Académique Documents
Professionnel Documents
Culture Documents
Column diagram
total condenser
feed
F, xF
feed stage
stripping section
reflux
L, xR
temperature
reflux drum
(accumulator)
enriching section
distillate
D, xD
xR = xD
yB xB
xD K xB
boilup
V, yB
partial reboiler
bottoms
B, xB
F=D+B
F xF = D xD + B xB
distillate
D, xD
feed
F, xF
x -x
B
D = F
F
xD - xB
B=F-D
bottoms
B, xB
distillate
D, xD
F hF + QC + QR
= D hD + B hB
F, hF are known
feed
F, xF
unknowns: QC, QR
need another equation
bottoms
B, xB
Balance on condenser
1. Mass balance
TMB:
V1 = D + L 0
CMB:
y1 = xD = xR (doesnt help)
unknowns: V1, L0
specify external reflux ratio R = L0/D
vapor
V1, y1
reflux
L0, xR
distillate
D, xD
V1 = D + (L0/D)D = (1 + R)D
2. Energy balance
V1H1 + QC = (D + L0)hD = V1hD
QC = V1(hD H1)
then calculate QR from column energy balance
hD > H1
QC < 0
QR > 0
Splits
Sometimes used instead of specifying
compositions in product streams.
What is the fractional recovery (FR) of
benzene in the distillate?
xF = 0.46
FRMVC =
xDD 0.99D
=
xF F 0.46F
FRLVC =
(1- xB )B 0.98D
=
(1- xF )F 0.54F
0.97
0.99 - 0.02
xD - xB
FRLVC
xDD 0.99(281)
=
=
= 0.975
xF F 0.46(620)
(1- xB )B 0.98(339)
=
=
= 0.992
(1- xF )F 0.54(620)
Stage-by-stage analysis
Lewis-Sorel method
Consider the top of the distillation column:
vapor
V1, y1
stage 1
L1
x1
V2
y2
distillate
D, xD
stage 1
L1
x1
reflux
L0, x0
distillate
D, xD
V2
y2
TMB:
CMB:
EB:
VLE:
L0 + V2 = L1 + V1
L0x0 + V2y2 = L1x1 + V1y1
L0h0 + V2H2 = L1h1 + V1H1
K1(T1,P) = y1/x1
V2,y2
stage 2
L2,x2
V3,y3
TMB: L1 + V3 = L2 + V2
CMB: L1x1 + V3y3 = L2x2 + V2y2
EB:
L1h1 + V3H3 = L2h2 + V2H2
VLE: K2(T2,P) = y2/x2
can solve for 4 unknowns (L2, x2, V3, y3)
Constant Molal Overflow (CMO): vapor and liquid flow rates are constant
Rectifying column
Feed enters at the bottom, as a vapor.
No reboiler required.
L, xR
D, xD
stage j
Vj+1,yj+1
F, xF
Lj,xj
B, xB
xD = x0
(x0,y1)
yint
L
L
L
D = R
= D=
(L + D)
V V
R +1
D
D
stage 1
(x1,y1)
stage 2
(x2,y2)
stage 3
(x3,y3)
yint
xD= x0
(x0,y1)
(x1,y2)
(x2,y3)
xB
L/V = 0
No reflux!
stage 1
(x1,y1)
0R
0 L/V 1
2. D 0
R = L/D TOTAL REFLUX
L/V = R/(R+1) 1
(LHpitals Rule)
Operating line is y=x
Max. distance between VLE and op. line
Max. separation on each equil. stage
Corresponds to Nmin, but no distillate!
L/V = 1
Total reflux!
xD= x0
(x0,y1)
xD= x0
(x0,y1)
Increasing R = L/D
Decreasing D
Decreasing xB (for fixed N)
L/V = 1
0R
capital cost
operating (energy) cost
stages
cost/lb
total cost
min. heat
required
Rmin
Ropt
Rule-of-thumb:
1.05 Ropt/Rmin 1.25
Ractual can be specified as a multiple of Rmin
Stripping column
Feed enters at the top, as a liquid.
F, xF
No reflux required.
D, xD
Lk-1,
xk-1
Vk,yk
stage k
B, xB
(xN+1,yN+1)
PR
L V +B
B
=
= 1+
V
V
V
xB = xN
(xN+1,yN+2)
(0.7,1)
stage 1
(xN-2,yN-2)
stage 2
(xN-1,yN-1) (xN-2,yN-2)
stage 3
(xN-1,yN)
(xN,yN)
xD,max for this
boilup ratio
PR
(xN+1,
yN+1)
(xN,yN+1)
xB= xN+1
(xN+1,yN+2)
x
D
1 L /V
V / B 0
2. B 0
TOTAL BOILUP
PR
L /V = 1
TOTAL BOILUP
Operating line is y=x
L /V =
xB= xN+1
NO BOILUP
yD ,max for
this boilup ratio
L /V = 1
Total boilup
PR
L /V =
xB= xN+1
No boilup
1 L /V
V / B 0
McCabe-Thiele analysis
of complete distillation column
Total condenser, partial reboiler
Specifications:
xD = 0.8, R = 2
xB = 0.07, V / B = 2
Find N required
Locate feed stage
Feed enters
on stage 2
stage 2
stage 1
xD
PR
xB
Feed condition
Changing the feed temperature affects internal
flow rates in the column
If the feed enters as a saturated liquid, the liquid
F + L +V = L +V
V =V + F
If the feed flashes as it enters the feed stage to form a
two-phase mixture, 50 % liquid, both the liquid and
vapor flow rates will increase:
L = L + 0.5F and
feed
F
L = L+F
V = V + 0.5F
Feed quality, q
EB:
rearrange:
TMB:
V -V = L - L - F
substitute:
combine terms:
(L - L)(HV - hL ) = F(HV - hF )
define:
L = L+F
q=1
V =V + F
q=0
L = L + qF
0<q<1
q>1
superheated vapor
- some liquid vaporizes on feed plate
q<0
Vy j+1 = Lx j + DxD
Vy k = Lxk-1 - BxB
substitute:
L - L = qF and
zF
q
y =x+
(1- q)
1- q
V -V = (1- q)F
sat'd liq
zF
q
y =x+
(1- q)
1- q
sat'd vapor
zF
zF
q
x =x+
(1- q)
1- q
q zF
x 1+
=
(1- q) 1- q
zF
x
=
y = x = zF
1- q 1- q
feed type
sat'd liquid
sat'd vapor
2-phase liq/vap
subcooled liq
superheated vap
q slope, m
q=1
m=
q=0
m=0
0<q<1 m < 0
q>1
m>1
q<0
0<m<1
N = 6 + PR
4
zF
xD
Operating
lines intersect
on stage 4.
