04 Apr 2015 A

This booklet contains 40 printed pages.
S c 40
PAPER - 1
S -
LMN
: PHYSICS, CHEMISTRY & MATHEMATICS

1 : , U
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PART A PHYSICS
1.
Two stones are thrown up simultaneously
1.
from the edge of a cliff 240 m high with

initial speed of 10 m/s and 40 m/s
respectively. Which of the following graph
best represents the time variation of
relative position of the second stone with
240 m U U ,
U U U ,
U 10 m/s 40 m/s , ,
() U
U U S U
(U) ?
respect to the first ?

(Assume stones do not rebound after
hitting the ground and neglect air
resistance, take g510 m/s2)
( , U UU
U U U U
, g510 m/s2)
scale)
( S U U S
U )
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
(The figures are schematic and not drawn to
A/Page 2
SPACE FOR ROUGH WORK /
2.
The period of oscillation of a simple

pendulum is T 5 2p
2.
L
. Measured value
g
U ,
L
20.0 cm
T 5 2p
L
g
100
90 s , 1s ,
g U
1 mm
of L is 20.0 cm known to 1 mm accuracy

and time for 100 oscillations of the
pendulum is found to be 90 s using a wrist
watch of 1s resolution. The accuracy in
the determination of g is :
(1)
2%
(1)
2%
(2)
3%
(2)
3%
(3)
1%
(3)
1%
(4)
5%
(4)
5%
3.
3.
Given in the figure are two blocks A and B

of weight 20 N and 100 N, respectively.
These are being pressed against a wall by
a force F as shown. If the coefficient of
friction between the blocks is 0.1 and
between block B and the wall is 0.15, the
U (U) A U B
U 20 N 100 N ,
F mU U U U
, A B 0.1
B U U 0.15 , U mU
B U
frictional force applied by the wall on block

B is :
(1)
100 N
(1)
100 N
(2)
80 N
(2)
80 N
(3)
120 N
(3)
120 N
(4)
150 N
(4)
150 N
A/Page 3
4.
A particle of mass m moving in the
4.
x direction with speed 2v is hit by another

particle of mass 2m moving in the
y direction with speed v. If the collision is
perfectly inelastic, the percentage loss in
x-
2v m
, y- v 2m
, UU UU (UU)
S , UU U
()
the energy during the collision is close to :
5.
(1)
44%
(1)
44%
(2)
50%
(2)
50%
(3)
56%
(3)
56%
(4)
62%
(4)
62%
Distance of the centre of mass of a solid
5.
uniform cone from its vertex is z0. If the
radius of its base is R and its height is h

then z0 is equal to :
U
U z0 U
R h z0
UU ?
(1)
h2
4R
(1)
h2
4R
(2)
3h
4
(2)
3h
4
(3)
5h
8
(3)
5h
8
(4)
3h 2
8R
(4)
3h 2
8R
A/Page 4
6.
From a solid sphere of mass M and radius
6.
R a cube of maximum possible volume is

cut. Moment of inertia of cube about an
axis passing through its center and
perpendicular to one of its faces is :
7.
(1)
MR 2
32 2p
(2)
MR 2
16 2p
(3)
4MR 2
9 3p
(4)
4MR 2
3 3p
From a solid sphere of mass M and radius

R
is
R, a spherical portion of radius
2
removed, as shown in the figure. Taking
7.
gravitational potential V50 at r5:, the

potential at the centre of the cavity thus
formed is :
(G5 gravitational constant)
U M
R
() U
, , -,
U $U
U ?
(1)
MR 2
32 2p
(2)
MR 2
16 2p
(3)
4MR 2
9 3p
(4)
4MR 2
3 3p
U
R
2 GM
2R
(1)
2 GM
2R
(2)
2 GM
R
(2)
2 GM
R
(3)
2 2GM
3R
(3)
2 2GM
3R
(4)
2 2GM
R
(4)
2 2GM
R
, U
2
U U r5:() U
L V (V50)
, U UU (U) U,
L
(G5 L SU )
(1)
A/Page 5
8.
A pendulum made of a uniform wire of
8.
cross sectional area A has time period T.

When an additional mass M is added to
its bob, the time period changes to TM. If
the Youngs modulus of the material of the
1
is equal to :
Y
(g5gravitational acceleration)
wire is Y then
9.
(1)
TM
2
A
21
Mg
(2)
TM
2
Mg
21
(3)
T
1 2 M
T
2
A

Mg
(4)
T
1 2
TM
(g5L
Mg
9.
temperature T. The black body radiation

inside it can be considered as an ideal gas
of photons with internal energy per unit
p5
u5
U
; T4
V
and
U)
(1)
2
A
21
Mg
(2)
TM
2
Mg
21
(3)
T
1 2 M
T
2
A

Mg
(4)
T
1 2
TM
Mg
() R U
T U c U U

U ,
pressure
1 U
. If the shell now undergoes
3 V
1
Y
TM
Consider a spherical shell of radius R at
volume
U SU
A
T U M
U
U TM U
p5
1 U

3 V
between T and R is :
(1)
T ; e2R
(1)
T ; e2R
(2)
T ; e23R
(2)
T ; e23R
(3)
T;
(3)
T;
(4)
T;
(4)
T;
A/Page 6
1
R
U
; T4
V
Lc
U , T R
an adiabatic expansion the relation
1
R
u5
1
R
1
R3
10.
A solid body of constant heat capacity
10.
1 J/8C is being heated by keeping it in

contact with reservoirs in two ways :
(i)
Sequentially keeping in contact with

2 reservoirs such that each reservoir
supplies same amount of heat.
(ii)
Sequentially keeping in contact with

