MSC Che Final 0910

M P BHOJ (OPEN) UNIVERSITY, BHOPAL
ASSIGNMENT QUESTION PAPER

2009-10
CLASS : M.Sc. Final Year SUBJECT : Chemistry
PAPER : I – Application of spectroscopy photo Chemistry and solid state
Chemistry
funsZ'k %&
1- lHkh iz'u Lo;a dh gLrfyfi esa gy djuk vfuok;Z gSA 2- nksuksa l=h; iz'ui= gy djuk vfuok;Z gsa
3- l=h; dk;Z mÙkjiqfLrdk ds vafre i`"B ij lacaf/kr fo"k; dh laiUu 4- vafre frfFk mijkar l=h; dk;Z mÙkjiqfLrdkvksa dks ekU; ugha djrs
laidZ d{kkvksa dh frfFk;ksa ,oa ijke'kZnkrk ds uke ,oa in dk gq, ewY;kafdr ugha dh tkosxhA
vo'; mYys[k djsaA
5- l=h; dk;Z mÙkjiqfLrdk,a tek djus dh vafre frfFk 20 6- l=h; dk;Z mÙkjiqfLrdk,a tek djus dh jlhn vo'; izkIr dj ysaA
vizsy 2010 gSA
7- nks l=h; dk;Z izkIrkadksa esa ls fdlh ,d esa vf/kdre vad dh iwoZ izpfyr O;oLFkk ds LFkku ij nksuksa l=h; dk;ksZa ds izkIrkadksa
ds vkSlr vad l=kar ijh{kk ifj.kke esa tksM+s tk,axsA lHkh iz'uksa ds vad leku gSaA
First Assignment Max Marks - 30

Q.1 Explain the shapes and symmetry of AB2 , AB3 , AB4 and AB6 molecules. OR
Details study of Woodward Rules for corbonyl Compound and butadiene.
Q.2 Write Note on the following -

(A) Chemical shift. (B) Spin – Spin Interaction . (C) Shielding mechanism.
OR Define the two dimensional NMR Spectroscopy COSY and INEPT.
Q.3 Describe the bonding and Structure of Fe2+ and Fe3+ Compounds including those
of inter mediate Spin. OR Define ORD and CD.
Q.4 Describe the cyclisation reaction rearrangement of 1, 4 and 1, 5 dienes. OR

Explain the photochemistry of aromatic compound.
Q.5 Explain the intrinsic and extrinsic defects. OR Describe the organic charge
transfer complex and new superconductors.
Second Assignment Max Marks - 30

Q.1 Describe the Characteristic vibrational Frequencies of alkenes, alkynes, alcohol
and phenol. OR Write note on the following -
(A) Overtones and Combination Band. (B) Fermi Resonance. (C) Beer-Lambert
Law.
Q.2 Explain the Complex Spin – Spin Interaction Between two, three, four
five and other Nuclei. OR Write Notes on the following -
(A) Contact Shift Reagent. (B) NOE. (C) DEPT.
P.T.O.
From Pre Page
Q.3 Describe the types of excitation and fate of excited molecules. OR Write Note on
the following -
(A) Photo dissociation. (B) Gas-phase photolysis. (C) octant Rule for ketone.
Q.4 Describe the photo Fries rearrangement and Barton Reaction. OR Write Note on
the following –
(a) Oxetane formation. (b) Photo chemistry of vision. (c) cyclo hexa dienones.
Q.5 Describe the general principle and experimental procedures of solid state
reactions. OR Explain the metals, insulators and semi-conductors.
2009-10
PAPER : II – Bio-inorganic Chemistry, Bio-organic chemistry
and Bio physical chemistry
funsZ'k %&
vo'; mYys[k djsaA
vizsy 2010 gSA

Q. 1 Explain the Biological cell structure and functions of proteins and enzymes. OR
Define the transport and storage of dioxygen.
Q. 2 Write the Standard free energy change in biochemical reactions. OR Explain the
electron transfer in biology.
Q. 3 Define the forces involving in biopolymer interaction. OR Explain the polypeptide
and protein structures.
Q. 4 Write the fischer's lock and key and koshlands induced fit hypothesis. OR Define
the typical enzyme mechanism for ribonuclease lysozyme.
Q. 5 Define the structure and function of co-enzyme A. OR Explain the recombinant
DNA technology.

