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M.M. : 198
2.
Blank spaces and blank pages are provided in this booklet for your rough work. No additional sheets will
be provided for rough work.
3.
Using a black ball point pen, darken the bubbles on the upper original sheet. Apply sufficient pressure
so that the impression is created on the bottom sheet.
4.
5.
Write your Name, Registration Number and the name of examination centre and sign with pen in the
boxes provided on the right part of the ORS. Do not write any of this information anywhere else. Darken
the appropriate bubble UNDER each digit of your Registration Number.
The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists of three
sections.
6.
Section I contains 14 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
7.
Section II contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE are correct.
8.
For each question in Section I, you will be awarded 3 marks if you darken the bubble corresponding to
the correct answer ONLY and zero (0) marks if no bubbles are darkened. In all other cases, minus one
(1) mark will be awarded in these sections.
9.
For each question in Section II, you will be awarded 4 marks if you darken ALL the bubble(s)
corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks will be awarded. No
negative marks will be awarded for incorrect answer(s) in this section.
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PART - I (CHEMISTRY)
66 MARKS
SECTION - I
STRAIGHT OBJECTIVE TYPE
This Section contains 14 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
1.
25 mL of an aqueous solution of KCl was found to require 20 mL of 1 M AgNO3 solution when titrated
using a K2CrO4 as indicator. The freezing point of KCl solution will be :
[ K f = 2.0 mol1 kg and molarity = molality]
(A)
2.
1.6 C
(B)
3.2 C
(C)
1.6 C
(D)
3.2 C
1
1
If there were three possible values , 0, + for spin magnetic quantum number. Which of the
2
following statement(s) is/are correct regarding a hypothetical periodic table based on these conditions
assuming all other laws remain same?
3.
(A)
(C)
Statement : 1
Statement : 2
(A)
(B)
(C)
(D)
4.
I.
[Ni(DMG)2]
II.
[Ag(SCN)4 ]3 III.
[AuBr4 ]
(A)
I, III
(B)
I, II, III
I, II
(C)
(D)
None of these
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5.
The pH at which in presence of a given indicator a titration is ended is sometimes known as titration
exponent and is denoted by pT. For methyl orange pT value is 4.0. Calculate the indicator (methyl
orange) error (in multiple of 102 ) if 0.1 N HCl is titrated by 0.1 N NaOH. [Hint : Visualise error in
(C)
30
(D)
40
6.
A CCP structure has the formula AB2C4 where C atoms are cubic closed packed, B atoms occupy half of
the octahedral voids A atoms are present in 1/8th of the tetrahedral voids. The packing fraction if A, B
atoms are in contact with C :
(A)
0.62
(B)
0.77
(C)
0.70
(D)
0.59
7.
2
4
3
X
Yellow ppt.
No change
NH
K CrO
soln
K 2 CrO4
NH3
K 2 CrO4
soln
NH3
Y Red ppt.
black ppt
Z Red ppt.
ppt. dissolves
soln
X, Y and Z are :
(A)
Pb 2 + , Hg 22 + , Ag +
(C)
8.
Hg 22+ , Ag + , Pb 2+
(B)
Ag + ,Hg 22+ , Pb 2+
(D)
Pb 2+ , Ag + , Hg 22+
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9.
The structure of a poly peptide formed from : Alanine, Glycine & Phenylalanine will be:
O
O
||
||
(A)
H 2 N C H C NH CH 2 C NH C H COOH
|
|
C6 H 5
CH 2C6 H 5
O
O
||
||
H 2 N C H C NH CH 2 C NH C H COOH
(B)
|
|
C6 H 5
C6 H 5
O
O
||
||
(C)
H 2 N C H C NH CH 2 C NH C H COOH
|
|
CH 3
CH 2C6 H 5
O
O
O
||
||
||
(D)
H 2 N C H C NH CH 2 C NH C C H CH 3
|
|
CH3
CH 2 C6 H5
10.
11.
Fe4[Fe(CN)6]2 (D)
Fe3[Fe(CN)6]3
In which of the following compound, the sodium fusion extract of nitrogen containing compound, on
treatment with iron(II) sulphate and H2SO4 in presence of air will not gives a Prussian blue precipitate.
