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NDI
G YA
N
Presents
C.B.S.E.
12th Class
CHEMISTRY
MOCK TEST PAPER
with
SOLUTIONS
NAGPUR CENTRE
JABALPUR CENTRE
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WRIGHT TOWN
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Technocrate Classes,
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www.momentumacademy.com
Page 2 of 12
Time : 3 Hours
Maximum Marks : 70
GENERAL INSTRUCTIONS
i.
ii.
iii.
iv.
v.
vi.
1.
2.
3.
Refining of which metal is done by using Monds precess ? What is the compound formed in this process?
4.
Lower alcohols are soluble in water, higher alcohols are not. Why ?
6.
7.
N H ( C H 3 )2 O C O C H 3
8.
9.
Aluminium metal forms a cubic face centred close packed crystal structure. Its atomic radius is 125 10 12 m
(a) Calculate the length of the side of the unit cell.
(b) How many unit cell are there is
1.0 m3 of aluminium ?
10.
What type of defect can arise when a solid is heated ? Which physical property is affected by it and in what
way ?
11.
12.
34.2 g L1 of sucrose
90 g L1 of glucose
18g of glucose
(b)
60 g L1 of urea
(d)
58.5 g L1 of NaCl
(C6 H12O6 ) is dissolved in 1kg of water in a saucepan. At what temperature will water boil
Page 3 of 12
13.
What aspect of a reaction is influenced by presence of catalyst which increases the rate or possibility of the
reaction ?
14.
The extractin of
15.
16.
Au by leaching with NaCN involves both oxidation and reduction. Justify giving equations.
(a)
XeF2 + H 2O
(b)
XeF6 + H 2O
(c)
XeF6 + PF5
(d)
XeF6 + NaF
17.
CH 3 Br or CH 3 I
(ii)
CH 3 Br or (CH 3 )3 CBr
S N 2 reaction ?
(b) Why does not ammonolysis of alkyl halides yield pure amines ?
18.
Describe laboratory prepareation of chloroform . Why is stored in dark coloured bottle ? Give four main
uses of chloroform.
19.
The catalytic decomposition of hydrogen peroxide was studied by titrating it at different intervals with
KMnO4 . Calculate the rate constant from the following data, assuming the reaction to be of first order.
t(sec)
600
1200
KMnO4 ( mL )
22.8
13.8
8.2
20.
What are emulsions ? What are their different types ? Give an examples of each type.
21.
22.
O2 and N 2 .
(b)
(b)
(c)
NO is paramagnetic in the gaseous state but diamagnetic in the liquid and solid states.
Page 4 of 12
23.
(a) Name the reagents and write the chemical equations for the preparation of the following compounds by
Willamsons synthesis :
(i) Ethoxybenzene
(ii) 2-Methyl-2-methoxypropane
(b) Why do phenols not give protonation reaction readily ?
24.
25.
26.
27.
(a) What is the problem with hard water for washing clothes with soap ?
(b) Explain the following terms :
(i) Broad spectrum antibiotics
28.
NaBr and NaI in aqueous solution liberate Br2 and I 2 respectively while that of
F = 96500 mol 1
Page 5 of 12
(ii)
(b) What is meants by lanthanoid contraciton? What effect does it have on the chemistry of the elements
which follow lanthanoids ?
30.
C5 H10O . The compound (B) gives iodoform test but does not reduce ammonical silver nitrate.
The compound (B) on reduction with Zn Hg / HCl gives compound (C) with molecular formula
C5 H12 .
C5 H10O forms phenyl hydrazone with phenyl hydrazine and gives negative Tollen
test and iodoform test. On reduction of compound (A), n-pentane is obtained. Identify the compound (A).
SO
LU
TI
O
N
S
Page 7 of 12
SOLUTION
1.
2.
M =
(a)
M=
60
= 1 mol L1 , = iMRT = 1 RT = RT
60
(c)
M =
60
= 0.5 mol L1 ,
180
Ni (CO) 4
3.
Nickel,
4.
Coordination isomerism
5.
34.2
= 0.1 mol L1 ,
342
(d)
58.5
= 1 mol L1 ,
58.5
6.
O
||
C H 3 C C C H = C H C O H
WB =
12.
M B Tb WA
WB K b
or Tb =
Kb
M B WA
7.