8 reservoirs such that each reservoir
supplies same amount of heat.
In both the cases body is brought from

initial temperature 1008C to final
temperature 2008C. Entropy change of the
U U (S) SU c U
1 J/8C c (c UU)
UU U ,
(i)
M 2 c
U UU c
c ,
(ii) M 8 c
U UU c
c ,
S U U 1008C
2008C , S U
U U ,
body in the two cases respectively is :
11.
(1)
ln2, 4ln2
(1)
ln2, 4ln2
(2)
ln2, ln2
(2)
ln2, ln2
(3)
ln2, 2ln2
(3)
ln2, 2ln2
(4)
2ln2, 8ln2
(4)
2ln2, 8ln2
Consider an ideal gas confined in an
11.
isolated closed chamber. As the gas

undergoes an adiabatic expansion, the
average time of collision between
q
molecules increases as V , where V is the

volume of the gas. The value of q is :
Cp
g 5
Cv
( ),
() (U)
Lc U U, UU
() Vq U ,
V q :
Cp
g 5
Cv
(1)
3g 1 5
6
(1)
3g 1 5
6
(2)
3g 2 5
6
(2)
3g 2 5
6
(3)
g11
2
(3)
g11
2
(4)
g21
2
(4)
g21
2
A/Page 7
12.
(graphs are schematic and not drawn to scale)
U , S d
U S d
S
() ?
( S U U S
U )
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
For a simple pendulum, a graph is plotted
12.
between its kinetic energy (KE) and

potential
energy
(PE)
against
its
displacement d. Which one of the

following represents these correctly ?
13.
A train is moving on a straight track with
13.
speed 20 ms21. It is blowing its whistle at

the frequency of 1000 Hz. The percentage
change in the frequency heard by a person
standing near the track as the train passes
him is (speed of sound5320 ms21) close
to :
U (U) UU U 20 ms21
U U U
1000 Hz
320 ms21 , UU U
U U U, mU
U U

(1)
6%
(1)
6%
(2)
12%
(2)
12%
(3)
18%
(3)
18%
(4)
24%
(4)
24%
A/Page 8
14.
A long cylindrical shell carries positive
14.
surface charge s in the upper half and

negative surface charge 2s in the lower
half. The electric field lines around the
cylinder will look like figure given in :
(figures are schematic and not drawn to scale)
15.
U U
cU s cU
2s (UU) U
U l -U,
U ?
( U S U U S
U )
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
A uniformly charged solid sphere of radius

R has potential V0 (measured with respect
15.
to :) on its surface. For this sphere the
equipotential surfaces with potentials
U
cU V0 (: )
,
3V0 5V0 3V0

,
,
2
4
4
V0
4
V
3V0 5V0 3V0
and 0 have radius R1,
,
,
4
2
4
4
R2, R3 and R4 respectively. Then
c U ,
R1, R2, R3 R4 ,
(1)
(1)
(2)
(3)
(4)
A/Page 9
R150 and R2 > (R42R3)

R1 0 and (R22R1) > (R42R3)
R150 and R2 < (R42R3)

2R < R4
(2)
(3)
(4)
R2 > (R42R3)
R1 0 (R22R1) > (R42R3)
R150 R2 < (R42R3)
R150
2R < R4
16.
and are not to scale)
U , C 1mF 3mF
U , 2mF U U Q2
U C M Q2
? (
S U U S U )
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
In the given circuit, charge Q2 on the 2mF

capacitor changes as C is varied from 1mF
16.
to 3mF. Q2 as a function of C is given

properly by : (figures are drawn schematically
17.
When 5V potential difference is applied
17.
across a wire of length 0.1 m, the drift

speed of electrons is 2.531024 ms21. If
the electron density in the wire is
831028 m23, the resistivity of the material
0.1 m
U U 5V UU
U U U
2.531024 ms21 U U
831028 m23 ,
U ,
is close to :
(1)
1.631028 Vm
(1)
1.631028 Vm
(2)
1.631027 Vm
(2)
1.631027 Vm
(3)
1.631026 Vm
(3)
1.631026 Vm
(4)
1.631025 Vm
(4)
1.631025 Vm
A/Page 10
18.
18.
resistor is :
(1)
1.3 A, from P to Q
(1)
1.3 A, P
(2)
0A
(2)
0 () A
(3)
0.13 A, from Q to P
(3)
0.13 A, Q
(4)
0.13 A, from P to Q
(4)
0.13 A, P
In the circuit shown, the current in the 1V
19.
Two coaxial solenoids of different radii
19.
carry current I in the same direction. Let
F1
be the magnetic force on the inner
F2
solenoid due to the outer one and
be
the magnetic force on the outer solenoid
1V U
Q U
U , I U
U , U U
U, U U U
F1
U U U, U U
F2
due to the inner one. Then :
(1)
F1 5 F25 0
(2)
F1 is radially inwards and F2 is
(2)
F1
(4)
A/Page 11
F2
F1 is radially inwards and F2 50
F1 is radially outwards and F2 50
F1 5 F25 0
radially outwards
(3)
(1)
(3)
(4)
F1
F1
U U U () U
U U U
U U U
F2 50
U U U
F2 50
20.
20.
Two long current carrying thin wires, both

with current I, are held by insulating
threads of length L and are in equilibrium
as shown in the figure, with threads
making an angle u with the vertical. If
wires have mass l per unit length then the
value of I is :
U I U U
L lU U
mU U
u S , U S
U U
l g L U , I

(g5gravitational acceleration)
(1)
sinu
(2)
2sinu
(3)
(4)
A/Page 12
plgL
m0 cosu
(1)
sinu
(2)
2sinu
pgL
tan u
m0
(3)
plgL
tan u
m0
(4)
plgL
m0 cosu
plgL
m0 cosu
plgL
m0 cosu
pgL
tan u
m0
plgL
tan u
m0
21.
figures below :
5 cm U
() l U, I 5 12 A, U
U U U
(S) U
(a)
(a)
(b)
(b)
(c)
(c)
(d)
(d)
If there is a uniform magnetic field of
equilibrium and (ii) unstable equilibrium ?
0.3 T
, z l ,
, () (i) S
(ii) S , ?
(1)
(a) and (b), respectively
(1)
(a) (b)
(2)
(a) and (c), respectively
(2)
(a) (c)
(3)
(b) and (d), respectively
(3)
(b) (d)
(4)
(b) and (c), respectively
(4)
A rectangular loop of sides 10 cm and
21.
5 cm carrying a current I of 12 A is placed

in different orientations as shown in the
0.3 T in the positive z direction, in which

orientations the loop would be in (i) stable
A/Page 13
10 cm
(b) (c)
22.
An inductor (L50.03H) and a resistor
22.
(R50.15 kV) are connected in series to a

battery of 15V EMF in a circuit shown
below. The key K1 has been kept closed
for a long time. Then at t50, K1 is opened
and key K 2 is closed simultaneously.