(A)
H2NCO NHNH2.HCl
(B)
NH2NH2.HCl
(C)
NH2CONH2
(D)
C6H5NH NH2.HCl
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Paragraph for Question 12 - 14
The Organic compounds undergo various types of reaction. Such as Electrophilic addition, Nucleophilic
substitution, Electrophilic substitution etc. The characteristic reaction of an organic compound depends on nature
of functional group, stability of intermediate and reaction conditions.
12.
HBr
NO2
Major Product
CH3
Br
Br
(A) CH3CHCH
NO2
CH3
NO2
CH3
CH3
(C) CH3CHCH
Br
13.
NO2
(D) CH3CHCH2
NO2
CH3
Br
CH2Br +
CH2N
Br
H
is influenced by the hyper conjugation effect of group R. If R sequentially is :
CH3
CH3
(P)
CH3,
(Q)
(R) CH3CH
CH3CH2
(S) CH3C
CH3
(A)
14.
R>Q>P>S
(A)
1 and 2 both
(B)
1 only
(C)
2 only
(D)
No substitution possible
VMC/2013
Vidyamandir Classes
SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
15.
(D)
(A)
(B)
(C)
(D)
16.
17.
(A)
A mixture of Toluene and aniline can be separated by reacting with hydrochloric acid
(B)
(C2H5)2 NH & C3H7OH can be separated by adding hot conc. H2SO4 followed by steam
distillation
(C)
Adding ceric ammonium nitrate to an aqueous solution of para-cresol given reddish brown
precipitate
(D)
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18.
Which of the following is(are) CORRECT statement(s) about the compound NO[BF4] ?
(A)
It has 5 and 2 bond
(B)
(C)
(D)
19.
K2MnO4 in unstable in solution and the green solution obtained is changed into purple colouration.
Correct statement(s) regarding the above change are :
(A)
It is a disproportionation reaction
(B)
It produces blackish-brown precipitate of MnO2
(C)
Purple colour is due to formation of KMnO4 which forms purple (almost black) crystals on
crystallization
(D)
Crystals of KMnO4 if heated will dissociate to give off oxygen
20.
The reagent that can be used to distinguish between the products obtained by the acid hydrolysis of (A)
and (B) given below is :
I.
2, 4-Dinitrophenyl hydrazine
III.
Iodoform Test
The correct option is :
(A)
I, II
(B)
II, III
II.
IV.
Lucas reagent
Tollens reagent
(C)
III, IV
(D)
I, III, IV
VMC/2013
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PART - II (PHYSICS)
66 MARKS
SECTION - I
STRAIGHT OBJECTIVE TYPE
This Section contains 14 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
21.
(A)
22.
23.
k
M
(B)
A 3
2
k
M
k
M
(D)
2A
M
k
A particle revolves in clockwise direction (as seen from point A) in a
circle C of radius 1 cm and completes one revolution in 2 sec. The axis
of the circle (coincides with) principal axis of the mirror and radius of
curvature of the mirror is 20 cm. Then, the direction of revolution
(as seen from A) of the image of the particle and its speed is:
(C)
A 3
(A)
(B)
(C)
(D)
The region between two concentric spheres of radii a and b(>a) contains volume charge
C
density ( r ) = , where C is a constant and r is the radial distance, as shown in
r
figure. A point charge q is placed at the origin, r = 0. Find the value of C for which the
electric field in the region between the spheres is constant (i.e., r independent).
q
q
q
q
(A)
(B)
(C)
(D)
2
2
2
2
a
2 a
2 b 2
a +b
a
q
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24.
Two ends A and B of a smooth chain of mass m and length l are situated as
shown in fig. If an external agent pulls A till it comes to same level of B,
work done by external agent is:
mgl
mgl
(A)
(B)
36
15
mgl
(C)
(D)
None of these
9
25.
In the figure shown the instantaneous speed of end A of the rod is v to the
left. The angular velocity of the rod of length L must be:
v
v
(A)
(B)
2L
L
(C)
26.