N , N Dimethylaniliniumethanoate
8.
Mass of solute
(WB ) = 18 g
C 1
Mass of water
(WA ) = 1kg
9.
Radius
(r ) =
a
Tb =
2 2
a = r 2 2 = 125 1012 2 2m
= 125 2 1.414 10 12 = 354 10 12 m
(b) Volume of unit cell
Al =
10.
11.
(1.0m 2 )
= 2.25 1028
29 3
(4.436 10 m )
MB =
K 2 SO4
WB R T
+V
WB = 0.8960 g ,
V =
500
= 0.5 L, T = 27C = 300 K
1000
Page 8 of 12
K 2 SO4 = 2 39 + 32 + 4 16
= 78 + 32 + 64 = 174g mol 1
Vant Hoff factor (i)
=
13.
18.
C l3 C C H ( O H ) 2 + N a O H
C h lo ra llh y d ra te
14.
CHCl3 + HCOONa + H 2O
It is stored in dark coloured bottles because it
reacts with
2 C O C l2 + H C l
light
2 C H C l 3 + O 2
Oxidation :
P hosgene
C hlorofo rm
Uses :
It is used as solvent.
It is used for preparation of chloretone which is
hypnotic drug (sleep inducing drug)
It is used in preparation of chloropicrin which is
used as tear gas as well as a insecticide.
It is used for testing of primary amines by
carbylamine reaction.
+4NaOH
in this reaction;
Reduciton :
Au is oxidised to Au + ions
(i)
(ii)
(iii)
(a)
2 XeF2 + 2 H 2O 2 Xe + 4 HF + O2
(b)
XeF6 + 3H 2O XeO3 + 6 HF
(iv)
Au
19.
k=
(i) [ Fe(CN )3 ( NH 3 )3 ]
k=
2.303
a
log
t
ax
(ii) [ Fe(OH )( NH 3 ) 2 ]2
2.303
22.8 2.303
=
log
[log 22.8 log13.8]
600
13.8
600
=
2.303
[1.3579 1.1399]
600
2.303
[0.2180] = 8.37 104 s 1
600
[ Pt ( NH 3 )3 ]( NCS )( SCN )
k=
2.303
22.8
log
1200
8.2
2.303
[log 22.8 log8.2]
1200
2.303
[1.3579 0.9138]
1200
2.303
[0.4441] = 8.52 104 s 1
1200
(i)
hindrance as comnpared to
(CH 3 )3 CBr
Page 9 of 12
= 8.455 10 s
(a)
(b)
21.(a)
P
H
(c)
(a)
(b)
2 N O + O2 2 N O2
(Bro w n )
(colou rless)
(c)
H 2O molecules.
in case of
NCl3 + 3H 2O NH 3 + 3HClO
ions to form
Therefore
22.(a)
S 2 molecules
OH
OH
( H 2 SO4 ) .
All the orbitals in argon are occupied by the
electrons and are completely filled hence it has
no tendency to lose gain or share electrons with
other atom of Ar to form diatomic molecule.
OH groups and
(b)
( H 3 PO3 )
1
8.37 104 + 8.52 104 s 1
2
4
20.
(b)
ONa
23.(a)(i)
OC2H 5
+ C2H 5 - Br
+ N aB r
B rom oethane
S odiu m
phe noixde
E th oxyb enzene
Page 10 of 12
CH 3
OH
C H 3 - C - O N a+ + C H 3 B r
(ii)
B rom om ethan e
CH 3
warm
H 2O
S odiu m
tert. butoxide
CH 3
C H 3 - C - O CH 3 + N aBr
25.(a)
(b)
(c)
CH 3
2-M eth yl-2-m e thoxypropane
(b)
24.(a) ( C H 3 ) C = O
2
NH 2 OH
( C H 3 )2 C = N O H
H 2O
26.