At t51ms, the current in the circuit will
be : (e5@150)
23.
U , U (L50.03H)
U (R50.15 kV) 15V l
(..) UU
K1 U
t50 U, K1 U
, K2 t51ms
U, U l U (e5@150)
(1)
100 mA
(1)
100 mA
(2)
67 mA
(2)
67 mA
(3)
6.7 mA
(3)
6.7 mA
(4)
0.67 mA
(4)
0.67 mA
the diode is :
U ..U. ( UU)
0.1 U U, U
UU 1 m U U, l

(1)
1.73 V/m
(1)
1.73 V/m
(2)
2.45 V/m
(2)
2.45 V/m
(3)
5.48 V/m
(3)
5.48 V/m
(4)
7.75 V/m
(4)
7.75 V/m
A red LED emits light at 0.1 watt uniformly
23.
around it. The amplitude of the electric

field of the light at a distance of 1 m from
A/Page 14
24.
Monochromatic light is incident on a glass
24.
prism of angle A. If the refractive index of

the material of the prism is m, a ray,
incident at an angle u, on the face AB
would get transmitted through the face AC
A U
,
m , AB
U, u U,
AC U
of the prism provided :
25.
(1)
1
u > sin21 m sin A 2 sin21
(1)
1
u > sin21 m sin A 2 sin21
(2)
1
u < sin21 m sin A 2 sin21
m
(2)
1
u < sin21 m sin A 2 sin21
m
(3)
1
u > cos21 m sin A 1 sin21
(3)
1
u > cos21 m sin A 1 sin21
(4)
1
u < cos21 m sin A 1 sin21
(4)
1
u < cos21 m sin A 1 sin21
that as it travels, the light beam :
c U , - U,
U -
, -U-
U , h
U ,
-U
(1)
becomes narrower
(1)
()
(2)
goes horizontally without any
(2)
,
U
On a hot summer night, the refractive
25.
index of air is smallest near the ground and

increases with height from the ground.
When a light beam is directed horizontally,
the Huygens principle leads us to conclude
deflection
(3)
bends downwards
(3)
(4)
bends upwards
(4)
U U
A/Page 15
26.
resolve at 500 nm wavelength is :
0.25 cm, U
ScU U 25 cm ,
500 nm U , S
U
U ?
(1)
1 mm
(1)
1 mm
(2)
30 mm
(2)
30 mm
(3)
100 mm
(3)
100 mm
(4)
300 mm
(4)
300 mm
Assuming human pupil to have a radius
26.
of 0.25 cm and a comfortable viewing

distance of 25 cm, the minimum separation
between two objects that human eye can
27.
hydrogen - like atom/ion :
U, U U /
S S
U
(1)
(1)
h S

(2)
, S

(3)
, S
U U
(4)

, S
As an electron makes a transition from an
27.
excited state to the ground state of a
its kinetic energy increases but

potential energy and total energy
decrease
(2)
kinetic energy, potential energy and

total energy decrease
(3)
kinetic energy decreases, potential

energy increases but total energy
remains same
(4)
kinetic energy and total energy

decrease but potential energy
increases
A/Page 16
28.
Match List - I (Fundamental Experiment)
28.
with List - II (its conclusion) and select

the correct option from the choices given
- I ( ) - II ( U)
() U

below the list :

List - I
29.
- I
List - II
(A)
Franck-Hertz
Experiment.
(i)
Particle nature
of light
(A)
(B)
Photo-electric
experiment.
(ii)
Discrete energy
levels of atom
(B)
(ii)
(C)
Davison - Germer
Wave nature of
(iii)
Experiment.
electron
(C)
U U
(iii)
(iv)
Structure of
atom
(i)
(iv)
- II

SU
U U
U U
(1)
(A) - (i)
(B) - (iv)
(C) - (iii)
(1)
(A) - (i)
(B) - (iv)
(C) - (iii)
(2)
(A) - (ii)
(B) - (iv)
(C) - (iii)
(2)
(A) - (ii)
(B) - (iv)
(C) - (iii)
(3)
(A) - (ii)
(B) - (i)
(C) - (iii)
(3)
(A) - (ii)
(B) - (i)
(C) - (iii)
(4)
(A) -(iv)
(B) - (iii)
(C) - (ii)
(4)
(A) -(iv)
(B) - (iii)
(C)- (ii)
signal is/are :
()
2 MHz U U U
, U ()

(1)
2 MHz only
(1)
2 MHz
(2)
2005 kHz, and 1995 kHz
(2)
2005 kHz,
(3)
2005 kHz, 2000 kHz and 1995 kHz
(3)
2005 kHz, 2000 kHz
(4)
2000 kHz and 1995 kHz
(4)
2000 kHz
A signal of 5 kHz frequency is amplitude
29.
modulated on a carrier wave of frequency

2 MHz. The frequencies of the resultant
A/Page 17
5 kHz
1995 kHz
1995 kHz
1995 kHz
30.
An LCR circuit is equivalent to a damped
30.
pendulum. In an LCR circuit the capacitor

is charged to Q0 and then connected to
the L and R as shown below :
If a student plots graphs of the square of
2
maximum charge ( QMax
) on the capacitor
with time(t) for two different values L1 and
L2 (L1>L2) of L then which of the following
represents this graph correctly ? (plots are

schematic and not drawn to scale)
(1)
LCR U U
Q0 , U U U
U L R
l L , , L1 L2
(L 1 >L 2) , t U U
2
QMax

?
(U S U S U
)
(1)
(2)
(2)
(3)
(3)
(4)
A/Page 18
LCR (..U) U
(4)
B U
PART B CHEMISTRY
31.
The molecular formula of a commercial
31.
resin used for exchanging ions in water

softening is C8H7SO3Na (Mol. wt. 206).
What would be the maximum uptake of
Ca21 ions by the resin when expressed in
U$ C8H7SO3Na
( U = 206) U$ Ca21
(
U$) ?
mole per gram resin ?
32.
(1)
1
103
(1)
1
103
(2)
1
206
(2)
1
206
(3)
2
309
(3)
2
309
(4)
1
412
(4)
1
412
Sodium metal crystallizes in a body centred
32.
cubic lattice with a unit cell edge of 4.29.