None of these
(D)
Figure shows a crude type of atomizer. When bulb A is compressed, air flows
swiftly through tube BC causing a reduced pressure in the particles of the
vertical tube. Liquid rises in the tube, enters BC and is sprayed out. If the
pressure in the bulb is Pa + P, where P is the gauge pressure and Pa is the
atmospheric pressure, v is the speed of air in BC, find how large would v
need to be to cause the liquid to rise to BC. Density of air = 1.3 Kg/m3.
(A)
27.
v 3
2L
P + gh
0.65
(B)
P gh
0.65
(C)
P + h g
0.65
(D)
P gh
0.65
Two particles of medium disturbed by the wave propagation are at x1 = 0 and x2 = 1 cm. The respective
displacements (in cm) of the particles can be given by the equations:
y1 = 2 sin 3 t , y2 = 2 sin ( 3 t / 8 )
The wave velocity is:
(A)
16 cm/s
(B)
24 cm/s
(C)
12 cm/s
(D)
8 cm/s
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28.
A tennis ball with (small) mass m2 rests on the top of a basketball of mass m1 which
is at a height h above the ground, and the bottom of the tennis ball is at height
(h + d) above the ground. The balls are dropped. To what height does the tennis ball
bounce with respect to ground? (Assume all collisions to be elastic and m1 m2 )
(A)
(C)
7h + d
9h
(B)
(D)
7h
9h + d
29.
30.
(D)
8s
(A)
3 103 ms 1
(B)
4 103 ms 1
(C)
10 103 ms 1 (C)
1 103 ms 1
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Paragraph for Question 31 - 32
In the circuit shown in fig the capacitor has capacitance C = 20mF and is initially charged to 100 V with the
polarity shown. The resistor R0 has resistance 10 . At time t = 0, the switch is closed. The smaller circuit is not
connected in any way to the larger one. The wire of the smaller circuit has a
resistance of 1.0 m1 and contains 25 loops and its dimensions are a = 10.0 cm
and b = 20.0 cm. The distance c is 5.0 cm. (The figure is not drawn to scale.) Both
circuits are held stationary in the same plane. Assume that only the wire nearest to
the smaller circuit produces an appreciable magnetic field through it and length of
that wire is much larger than the smaller circuit. (ln2 = 0.0693 and ln3 = 1.010)
31.
32.
33.
(D)
10
A
e
(D)
0.36 A
(D)
4.8 m
34.
A uniform magnetic field of induction B is confined to a cylindrical region of radius R. The magnetic
field is increasing at a constant rate of dB / dt Ts 1 . An electron placed at the point P on the periphery of
the field, experiences an acceleration of:
eR dB
eR dB
(A)
(B)
towards left
towards right
2 m dt
2 m dt
(C)
eR dB
towards left
m dt
(D)
zero
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SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
35.
A parallel-plate air capacitor has initial capacitance C. If plate separation is slowly increased from d1 to
d2, then mark the correct statement(s). [Take potential of the capacitor to be constant, i.e., throughout the
process it remains connected to battery.]
(A)
Work done by electric force = work done by external agent
(B)
Work done by external force = F .dx, where F the electric force of attraction between the
(C)
(D)
36.
37.
A plank with a uniform sphere placed on it rests on a smooth horizontal plane. The plank is pulled to the
right by a constant force F. If the sphere does not slip over the plank, then
(A)
(B)
(C)
(D)
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38.
39.
E1
E2
G
S
(C)
40.
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66 MARKS
SECTION - I
STRAIGHT OBJECTIVE TYPE
This Section contains 14 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
Only One is Correct :
a
41.
xa
[log a x ]
dx =
e 1
value of a is :
e
(A)
2
42.
43.
(C)
e
2
(D)
The plane lx + my = 0 is rotated about its line of intersection with the XOY plane through an angle ,
then the equation of plane is lx + my + nz = 0, where n is:
(A)
l 2 + m2 cos
(B)
l 2 + m2 sin
(C)
l 2 + m2 tan
(D)
l 2 + m2 cot
(A)
44.
