II PUC Chemistry (34)

Time : 3 Hrs. 15min.

Blue Print of Model Question Paper 5
PartA
Group

Unit

Title

Hours Marks

I
10x1
mark

Part B

Part C

Part D

II

III

IV & V

8x2
mark

8x3
mark

11x5
mark

The Solid state

Solution

Electrochemistry

Chemical kinetics

Surface chemistry

Total of Group-I

41

36

General principles and

processes of isolation of
elements

The p-block elements

11

10

10

The d and f-block

elements

Coordination compounds

Total of Group-II

32

28

10

Haloalkanes and
haloarenes

11

Alcohols, phenols and

ethers

12

Aldehydes, ketones and

carboxylic acids

13

Amines

Group-I

Total

Physical

Group-II
Inorganic

Group-III
Organic

36

28

14

Biomolecules

15

Polymers

16

Chemistry in everyday
life

Total of Group-III

47

41

TOTAL

120

105

4
41

11

14

24

30

105

SECOND PUC MODEL QUESTION PAPER -5

Time 3.15 Hr

Marks-70

Instructions:
1. The question paper has four parts: A, B, C and D. All the parts are compulsory
2. Write balanced chemical equations and draw labelled diagram wherever required.
3. Use log tables and simple calculators if necessary
(Use of scientific calculators is not allowed)

PART- A

I. Answer all the questions (Each questions carries 1 mark)

10 x1 = 10

1. How many particles are present in a unit cell of fcc?

2. What happens to the vapour pressure of the liquid when temperature is increased?
3. Write the mathematical expression of Henrys law.
4. State Faradays first law of electrolysis.
5. Give an example for a ter molecular reaction.
6. Name the method used for purification of silicon.
7. Identify the product A in the following reaction
XeF6 + 2 H2O

+ 4HF

8. What are enantiomers?

9. Among methanoicacid, ethanoicacid and propanoicacid which one is most acidic?
10. Which vitamin deficiency causes the disease scurvy?

PART- B

II. Answer any FIVE of the following. (Each questions carries 2 marks)

5 x 2 = 10

11. What are ferromagnetic substances? Give an example.

12. Draw a schematic diagram of H2- O2 fuel cell.
13. Define activation energy. What is the effect of a catalyst on the activation energy of a reaction
14. What are lanthanoids? Write the most common oxidation state of lanthanoids.
15. What is Williamsons ether synthesis? Give an example.
16. How do you convert ethanoic acid into 2-chloro ethanoic acid? Name the reaction.
17. Name the class of the drugs to which the following belong?
i) Dettol ii) Brompheniramine ( Dimetapp)
18. Give an example for each of the following
a) Artificial sweetening agents b) Detergents.

Part C
III. Answer any FIVE of the following (Each question carries 3 marks)

5 x 3 = 15

19. Write the chemical equations involved in the extraction of blister copper
from copper matte.

20. Decribe the manufacture of ammonia by Habers process.

21. a) Explain the oxidizing property of ozone with lead sulphide.

b) Write the structure of pyrosulphuric acid

22. Complete the following equations
I .S8 + 4 Cl2
II. NH3 + HCl
III. Br2 + 5 F2 (excess)

1
3

23. a) Give reason: Solution containing Cu2+ ion is coloured whereas Cu+ is colourless.

b) Name the 3d element which contains highest number of unpaired electrons in the ground state.
1
24. Explain the preparation of potassium permanganate from manganous dioxide.

25. With the help of VBT, explain the hybridisation, geometry and magnetic property of [Ni(CN)4]23
26. a) Write the energy level diagram for the crystal field splitting in octahedral
2

complexes.

b) Write the IUPAC name of [Cr (H2O)6]Cl3

Part D
IV. Answer any THREE of the following (Each question carries 5 marks)

3 x 5 = 15

27. a)Calculate the packing efficiency in bcc crystal.

b) An element having atomic mass 60 has fcc lattice, the edge length of the unit cell
400 pm. Calculate the density of the crystal (NA= 6.022 x 1023)

(3 + 2)

28. a) A 5.50 g sample of a non-volatile solute is dissolved in 250 g of benzene the

freezing point of this solution is 1.020C below that of pure benzene. Calculate the
molar mass of the solute (Kf for benzene = 5.120C/mol)
b) State Raoults law. Write its mathematical expression

(3 + 2)

29.a) Calculate the emf of the cell Zn(s) Zn2+ (0.2M)Cu2+(0.1M) Cu(s).
Given E0Zn = -0.76 V and E0Cu = +0.34 V at 250C
b) Define molar conductivity. How is it related to conductivity of the solution?
30 a) Derive integrated rate equation for the rate constant of zero order reaction.