The
radius
of
sodium
atom
is
U
SU U 4.29
U U
approximately :
33.
(1)
1.86
(1)
1.86
(2)
3.22
(2)
3.22
(3)
5.72
(3)
5.72
(4)
0.93
(4)
0.93
possible excited state of hydrogen ?
U S
?
(1)
113.6 eV
(1)
113.6 eV
(2)
26.8 eV
(2)
26.8 eV
(3)
23.4 eV
(3)
23.4 eV
(4)
16.8 eV
(4)
16.8 eV
Which of the following is the energy of a
A/Page 19
33.
34.
The intermolecular interaction that is
34.
dependent on the inverse cube of distance
U-
U U U ,
between the molecules is :
35.
(1)
ion - ion interaction
(1)
(2)
ion - dipole interaction
(2)
- m
(3)
London force
(3)
(4)
hydrogen bond
(4)
The following reaction is performed at
35.
298 K U
298 K.
2NO(g) 1 O 2 (g) 2NO 2 (g)
2NO(g) 1 O 2 (g) 2NO 2 (g)

298 K U NO(g)

86.6 kJ/mol 298 K U NO2(g)
? (Kp51.631012)
The standard free energy of formation of

NO(g) is 86.6 kJ/mol at 298 K. What is
the standard free energy of formation of
NO2(g) at 298 K? (Kp51.631012)
36.
(1)
R(298) ln(1.6310 12)286600
(1)
R(298) ln(1.6310 12)286600
(2)
866001R(298) ln(1.6310 12)
(2)
866001R(298) ln(1.6310 12)
(3)
86600 2
(3)
86600 2
(4)
0.5[2386,6002R(298) ln(1.631012)]
(4)
0.5[2386,6002R(298) ln(1.631012)]
ln (1.6 3 1012 )
R (298)
The vapour pressure of acetone at 208C is
36.
185 torr. When 1.2 g of a non-volatile

substance was dissolved in 100 g of acetone
at 208C, its vapour pressure was 183 torr.
The molar mass (g mol21) of the substance
ln (1.6 3 1012 )
R (298)
208C U
U c 185 torr
208C U, 1.2 g c 100 g
U , c 183 torr
U (g mol21 )

is :
(1)
32
(1)
32
(2)
64
(2)
64
(3)
128
(3)
128
(4)
488
(4)
488
A/Page 20
37.
300 K for the reaction 2A B 1 C is
U 2A B 1 C
$ 2494.2 J
2494.2 J. At a given time, the composition
The standard Gibbs energy change at
of the reaction mixture is [A] 5
37.
1
, [B]52
2
[B]52 U [C] 5
1
. The reaction proceeds in
2
the : [R58.314 J/K/mol, e52.718]
38.
300 K
1
2
[A] 5
and [C] 5
[R58.314 J/K/mol, e52.718]
(1)
forward direction because Q > Kc
(1)
(2)
reverse direction because Q > Kc
(2)
(3)
forward direction because Q < Kc
(3)
(4)
reverse direction because Q < Kc
(4)
Q > Kc
U Q > Kc
Q < Kc
U Q < Kc
Two Faraday of electricity is passed
38.
through a solution of CuSO4. The mass of
copper deposited at the cathode is :
1
,
2
CuSO4
, UU l
U U :
(Cu U 563.5 amu)
(at. mass of Cu563.5 amu)
39.
(1)
0g
(1)
0g
(2)
63.5 g
(2)
63.5 g
(3)
2g
(3)
2g
(4)
127 g
(4)
127 g
Higher order (>3) reactions are rare due
39.
U (>3)
to :
(1)
low probability of simultaneous
(1)
collision of all the reacting species

(2)
increase in entropy and activation
(2)
energy as more molecules are
UU

U U
h
involved
(3)
shifting of equilibrium towards
(3)
reactants due to elastic collisions

(4)
A/Page 21
loss of active species on collision

(4)
U UU U U
SU
UU S$
40.
adsorbed (per gram of charcoal) is :
S 0.06N U 50 mL
3 g cU
U U U S
0.042 N U
(cU- U)

(1)
18 mg
(1)
18 mg
(2)
36 mg
(2)
36 mg
(3)
42 mg
(3)
42 mg
(4)
54 mg
(4)
54 mg
3 g of activated charcoal was added to
40.
50 mL of acetic acid solution (0.06N) in a

flask. After an hour it was filtered and
the strength of the filtrate was found to be
0.042 N.
41.
42.
The amount of acetic acid
The ionic radii (in ) of N32, O22 and F2
41.
N32, O22 F2
( )
are respectively :
(1)
1.36, 1.40 and 1.71
(1)
1.36, 1.40
1.71
(2)
1.36, 1.71 and 1.40
(2)
1.36, 1.71
1.40
(3)
1.71, 1.40 and 1.36
(3)
1.71, 1.40
1.36
(4)
1.71, 1.36 and 1.40
(4)
1.71, 1.36
1.40
In the context of the Hall - Heroult process
42.
for the extraction of Al, which of the
-UU c
?
following statements is false ?