+ +
Q. 1 Describe the Na /K Pump. OR Write note on essential and trace metals.
Q. 2 Explain the hydrolysis of ATP and synthesis of ATP from ADP. OR Describe the
photo System I and photo system II.
Q. 3 Write notes on the chain configuration of macromolecules. OR Define the
diffusion and sedimentary Velocity method.
Q. 4 Write note on the following
(A) Michaelis – Menten and lineweaver Burkplots. (B) Transition state theory.
OR Explain the multiple displacement reaction and the coupling of ATP cleavage
to eridergonic process.
Q. 5 Write Notes on the following
(A) NAD (B) NADP (C) FAD
OR Describe the technique and method of immobilization of enzyme.
2009-10
PAPER : III – Environmental Chemistry
funsZ'k %&
vo'; mYys[k djsaA
vizsy 2010 gSA

Q. 1 Describe the C and S cycle. OR Explain the Biodistribution of elements.
Q. 2 Write note on the aquatic pollution. OR Describe the BOD, DO and COD.
Q. 3 Explain the soil composition, macro and micro nutrients. OR Describe the
fertilizer and pesticides pollution.
Q. 4 Explain the green house effect. OR Write notes on the following -

(A) CFC (B) Smog Formation
Q. 5 Details study of cement Industry pollution. OR Writs notes on the Bhopal gas
tragedy.

Q. 1 Explain the environmental composition of atmosphere. OR Describe the N & P
cycle.
Q. 2 Describe the purification and treatment of waters. OR Write note on the following
(A) Residual chloride. (B) chlorine demand.
Q. 3 Explain the plastic and metals pollution. OR Explain the waste water treatment
process.
Q. 4 Describe the oxides of N, C, S and O and their effect. OR Explain the chemical
and photo chemical reaction in atmosphere.
Q. 5 Detail study of thermal power plant pollution. OR Write notes on the minamata
disasters.
2009-10
PAPER : IV – Organo transition metal Chemistry
funsZ'k %&
vo'; mYys[k djsaA
vizsy 2010 gSA

Q. 1 Discuss about the stability and become position pathways of the aryls of transition
metal. OR Explain the Organocopper inorganic synthesis of the Alkyls of
transition metals.
Q. 2 Explain the nucleophilic and eletrophilic reactions of the ligands. OR Describe the
carbenes of transition metal carbon multiple bond .
Q. 3 Explain the Important reaction relating to Nucleophilic and eletrophilic attach an
ligand. OR Discuss the alkenes and alkynes transition metal π - complexes.
Q. 4 Explain the Zeigler Natta polymerisation. OR Discuss the Oxo Reaction.
Q. 5 Explain the Fluxionality and dynamic equilibrium in η2 - olefin Compound. OR
Explain the Fluxional organometallic Compounds.

Q. 1 Describe the alkyl transition metal types and Routes of synthesis. OR Explain the
stability and decomposing pathway of alkyl transition metals.
Q. 2 Write the note an carbines synthesis and Nature of Bond . OR Explain the
synthesis and Nature of bond alkylidenes.
Q. 3 Discuss the allyl and arene transition metal π complexes. OR Explain the
structure bonding preparation of diene compound.
Q. 4 Discuss the transition metal compouneds with bond of hyolrgen. OR Explain the
stoichimetric reaction for catalysis.
Q. 5 Explain the fluxionality and dynamic equilibrium in η3 allyl compound. OR Write
notes of Fluxionality dienyl complexes
2009-10
PAPER : IV (B) – Medicinal Chemistry
funsZ'k %&
vo'; mYys[k djsaA
vizsy 2010 gSA

Q. 1 Explain the history and development of QSAR OR Discuss about the free –wilson
and Hansh analysis
Q. 2 Explain the uses of pharmacokinetics in drug development process. OR Write a
short note on the significance of drug metabolism in medicinal chemistry.
Q. 3 Explain the synthesis of mechlor ethamine melphalan and uracil. OR Write notes
the following
(A) Amyl Nitrate. (B) Sorbitrate
Q. 4 Explain the synthesis of chloroquin . OR Discuss the synthesis of diazepam.
Q. 5 Explain the Synthesis of Penicillin-V. OR Write short note on the following -
(A) Tetracycline. (B) Streptomycin.

