner-process:
The Kvrner-process or Kvaerner carbon black & hydrogen
process is a method, developed in the 1980s by a Norwegian
company of the same name, for the production of hydrogen
from hydrocarbons, such as methane, natural gas and biogas.
2. Biological production
Fermentative hydrogen production is the fermentative
conversion of organic substrate to biohydrogen by a diverse
group bacteria using multi enzyme systems. They do not
require light energy, so they are capable of constantly
producing hydrogen from organic compounds throughout the
day and night. Electrohydrogenesis is used in microbial fuel
cells where hydrogen is produced from organic matter (e.g.
from sewage, or solid matter while 0.2 - 0.8 V of electricity is
applied.
Prime Minister Shinz Abe, one of the worlds first Mirai owners,
says he wants all his ministries and agencies to adopt fuel-cell
vehicles. To help sales, Japan is introducing a massive subsidy
program worth up to 3 million yen ($25,550) per purchase.
This is more than three times the 950,000 yen being offered to
prospective owners of Mitsubishis i-MiEV electric car.
Refueling ease is another reason Japanese consumers are
increasingly choosing hydrogen. Car owners can top up a
hydrogen tank within about five minutes, compared to the two
hours or so that it can take to recharge lithium-ion car batteries.
Finally, the Mirai comes with a range of about 430 miles per tank,
beating electric models. The Model S has a range of about 265
miles.
On the other hand, hydrogen fuel costs more per mile than driving
an electric car or even a hybrid. And an electric car can, in theory,
be charged from any standard power socket, while fuel-cell
vehicle owners are dependent on the availability of hydrogen
filling stations.
To deal with this, Abe last month said Japan will support the
introduction of 100 self-service refueling points this year, as well
as easing fuel-cell regulations. No further details have been
announced. But hydrogen infrastructure suppliers are already
taking positions in the market.
Air Liquide of France, for example, last month trumpeted the
completion of its fourth and fifth hydrogen filling station projects
on Japanese soil.
JX Nippon Oil & Energy Corp., meanwhile, opened its first filling
station in December and plans to have 40 by March of next year,
according to Japan Times. Tokyo Gas Co. and Iwatani Corp. also
unveiled their first filling stations last year.
The battery-powered cars are good for short trips and city driving.
The fuel cell electric cars are better for longer ranges and have
shorter refueling times. You can fill a hydrogen tank in three or
four minutes."
Fuel cell vehicles have been overshadowed recently by battery
electric vehicles. Models like the Tesla Roadster, Nissan Leaf and
Chevrolet Volt have been launched with great fanfare. Innovative
companies like Better Place and Nuvve are testing speedy battery
replacement systems and ways to sell power from battery
electrics back to the grid, respectively
Daimler is also active in the battery electric arena. It has 1,500
Smart electric cars on the road now. Next month, it will roll out a
new version of the Smart Fortwo. The newer version has more
power and a longer range. Daimler plans to boost production to
10,000 Smart electrics. "We'll build a number of battery-powered
cars in the five-digit range every year," Brock explained.
Infrastructure limitations may prevent manufacturers at first from
rolling out fuel cell cars on the same wide scale as electric
vehicles, but they will be on the streets in increasing numbers by
2015. They will tend to be larger and more high-end than the
electrics, and they will have a bigger range, while battery
electrics may be mainly city cars, Brock added.
Case study of Iceland
Tiny Iceland, already the greatest harnesser of renewables, with
99% of electricity coming via geysers and hydroelectric dams, is
politically committed to becoming the world's first hydrogen
economy - cutting greenhouse emissions to zero, it hopes, within
30 years and leading a global energy revolution.
At present, Iceland spends $150m a year importing 850,000 tons
of oil to meet 35% of its energy needs, which are mainly in
transport, fishing and metals production. Ironically, this make the
country one of the world's higher per capita carbon emitters, but
its vision is to work with others to break through the technological