(1)
CO and CO2 are produced in this

process
(1)
(2)
Al 2 O 3 is mixed with CaF 2 which

lowers the melting point of the
(2)
CaF2 Al2O3
U
U
(3)
U U Al31 U Al
(4)
Na3AlF6
mixture and brings conductivity

(3)
Al31 is reduced at the cathode to

form Al
(4)
A/Page 22
Na3AlF6 serves as the electrolyte

CO CO2
l U U
43.
H2O2, choose the incorrect statement :
(1)
It can act only as an oxidizing agent
(1)
(2)
It decomposes on exposure to light
(2)
(3)
It has to be stored in plastic or wax
(3)
SU U U

(4)
U U
From the following statements regarding
43.
H2O2
lined glass bottles in dark

(4)
44.
It has to be kept away from dust
greater than its lattice enthalpy ?
U U

?
(1)
CaSO 4
(1)
CaSO 4
(2)
BeSO4
(2)
BeSO4
(3)
BaSO4
(3)
BaSO4
(4)
SrSO 4
(4)
SrSO 4
Which one of the following alkaline earth
44.
metal sulphates has its hydration enthalpy
45.
Which among the following is the most
45.
reactive ?
(1)
Cl2
(1)
Cl2
(2)
Br2
(2)
Br2
(3)
I2
(3)
I2
(4)
ICl
(4)
ICl
A/Page 23
46.
Match the catalysts to the correct
46.
processes :
Catalyst
47.
48.
49.
Process
U
U
U
(A) TiCl3
(i)
U
(B) PdCl2
(ii) -^
UU
(C) CuCl2
(iii) S
(D) V 2O 5
(iv) U
(A)
TiCl3
(i)
Wacker process
(B)
PdCl2
(ii)
Ziegler - Natta
(C)
CuCl2
(iii)
Contact process
(D)
V 2O 5
(iv)
Deacons process
(1)
(A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)
(1)
(A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)
(2)
(A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)
(2)
(A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)
(3)
(A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)
(3)
(A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)
(4)
(A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)
(4)
(A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)
polymerization
Which one has the highest boiling point ?
47.
(1)
He
(1)
He
(2)
Ne
(2)
Ne
(3)
Kr
(3)
Kr
(4)
Xe
(4)
Xe
exist for square planar [Pt (Cl) (py) (NH3)

(NH2OH)]1 is (py 5 pyridine) :
[Pt (Cl) (py) (NH3) (NH2OH)]1

(py 5 pyridine)

(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
The number of geometric isomers that can
The color of KMnO4 is due to :

(1) M L charge transfer transition
48.
49.
KMnO4
(1)
(2)
d 2 d transition
(2)
(3)
L M charge transfer transition
(3)
(4)
s 2 s* transition
(4)
A/Page 24
U U
M L SU
d 2 d
L M SU
s 2 s*
50.
Assertion : Nitrogen and Oxygen are the
50.
main components in the

atmosphere but these do not
U U U
U U U
U U
react to form oxides of nitrogen.

Reason :
The reaction between nitrogen

and oxygen requires high
temperature.
(1)
Both assertion and reason are
(1)
correct, and the reason is the correct
U U

U U
ScUU
explanation for the assertion

(2)
Both assertion and reason are
(2)
U U
ScUU
(3)
(4)
correct, but the reason is not the

correct explanation for the assertion
(3)
The assertion is incorrect, but the

reason is correct
(4)
Both the assertion and reason are

incorrect
51.
In Carius method of estimation of
51.
halogens, 250 mg of an organic compound

gave 141 mg of AgBr. The percentage of
bromine in the compound is :
U 250 mg
141 mg AgBr
:
(U Ag5108; Br580)
(at. mass Ag5108; Br580)
52.
(1)
24
(1)
24
(2)
36
(2)
36
(3)
48
(3)
48
(4)
60
(4)
60
Which of the following compounds will
52.
exhibit geometrical isomerism ?

(1)
1 - Phenyl - 2 - butene
(2)
(3)
(4)
1, 1 - Diphenyl - 1 - propane
A/Page 25

?
(1) 1 - - 2 - U
(2) 3 - - 1 - U
(3) 2 - - 1 - U
(4) 1, 1 - U - 1 -
U
53.
Which
compound
would
give
53.
5 - keto - 2 - methyl hexanal upon
$ U U
5 - U - 2 - ?
ozonolysis ?
54.
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
accomplished by :
UU
U
(1)
Free radical fluorination
(1)
(2)
Sandmeyers reaction
(2)
UU
(3)
Finkelstein reaction
(3)
SU
(4)
Swarts reaction
(4)
SU
The synthesis of alkyl fluorides is best
A/Page 26
54.
55.
In the following sequence of reactions :

KMnO
SOCl
55.
H /Pd
BaSO 4

KMnO
4
2
2
Toluene
A
B
C,
SOCl
H /Pd
BaSO 4
4
2
2
Toluene
A
B
C
the product C is :
56.
(1)
C6H5COOH
(1)
C6H5COOH
(2)
C6H5CH3
(2)
C6H5CH3
(3)
C6H5CH2OH
(3)
C6H5CH2OH
(4)
C6H5CHO
(4)
C6H5CHO
In the reaction
56.
NaNO /HCl
0258 C
CuCN/KCN
D
NaNO /HCl
0258 C
D E 1 N 2
the product E is :
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
A/Page 27
CuCN/KCN
D
D
E 1 N2
57.
58.
59.
of paints and lacquers ?
U
?
(1)
Bakelite
(1)
(2)
Glyptal
(2)
(3)
Polypropene
(3)
(4)
Poly vinyl chloride
(4)
UU
Which polymer is used in the manufacture
57.
soluble ?
(1)
Vitamin C
(1)
U C
(2)
Vitamin D
(2)
U D
(3)
Vitamin E
(3)
U E
(4)
Vitamin K
(4)
U K
Which of the vitamins given below is water
Which of the following compounds is not
58.
59.
an antacid ?
60.
(1)
Aluminium hydroxide
(1)
UU
(2)
Cimetidine
(2)
UU
(3)
Phenelzine
(3)
(4)
Ranitidine
(4)
UUU
Which of the following compounds is not
60.
colored yellow ?
U
?
(1)
Zn2[Fe(CN)6]
(1)
Zn2[Fe(CN)6]
(2)
K3[Co(NO2)6]
(2)
K3[Co(NO2)6]
(3)
(NH4)3 [As (Mo3 O10)4]
(3)
(NH4)3 [As (Mo3 O10)4]
(4)
BaCrO4
(4)
BaCrO4
A/Page 28
PART C MATHEMATICS
61.
having at least three elements is :
A B U
, A3B
,
,
(1)
219
(1)
219
(2)
256
(2)
256
(3)
275
(3)
275
(4)
510
(4)
510
Let A and B be two sets containing four
61.
and two elements respectively. Then the

number of subsets of the set A3B, each
62.
A complex number z is said to be
62.
unimodular if ?z?51. Suppose z1 and z2

z1 2 2 z2
are complex numbers such that
2 2 z1 z2
63.
z
?z?51 z1 z2
z1 2 2 z2
2 2 z1 z2
z2
is unimodular and z2 is not unimodular.

