HARSHA TUITION CENTRE

106/2 Valga Valamudan Illam, Gopal Nagar, YMR Patti, Dindigul -1

S. Sadaiappan, B.E., M.E., A. Sree Saradha, B.Sc., M.Sc., M.Phil., B.Ed.,,
Contact No: 8012918351

Chemistry - Answer All Questions Are Compulsory- Total Marks:100

Part A
20x1=20
1. An example of metal deficiency defect
(a) NaCl
(b) AgCl
(c) CsCl
(d) FeS
2. The total number of atoms per unit cell is bcc is
(a) 1
(b) 2
(c) 3
(d) 4
3. In a simple cubic cell, each point on a corner is shared by
(a) One unit cell
(b) Two unit cell
(c) 8 unit cell
(d) 4 unit cell
4. The number of close neighbours in a body centred cubic lattice of identical spheres is
(a) 6
(b) 4
(c) 12
(d) 8
5. In the Braggs equation for diffraction of X-rays,n represents
(a) The number of moles (b) Avogadro number (c) A quantum number (d) Order of reflection
6. Semiconductors which exhibit conductivity due to the flow of excess negative electrons are
called
(a) Super conductors
(b) n-type semiconductors (c) p-type semiconductors (d) Insulators
7. The crystal structure of CsCl is
(a) Simple cubic
(b) face-centred cubic (c) Tetragonal (d) Body centred cubic
8. The Braggs equation is

9. The amount of heat exchanged with the surrounding at constant temperature and pressure is

called
10.. All the naturally occurring processes proceed spontaneously in a direction which leads to
a) decrease of entropy b) increase in enthalpyc) increase in free energy d) decrease of free energy
11. When a liquid boils, there is
a) an increase in entropy
b) a decrease in entropy c) an increase in heat of
vapourisation
d) an increase in free energy
12. If
for a reaction is negative, the change is
a) Spontaneous b) Non-spontaneous
c) Reversible
d) Equilibrium
13. Which of the following does not result in an increase in the entropy?
a) crystallisation of sucrose from solution
b) rusting of iron
c) conversion of ice to water
d) vaporisation of camphor
14. In which of the following process, the process is always non-feasible?

15.Change in Gibbs free energy is given by

16.For the reaction 2Cl(g)Cl

2(g), the signs of H and S respectively are
a) +,
b) +, +
c) ,

d) , +

HARSHA TUITION CENTRE

106/2 Valga Valamudan Illam, Gopal Nagar, YMR Patti, Dindigul -1
S. Sadaiappan, B.E., M.E., A. Sree Saradha, B.Sc., M.Sc., M.Phil., B.Ed.,,
Contact No: 8012918351

17. SI unit of entropy is a) JK-1 mol-1 b) JK-2 mol-1 c) JK-1 mol-2 d) JK-2 mol-2
18. Half-Life period of a radioactive element is 100 seconds; its average life period is
a) 144 seconds
b) 120 seconds
c) 100 seconds
d) 244 seconds
19. The in Braggs equation is angle of a) reflection b) refraction c) index d) none of these.
20. Standard free energies of formation of elements are taken as a) zero b) infinity c) 45 d) 90
Part B
10 x3=30
1. What are super conductors?
2. Write a note on molecular crystal
3. State Braggs Law?
4. How glasses are formed?
5. Sketch the following lattice a) simple centered cubic c) Body centered cubic
6. What types of liquids or substances deviate from Troutons rule?
7. What is Gibbs free energy?
8. State Troutons law
9. What is Entropy? Give its units?
10. State the Kelvin-Planks statement of second law of thermodynamics?
Part B
1. Explain Braggs spectrometer method.
2. What are ionic crystals? Write the properties of ionic crystals.
3. Write the characteristics of free energy G.
4. What are the characteristics of entropy?
5. Explain the nature of glass.

6x5=30

6. Write a note on super conductors

Part C
2x10=20
1. a) State the various statements of second law of thermodynamics.
b) Explain AB and AB2 type ionic crystals with one example for each.
2. a) Explain Schottky and Frenkel defects.
b) What are spontaneous reactions? What are the conditions for the spontaneity of a
process?