(3 + 2)

b) The rate constant of a first order reaction is 1.2 x10-3 s-1. Calculate half-life period of the reaction.
(3+2 )
31. a) Write any two differences between physisorption and chemisorption?
b) What is coagulation of colloids? Mention one method of coagulation of lyophobic sols.
c) Give an example for shape selective catalyst.

(2 + 2+ 1)

V. Answer any FOUR of the following (Each question carries 5 marks)

4x 5 = 20

32. a) i)Explain dehydrohalogenation of alkyl halides with an example.

ii) Write the name of the following reaction

R-X + NaI R-I + NaX where X = Cl, Br

b) Mention two reasons to show haloarenes are less reactive towards nucleophilic substitution
reactions.
2
33. a) Write the mechanism of dehydration of ethanol to ethene?

b) Name the conjugated diketone formed, when phenol is treated with

chromic acid? Write the chemical equation.

34. a) How is benzaldehyde prepared by Rosenmunds reduction?

b) What happens when propanone is heated with sodium hypoiodite?

Write the chemical equation.

c) Name the product produced when ethanal is treated with dilute alkali
followed by heating.

35. a) Explain the preparation of primary amines by Gabriel phthalimide synthesis.

b) Explain Sandmeyers reaction with an example.

36. a Give the reaction to show that

i) Glucose contains 5- OH groups

ii) Glucose contains a carbonyl group

b) What are hormones? Mention the function of thyroxin.

c) Name the nitrogeneous base present only in RNA.

37. a) Explain addition polymerisation with an example.

b) What are biodegradable polymers? Give an example

c) Give an example for synthetic rubber.

Scheme of valuation for model question paper for model question paper -5
Note : Any other correct alternate answer can be honoured wherever applicable
Q.N
o

Value points

Mark
s
PART- A

4 or four

Increases

p = KH x

The mass of the substance liberated or deposited on an electrode is directly proportional

to the quantity of electricity supplied. or
any other suitable definition
2 NO + O2 2NO2 or any other suitable example

Zone refining

XeO2F2

The optical isomers of a compound which are non- superimposable mirror images of
each other.
Methanoic acid

10

Vitamin C

II
11

PART- B
The substances which are strongly attracted by the magnetic field
H2O
Ex. Fe Co, Ni etc.
Anode
Cathode +

1
1

12
Aqueous electrolyte

H2

O2

13

The minimum extra energy that the normal reactant molecule has to acquire in order to
attain threshold energy. or Energy required to form the activated complex

1
1

Ea decreases
14

15

The 14 elements following lanthanum.

or The elements in which the differentiating electron enters the 4f orbitals

+3

When bromoethane is treated with sodium ethoxide, ethoxy ethane is obtained

or general statement

C2H5Br + C2H5ONa C2H5 O C2H5 + 2NaBr

OR
Self-explanatory equation

16

When ethanoic acid is treated with chlorine in presence of red phosphorus,

2-chloro ethanoic acid is obtained

CH3COOH + Cl2

Red P
ClCH2COOH + HCl

OR

17

18

Self-explanatory equation

I. Antiseptic

II. Antihistamine

a) Saccharin or Aspartame or any other suitable example

b) sodium laurylsulphate or sodium dodecylbenzenesulphonate or any other suitable

example

III
19

PART- C
2FeS +3O2 2FeO + 2SO2

FeO + SiO2 FeSiO3

2Cu2S + 3O2 2 Cu2O + 2SO2

2Cu2O + Cu2S 6Cu +SO2

20

N2 + 3H2

21

2 NH3

Conditions: T = 700K P= 200atm catalyst = Iron oxide with small amount of K2O & Al2O3

a) Ozone oxidises lead sulphide to lead sulpahate

1
1

PbS + 4O3 PbSO4 + 4 O2

b)

O = S - O S =O

22

23

OH

OH

S8 + 4 Cl2

ii.

NH3 + HCl

iii.

Br2 + 5 F2 (excess)

4 S2Cl2

NH4Cl

1
2 Br F5

a) Cu2+ ion has d9 configuration, it contains one unpaired electron and d-d
transition takes place.
Cu+ has d10 configuration and has no unpaired electrons, so

1
1

d-d transition does not take place

24.

b) Chromium

a) KmnO4 is prepared by the fusion of MnO2 with KOH and an oxidising agent

like KNO3followed by acidification.

25.