Then the point z1 lies on a :
, z1 S
(1)
straight line parallel to x-axis.
(1)
x-
U U U
(2)
straight line parallel to y-axis.
(2)
y-
U U U
(3)
circle of radius 2.
(3)
(4)
circle of radius
2.
Let a and b be the roots of equation
(4)
63.
x 2 26x2250. If a n 5a n 2b n , for n/1,

a 2 2a8
then the value of 10
is equal to :
2a9
a10 2 2a8
2a9
(1)
(2)
26
(2)
26
(3)
(3)
(4)
23
(4)
23
a b m U x226x2250
n/1 , an5an2bn ,
(1)
A/Page 29
64.
1 2 2
If A 5 2 1 22 is a matrix satisfying
a 2 b
64.
(a, b) is equal to :
(1)
(2, 21)
(1)
(2, 21)
(2)
(22, 1)
(2)
(22, 1)
(3)
(2, 1)
(3)
(2, 1)
(4)
(22, 21)
(4)
(22, 21)
identity matrix, then the ordered pair
66.
U AAT59I, cU U ,
I, 333 ,
(a, b)
the equation AA T 59I, where I is 333
65.
1 2 2
A 5 2 1 22
a 2 b
system of linear equations :
, U
U
2x 122x21x 35lx 1
2x 122x21x 35lx 1
2x 123x 212x 35lx 2
2x 123x 212x 35lx 2
2x112x2
2x112x2
The set of all values of l for which the
65.
5lx3
5lx3
has a non-trivial solution,
U ,
(1)
is an empty set.
(1)
(2)
is a singleton.
(2)
(3)
contains two elements.
(3)
(4)
contains more than two elements.
(4)
The number of integers greater than 6,000
66.
that can be formed, using the digits 3, 5, 6,
3, 5, 6, 7 8 , U,
6,000 Z
7 and 8, without repetition, is :

(1)
216
(1)
216
(2)
192
(2)
192
(3)
120
(3)
120
(4)
72
(4)
72
A/Page 30
67.
The sum of coefficients of integral powers
67.
68.
69.
50
50
m U
of x in the binomial expansion of
(1 2 2 x )
(1 2 2 x )
is :
(1)
1 50
3 11
2
(2)
1 50
3
2
(3)
1 50
3 21
2
(4)
1 50
2 11
2
( )
(
)
)
(1)
1 50
3 11
2
(2)
1 50
3
2
(3)
1 50
3 21
2
(4)
1 50
2 11
2
( )
(
)
)
numbers l and n (l, n > 1) and G1, G2 and
G3 are three geometric means between l
S l n
(l, n > 1) U (A.M.) m U l
n U (G.M.) G1, G2
and n, then G14 1 2G24 1 G 34 equals.
G3 ,
If m is the A.M. of two distinct real
68.
(1)
4 l2mn
(1)
4 l2mn
(2)
4 lm2n
(2)
4 lm2n
(3)
4 lmn2
(3)
4 lmn2
(4)
4 l2m2n2
(4)
4 l2m2n2
The sum of first 9 terms of the series
69.
13 1 2 3
13 1 2 3 1 3 3
13
1
1
1 .... is :
1
113
11 31 5
13 1 2 3
13 1 2 3 1 3 3
13
1
1
1 ....
1
113
11 31 5
(1)
71
(1)
71
(2)
96
(2)
96
(3)
142
(3)
142
(4)
192
(4)
192
UU
A/Page 31
G1 1 2G2 1 G 3
70.
lim
x0
72.
x tan 4 x
is equal to :
70.
lim
x0
( 1 2 cos 2 x )( 3 1 cos x ) UU
x tan 4 x
(1)
(1)
(2)
(2)
(3)
2
1
2
(3)
2
1
2
(4)
71.
( 1 2 cos 2 x )( 3 1 cos x )
(4)
If the function.
71.
k x 1 1 , 0 [ x [ 3
g( x ) 5
m x 1 2 , 3 < x [ 5
k x 1 1 , 0 [ x [ 3
g( x ) 5
m x 1 2 , 3 < x [ 5
is differentiable, then the value of k1m is :
, k1m
(1)
(1)
(2)
16
5
(2)
16
5
(3)
10
3
(3)
10
3
(4)
(4)
at (1, 1) :
x 2 12xy23y 250

(1)
does not meet the curve again.
(1)
(2)
meets the curve again in the second
(2)
U m Z
(3)
U Z
(4)
U Z
The normal to the curve, x212xy23y250,
72.
(1, 1)
quadrant.
(3)
meets the curve again in the third

quadrant.
(4)
meets the curve again in the fourth

quadrant.
A/Page 32
73.
Let f (x) be a polynomial of degree four
73.
f (x)