Q. 1 Explain the concept of lead compound and lead modification. OR Describe the
drug occupancy theory and rate theory.
Q. 2 Describe the absorption, disposition and elimination using pharmacokinetics. OR
Explain the Drug metabolism and Xenobiotics.
Q. 3 Discuss the Cancer chemotherapy. OR Describe the cardiovascular drug.
Q. 4 Write notes on the following -
(A) Sulphonamides (B) Nalidilic acid
OR Discuss the Antipsychotic Drug.
Q. 5 Describe the antibiotics cell wall synthesis and β - lactum ring . OR Write notes
on the following -
(A) Penicillin - G (B) Ampicillin
2009-10
PAPER : V – Chemistry of Natural Products
funsZ'k %&
vo'; mYys[k djsaA
vizsy 2010 gSA

Q. 1 Discuss about the general methods of structure determination of terpenoids and
carotenoids. OR Discuss the biosynthesis of α - Terpeneol and β – carotene.
Q. 2 Explain the physiological action and nomenclature of alkaloids. OR Discuss the

role of alkaloids in plants.
Q. 3 Explain the synthesis of cholesterol. OR Discuss the biosynthesis of steroids.
Q. 4 Explain the synthesis of Myrcetin. OR Discuss the synthesis of luteolin.
Q. 5 Explain the Synthesis of haemoglobin. OR Discuss the synthesis of PGE2.

Q. 1 Explain the synthesis of phytol. OR What is isoprene rule. Discuss about the
synthesis of citrol.
Q. 2 Discuss about the general methods of structure elucidation of Alkaloids. OR

Explain the occurrence and isolation of alkaloids.
Q. 3 Explain the occurrence and stereochemistry of steroids. OR Discuss about the

synthesis of progesterone.
Q. 4 Explain the synthesis of cyanidin. OR Discuss about the synthesis of Butein.
Q. 5 Explain the occurrence and Classification of prostaglandins. OR Discuss about the

synthesis of PGF2 α
2009-10
PAPER : V (B) – Analytical Chemistry
funsZ'k %&
vo'; mYys[k djsaA
vizsy 2010 gSA

Q. 1 Explain the role of analytical chemistry. OR Discuss about the laboratory
operations and practices.
Q. 2 Write the short notes on following
(A) Standard deviation (B) Mean and Median
OR Explain the types of error in experimental data determination.
Q. 3 Explain the Thin layer chromatography for the identification of Chlorinated
Pesticides in food products. OR What is food adulteration. Discuss about the
common adulterants in food.
Q. 4 Explain the types of water pollution. OR Explain the measurements of DO, BOD.
Q. 5 Explain the Principles and applications of radio immunoassay (RIA). OR Discuss
about the clinical analysis of blood glucose.

Q. 1 Write a short notes on safety in the analytical laboratory. OR Discuss about the
types of instrumental analysis.
Q. 2 Discuss the sources of errors and the effects upon the analytical results. OR
Explain the method for reporing analytical data.
Q. 3 Explain the extraction and purification of food sample by HPLC. OR Explain the
pesticide analysis in food products.
Q. 4 Discuss about the origin of waste water. OR Write a short note on heavy metal
pollution.
Q. 5 How to analysis the pH and total nitrogen in given soil sample. Explain it. OR
Discuss about the classification of drugs.

MSC Che Final 0910

Transféré par

Informations du document

Titre original

Copyright

Formats disponibles

Partager ce document

Partager ou intégrer le document

Options de partage

Avez-vous trouvé ce document utile ?

Ce contenu est-il inapproprié ?

Droits d'auteur :

Formats disponibles

MSC Che Final 0910

Transféré par

Droits d'auteur :

Formats disponibles

M P BHOJ (OPEN) UNIVERSITY, BHOPAL

ASSIGNMENT QUESTION PAPER

First Assignment Max Marks - 30

Q.2 Write Note on the following -

Q.4 Describe the cyclisation reaction rearrangement of 1, 4 and 1, 5 dienes. OR

Second Assignment Max Marks - 30

First Assignment Max Marks - 30

Second Assignment Max Marks - 30

First Assignment Max Marks - 30

Q. 4 Explain the green house effect. OR Write notes on the following -

Second Assignment Max Marks - 30

First Assignment Max Marks - 30

Second Assignment Max Marks - 30

First Assignment Max Marks - 30

Second Assignment Max Marks - 30

First Assignment Max Marks - 30

Q. 2 Explain the physiological action and nomenclature of alkaloids. OR Discuss the

Q. 3 Explain the synthesis of cholesterol. OR Discuss the biosynthesis of steroids.

Q. 4 Explain the synthesis of Myrcetin. OR Discuss the synthesis of luteolin.

Q. 5 Explain the Synthesis of haemoglobin. OR Discuss the synthesis of PGE2.

Second Assignment Max Marks - 30

Q. 2 Discuss about the general methods of structure elucidation of Alkaloids. OR

Q. 3 Explain the occurrence and stereochemistry of steroids. OR Discuss about the

Q. 4 Explain the synthesis of cyanidin. OR Discuss about the synthesis of Butein.

Q. 5 Explain the occurrence and Classification of prostaglandins. OR Discuss about the

First Assignment Max Marks - 30

Second Assignment Max Marks - 30

Vous aimerez peut-être aussi