This is NF,opt.
PR
xB
rectifying column
xD
yD
z
F
z
F
xB
PR
top operating
line
xB
Design freedom
Fixed q. Vary R:
Fixed R. Vary q:
Rmin
xD
xD
pinch
point
decrease R
zF
xB
choice of R dictates
required boilup ratio.
zF
qmin
pinch point
xB
You cannot step over a pinch point this would require N = . It corresponds to a position in
the column where there is no difference in composition between adjacent stages.
pinch
point
zF
xB
xD
Column with
three products:
feed 2
F2, z2, q2
feed 1
F1, z1, q1
L
distillate
D, xD
z2 > z1
and/or
q 2 > q1
feed
F, z
L
bottoms
B, xB
distillate
D, xD
side-stream
S, xS or yS
side-streams
must be
saturated
liquid or vapor
bottoms
B, xB
Each intermediate input/output stream changes the mass balance, requiring a new operating line.
Multiple feedstreams
Total condenser, partial reboiler
Specifications:
xD = 0.9, xB = 0.07, z1 = 0.4, z2=0.6
Some specified q-values
R = 1. Find N, NF1,opt, NF2,opt
z2
z1 = z2
xD
PR
xB
Optimum location
for feed 1 is stage 5.
Optimum location
for feed 2 is stage 3.
feed 2
F2, z2, q2
D, xD
stage j
L
stage j
side-stream
S, xS or yS
V
xD
yS
xS
x
B
x
B
xD
Partial condensers
A partial condenser can be used when a
vapor distillate is desired:
2
D, yD
V, y1
L, x0
L
PC
yD
Total reboilers
A total reboiler is simpler (less expensive)
than a partial reboiler and is used when the
bottoms stream is readily vaporized:
N-1
stage N
V, yB
B, xB
A total reboiler is not an equilibrium
stage.
TR xB,yB
Stage efficiency
Under real operating conditions, equilibrium is approached but not achieved:
Nactual > Nequil
overall column efficiency:
Eoverall = Nequil/Nactual
EMV =
y n - y n+1
y n * -y n+1
EML =
x n - x n-1
x n * -x n-1
xj* = yj / Kj
1 xD
PR
NF,opt = 6
N = 8 + PR
xB
distillate
D, xD
feed
F, z
S, xS
L
intermediate
reboiler
V
yS = xS
bottoms
B, xB
Subcooled reflux
If the condenser is located below the top of the
column, the reflux stream has to be pumped to
the top of the column.
Pumping a saturated liquid damages the
pump, by causing cavitation. The reflux
stream (L0) should be subcooled. This will
cause some vapor to condense.
V1 = V2 - c
and
stage 1
c
V2
L0, x0
L1
L1 = L0 + c
D, xD
V1, y1
h - h0
L = (1- q0 )L0 q quality of reflux
0
H -h 0
2 - q0 L0 / V1
L1 L0 + c L0 + (1- q0 )L0
=
=
=
V2 V1 + c V1 + (1- q0 )L0 1+ (1- q0 )L0 / V1
where L0/V1 = (L0/D)/(1 + L0/D) = R/(R + 1)
MeOH/H2O
feed
F, z
stage j
TMB:
Vj+1,
yj+1
S, yS
Lj,
xj
B, xB
V + B = L + S
usually 0
mostly H2O
bottoms
B, xB
CMB:
V yj+1 + B xB = L xj + S yS
CMO:
B=L
y = (L/V) x - (L/V) xB
xint: x = xB
xD
zF
3. Plot xB on x-axis
4. Draw feed line, slope = q/(q-1)
5. Draw top op. line, slope = L/V
6. Draw bottom op. line (no
calc. required)
xB
NF,opt = 4
Column internals
Sieve tray
Downcomers
Dual-flow tray (no downcomer)
Both liquid and vapor pass through holes
Narrow operating range
Dual-pass tray
Tray efficiency
efficiency
design
point
flooding
weeping/du
mping
Column flooding
1. jet flood (due to entrainment)
Column sizing
1. Calculate vapor flood velocity, uflood (ft/s)
s
= Csb,f
20
0.2
uflood
rL - rV
rV
where Csb,f is the capacity factor, from empirical correlation with flow parameter, FP
WL
FP =
WV
rV
rL
where WL and WV are the mass flow rates of liquid and vapor, respectively
Tray spacing
where h is the fraction of the cross-sectional area available for vapor flow (i.e., not
occupied by the downcomer)
4V MWV
3600phrV uop
4V
RT
3600phuop P
Packed columns
structured packing:
random packing:
larger surface area, for better contact between liquid and vapor
preferred for column diameters < 2.5
packing is considerably more expensive than trays
change in vapor/liquid composition is continuous (unlike staged column)
analysis like a staged column: HETP (= Height Equivalent to a Theoretical Plate/Tray)