CONCEPTUAL QUESTIONS

H 2SO4

1.

(c) Wt. of
98g.

per litre

N eq.mass 2 49

11. (d) Osmotic

(a) In alkaline medium

as follows.

Hence its

and
will produce same number of
solute particles.

Al2(SO4 )3

12. (a)

Now, Normality

mass

100
g 1.58 g.
1000

ions in

PPm

w 0.2 100

w 1.26gm
63
1000

ions but

5.

(b) 5.85 g NaCl = 0.1 mol as it present in 1

kg of
wt.
5.85

mwt. l 58.5 1

8.

(d)

CH 3COCH

Kb w 1000
Tb W

2.16 0.11 1000

158.40~
158
0.1 15

Substituting these values in expression

K b 1000 w
Tb W

M Solute

is non ideal solution

which shown negative deviation.

Where,
M solute

solution will be

maximum due to ionisation less in

and minimum in urea

molar

mass

of

weight of

the

58gmmol

Kb

16. (a)
m

More the number of particles in solution

more is the osmotic pressure a colligative
properties.

17. (d)

5 0.0821 1000 423

5.07atm
342 100

18. (d)

weight of solute,

2.53 1.8 1000

58gmmol1
0.88 90

Hence,

AlCl 3 Al 3 3Cl 4
BaCl2 Ba2 2Cl 3

solvent

BaCl2

10. (c)

in the boiling point

354.11K 353.23K 0.88K

=0.1molal

CHCl 3

(a) The particle come of

(Tb )

AlCl3

9.

is more ionic than

15. (c) The elevation

P o Ps
P o Ps w M
n

80
n N
m W
Po
Po

(d)

ZnSO4

(a)

7.

gives 2

K b 2.16, w 0.11, W 15g, Tb 0.1

(c)

water ; molality

NaCl

ZnSO4

and

14. (b)

0.2
106 400
500

4.

NaCl

Deci-molar gives maximum ion.

Hence, its osmotic pressure is maximum.

13. (b)

(d) For complete neutralization equivalent of

oxalic acid = equivalent of NaOH =
w
NV

eq.wt 1000

2Na SO42

Na2(SO4 )

0.1 158

Ca2 2NO3

CaNO3

Mass
1

Eq.mass V(L)

6.

coligative

Na2SO4

act as oxidant

m. wt. 158

eq.wt.

properties equimolar solution of

2KMnO4 2KOH 2K 2 MnO4 H 2O (O)

3.

is

Ca(NO3)2

KMnO4

2.

pressure

0.18
1.8
0.1

K f 1000 w
W Tf

5.1 1000 4.8

400
60 1.02

.
Tf mkf

0.40

0.01 1000
kf kf 4
100

ENDEAVOUR CLASSES_CHEMISTRY

solute

CONCEPTUAL QUESTIONS
Tf mkf

Si4

26. (d) All are the iso-electronic species but

has high positive charge so have lowest
radius.

again

0.03 1000
4
50

sin n

2.4

27. (d) 2d

La(NO3)3

19. (d)

will furnish four ions and thus will

develop more lowering in freezing point
whereas glucose gives only one particle
and thus minimum lowering in freezing
point.
K 3[Fe(CN )6 ] 3K [Fe(CN )6 ]3 .

20. (d)

or

(ZnS)

25. (d) In zinc blende

half number of
tetrahedral holes are filled by zinc atoms.

d 1.15 (sin 60 3 / 2

28. (c) Distance between centres of

rNa rCl 276pm

0.8660)

or
Na

.
and

Cl

95 rCl 276pm

or
rCl 276 95 181pm

or

22. (a) Constituent particles of covalent

compounds are atoms.

24. (d) Molecular crystals are soft and have low

melting point.

2 d 0.8660 2

or

21. (c) Quartz is a covalent solid in which

constituent particles are atoms which are
held together by covalent bond forces.

23. (d) Iodine crystals are molecular crystals, in

which constituent particles are molecules
having interparticle forces are Vander
Waals forces.

2 d sin60 2 1

or

rc
ra

1.46
0.676
2.16

29. (c)
It permits co-ordination number 6 and
octahedral structure of type

NaCl

30. (d) The co-ordination number of a cation

occupying a tetrahedral hole is 4.
31. (d) When electrons are trapped in anion
vacancies, these are called F-centres.

ENDEAVOUR CLASSES_CHEMISTRY