A ceto xine
A cetone
LiAlH 4
Reduction
( C H 3 )2 C H N H 2
Iso propylam ine
CHO
(i)
(ii)
(iii)
27.(a)
COOH
NH 3
( Heat )
Oxidation
(b)
B enzalde hyd e
B enzoic acid
CN
CONH 2
2C 17 H 3 5 C O O N a + C a 2 +
( P2O5 / heat )
H 2O
NO2
(C17 H 35C O O ) 2 C a
3+
Br2 / Fe
N itrobenzen e
Br
m -Brom onitrobenzen e
Sn / HCl
Reduction
NH 2
m -Brom oa niline
2Na+
N 2C l
Diazotisation
Br
NO2
(c)
Br
D iazonium salt
Page 11 of 12
28.(a)
= 1.08 0.208
= 1.288V
Ecell
= ERight
ELeft
(b)
Zn ( s ) + Cd 2+ ( aq ) Zn 2+ ( aq ) + Cd ( s )
By Nernst equation
Here
be reduced to
Zn 2 +
0.0591
log
n
Cd 2+
Ecell = Ecell
29.(a)
(b)
follows :
G = nFEcell
= 2 96500 0.438
= 84535 J = 84.53 kJ
(b)
(c)
(a)
(d)
At anode : 2 Br
At cathode :
O2 gas.
(oxidation)
( aq ) Br2 (l) + 2e
2 Br
Here
( aq ) + 2 H ( aq ) Br2 (l ) + H 2 ( g )
(e)
n=2
Ecell = Ecell
[ Br2 ][ H 2 ]
0.0591
1 1
= 1.08
log
2
2
2
[0.01] [0.03]
2
(a)
K 2Cr2O7 and
equations :
H 2 ) =1 atm
108
9
(Partial pressure of
Cr 3+ / Cr 2 + couple.
In Sc the last electron enters the 3d orbital.
Therefore it is regarded as transition element.
OR
2.303RT
log
2
2
nF
H + Br
[Br2 ] = 1 and [H 2 ] = PH
Cr 3+ has
2 H + 2e H 2 ( g ) (Reduction)
+
OR
As given in the cell representation anode is on
LHS and cathode is RHS.
0.0591
4 104
log
n
2 101
take place : F2 + 2 I 2 F + I 2
n=2
Ecell = Ecell
=
(i)
electrolysis
MnO4 + e
MnO42
3d and 4d series.
Page 12 of 12
(ii)
30.
(a)
COOH
HOOC
2 7
C H 3 C H 2 C H 2 C H 2 O H
Acidified KlCr O
B utan-l-o l
C H 3C H 2 C H 2 C O O H
B utanoic acid
(e)
Ammoniacal AgNO3
C H 3 C H 2 C H 2 C H O
(Tollen ' s reagent )
B utanal
(b)
HBr
KCN
C 6 H 5 C H 2 O H
C 6 H 5 C H 2 B r
B e n z y l a lc o h o l
B e n z y l b ro m id e
H 3O +
C 6 H 5C H 2C N
C 6 H 5C H 2C O O H
P h e n y le th a n o ic a c id
B e n z y l c y a n id e
OH
(c)
C H 3C H 2 C H 2 C O O H
Mg
ether
O2 N
(a)
B utanoic acid
OR
A careful study of the given data indicates that B
is an ketone not an aldehyde. The formation of B
(methyl ketone) on oxidation of A indicates that
A is sec-alcohol which gives methyl ketone on
oxidation. It means that A is 2-pentanol the
compound B on reduction (i.e. 2-pentanone) gives
n-pentane
Oxidation
C H 3 - C H - C H 2 C H 2 C H 3
[O ], H 2O
OH
M gB r
CO2
( dry ice )
O2N
2-pen tanol (A )
C H 3 - C - C H 2 C H 2C H 3
O
B utanoic acid
O
C
O M g B r
H 3O +
C H 3 - C - C H 2 C H 2C H 3
O
O2N
2-penta none(B )
(M ethylketone)
gives iodoform test
O
C
OH
Reduction
Zn Hg / HCl
C H 3C H 2 C H 2 C H 2 C H 3
n-pen tane (C )
m olecular
form ula C 5 H 12
2-pentanone does not reduce ammonical
O2N
3-N itroben zoic a cid
COCH 3
(d)
KMnO4 / KOH
H 3C
COOK
KOOC
D ipo tassium benzen e
1,4-dicarboxylate
C H 3 - C - C H 2C H 2C H 3 + 3 I 2 + 4 N a O H
C H 3 I + 3 N a I + C H 3C H 2 C H 2 C O O N a + 3 H 2 O
dil . H 2 SO4
yellow
ppt
(b) The compound (A) is 3-pentanone i.e.