(B)
No real root
(B)
1
2
3
+
+
= 0 has :
y f (1) y f (2) y f (3)
(B)
The maximum number of points into which 4 circles and 4 straight lines interest is :
(A)
26
(B)
50
(C)
56
(D)
72
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45.
f ( x ) dx is equal to :
0
(A)
(B)
2t
(C)
(D)
46.
The set of points on the axis of the parabola y2 = 4x + 8 from which the 3 normals to the parabola are all
real and distinct is :
(A)
{(K, 0): K 2}
(B)
{(K, 0): K > 2}
(C)
{(0, K): K > 2}
(D)
{(K, 0): K > 0}
47.
(A)
48.
7 : 19 : 25
(B)
If a , b are orthogonal unit vectors then for a vector r , non-coplanar with a and b , the vector r a is
equal to :
(A)
(C)
r a b b +
r a b a +
(r b )b a
(r a )a b
(B)
r a b a + b
(D)
None of these
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49.
Let f n ( x ) =
(A)
n +1 n
x . The value of
( n 1)!
f n ( x ) dx is :
0
n =1
(C)
2e
(B)
(D)
None of these
50.
The value of
( 4n +1 C j + 4n +1C2n j ) is :
j=0
(A)
51.
24 n +
4n + 1
Cn
2 4 n +1
(B)
(C)
2 4 n +1 +
4n + 1
Cn (D)
24n
Let f and g are two functions such that f (x) and g (x) are continuous in [a, b] and differentiable in (a, b).
Then at least one c ( a, b ) such that f ( c ) =
I.
II.
III.
If f ( x ) = f ( b ) , then f ( c ) = 0
If g ( x ) 0 , then
tan
(LMVT)
f (b) f ( a )
g (b) g ( a )
, then
(B)
ba
(RMVT)
f ( a ) f ( b ) and a b
f (b ) f ( a )
f (c)
(cauchy theorem)
g(c)
sin sin
is equal to :
cos cos
tan
(C)
cot
(D)
cot
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52.
53.
If f ( x ) =
f (a )
ex
1+ e
, I1 =
x g {x (1 x )}dx and I 2 =
f ( a )
f (a )
f (a)
I2
is :
I1
(A)
S1 :
Radius of great circle of section of a plane with a sphere is equal to the radius of the sphere.
S2 :
Points
(B)
( x1 , y1 , z1 )
and
(C)
( x2 , y2 , z2 )
(D)
S3 :
S3 :
(A)
54.
TFTT
(B)
FFTT
(C)
TTFF
(D)
FTFT
(A)
(C)
n 2 n5 + 2 tan 1 2 1
2
2
3
5
1
n 2 n5 + 2 tan 1 2 + 1
2
2
4
5
(B)
(D)
n 2 n5 + 2 tan 1 2 + 1
2
2
4
5
1
n 2 n5 + 2 tan 1 2 1
2
2
4
5
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SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which one
or More Choices may be Correct:
55.
2
1
and P ( A B ) = . Then P(B) is equal
15
6
to :
(A)
56.
(B)
(C)
(D)
5
4
A plane parallel to x + y + z = 3 and at distance
from it has the equation :
3
(A)
(B)
x 2y z = 0
x + y + z +1 = 0
(C)
57.
4
5
2x y z =
3 3+4
3
(D)
ABC is right-angled
(C)
a:c=3:1
3
. Then :
5
(B)
(D)
5
6
x+ y+z=7
ABC is obtuse-angled
a : c = 5 :1
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58.
Let c = a + b + a b where a and b are unit vectors such that a b = 0 . Then :
(A)
=b c
(B)
= a c
(C)
= a b c
(D)
+ + = a + b + a b c
59.
60.
1 + 2 cos 2 1
(B)
2 + sin 2 1
f (10 ) =
f ( 20 ) =
1
2
1
2
(C)
3
4
+8
1
2 20
+ 19
7
8
15
16
2 + cos 2
(D)
1 + log 2
+ . . . is f (n) then :
(B)
f (10 ) =
(D)
f ( 30 ) =
1
210
1
230
+9
+ 31
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