U U
having extreme values at x51 and x52.
x51
f ( x )
If lim 1 1
5 3 , then f (2) is equal
x 0
x2
f ( x )
lim 1 1
53
x 0
x2
x52
, f (2) UU
to :
74.
(1)
28
(1)
28
(2)
24
(2)
24
(3)
(3)
(4)
(4)
The integral
dx
x 2 ( x 4 1 1)3 4
equals :
74.
(1)
x4 1 1 4
1c
x4
(2)
( x 411) 4 1 c
(3)
2( x 4 1 1) 4 1 c
(4)
x 41 1 4
2
1c
x4
2 log
(1)
(2)
( x 411) 4 1 c
UU
(3)
2( x 4 1 1) 4 1 c
(4)
x 41 1 4
2
1c
x4
75.
log x 2
dx
x 2 1 log (36 2 12 x 1 x 2 )
2 log
log x 2
dx
x 2 1 log (36 2 12 x 1 x 2 )
is equal to :
UU
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
A/Page 33
The integral
x 2 ( x 4 1 1)
x4 1 1 4
1c
x4
75.
dx
76.
The area (in sq. units) of the region
76.
described by
{(x, y) : y2[ 2x y / 4x 2 1} mU
( )
{(x, y) : y2 [ 2x and y / 4x 2 1} is :
77.
(1)
7
32
(1)
7
32
(2)
5
64
(2)
5
64
(3)
15
64
(3)
15
64
(4)
9
32
(4)
9
32
Let y(x) be the solution of the differential
77.
equation
dy
1 y 5 2 x log x , ( x / 1).
dx
Then y(e) is equal to :
(1)
(1)
(2)
(2)
(3)
(3)
(4)
2e
(4)
2e
( x log x )
78.
The number of points, having both
dy
1 y 5 2 x log x , ( x / 1)
dx
y(x) , y(e) UU
( x log x )
78.
co-ordinates as integers, that lie in the

interior of the triangle with vertices (0, 0),
, (0, 0), (0, 41) (41, 0) ,

U S
Z ,
(0, 41) and (41, 0), is :

(1)
901
(1)
901
(2)
861
(2)
861
(3)
820
(3)
820
(4)
780
(4)
780
A/Page 34
79.
Locus of the image of the point (2, 3) in
79.
the line (2x23y14)1k (x22y13)50,
80.
straight line parallel to x-axis.
(2)
straight line parallel to y-axis.
(3)
circle of radius
2.
(4)
circle of radius
3.
The number of common tangents to the

circles
x 2 1y 2 24x26y21250
x21y216x118y12650,
81.
(2, 3)

(1) x- U U
(2) y- U U
2
(3)
3
(4)
80.
is :
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
81.
cU S
x21y224x26y21250
x21y216x118y12650
and
The area (in sq. units) of the quadrilateral
(2x23y14)1k (x22y13)50, k e R
k e R, is a :
(1)
y2
x2
1
51
9
5
U U
S U mU
( )
formed by the tangents at the end points

of the latera recta to the ellipse
y2
x2
1
5 1 , is :
9
5
82.
(1)
27
4
(1)
27
4
(2)
18
(2)
18
(3)
27
2
(3)
27
2
(4)
27
(4)
27
Let O be the vertex and Q be any point on
82.
the parabola, x258y. If the point P divides

the line segment OQ internally in the ratio
1 : 3, then the locus of P is :
U x258y O U
Q P, U U OQ
1 : 3 U U , P

(1)
x 2 5y
(1)
x 2 5y
(2)
y 2 5x
(2)
y 2 5x
(3)
y 2 52x
(3)
y 2 52x
(4)
x 2 52y
(4)
x 2 52y
A/Page 35
83.
The distance of the point (1, 0, 2) from the

point
84.
of
intersection
of
the
83.
line
y 11
x 22
z 22
5
5
and the plane
3
4
12
x2y1z516, is :
(1)
2 14
(1)
(2)
2 14
(2)
(3)
3 21
(3)
(4)
13
3 21
(4)
13
The equation of the plane containing the

line 2x25y1z53; x1y14z55, and
84.
parallel to the plane, x13y16z51, is :
85.
y 11
x 22
z 22
5
5
3
4
12
x2y1z516 U ,
(1)
2x16y112z513
(2)
x13y16z527
(3)
x13y16z57
(4)
2x16y112z5213

Let a , b and c be three non-zero vectors

such that no two of them are collinear and
( a 3 b )3 c 5
85.
1
b c a . If u is the
3
angle between vectors b and c , then a

value of sin u is :
(1)
2x16y112z513
(2)
x13y16z527
(3)
x13y16z57
(4)
2x16y112z5213

a , b c U
U
( a 3 b )3 c 5
1
b c a
3
u , sin u
2 2
3
(1)
2 2
3
(2)
2 2
3
(2)
2 2
3
(3)
2
3
(3)
2
3
(4)
22 3
3
(4)
22 3
3
(1, 0, 2)
U 2x25y1z53, x1y14z55 cU
U , x13y16z51
U , U
(1)
A/Page 36
86.
If 12 identical balls are to be placed in 3
86.
identical boxes, then the probability that

one of the boxes contains exactly 3 balls
12 , 3 U
, U 3

is :
87.
(1)
55 2 11

3 3
(2)
2
55
3
(3)
1
220
3
(4)
1
22
3
(1)
55 2 11

3 3
(2)
2
55
3
(3)
1
220
3
(4)
1
22
3
10
12
11
The mean of the data set comprising of 16
87.
observations is 16. If one of the observation

valued 16 is deleted and three new
observations valued 3, 4 and 5 are added
10
12
11
16
16 , U U, 3
3, 4 5 ,
,
16
to the data, then the mean of the resultant

data, is :
88.
(1)
16.8
(1)
16.8
(2)
16.0
(2)
16.0
(3)
15.8
(3)
15.8
(4)
14.0
(4)
14.0
If the angles of elevation of the top of a
88.
tower from three collinear points A, B and

C, on a line leading to the foot of the
tower, are 308, 458 and 608 respectively,
U A, B C, U U
S U ,
U U
308, 458 608 , AB : BC
then the ratio, AB : BC, is :