2MnO2 + 4KOH + O2 2 K2MnO4 + 2 H2O

3 MnO42 + 4 H+ 2 MnO4-- + MnO2 + 2 H2O

1
2

Since it has dsp Hybridisation the geometry is Square planar

1
Since it does not contain any unpaired electron it is diamagnetic in nature

26

a)

b) hexaaquachromium(III) chloride

Packing efficiency in Body-centred cubic structure:

27

In the triangle EFD

Face diagonal, b 2 = a 2 + a 2 = 2a 2
\ b = 2 a
1

Now in the triangle AFD

Body diagonal c 2 = b 2 + a 2

c 2 = 2a 2 + a 2
c 2 = 3a 2
\c =
Length of body diagonal

3 a
c = 4r

3 a = 4r
\r=

Packing efficiency =

3
a
4

Volume occupied by 2 speres in the unit cell

100
Total volume of the unit cell

4
2 pr 3
3
=
100
a3
3

4 22 3
2
a
3 7 4
100%
=
a3
4 22 3 3 3/
2
a/
3 7
64
=
100%
a/ 3/
= 68%

b)

d=

28

zM
a3 N A

4 X 60

( 400 x10 )
10

x 6.022 x 1023

= 6.227 g / cm3
1

a)

d=
d=

K f wB 1000
DTf w A

5.12 5.5 1000

= 110.43 g / mol
1.02 250

1+1
b) Partial vapour pressure of each volatile component in the solution is directly
proportional to its mole fraction.

p1 x1 or p1 = x1p10

1
29
a)

E0cell = E0Cu E0Zn

= 0.34 (-0.76)
= 1.1 V

0.0591
[Zn2+ ]
log
2
[Cu2+ ]
0.0591
0.2
Ecell = 1.1 log
2
0.1
= 1.1 0.0295 ( log 2 )
0
Ecell = Ecell
-

= 1.1 0.0295 x 0.3010 = 1.09 V

1
1
1

b) The conductivity of all the ions present in solution containing

one mole of the electrolyte.
Relation: m = K/c

30

a)

k=

R - R
0
t

t1
b)

t1 =
2

0.693
=
k
0.693
1.2 x10-3

1
= 577.5 s
31

a)
Physical adsorption

Chemical adsorption

It involves weak vander Waals force

It involves strong chemical bond

It is not specific in nature

It is specific in nature

It is reversible

It is irreversible

Enthalpy of adsorption is low

The enthalpy of adsorption is high

Multimolecular layer of adsorption

Monomolecular layer of adsorption

Activation energy is low

Activation energy is High

Etc .. Any two differences

b) The process of settling of colloidal particles is called coagulation

Addition of electrolyte or electrophoresis or any other suitable method

1
1

c) ZSM-5 or any other suitable example

1
32

a) i) When bromoethane is heated with alcoholic potash ethene is formed

or general statement

C2H5Br + alc KOH C2H4 + KBr + H2O

or any other suitable example

ii) Finkelstein reaction

b)

- Halogen is bonded to sp2hybridised carbon

- Due to resonance
- Partial C- X double bond character etc

( any two )
a)
Mechanism of dehydration of ethanol:
It involves the following steps.
Setp1: Protonation of alcohol
33

Step2: Formation of carbocation

1
Step3: Elimination of proton

1
H2C

CH2

H+

Ethene
H

b) Benzoquinone is formed
Equation

34

1
1

a) When benzoyl chloride is heated with hydrogen in presence of deactivated

palladium catalyst benzaldehyde is formed

Pd/ BaSO4
C6H5COCl + H2

C6H5CHO + HCl

b) Iodoform and sodium acetate are formed or iodoform is formed

1
1

NaOI
CH3COCH3

CH3COONa + CHI3

c) Crotonaldehyde or But-2-enal

35.

a)

b) When benzene diazonium chloride is heated with cuprous chloride in con HCl

chlorobenzene is formed

Cu2Cl2/ con HCl

C6H5 N2CCl

C6H5Cl + N2

or any other suitable answer

36.

a) i) When glucose reacts with acetyl chloride or acetic anhydride penta- acetyl

glucose is formed
ii) When glucose reacts with hydroxyl amine forms oxime is formed

b) Biochemical messenger are called Hormones

or
Chemical substances secreted by ductless (endocrine glands )

Growth and development

37.

c) Uracil

a) The process of repeated addition of monomer molecules to form a polymer

n(CH2= CH2)

or

-(CH2CH2-)n

any other suitable example

b) The poymer which undergoes decomposition by biological means is called

biodegradable polymer
Ex: PHBV Or any other suitable example

c) BuNa-S or Neoprene , any other suitable Example