(1)
3:1
(1)
3:1
(2)
3: 2
(2)
3: 2
(3)
1: 3
(3)
1: 3
(4)
2:3
(4)
2:3
A/Page 37
89.
89.
Let
2x
tan21 y 5 tan21 x 1 tan21
1 2 x2
where ? x ? <
(1)
(2)
(3)
(4)
90.
2x
tan21 y 5 tan21 x 1 tan21
1 2 x2
1
. Then a value of y is :
3
3 x 2 x3
(1)
1 2 3 x2
3 x 1 x3
(2)
1 2 3 x2
3 x 2 x3
(3)
1 1 3 x2
3 x 1 x3
(4)
1 1 3 x2
The negation of ~ s (~ r s ) is equivalent
90.
?x? <
1
3
, y
3 x 2 x3
1 2 3 x2
3 x 1 x3
1 2 3 x2
3 x 2 x3
1 1 3 x2
3 x 1 x3
1 1 3 x2
~ s (~ r s )
to :
(1)
s~r
(1)
s~r
(2)
s (r ~ s)
(2)
s (r ~ s)
(3)
s (r ~ s)
(3)
s (r ~ s)
(4)
sr
(4)
sr
-o0o-
A/Page 38
-o0o-
A/Page 39
Read the following instructions carefully :

U U S U U (D -1) U U
U / U U
U D-2 U U / U
/ U U
3. U S/U U U S U
R
4. U

5. U U
- () U
U U ,
U
6. U S U U
US ( U S U
S UU), U U S
U
7. U U U U
, U S
U U mU
, U D U U U
S D U (D 39)
8. U, U / U U
U U
U S
9. U U U
10. U U
S U
11. U U U S
U U SU U U U
U U U S U SU
U U
U
U S S U

12. U/S U , U
U U
13. U U U .../U
U mU
.../U
U
14. S U S U

15. U mU U / U
U U , S,
, U, U
U U U
U
1. The candidates should fill in the required particulars 1.

on the Test Booklet and Answer Sheet (Side1) with
Blue/Black Ball Point Pen.
2. For writing/marking particulars on Side2 of the 2.
Answer Sheet, use Blue/Black Ball Point Pen only.
3. The candidates should not write their Roll Numbers

anywhere else (except in the specified space) on the
Test Booklet/Answer Sheet.
4. Out of the four options given for each question, only
one option is the correct answer.
5. For each incorrect response, onefourth () of the total
marks allotted to the question would be deducted from
the total score. No deduction from the total score,
however, will be made if no response is indicated for
an item in the Answer Sheet.
6. Handle the Test Booklet and Answer Sheet with care,
as under no circumstances (except for discrepancy in

Test Booklet Code and Answer Sheet Code), another set
will be provided.
7. The candidates are not allowed to do any rough work

or writing work on the Answer Sheet. All calculations/
writing work are to be done in the space provided for
this purpose in the Test Booklet itself, marked Space
for Rough Work. This space is given at the bottom of
each page and in one page (i.e. Page 39) at the end of
the booklet.
8. On completion of the test, the candidates must hand
over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to
take away this Test Booklet with them.
9. Each candidate must show on demand his/her Admit
Card to the Invigilator.
10. No candidate, without special permission of the
Superintendent or Invigilator, should leave his/her
seat.
11. The candidates should not leave the Examination Hall
without handing over their Answer Sheet to the
Invigilator on duty and sign the Attendance Sheet
again. Cases where a candidate has not signed the
Attendance Sheet second time will be deemed not to
have handed over the Answer Sheet and dealt with as
an unfair means case. The candidates are also required
to put their left hand THUMB impression in the space
provided in the Attendance Sheet.
12. Use of Electronic/Manual Calculator and any
Electronic device like mobile phone, pager etc. is
prohibited.
13. The candidates are governed by all Rules and
Regulations of the JAB/Board with regard to their
conduct in the Examination Hall. All cases of unfair
means will be dealt with as per Rules and Regulations
of the JAB/Board.
14. No part of the Test Booklet and Answer Sheet shall be
detached under any circumstances.
15. Candidates are not allowed to carry any textual
material, printed or written, bits of papers, pager,
mobile phone, electronic device or any other material
except the Admit Card inside the examination
room/hall.
A/Page 40

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This booklet contains 40 printed pages.

: PHYSICS, CHEMISTRY & MATHEMATICS

1. Immediately fill in the particulars on this page of the Test

Examination Centre Number :

Name of Examination Centre (in Capital letters) :

Test Booklet Code

Name of the Candidate (in Capital letters ) :

Two stones are thrown up simultaneously

from the edge of a cliff 240 m high with

respect to the first ?

(The figures are schematic and not drawn to

SPACE FOR ROUGH WORK /

The period of oscillation of a simple

of L is 20.0 cm known to 1 mm accuracy

Given in the figure are two blocks A and B

frictional force applied by the wall on block

SPACE FOR ROUGH WORK /

A particle of mass m moving in the

x direction with speed 2v is hit by another

the energy during the collision is close to :

Distance of the centre of mass of a solid

uniform cone from its vertex is z0. If the

radius of its base is R and its height is h

SPACE FOR ROUGH WORK /

From a solid sphere of mass M and radius

R a cube of maximum possible volume is

From a solid sphere of mass M and radius

gravitational potential V50 at r5:, the

SPACE FOR ROUGH WORK /

A pendulum made of a uniform wire of

cross sectional area A has time period T.

temperature T. The black body radiation

Consider a spherical shell of radius R at

SPACE FOR ROUGH WORK /

an adiabatic expansion the relation

A solid body of constant heat capacity

1 J/8C is being heated by keeping it in

Sequentially keeping in contact with

Sequentially keeping in contact with

In both the cases body is brought from

body in the two cases respectively is :

Consider an ideal gas confined in an

isolated closed chamber. As the gas

molecules increases as V , where V is the

SPACE FOR ROUGH WORK /

(graphs are schematic and not drawn to scale)

For a simple pendulum, a graph is plotted

between its kinetic energy (KE) and

displacement d. Which one of the

A train is moving on a straight track with

speed 20 ms21. It is blowing its whistle at

SPACE FOR ROUGH WORK /

A long cylindrical shell carries positive

surface charge s in the upper half and

A uniformly charged solid sphere of radius

to :) on its surface. For this sphere the

equipotential surfaces with potentials

3V0 5V0 3V0

R150 and R2 > (R42R3)

R150 and R2 < (R42R3)

SPACE FOR ROUGH WORK /

and are not to scale)

In the given circuit, charge Q2 on the 2mF

to 3mF. Q2 as a function of C is given